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1. 发明申请

US20060160950A1 Pigment compositions with modified ATRP copolymer dispersants 有权
标题翻译：具有改性ATRP共聚物分散剂的颜料组合物
公开(公告)号：US20060160950A1
公开(公告)日：2006-07-20
申请号：US11387020
申请日：2006-03-21
申请人： Clemens Auschra , Ernst Eckstein , Marie-Odile Zink , Andreas Muhlebach
发明人： Clemens Auschra , Ernst Eckstein , Marie-Odile Zink , Andreas Muhlebach
IPC分类号： C08L53/00 , C08K5/07 , C08K5/16
CPC分类号： C08F293/005 , C08F293/00 , C08F2438/01 , C08K5/0041 , C08L53/00 , C09D11/03 , C09D153/00
摘要： The present invention relates to a composition containing modified block copolymer dispersants and dispersible inorganic or organic pigments. The block copolymers are prepared by atom transfer radical polymerisation (ATRP) and modified with a salt forming group. The pigment composition is useful for preparing coating compositions, prints, images, inks or lacquers and other disperse systems.
摘要翻译：本发明涉及含有改性嵌段共聚物分散剂和可分散无机或有机颜料的组合物。嵌段共聚物通过原子转移自由基聚合（ATRP）制备并用成盐基团改性。颜料组合物可用于制备涂料组合物，印刷品，图像，油墨或漆和其它分散体系。

2. 发明申请

US20050004317A1 Pigment compositions with modified atrp copolymer dispersants 审中-公开
标题翻译：具有改性的atrp共聚物分散剂的颜料组合物
公开(公告)号：US20050004317A1
公开(公告)日：2005-01-06
申请号：US10495519
申请日：2002-11-21
申请人： Clemens Auschra , Ernst Eckstein , Marie-Odile Zink , Andreas Muhlebach
发明人： Clemens Auschra , Ernst Eckstein , Marie-Odile Zink , Andreas Muhlebach
IPC分类号： C08F2/38 , C08F4/40 , C08F293/00 , C08K3/00 , C08K5/00 , C08L53/00 , C09D7/12 , C09D11/02 , C09D17/00 , C09D153/00 , C09J11/00
CPC分类号： C08F293/005 , C08F293/00 , C08F2438/01 , C08K5/0041 , C08L53/00 , C09D11/03 , C09D153/00
摘要： The present invention relates to a composition containing modified block copolymer dispersants and dispersible inorganic or organic pigment. The block copolymers are prepared by atom transfer radical polymerization (ATRP) and modified with a salt forming group. The pigment composition is useful for preparing coating compositions, prints, images, inks or lacquers and other disperse systems.
摘要翻译：本发明涉及含有改性嵌段共聚物分散剂和可分散无机或有机颜料的组合物。嵌段共聚物通过原子转移自由基聚合（ATRP）制备并用成盐基团改性。颜料组合物可用于制备涂料组合物，印刷品，图像，油墨或漆和其它分散体系。

3. 发明授权

US06849679B2 Pigment compositions with modified block copolymer dispersants 有权
标题翻译：具有改性嵌段共聚物分散剂的颜料组合物
公开(公告)号：US06849679B2
公开(公告)日：2005-02-01
申请号：US10128836
申请日：2002-04-23
申请人： Clemens Auschra , Ernst Eckstein , Marie-Odile Zink , Andreas Mühlebach
发明人： Clemens Auschra , Ernst Eckstein , Marie-Odile Zink , Andreas Mühlebach
IPC分类号： C09D133/08 , C08F293/00 , C08F297/00 , C08K3/00 , C08K5/00 , C08L53/00 , C09B67/20 , C09B67/46 , C09D7/02 , C09D7/12 , C09D11/00 , C09D11/02 , C09D11/10 , C09D17/00 , C09D153/00 , C09D201/00
CPC分类号： C09D153/00 , C08F293/005 , C08F2438/02 , C08K3/013 , C08K5/0041 , C08L53/00 , C08L53/005 , C09B67/0063 , C09D7/45 , C09D11/037 , C09D11/101 , C09D11/326 , C09D17/00 , C09D153/005 , C08L2666/02
摘要： The present invention relates to a composition containing modified block copolymer dispersants and dispersible inorganic or organic pigments. The block copolymers are modified with a salt forming group. The pigment composition is useful for preparing coating compositions, prints, images, inks or lacquers and other disperse systems.
摘要翻译：本发明涉及含有改性嵌段共聚物分散剂和可分散无机或有机颜料的组合物。嵌段共聚物用成盐基团改性。颜料组合物可用于制备涂料组合物，印刷品，图像，油墨或漆和其它分散体系。

4. 发明授权

US07723425B2 Pigment compositions with modified ATRP copolymer dispersants 有权
标题翻译：具有改性ATRP共聚物分散剂的颜料组合物
公开(公告)号：US07723425B2
公开(公告)日：2010-05-25
申请号：US11387020
申请日：2006-03-21
申请人： Clemens Auschra , Ernst Eckstein , Marie-Odile Zink , Andreas Mühlebach
发明人： Clemens Auschra , Ernst Eckstein , Marie-Odile Zink , Andreas Mühlebach
IPC分类号： C08L53/00
CPC分类号： C08F293/005 , C08F293/00 , C08F2438/01 , C08K5/0041 , C08L53/00 , C09D11/03 , C09D153/00
摘要： The present invention relates to a composition containing modified block copolymer dispersants and dispersible inorganic or organic pigments. The block copolymers are prepared by atom transfer radical polymerisation (ATRP) and modified with a salt forming group. The pigment composition is useful for preparing coating compositions, prints, images, inks or lacquers and other disperse systems.
摘要翻译：本发明涉及含有改性嵌段共聚物分散剂和可分散无机或有机颜料的组合物。嵌段共聚物通过原子转移自由基聚合（ATRP）制备并用成盐基团改性。颜料组合物可用于制备涂料组合物，印刷品，图像，油墨或漆和其它分散体系。

5. 发明授权

US07579411B2 Process for the controlled increase in the molecular weight of polyethylenes 有权
标题翻译：控制聚乙烯分子量增加的方法
公开(公告)号：US07579411B2
公开(公告)日：2009-08-25
申请号：US12069641
申请日：2008-02-12
申请人： Michael Roth , Rudolf Pfaendner , Peter Nesvadba , Marie-Odile Zink
发明人： Michael Roth , Rudolf Pfaendner , Peter Nesvadba , Marie-Odile Zink
IPC分类号： C08C19/22 , C08F8/32
CPC分类号： C07D491/10 , C07C239/22 , C07D209/44 , C07D211/94 , C07D233/32 , C07D233/38 , C07D241/08 , C07D295/24 , C07D401/14 , C07D487/10 , C07F9/59 , C08F2/38 , C08F4/00 , C08F8/30 , C08F8/50 , C08F110/02 , C08F110/06 , C08K5/3435 , C08L23/06 , C08L23/10 , C08L2023/44 , C08L2205/02 , C08L2666/06 , C08F8/00
摘要： The invention relates to hydroxylamine esters and polymerizable compositions comprising these hydroxylamine esters and an ethylenically unsaturated monomer or oligomer and methods for achieving a controlled increase in the molecular weight of polyethylene.
摘要翻译：本发明涉及羟胺酯和包含这些羟胺酯和烯属不饱和单体或低聚物的可聚合组合物以及用于实现聚乙烯分子量控制增加的方法。

6. 发明授权

US07572869B2 N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, their corresponding n-oxides and controlled radical polymerization therewith 失效
标题翻译： N-烷氧基-4,4-二氧基 - 多烷基 - 哌啶化合物，它们相应的N-氧化物和受控的自由基聚合
公开(公告)号：US07572869B2
公开(公告)日：2009-08-11
申请号：US11903093
申请日：2007-09-20
申请人： Peter Nesvadba , Marie-Odile Zink , Wiebke Wunderlich
发明人： Peter Nesvadba , Marie-Odile Zink , Wiebke Wunderlich
IPC分类号： C08F2/38 , C07D211/94 , C08F12/08
CPC分类号： C07D211/94 , C07D491/113 , C07D491/22 , C07D519/00 , C08F2/46 , C08F4/00
摘要： The present invention relates to selected 1-alkoxy-2,2,6,6 tetramethyl piperidine, 1-alkoxy-2,2 diethyl-6,6 dimethyl piperidine and 1-alkoxy-2,6 diethyl-2,3,6 dimethyl piperidine derivatives which are substituted in the 4 position by two oxygen atoms forming an open chain or cyclic ketal structure, a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b) said piperidine derivatives. Further aspects of the present invention are a process for polymerizing ethylenically unsaturated monomers, and the use of 1-alkoxy-2,2,6,6 tetramethyl piperidine, 1-alkoxy-2,2 diethyl-6,6 dimethyl piperidine and 1-alkoxy-2,6 diethyl-2,3,6 dimethyl piperidine derivatives which are substituted in the 4 position by two oxygen atoms forming an open chain or cyclic ketal structure for controlled polymerization. The intermediate N-oxyl derivatives, a composition of the N-oxyl derivatives with ethylenically unsaturated monomers and a free radical initiator, as well as a process for polymerization are also subjects of the present invention.
摘要翻译：本发明涉及选择的1-烷氧基-2,2,6,6四甲基哌啶，1-烷氧基-2,2二乙基-6,6二甲基哌啶和1-烷氧基-2,6-二乙基-2,3,6-二甲基哌啶衍生物，其在4位被两个形成开链或环状缩酮结构的氧原子取代，所述可聚合组合物包含a）至少一种烯属不饱和单体和b）所述哌啶衍生物。本发明的另外的方面是使烯属不饱和单体聚合的方法，以及使用1-烷氧基-2,2,6,6四甲基哌啶，1-烷氧基-2,2二乙基-6,6二甲基哌啶和1- 烷氧基-2,6-二乙基-2,3,6二甲基哌啶衍生物，其在4位被两个氧原子取代，形成用于受控聚合的开链或环状缩酮结构。中间体N-氧基衍生物，具有烯键式不饱和单体的N-氧基衍生物和自由基引发剂的组合物以及聚合方法也是本发明的主题。

7. 发明授权

US06518326B1 Open chain alkoxyamine compounds and their use as polymerization regulators 有权
标题翻译：开链烷氧基胺化合物及其作为聚合调节剂的用途
公开(公告)号：US06518326B1
公开(公告)日：2003-02-11
申请号：US09744731
申请日：2001-01-29
申请人： Peter Nesvadba , Andreas Kramer , Marie-Odile Zink , Dario Lazzari
发明人： Peter Nesvadba , Andreas Kramer , Marie-Odile Zink , Dario Lazzari
IPC分类号： C07C23918
CPC分类号： C08L53/00 , C07C219/06 , C07C219/14 , C07C237/06 , C07C237/24 , C07C239/12 , C07C239/18 , C07C239/20 , C07C255/16 , C07C255/46 , C07C291/04 , C07C2601/08 , C07C2601/14 , C07D309/12 , C08F291/00 , C08F293/005 , C08L51/003 , C09J151/00 , C09J153/00
摘要： The invention relates to open chain alkoxyamine compounds useful as polymerization regulators. The open chain alkoxyamine compounds are useful for the polymerization of ethylenically unsaturated monomers. The compounds of the present invention provide polymeric resin products having low polydispersity. The polymerization process proceeds with enhanced monomer to polymer conversion efficiency. In particular, this invention relates to stable free radical-mediated polymerization processes which provide homopolymers, random copolymer, block copolymers, multiblock copolymers, graft copolymers and the like, at enhanced rates of polymerization and enhanced monomer to polymer conversions.
摘要翻译：本发明涉及用作聚合调节剂的开链烷氧基胺化合物。开链烷氧基胺化合物可用于烯属不饱和单体的聚合。本发明的化合物提供了具有低多分散性的聚合物树脂产品。聚合过程由单体转化为聚合物转化效率提高。特别地，本发明涉及稳定的自由基介导的聚合方法，其提供均聚物，无规共聚物，嵌段共聚物，多嵌段共聚物，接枝共聚物等，以提高聚合速率和提高单体与聚合物的转化率。

8. 发明授权

US07358365B2 Process for the controlled increase in the molecular weight of polyethylenes 有权
标题翻译：控制聚乙烯分子量增加的方法
公开(公告)号：US07358365B2
公开(公告)日：2008-04-15
申请号：US11339214
申请日：2006-01-25
申请人： Michael Roth , Rudolf Pfaendner , Peter Nesvadba , Marie-Odile Zink
发明人： Michael Roth , Rudolf Pfaendner , Peter Nesvadba , Marie-Odile Zink
IPC分类号： C07D471/02
CPC分类号： C07D491/10 , C07C239/22 , C07D209/44 , C07D211/94 , C07D233/32 , C07D233/38 , C07D241/08 , C07D295/24 , C07D401/14 , C07D487/10 , C07F9/59 , C08F2/38 , C08F4/00 , C08F8/30 , C08F8/50 , C08F110/02 , C08F110/06 , C08K5/3435 , C08L23/06 , C08L23/10 , C08L2023/44 , C08L2205/02 , C08L2666/06 , C08F8/00
摘要： The invention relates to novel cyclic hydroxylamine esters and to the use of known hydroxylamine esters selected from the group consisting of HALS (sterically hindered amine) compounds and the novel hydroxylamine esters achieving a controlled increase in the molecular weight of polyethylene.
摘要翻译：本发明涉及新的环状羟胺酯，以及选自HALS（空间位阻胺）化合物和新型羟胺酯的已知羟胺酯的用途，可实现聚乙烯分子量的可控增加。

9. 发明授权

US07288613B2 N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, their corresponding N-oxides and controlled radical polymerization therewith 失效
标题翻译： N-烷氧基-4,4-二氧基 - 多烷基 - 哌啶化合物，它们相应的N-氧化物和受控自由基聚合
公开(公告)号：US07288613B2
公开(公告)日：2007-10-30
申请号：US11364537
申请日：2006-02-28
申请人： Peter Nesvadba , Marie-Odile Zink , Wiebke Wunderlich
发明人： Peter Nesvadba , Marie-Odile Zink , Wiebke Wunderlich
IPC分类号： C08F2/38 , C08F4/00
CPC分类号： C07D211/94 , C07D491/113 , C07D491/22 , C07D519/00 , C08F2/46 , C08F4/00
摘要： The present invention relates to selected 1-alkoxy-2,2,6,6 tetramethyl piperidine, 1-alkoxy-2,2 diethyl-6,6 dimethyl piperidine and 1-alkoxy-2,6 diethyl-2,3,6 dimethyl piperidine derivatives which are substituted in the 4 position by two oxygen atoms forming an open chain or cyclic ketal structure, a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b) said piperidine derivatives. Further aspects of the present invention are a process for polymerizing ethylenically unsaturated monomers, and the use of 1-alkoxy-2,2,6,6 tetramethyl piperidine, 1-alkoxy-2,2 diethyl-6,6 dimethyl piperidine and 1-alkoxy-2,6 diethyl-2,3,6 dimethyl piperidine derivatives which are substituted in the 4 position by two oxygen atoms forming an open chain or cyclic ketal structure for controlled polymerization. The intermediate N-oxyl derivatives, a composition of the N-oxyl derivatives with ethylenically unsaturated monomers and a free radical initiator, as well as a process for polymerization are also subjects of the present invention.
摘要翻译：本发明涉及选择的1-烷氧基-2,2,6,6四甲基哌啶，1-烷氧基-2,2二乙基-6,6二甲基哌啶和1-烷氧基-2,6-二乙基-2,3,6-二甲基哌啶衍生物，其在4位被两个形成开链或环状缩酮结构的氧原子取代，所述可聚合组合物包含a）至少一种烯属不饱和单体和b）所述哌啶衍生物。本发明的另外的方面是使烯键式不饱和单体聚合的方法，以及使用1-烷氧基-2,2,6,6四甲基哌啶，1-烷氧基-2,2二乙基-6,6二甲基哌啶和1- 烷氧基-2,6-二乙基-2,3,6二甲基哌啶衍生物，其在4位被两个氧原子取代，形成用于受控聚合的开链或环状缩酮结构。中间体N-氧基衍生物，具有烯键式不饱和单体的N-氧基衍生物和自由基引发剂的组合物以及聚合方法也是本发明的主题。

10. 发明申请

US20060149011A1 N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, their corresponding N-oxides and controlled radical polymerization therewith 失效
标题翻译： N-烷氧基-4,4-二氧基 - 多烷基 - 哌啶化合物，它们相应的N-氧化物和受控自由基聚合
公开(公告)号：US20060149011A1
公开(公告)日：2006-07-06
申请号：US11364537
申请日：2006-02-28
申请人： Peter Nesvadba , Marie-Odile Zink , Wiebke Wunderlich
发明人： Peter Nesvadba , Marie-Odile Zink , Wiebke Wunderlich
IPC分类号： C08F4/00 , C07D491/10
CPC分类号： C07D211/94 , C07D491/113 , C07D491/22 , C07D519/00 , C08F2/46 , C08F4/00
摘要： The present invention relates to selected 1-alkoxy-2,2,6,6 tetramethyl piperidine, 1-alkoxy-2,2 diethyl-6,6 dimethyl piperidine and 1-alkoxy-2,6 diethyl-2,3,6 dimethyl piperidine derivatives which are substituted in the 4 position by two oxygen atoms forming an open chain or cyclic ketal structure, a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b) said piperidine derivatives. Further aspects of the present invention are a process for polymerizing ethylenically unsaturated monomers, and the use of 1-alkoxy-2,2,6,6 tetramethyl piperidine, 1-alkoxy-2,2 diethyl-6,6 dimethyl piperidine and 1-alkoxy-2,6 diethyl-2,3,6 dimethyl piperidine derivatives which are substituted in the 4 position by two oxygen atoms forming an open chain or cyclic ketal structure for controlled polymerization. The intermediate N-oxyl derivatives, a composition of the N-oxyl derivatives with ethylenically unsaturated monomers and a free radical initiator, as well as a process for polymerization are also subjects of the present invention.
摘要翻译：本发明涉及选择的1-烷氧基-2,2,6,6四甲基哌啶，1-烷氧基-2,2二乙基-6,6二甲基哌啶和1-烷氧基-2,6-二乙基-2,3,6-二甲基哌啶衍生物，其在4位被两个形成开链或环状缩酮结构的氧原子取代，所述可聚合组合物包含a）至少一种烯属不饱和单体和b）所述哌啶衍生物。本发明的另外的方面是使烯键式不饱和单体聚合的方法，以及使用1-烷氧基-2,2,6,6四甲基哌啶，1-烷氧基-2,2二乙基-6,6二甲基哌啶和1- 烷氧基-2,6-二乙基-2,3,6二甲基哌啶衍生物，其在4位被两个氧原子取代，形成用于受控聚合的开链或环状缩酮结构。中间体N-氧基衍生物，具有烯键式不饱和单体的N-氧基衍生物和自由基引发剂的组合物以及聚合方法也是本发明的主题。

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