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    • 24. 发明授权
    • Humidity sensor and method for manufacturing the same
    • 湿度传感器及其制造方法
    • US06615659B2
    • 2003-09-09
    • US10095435
    • 2002-03-13
    • Akira ShibueKenryo Namba
    • Akira ShibueKenryo Namba
    • G01N900
    • G01N27/121G01N27/126
    • In a humidity sensor device comprising a pair of opposed electrodes disposed on an insulating substrate to define a gap therebetween and a humidity sensitive thin film lying on the gap, the humidity sensitive thin film is a thin film comprising a polymer or copolymer obtained from a monomer of formula (1), and formation of the humidity sensitive thin film is optionally combined with treatment of the insulating substrate by physical means. A humidity sensor device for detecting and determining moisture in the surrounding atmosphere which has improved water resistance, solvent resistance, and gas resistance, and exhibits stable output performance in a wide humidity region without hysteresis is provided as well as a method for preparing the same. In formula (1), A11 is a divalent group, R11 to R14 are alkyl, Y11 and Y12 are monovalent groups terminated with an ethylenically unsaturated reactive group, any two or more of R11to R14, Y11, Y12, A11 and portions thereof adjoining the nitrogen (N) atom may bond together to form a ring with the nitrogen (N) atom, and X11− and X12− are anions.
    • 在一种湿度传感器装置中,所述湿度传感器装置包括设置在绝缘基板上的一对相对电极以限定它们之间的间隙和位于所述间隙上的湿度敏感性薄膜,所述湿度敏感薄膜是包含由单体获得的聚合物或共聚物 (1)的形式,并且任选地通过物理方法与绝缘基板的处理组合形成湿敏薄膜。 一种用于检测和测定周围环境中的水分的湿度传感器装置,其具有改进的耐水性,耐溶剂性和耐气体性,并且在没有迟滞的宽湿度区域中表现出稳定的输出性能以及其制备方法。 在式(1)中,A11为二价基团,R11至R14为烷基,Y11和Y12为以烯属不饱和反应性基团封端的单价基团,R11至R14,Y11,Y12,A11中的任何两个或多个, 氮(N)原子可以键合在一起形成与氮(N)原子的环,X11-和X12-是阴离子。
    • 25. 发明授权
    • Sold electrolytes, carbon dioxide sensors and method for correcting the output of sensors
    • 销售电解质,二氧化碳传感器和校正传感器输出的方法
    • US06241873B1
    • 2001-06-05
    • US09118832
    • 1998-07-20
    • Kenryo NambaAkira ShibueShizuko Kumazawa
    • Kenryo NambaAkira ShibueShizuko Kumazawa
    • G01N27407
    • G01N27/4074
    • The present invention provides a solid electrolyte having high stability against humidity at room temperature and a carbon dioxide sensor which not only can have sufficient sensitivity but also has excellent responsiveness at room temperature and which is excellent in humidity resistance due to the use of the above solid electrolyte, the solid electrolyte of the present invention being formed by heat-treating a polymer having a quaternary ammonium group in its main chain and having a halide ion as counter ion, and a metal halide, the carbon dioxide sensor of the present invention comprising a detection electrode and a reference electrode formed respectively in contact with a solid electrolyte, the detection electrode containing a metal carbonate which forms a dissociation equilibrium with carbon dioxide, the solid electrolyte being a product formed by heat-treating a compound having an ammonium ion portion and a metal halide or a product formed by heat-treating a polymer having a quaternary ammonium group in its main chain and having a halide ion as counter ion, and a metal halide.
    • 本发明提供了一种在室温下具有高湿度稳定性的固体电解质和二氧化碳传感器,其不仅可以具有足够的灵敏度,而且在室温下具有优异的响应性,并且由于使用上述固体而具有优异的耐湿性 电解质,本发明的固体电解质是通过在其主链中热处理具有季铵基的聚合物并具有作为抗衡离子的卤离子形成的金属卤化物形成的,本发明的二氧化碳传感器包括 检测电极和分别与固体电解质接触的参比电极,所述检测电极含有与二氧化碳形成解离平衡的金属碳酸盐,所述固体电解质是通过热处理具有铵离子部分的化合物和 金属卤化物或通过热处理具有季铵盐的聚合物形成的产品 其主链中具有卤化铵离子作为抗衡离子,和金属卤化物。
    • 28. 发明授权
    • Cyanine dyes for use in optical recording medium
    • 用于光记录介质的花青染料
    • US5506357A
    • 1996-04-09
    • US254284
    • 1994-06-06
    • Kenryo Namba
    • Kenryo Namba
    • C07F15/00C07F15/02C07F15/03C07F15/04C07F15/06C09B23/00G03C1/76G11B7/246
    • G11B7/2495C09B23/00G11B7/246G11B7/2472G11B7/245G11B7/256Y10S430/146
    • A photostable cyanine dye possessing a structure represented by the general formula I or II:.PHI..sup.+ -L=.PSI..multidot.Q.sup.- (I).PHI.=L-.PSI..sup.+ .multidot.Q.sup.- (II)wherein .PHI. denotes a monovalent or divalent residue of thiazole ring, oxazole ring, selenazole ring, imidazole ring, pyridine ring, indolenine ring, benzoindolenine ring or dibenzoindolenine ring which may have an aromatic ring condensed thereto, .PSI. denotes a divalent or monovalent residue of thiazole ring, oxazole ring, selenazole ring, imidazole ring, pyridine ring, indolenine ring, benzoindolenine ring or dibenzoindolenine ring which may have an aromatic ring condensed thereto, L denotes a polymethine connecting group for the formation of a cyanine dye, and Q.sup.- denotes an anion represented by the general formula III: ##STR1## wherein M denotes a transition metal atom, R.sup.1, R.sup.2, R.sup.3 and R.sup.4 each denote a hydrogen atom, a halogen atom, an alkyl group, or a dialkylamino group and preparation thereof, and an optical recording medium according to Claim 18, wherein said photostable cyanine dye possesses a structure represented by the general formula I or II..PHI..sup.+ -L=.PSI..multidot.Q.sup.- (I).PHI.=L-.PSI..sup.+ .multidot.Q.sup.- (II)wherein .PHI., .PSI., L and Q.sup.- have the same meanings as defined above.
    • 具有由通式I或II表示的结构的光稳定花青染料:PHI + -L = PSI xQ-(I)PHI = L- PSI + xQ-(II)其中PHI表示噻唑环的一价或二价残基, 恶唑环,硒唑环,咪唑环,吡啶环,吲哚宁环,苯并吲哚宁环或二苯并二吲哚宁环,其中可具有稠环的芳香环,PSI表示噻唑环的二价或单价残基,恶唑环,硒唑环,咪唑环,吡啶 环,吲哚宁环,苯并吲哚宁环或二苯并二吲哚宁环,其中可以具有稠合的芳香环,L表示形成花青染料的聚甲基化连接基团,Q表示由通式III表示的阴离子: III)其中M表示过渡金属原子,R 1,R 2,R 3和R 4各自表示氢原子,卤素原子,烷基或二烷基氨基及其制备方法,以及根据权利要求1的光学记录介质 8,其中所述光稳定花青染料具有由通式I或II表示的结构。 PHI + -L = PSI xQ-(I)PHI = L- PSI + xQ-(II)其中PHI,PSI,L和Q-具有与上述相同的含义。
    • 30. 发明授权
    • Conductive member and manufacturing method thereof, and electric device and manufacturing method thereof
    • 导电构件及其制造方法以及电气装置及其制造方法
    • US07663468B2
    • 2010-02-16
    • US10541733
    • 2004-01-16
    • Yukie MoriNobuo KobayashiKenryo Namba
    • Yukie MoriNobuo KobayashiKenryo Namba
    • H01C7/13
    • H01C17/06586H01B1/24H01C7/028
    • An electric device 1 is an organic positive thermistor in which, between two plate electrodes 2a and 2b constituting an electrode couple 2, a conductive member 41 is disposed in a state being in a close contact with the plate electrodes 2a and 2b. The conductive member 41 is formed of many piled up resin particles each having its surface formed with a conductive layer of a residual material (fullerene residual), which is the soot including fullerenes generated via, for example, an arc discharging method, from which at least a part of fullerenes is removed. Such conductive layers are joined to each other to structure the conductive path and the conduction of the electric device 1 is ensured in a normal state. When an inrush current flows, the conductive path is readily shut off by a small inflation of the resin particles due to the temperature rise.
    • 电气装置1是有机正热敏电阻,其中,在构成电极对2的两个平板电极2a和2b之间,以与电极2a和2b紧密接触的状态配置导电构件41。 导电构件41由许多堆积的树脂颗粒形成,每个树脂颗粒的表面形成有残留材料(富勒烯残留物)的导电层,其是包含通过例如电弧放电法产生的富勒烯的烟炱, 至少部分富勒烯被去除。 这样的导电层彼此接合以构成导电路径,并且在正常状态下确保电气设备1的导通。 当浪涌电流流动时,由于温度升高,导电路径容易被树脂颗粒的小的膨胀所切断。