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21. 发明授权

US07695863B2 Nonaqueous electrolyte solution and lithium secondary battery using same 有权
标题翻译：非水电解液和锂二次电池使用相同
公开(公告)号：US07695863B2
公开(公告)日：2010-04-13
申请号：US11722883
申请日：2005-11-24
申请人： Koji Abe , Takaaki Kuwata , Hirofumi Takemoto
发明人： Koji Abe , Takaaki Kuwata , Hirofumi Takemoto
IPC分类号： H01M6/04
CPC分类号： H01M10/0567 , H01M6/164 , H01M10/052 , H01M2300/0025
摘要： The present invention provides a lithium secondary battery having excellent battery cycle property, electrical capacity, storage characteristic and other battery characteristics for a long period of time, and a nonaqueous electrolytic solution which is usable for the lithium secondary battery.A nonaqueous electrolytic solution in which an electrolyte salt is dissolved in a nonaqueous solvent, comprising (i) a dicarbonyl compound represented by the general formula (I), or (ii) a dicarbonyl compound represented by the general formula (II) and vinylene carbonate and the like in the nonaqueous electrolytic solution. (wherein R1 represents a hydrogen atom, an alkyl group, an alkenyl group, a phenyl group or the like; and X represents a hydrogen atom, an R2 group or an OR2 group. R2 represents an alkyl group, an alkenyl group, a phenyl group or the like.) (wherein R1 and X are the same as above; Y and Z represents a hydrogen atom, an R2 group, an OR2 group, a COR2 group or a CH2COR2 group; and n is 1 to 6.).
摘要翻译：本发明提供一种长时间具有优异的电池循环性能，电容量，储存特性等电池特性的锂二次电池和可用于锂二次电池的非水电解液。其中电解质盐溶解在非水溶剂中的非水电解液，包括（i）由通式（I）表示的二羰基化合物或（ii）由通式（II）表示的二羰基化合物和碳酸亚乙烯酯在非水电解液中。（其中R1表示氢原子，烷基，烯基，苯基等; X表示氢原子，R2基或OR2基，R2表示烷基，烯基，苯基基团等）（其中R1和X与上述相同; Y和Z表示氢原子，R2基团，OR2基团，COR2基团或CH2COR2基团; n为1至6.）。

22. 发明授权

US07261975B2 Non-aqueous electrolytic solution and lithium secondary battery using the same 有权
公开(公告)号：US07261975B2
公开(公告)日：2007-08-28
申请号：US10572571
申请日：2004-09-17
申请人： Koji Abe , Takaaki Kuwata
发明人： Koji Abe , Takaaki Kuwata
IPC分类号： H01M10/08
CPC分类号： H01M10/0567 , C07C309/66 , H01M10/0525 , H01M2300/004
摘要： The present invention provides a lithium secondary battery which is improved particularly in cycle characteristics. Disclosed is a lithium secondary battery which uses a non-aqueous electrolytic solution obtained by dissolving electrolyte salt in a non-aqueous solvent. The non-aqueous electrolytic solution further contains a pentafluorophenyloxy compound represented by the formula (I), and vinylene carbonate and/or 1,3-propanesultone. In the formula (I), R1 is a substituent selected from the group consisting of an alkylcarbonyl group having 2 to 12 carbon atoms, an alkoxycarbonyl group having 2 to 12 carbon atoms, an aryloxycarbonyl group having 7 to 18 carbon atoms, and an alkanesulfonyl group having 1 to 12 carbon atoms. At least one hydrogen atom of the substituent can be substituted with a halogen atom or an aryl group having 6 to 18 carbon atoms.

23. 发明申请

US20050250007A1 Lithium secondary battery 有权
标题翻译：锂二次电池
公开(公告)号：US20050250007A1
公开(公告)日：2005-11-10
申请号：US10521797
申请日：2003-07-31
申请人： Koji Abe , Takashi Hattori , Takaaki Kuwata , Yasuo Mstsunori
发明人： Koji Abe , Takashi Hattori , Takaaki Kuwata , Yasuo Mstsunori
IPC分类号： H01M2/02 , H01M4/58 , H01M4/587 , H01M6/16 , H01M10/0525 , H01M10/0567 , H01M10/36 , H01M10/40
CPC分类号： H01M10/0525 , H01M2/0222 , H01M4/587 , H01M10/0567 , H01M2300/0037
摘要： A lithium secondary battery comprising a positive electrode, a negative electrode of artificial graphite or natural graphite and a nonaqueous electrolytic solution having an electrolyte dissolved in a nonaqueous solvent, wherein 0.1 to 20 wt. % of a cyclohexylbenzene having a halogen atom bonded to a benzene ring thereof is contained in the nonaqueous electrolytic solution exhibits large electric capacity and excellent cycle performance.
摘要翻译：一种锂二次电池，其包含正极，人造石墨或天然石墨的负极以及溶解在非水溶剂中的电解质的非水电解液，其中，0.1〜20重量％在非水电解液中含有具有与苯环结合的卤素原子的环己基苯的％具有大的电容和优异的循环性能。

24. 发明授权

US07794876B2 Pentafluorophenyloxy compound, and nonaqueous electrolyte solution and lithium secondary battery using same 有权
标题翻译：五氟苯氧基化合物和非水电解质溶液以及使用其的锂二次电池
公开(公告)号：US07794876B2
公开(公告)日：2010-09-14
申请号：US11632840
申请日：2006-11-08
申请人： Koji Abe , Takaaki Kuwata , Manabu Takase
发明人： Koji Abe , Takaaki Kuwata , Manabu Takase
IPC分类号： H01M6/04
CPC分类号： H01M10/0566 , C07C67/14 , C07C301/02 , H01M10/052 , C07C69/36
摘要： To provide a novel pentafluorophenyloxy compound, a method for producing same, a nonaqueous electrolyte solution capable of forming a lithium secondary battery having excellent battery characteristics such as electrical capacity, cycling property and storage property, and a lithium secondary battery.A pentafluorophenyloxy compound represented by the general formula (I) shown below, a method for producing same, a nonaqueous electrolyte solution containing same and a lithium secondary battery: wherein R1 represents a —COCO— group, a S═O group or a S(═O)2 group, R2 represents an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aryl group or an aralkyl group with the proviso that at least one of the hydrogen atoms of R2 may be each substituted with a halogen atom and that R2 does not represent an aryl group when R1 represents a —COCO— group.
摘要翻译：为了提供一种新的五氟苯氧基化合物，其制备方法，能够形成具有优异电池特性如电容，循环性能和储存性能的锂二次电池的非水电解质溶液和锂二次电池。由下述通式（I）表示的五氟苯氧基化合物，其制备方法，含有它们的非水电解质溶液和锂二次电池：其中R1表示-COCO-基，S = O基或S（ ≡O）2基团，R 2表示烷基，环烷基，烯基，炔基，芳基或芳烷基，条件是R 2的至少一个氢原子可以各自被当R 1表示-COCO-基团时，R 2不表示芳基。

25. 发明申请

US20080102377A1 Nonaqueous Electrolyte Solution and Lithium Secondary Battery Using Same 有权
标题翻译：非水电解液和锂二次电池
公开(公告)号：US20080102377A1
公开(公告)日：2008-05-01
申请号：US11722883
申请日：2005-11-24
申请人： Koji Abe , Takaaki Kuwata , Hirofumi Takemoto
发明人： Koji Abe , Takaaki Kuwata , Hirofumi Takemoto
IPC分类号： H01M10/40
CPC分类号： H01M10/0567 , H01M6/164 , H01M10/052 , H01M2300/0025
摘要： The present invention provides a lithium secondary battery having excellent battery cycle property, electrical capacity, storage characteristic and other battery characteristics for a long period of time, and a nonaqueous electrolytic solution which is usable for the lithium secondary battery.A nonaqueous electrolytic solution in which an electrolyte salt is dissolved in a nonaqueous solvent, comprising (i) a dicarbonyl compound represented by the general formula (I), or (ii) a dicarbonyl compound represented by the general formula (II) and vinylene carbonate and the like in the nonaqueous electrolytic solution. (wherein R1 represents a hydrogen atom, an alkyl group, an alkenyl group, a phenyl group or the like; and X represents a hydrogen atom, an R2 group or an OR2 group. R2 represents an alkyl group, an alkenyl group, a phenyl group or the like.) (wherein R1 and X are the same as above; Y and Z represents a hydrogen atom, an R2 group, an OR2 group, a COR2 group or a CH2COR2 group; and n is 1 to 6.)
摘要翻译：本发明提供一种长时间具有优异的电池循环性能，电容量，储存特性等电池特性的锂二次电池和可用于锂二次电池的非水电解液。其中电解质盐溶解在非水溶剂中的非水电解液，包括（i）由通式（I）表示的二羰基化合物或（ii）由通式（II）表示的二羰基化合物和碳酸亚乙烯酯在非水电解液中。（其中R 1表示氢原子，烷基，烯基，苯基等; X表示氢原子，R 2 O 2基团或 OR 2基团，R 2表示烷基，烯基，苯基等）（其中R 1和R 2） X与上述相同; Y和Z表示氢原子，R 2 O 2基团，OR 2基团，COR 2 O 2基团或CH 2 CO 2 O 2基团; n为1至6.）

26. 发明申请

US20080038644A1 Nonaques Electrolyte Solution And Lithium Secondary Battery Using Same 有权
标题翻译： Nonaques电解液和锂二次电池使用相同
公开(公告)号：US20080038644A1
公开(公告)日：2008-02-14
申请号：US11596862
申请日：2005-05-18
申请人： Koji Abe , Takaaki Kuwata , Hirofumi Takemoto
发明人： Koji Abe , Takaaki Kuwata , Hirofumi Takemoto
IPC分类号： H01M10/00
CPC分类号： H01M10/0569 , H01M10/0525 , H01M10/0567 , H01M2300/0025 , H01M2300/0037
摘要： Disclosed is a lithium secondary battery which is excellent in battery characteristics such as long-term cycle characteristics, capacity and shelf life characteristics. Also disclosed is a nonaqueous electrolyte solution which can be used for such a lithium secondary battery. Specifically disclosed is a nonaqueous electrolyte solution for lithium secondary batteries obtained by dissolving an electrolyte salt in a nonaqueous solvent which is characterized by containing 0.01-10% by weight of a carboxylate compound represented by the general formula (I) below and 0.01-10% by weight or 0.01-10% by volume of a vinylene carbonate and/or 1,3-propane sultone. Also disclosed is a lithium secondary battery using such a nonaqueous electrolyte solution. (In the formula, R2 represents a hydrogen atom or COOR3 group, R1 and R3 respectively represent an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group or a phenyl group, and X represents an alkynylene group or an alkenylene group.)
摘要翻译：公开了电池特性如长期循环特性，容量和保质期特性优异的锂二次电池。还公开了可用于这种锂二次电池的非水电解质溶液。具体公开了通过将电解质盐溶解在非水溶剂中得到的锂二次电池用非水电解液，其特征在于含有0.01〜10重量％的下述通式（I）表示的羧酸酯化合物和0.01-10重量％或0.01-10体积％的碳酸亚乙烯酯和/或1,3-丙磺酸内酯。还公开了使用这种非水电解质溶液的锂二次电池。（式中，R 2分别表示氢原子或COOR 3基团，R 1和R 3分别表示氢原子或COOR 3 表示烷基，环烷基，烯基，炔基或苯基，X表示亚炔基或亚链烯基。

27. 发明申请

US20070054185A1 Non-aqueous electrolytic solution and lithium secondary battery using the same 有权
标题翻译：非水电解液和使用其的锂二次电池
公开(公告)号：US20070054185A1
公开(公告)日：2007-03-08
申请号：US10572571
申请日：2004-09-17
申请人： Koji Abe , Takaaki Kuwata
发明人： Koji Abe , Takaaki Kuwata
IPC分类号： H01M10/40
CPC分类号： H01M10/0567 , C07C309/66 , H01M10/0525 , H01M2300/004
摘要： The present invention provides a lithium secondary battery which is improved particularly in cycle characteristics. Disclosed is a lithium secondary battery which uses a non-aqueous electrolytic solution obtained by dissolving electrolyte salt in a non-aqueous solvent. The non-aqueous electrolytic solution further contains a pentafluorophenyloxy compound represented by the formula (I), and vinylene carbonate and/or 1,3-propanesultone. In the formula (I), R1 is a substituent selected from the group consisting of an alkylcarbonyl group having 2 to 12 carbon atoms, an alkoxycarbonyl group having 2 to 12 carbon atoms, an aryloxycarbonyl group having 7 to 18 carbon atoms, and an alkanesulfonyl group having 1 to 12 carbon atoms. At least one hydrogen atom of the substituent can be substituted with a halogen atom or an aryl group having 6 to 18 carbon atoms.
摘要翻译：本发明提供一种特别在循环特性方面得到改善的锂二次电池。公开了一种锂二次电池，其使用通过将电解质盐溶解在非水溶剂中而获得的非水电解液。非水电解液还含有式（I）表示的五氟苯氧基化合物和碳酸亚乙烯酯和/或1,3-丙磺酸内酯。在式（I）中，R 1是选自具有2至12个碳原子的烷基羰基，具有2至12个碳原子的烷氧基羰基，具有7个碳原子的芳氧基羰基至18个碳原子，和具有1至12个碳原子的链烷磺酰基。取代基的至少一个氢原子可以被卤素原子或具有6至18个碳原子的芳基取代。

28. 发明申请

US20050255384A1 Nonaqueous electrolytic solution and lithium secondary battery employing the same 有权
标题翻译：非水电解液和采用其的锂二次电池
公开(公告)号：US20050255384A1
公开(公告)日：2005-11-17
申请号：US10507110
申请日：2003-03-13
申请人： Koji Abe , Takaaki Kuwata , Takashi Hattori , Yasuo Matsumori
发明人： Koji Abe , Takaaki Kuwata , Takashi Hattori , Yasuo Matsumori
IPC分类号： H01M10/05 , H01M10/052 , H01M10/0567 , H01M10/40 , H01M4/50 , H01M4/52 , H01M4/58
CPC分类号： H01M10/0525 , H01M4/131 , H01M4/133 , H01M6/164 , H01M6/168 , H01M10/0567 , H01M10/0569 , H01M2300/0025
摘要： 1. A non-aqueous electrolytic solution comprising an electrolytic salt in a non-aqueous solvent, which further contains a pentafluorophenoxy compound having the formula (I): in which R represents a substituting group such as an alkylcarbonyl group, an alkoxycarbonyl group, an aryloxy-carbonyl group, and an alkanesulfonyl group, under the condition that at least one hydrogen atom contained in the substituting group can be substituted with a halogen atom or an aryl group.
摘要翻译： 1.一种非水电解液，其包含在非水溶剂中的电解质盐，其还含有具有式（I）的五氟苯氧基化合物：其中R表示取代基，例如烷基羰基，烷氧基羰基，芳氧基 - 羰基和链烷磺酰基，在取代基中所含的至少一个氢原子可以被卤素原子或芳基取代的条件下进行。

29. 发明授权

US5293512A Semiconductor device having a groove type isolation region 失效
标题翻译：具有凹槽型隔离区域的半导体器件
公开(公告)号：US5293512A
公开(公告)日：1994-03-08
申请号：US834829
申请日：1992-02-13
申请人： Tadashi Nishigoori , Takaaki Kuwata
发明人： Tadashi Nishigoori , Takaaki Kuwata
IPC分类号： H01L21/336 , H01L21/74 , H01L29/06 , H01L29/417 , H01L29/78 , H01L27/02
CPC分类号： H01L23/485 , H01L21/743 , H01L29/0653 , H01L29/41766 , H01L29/66636 , H01L29/7834 , H01L2924/0002
摘要： A semiconductor device is disclosed in which a groove type element isolation region in the surroundings of a first diffused layer of one conductivity type formed on the surface of a silicon substrate of the opposite conductivity type, an insulating film is embedded in the groove type element isolation region, and an interlayer insulating film is provided on the silicon substrate. A contact hole for connecting the first diffused layer to a metallic wiring is provided at a position that straddles the boundary between the first diffused layer and the groove type element isolation region, the insulating film embedded in the groove type element isolation region is exposed in a part of the bottom face of the contact hole, and the silicon substrate including the first diffused layer is exposed on the side face of the contact hole. On the surface of the silicon substrate exposed to the contact hole there is formed a second diffused layer of the one conductivity type, and this diffused layer is connected to the first diffused layer. Because of the structure as described in the above, the increase in the contact resistance between the first and the second diffused layer, and the metallic wiring can be suppressed even if the aperture of the contact hole is decreased. Moreover, it becomes unnecessary to provide a space between the contact hole and the groove type element isolation region so that it becomes possible to reduce the area of the first diffused layer, and it is effective to enhance the operating speed due to the increase in the integration of the semiconductor device and to the decrease in the junction capacitance.
摘要翻译：公开了一种半导体器件，其中形成在相反导电类型的硅衬底的表面上的一种导电类型的第一扩散层的周围的沟槽型元件隔离区域，绝缘膜嵌入在沟槽型元件隔离中区域，并且在硅衬底上设置层间绝缘膜。在跨越第一扩散层和槽型元件隔离区域之间的边界的位置处设置用于将第一扩散层连接到金属布线的接触孔，将嵌入在槽型元件隔离区域中的绝缘膜暴露在接触孔的底面的一部分，包含第一扩散层的硅基板在接触孔的侧面露出。在暴露于接触孔的硅衬底的表面上形成有一种导电类型的第二扩散层，并且该扩散层连接到第一扩散层。由于如上所述的结构，即使接触孔的孔径减小，也可以抑制第一和第二扩散层与金属布线之间的接触电阻的增加。此外，不需要在接触孔和槽型元件隔离区域之间设置空间，从而可以减小第一扩散层的面积，并且由于增加了第一扩散层的面积而提高操作速度是有效的半导体器件的集成和结电容的减小。

30. 发明授权

US5376620A Sulfonamide derivative, process for preparing the same and herbicide using the same 失效
标题翻译：磺酰胺衍生物，其制备方法和使用其的除草剂
公开(公告)号：US5376620A
公开(公告)日：1994-12-27
申请号：US41998
申请日：1993-04-02
申请人： Takaaki Abe , Yuji Akiyoshi , Hiroshi Shiraishi , Ikuo Shiraishi , Mikio Kojima , Takashi Hayama , Takaaki Kuwata
发明人： Takaaki Abe , Yuji Akiyoshi , Hiroshi Shiraishi , Ikuo Shiraishi , Mikio Kojima , Takashi Hayama , Takaaki Kuwata
IPC分类号： A01N43/54 , A01N43/66 , C07D239/60 , C07D251/34 , C07D251/38 , C07D401/12
CPC分类号： C07D401/12 , A01N43/54 , A01N43/66 , C07D239/60 , C07D251/34 , C07D251/38
摘要： Disclosed are a sulfonamide compound represented by the following formula (I): ##STR1## wherein Y represents a lower akyl group, a lower alkenyl group, a lower alkynyl group, a halo-lower alkyl group, a cyano-lower alkyl group or --C(CH.sub.3).sub.2 (OR.sup.1) where R.sup.1 represents a lower akyl group, a lower alkenyl group, a lower alkynyl group, a halo-lower alkyl group or a cyano-lower alkyl group; Q represents a substituted or unsubstituted pyridyl group or --NR.sup.2 R.sup.3 where R.sup.2 represents a hydrogen atom, a lower alkyl group, a lower alkoxy group; and R.sup.3 represents a lower alkyl group, a lower alkenyl group, a lower alkynyl group, a phenyl group or a benzyl group; or R.sup.2 and R.sup.3 may be combined to form a cycloamino group; X represents an oxygen atom or a sulfur atom; and Z represents a nitrogen atom or --CH.dbd. group;processes for preparing the same and a herbicide containing the same as an active ingredient(s).
摘要翻译：公开了由下式（I）表示的磺酰胺化合物：其中Y表示低级烷基，低级烯基，低级炔基，卤代低级烷基，氰基 - 低级烷基基团或-C（CH 3）2（OR 1），其中R 1表示低级烷基，低级烯基，低级炔基，卤代低级烷基或氰基 - 低级烷基; Q表示取代或未取代的吡啶基或-NR2R3，其中R2表示氢原子，低级烷基，低级烷氧基; R3表示低级烷基，低级烯基，低级炔基，苯基或苄基。或者R 2和R 3可以组合形成环氨基; X表示氧原子或硫原子; Z表示氮原子或-CH =基团; 其制备方法和含有其作为活性成分的除草剂。

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