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21. 发明授权

US5134054A Positive-type photosensitive electrodeposition coating composition and process for producing circuit plate 失效
标题翻译：正型感光电沉积涂料组合物及其制造方法
公开(公告)号：US5134054A
公开(公告)日：1992-07-28
申请号：US476543
申请日：1992-02-07
申请人： Naozumi Iwasawa , Junichi Higashi
发明人： Naozumi Iwasawa , Junichi Higashi
IPC分类号： C09D5/44 , C09D133/04 , C09D175/04 , G03F7/023 , G03F7/16 , H05K3/06
CPC分类号： G03F7/023 , G03F7/164
摘要： A positive-type photosensitive electrodeposition coating composition comprising(A) a photosensitive compound having a molecular weight of less than 6,000 and containing at least one modified quinonediazidesulfone units represented by the following formula (I) ##STR1## wherein R.sub.1 represents ##STR2## R.sub.2 represents a hydrogen atom, an alkyl group, a cycloalkyl group or an alkyl ether group, andR.sub.3 represents an alkylene group, a cycloalkylene group or an alkylene ether group, in the molecule and(B) an acrylic resin having a salt-forming group.
摘要翻译：一种正型光敏电沉积涂料组合物，其包含（A）分子量小于6000的感光性化合物，并含有至少一种由下式（I）表示的改性醌二叠氮化物单元，其中R1表示 R 2表示分子中的氢原子，烷基，环烷基或烷基醚基，R 3表示亚烷基，亚环烷基或亚烷基醚基，（B）具有盐 - 成型组。

22. 发明授权

US5093223A Method of forming a cured coating film 失效
标题翻译：形成固化涂膜的方法
公开(公告)号：US5093223A
公开(公告)日：1992-03-03
申请号：US278505
申请日：1988-12-01
申请人： Naozumi Iwasawa , Osamu Isozaki
发明人： Naozumi Iwasawa , Osamu Isozaki
IPC分类号： B05D3/06 , C08G59/14 , C08J3/28 , G03F7/038
CPC分类号： G03F7/038 , B05D3/068 , C08G59/1433 , C08J3/28 , G03F7/0388 , Y10S522/904
摘要： The invention provides a method of forming a cured coating film which comprises exposing a coating composition consisting of, or containing as a main component, a resin containing polymerizable unsaturated group and aprotic onium-containing group of the formula ##STR1## wherein R.sub.1 means a hydrogen atom or a hydrocarbon group of 1 to 8 carbon atoms which may optionally be substituted by a hydroxyl, alkoxy or ester group or a halogen atom; ##STR2## where Z means a nitrogen atom or phosphorus atom and Y means a sulfur atom; R.sub.2, R.sub.3 and R.sub.4 are the same or different and respectively mean an organic group of 1 to 14 carbon atoms, provided that R.sub.2 and R.sub.3, or R.sub.2, R.sub.3 and R.sub.4 may jointly form a heterocyclic group taken together with the adjacent nitrogen, phosphorus or sulfur atom, to actinic radiation or electron beams to thereby induce a crosslinking reaction and, then, subjecting the composition to heat treatment at a temperature not less than 80.degree. C.
摘要翻译：本发明提供一种形成固化涂膜的方法，该方法包括使包含可聚合不饱和基团的树脂和式（Ⅰ）所示的非质子含鎓基团组成或包含作为主要成分的涂料组合物，其中R 1 是指氢原子或可任选被羟基，烷氧基或酯基或卤素原子取代的1至8个碳原子的烃基; 其中Z表示氮原子或磷原子，Y表示硫原子; R 2，R 3和R 4相同或不同，分别表示1至14个碳原子的有机基团，条件是R 2和R 3或R 2，R 3和R 4可以与相邻的氮，磷或磷一起形成杂环基硫原子，光化辐射或电子束，从而引起交联反应，然后使组合物在不低于80℃的温度下进行热处理。

23. 发明授权

US5045434A Visible radiation sensitive composition containing substituted 3-(benzothiazo-2-yl)-7-diethylaminocoumarin as sensitizers 失效
标题翻译：含有取代的3-（苯并噻唑-2-基）-7-二乙氨基香豆素作为敏化剂的可见辐射敏感组合物
公开(公告)号：US5045434A
公开(公告)日：1991-09-03
申请号：US629484
申请日：1990-12-18
申请人： Ichiro Yoshihara , Motoko Okuhara , Takao Yamamoto , Naozumi Iwasawa , Yasuo Doi , Tsukasa Ohyama , Kazuhiko Murayama , Yoriaki Matsuzaki , Susumu Kasamatsu , Keisuke Takuma , Kimitoshi Kato
发明人： Ichiro Yoshihara , Motoko Okuhara , Takao Yamamoto , Naozumi Iwasawa , Yasuo Doi , Tsukasa Ohyama , Kazuhiko Murayama , Yoriaki Matsuzaki , Susumu Kasamatsu , Keisuke Takuma , Kimitoshi Kato
IPC分类号： C08F2/50 , G03F7/031 , G03F7/038
CPC分类号： G03F7/031 , C08F2/50 , G03F7/0388 , Y10S430/115 , Y10S430/116 , Y10S430/127 , Y10S430/136 , Y10S430/148
摘要： A visible radiation sensitive composition comprising:(A) a photosetting resin containing a photosensitive group capable of crosslinking or polymerizing by photoirradiation,(B) a sensitizer represented by the formula (i): ##STR1## wherein R.sub.1 and R.sub.2 are the same or different lower alkyl, and R.sub.3 is a hydrogen atom, lower alkyl group, alkoxyalkyl group, hydroxyalkoxyalkyl group or alkoxycarbonylalkyl group, and(C) a polymerization initiator.

24. 发明授权

US5026793A Resin compositions and a method of curing the same 失效
标题翻译：树脂组合物及其固化方法
公开(公告)号：US5026793A
公开(公告)日：1991-06-25
申请号：US402408
申请日：1989-09-05
申请人： Noboru Nakai , Osamu Isozaki , Naozumi Iwasawa
发明人： Noboru Nakai , Osamu Isozaki , Naozumi Iwasawa
IPC分类号： C08G59/40 , C07F7/08 , C07F7/18 , C08G59/00 , C08G59/02 , C08G59/04 , C08G59/30 , C08G59/32 , C08G59/70 , C08K5/00 , C08K5/07 , C08K5/1515 , C08K5/5415 , C08L33/06 , C08L43/04 , C08L63/00 , C08L75/04 , C08L101/06 , C09D133/06 , C09D133/14 , C09D143/04 , C09D163/00
CPC分类号： C08L63/00 , C07F7/0836 , C07F7/0858 , C07F7/0859 , C07F7/182 , C07F7/1836 , C07F7/1844 , C07F7/1896 , C08G59/02 , C08G59/04 , C08G59/306 , C08G59/3254 , C08G59/70 , C08K5/00 , C08K5/0091 , C08K5/07 , C08K5/1515 , C08K5/5415 , C08L101/06 , C08L75/04 , C09D133/064 , C09D133/068 , C09D143/04 , C09D163/00 , C08L33/068 , C08L43/04
摘要： A resinous composition containing (A) a high molecular weight hydroxy compound having 2 or more hydroxy groups per molecule and having a number average molecular weight of 3,000 to 200,000, (B) a high molecule weight epoxy compound having 2 or more epoxy groups per molecule and having a number average molecular weight of 120 to 200,000, (C) a silane compound having one or more silicon-containing functional groups per molecule and (D) a chelate of aluminum, titanium or zirconium with a ligand exhibiting ketoenol tautomerism, can be cured at temperatures not exceeding 100.degree. C. and forms a desirable coating when cured.

25. 发明授权

US4329266A Water-dispersed coating composition comprising an acrylic graft polymer containing carboxyl groups, hydroxyl and/or amide groups 失效
标题翻译：包含含有羧基，羟基和/或酰胺基团的丙烯酸接枝聚合物的水分散涂料组合物
公开(公告)号：US4329266A
公开(公告)日：1982-05-11
申请号：US186557
申请日：1980-09-12
申请人： Yukio Suzuki , Naozumi Iwasawa , Tadashi Watanabe
发明人： Yukio Suzuki , Naozumi Iwasawa , Tadashi Watanabe
IPC分类号： C08F290/12 , C09D151/00 , C08L61/28
CPC分类号： C08F290/126 , C09D151/003
摘要： A water-dispersed coating composition comprising (1) a dispersion of a water-dispersible form of an acrylic graft polymer containing carboxyl groups and hydroxyl and/or amide groups in an aqueous medium containing 60 to 90% by weight of water, and (2) an amino resin. The water-dispersible form of this polymer is obtained by neutralizing at least 50% of the carboxyl groups of the polymer with a basic substance. Prior to neutralization, the polymer has an acid value of 15 to 40 and a glass transition temperature of -10.degree. C. to 70.degree. C., and is produced by polymerizing (A) an acrylic copolymer and (B) a mixture of an alpha,beta-ethylenically unsaturated carboxylic acid and another copolymerizable unsaturated monomer. The copolymer (A) and the mixture (B) is selected so that either one of them has hydroxyl and/or amide groups and the difference between the acid value of the copolymer (A) and that of the mixture (B) is from 25 to 200. The present invention also provides a water-dispersed coating composition comprising a dispersion of a water-dispersible form of a self-curable acrylic graft polymer without an amino resin.
摘要翻译：一种水分散涂料组合物，其包含（1）含水分散体形式的含羧基和羟基和/或酰胺基的丙烯酸接枝聚合物在含有60-90％重量水的水性介质中的分散体，和（2））氨基树脂。该聚合物的水分散形式通过用碱性物质中和聚合物的至少50％的羧基而获得。在中和之前，聚合物的酸值为15至40，玻璃化转变温度为-10℃至70℃，并通过聚合（A）丙烯酸共聚物和（B）将 α，β-烯属不饱和羧酸和另一种可共聚的不饱和单体。选择共聚物（A）和混合物（B），使得它们中的任一个具有羟基和/或酰胺基，并且共聚物（A）和混合物（B）的酸值之间的差异为25 本发明还提供一种水分散涂料组合物，其包含不具有氨基树脂的可分散自由基的丙烯酸接枝聚合物的分散体。

26. 发明授权

US4089910A Thermosetting powder coating compositions 失效
标题翻译：热固性粉末涂料组合物
公开(公告)号：US4089910A
公开(公告)日：1978-05-16
申请号：US588709
申请日：1975-06-20
申请人： Minoru Shibata , Naozumi Iwasawa , Tadashi Watanabe , Ichiro Yoshihara
发明人： Minoru Shibata , Naozumi Iwasawa , Tadashi Watanabe , Ichiro Yoshihara
IPC分类号： B05D7/14 , B05D1/38 , C08F299/04 , C08G59/32 , C08G59/42 , C08L63/00
CPC分类号： C08G59/42 , C08F299/0478 , C08G59/3209 , Y10S524/904 , Y10T428/31529
摘要： A thermosetting powder coating composition comprising:(A) a graft copolymer ofA. 10 to 40 percent of a linear polyester having a number average molecular weight of 600 to 3,000 and containing one ethylenically unsaturated double bond only at one end of the molecule,B. 5 to 30 percent of at least one of glycidyl esters having the formula ##STR1## wherein R.sub.1 is hydrogen or methyl, and C. 10 TO 85 PERCENT OF AT LEAST ONE OF ACRYLIC COMPOUNDS HAVING THE FORMULA OF CH.sub.2 .dbd.C(R.sub.2)COOR.sub.3, wherein R.sub.2 is hydrogen or methyl and R.sub.3 is alkyl having 1 to 14 carbon atoms, cyclohexyl or hydroxyalkyl represented by ##STR2## wherein R.sub.4 is hydrogen, methyl or ethyl, said graft copolymer having a softening point of 70.degree. to 110.degree. C and a number average molecular weight of 2,000 to 30,000; and(B) at least one of polycarboxylic acids and anhydrides thereof in an amount of 0.6 to 1.2 moles in terms of carboxyl group per mole of the glycidyl group contained in the graft copolymer.
摘要翻译：一种热固性粉末涂料组合物，

27. 发明授权

US3974303A Method for forming coating films 失效
标题翻译：涂膜形成方法
公开(公告)号：US3974303A
公开(公告)日：1976-08-10
申请号：US490753
申请日：1974-07-22
申请人： Seigo Iwase , Osamu Isozaki , Naozumi Iwasawa , Tadashi Watanabe
发明人： Seigo Iwase , Osamu Isozaki , Naozumi Iwasawa , Tadashi Watanabe
IPC分类号： C09D5/00 , B05D3/06 , C08G18/32 , C08G18/67 , C08J3/28 , C09D4/00 , C09D5/03 , C09D175/16 , B05B5/02
CPC分类号： C08G18/3206 , B05D3/067 , B05D3/068 , C08G18/672 , C08J3/28 , C09D175/16 , B05D2401/32 , C08G2150/20
摘要： A method for forming coating films which can provide coating films having good surface appearance and being excellent in such properties as impact resistance, adhesion to the substrate article, flexibility and chemical resistance, said method comprising coating a powdery composition of a thermoplastic resin having 0.5 to 3.5 polymerizable unsaturated bonds per 1000 of the molecular weight on an article to be coated, heat-melting the powdery resinous composition, and curing the molten film under application of ionizing radiation or ultraviolet radiation.
摘要翻译：一种形成涂膜的方法，其可以提供具有良好的表面外观并且具有优异的耐冲击性，对基材制品的粘附性，柔韧性和耐化学性的性能的涂膜，所述方法包括将具有0.5的热塑性树脂的粉末组合物涂覆至 3.5可聚合的不饱和键，每1000个待涂覆的物品上的分子量，对粉末状树脂组合物进行加热熔融，并在施加电离辐射或紫外线辐射下固化熔融膜。

28. 发明授权

US07179358B2 Method for forming electrodeposition coating film 失效
标题翻译：电沉积涂膜形成方法
公开(公告)号：US07179358B2
公开(公告)日：2007-02-20
申请号：US10417184
申请日：2003-04-17
申请人： Akira Tominaga , Naozumi Iwasawa , Koji Kamikado , Yasuyuki Hirata , Susumu Midogochi
发明人： Akira Tominaga , Naozumi Iwasawa , Koji Kamikado , Yasuyuki Hirata , Susumu Midogochi
IPC分类号： C25D13/12
CPC分类号： C25D13/22
摘要： A method for forming an electrodeposition coating film, comprises a step of subjecting a steric metal article to be coated to electrodeposition coating, and a step of selectively heating/drying the resultant coating film by a plurality of induction heating devices.
摘要翻译：一种形成电沉积涂膜的方法，包括对空间金属制品进行电沉积涂布的步骤，以及通过多个感应加热装置选择性地加热/干燥所得涂膜的步骤。

29. 发明授权

US5624781A Positive type anionic electrodeposition photo-resist composition and process for pattern formation using said composition 失效
标题翻译：正型阴离子电沉积光致抗蚀剂组合物和使用所述组合物的图案形成方法
公开(公告)号：US5624781A
公开(公告)日：1997-04-29
申请号：US250623
申请日：1994-05-27
申请人： Keisuke Naruse , Yukari Takeda , Naozumi Iwasawa , Hideo Kogure
发明人： Keisuke Naruse , Yukari Takeda , Naozumi Iwasawa , Hideo Kogure
IPC分类号： C09D5/44 , G03F7/023 , G03F7/16 , C25D13/00 , G03F7/38 , G03F7/40
CPC分类号： C09D5/4484 , G03F7/0233 , G03F7/164
摘要： A positive type anionic electrodeposition photoresist composition comprising, as a main component, a dispersion obtained by neutralizing, with a base, a mixture comprising:(A) an acrylic resin containing carboxyl group(s) and hydroxyl group(s),(B) a vinylphenol resin containing a hydroxystyrene unit in an amount of at least 25% by weight based on the resin, and(C) an ester between a polyhydroxybenzophenone and 1,2-naphthoquinone diazide sulfonic acid or benzoquinone diazide sulfonic acid, and dispersing the resulting neutralization product in water.This composition is superior in running stability during electrodeposition and is useful for formation of highly reliable resist pattern or conductor pattern.
摘要翻译：一种正型阴离子电沉积光致抗蚀剂组合物，其包含作为主要成分的通过用碱中和混合物获得的分散体，所述混合物包含：（A）含有羧基和羟基的丙烯酸树脂，（B）含有基于树脂的至少25重量％的羟基苯乙烯单元的乙烯基酚树脂和（C）多羟基二苯甲酮与1,2-萘醌二叠氮化物磺酸或苯醌二叠氮磺酸之间的酯，并将所得中和产品在水中。该组合物在电沉积中的运行稳定性优异，并且可用于形成高度可靠的抗蚀剂图案或导体图案。

30. 发明授权

US5518859A Positive-type photosensitive electrodeposition coating composition and process for producing circuit plate 失效
标题翻译：正型感光电沉积涂料组合物及其制造方法
公开(公告)号：US5518859A
公开(公告)日：1996-05-21
申请号：US405293
申请日：1995-03-16
申请人： Naozumi Iwasawa , Junichi Higashi
发明人： Naozumi Iwasawa , Junichi Higashi
IPC分类号： G03F7/023 , C09D5/44 , G03F7/16
CPC分类号： G03F7/023 , G03F7/164
摘要： A positive-type photosensitive electrodeposition coating composition comprising a water-soluble or water-dispersible resin having an ionic group and containing at least one modified quinonediazidesulfone unit represented by the following formula (I) or (II) ##STR1## wherein R.sub.1 represents ##STR2## R.sub.2 represents a hydrogen atom, an alkyl group, a cycloalkyl group or an alkyl ether group, andR.sub.3 represents an alkylene group, a cycloalkylene group, an alkylene ether group, a phenylene group which may optionally be substituted with an alkyl group having 1 to 20 carbon atoms, or an alkylene, cycloalkylene or alkylene ether group containing in its chain a phenylene group which may optionally be substituted with an alkyl group having 1 to 20 carbon atoms, in the molecule.
摘要翻译：一种正型光敏电沉积涂料组合物，其包含具有离子性基团的水溶性或水分散性树脂，并含有由下式（I）或（II）表示的至少一种改性的醌二叠氮化物单元。 >（II）其中R 1表示R 2表示氢原子，烷基，环烷基或烷基醚基，R 3表示亚烷基，亚环烷基，亚烷基醚基，亚苯基，或者可以被分子内被碳原子数为1〜20的烷基取代的亚烷基，亚环烷基或亚烷基醚基在其链中含有可以被碳原子数1〜20的烷基取代的亚苯基。

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