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21. 发明授权

US4663382A Non-rigid vinyl chloride polymer resin composition 失效
标题翻译：非刚性氯乙烯聚合物树脂组合物
公开(公告)号：US4663382A
公开(公告)日：1987-05-05
申请号：US795518
申请日：1985-11-06
申请人： Kazuo Kishida , Kazuo Ueda , Kiyokazu Kitai , Tsuruyoshi Matsumoto
发明人： Kazuo Kishida , Kazuo Ueda , Kiyokazu Kitai , Tsuruyoshi Matsumoto
IPC分类号： C08K5/00 , C08L1/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L27/00 , C08L27/06 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L51/06 , C08L67/00 , C08L101/00 , C08L13/00 , C08L51/04
CPC分类号： C08K5/0016 , C08L27/06 , C08L51/003
摘要： Disclosed is a non-rigid vinyl chloride polymer composition comprising 100 weight parts of a vinyl chloride polymer resin, 5-50 weight parts of a graft copolymer modifier and 10-300 weight parts of a plasticizer. The graft copolymer modifier is obtained by graft-polymerizing 25-150 weight parts of an alkyl ester of methacrylic acid having 1 to 4 carbon atoms in the alkyl group or a monomer mixture composed of at least more than 50% by weight of said alkyl ester of methacrylic acid onto 100 weight parts of an acrylic elastomer having a swelling degree of 5 to 25 so that the grafting ratio is not larger than 50%. The acrylic elastomer is obtained by polymerizing a mixture comprising an alkyl ester of acrylic acid having 2 to 10 carbon atoms in the alkyl group or a monomer mixture composed of at least 50% by weight of said alkyl ester of acrylic acid, and a polyfunctional crosslinking agent. The non-rigid vinyl chloride polymer composition has excellent weatherability and impact resistance, and exhibits a good molding processability.
摘要翻译：公开了一种非刚性氯乙烯聚合物组合物，其包含100重量份的氯乙烯聚合物树脂，5-50重量份的接枝共聚物改性剂和10-300重量份的增塑剂。接枝共聚物改性剂通过在烷基中接枝聚合25-150重量份的具有1至4个碳原子的甲基丙烯酸的烷基酯或由至少大于50重量％的所述烷基酯组成的单体混合物的甲基丙烯酸加入到100重量份的溶胀度为5〜25的丙烯酸类弹性体中，使得接枝率不大于50％。丙烯酸弹性体是通过在烷基中聚合含有2-10个碳原子的丙烯酸烷基酯的混合物或由至少50重量％的所述丙烯酸烷基酯组成的单体混合物和多官能交联代理商非刚性氯乙烯聚合物组合物具有优异的耐候性和耐冲击性，并且表现出良好的成型加工性。

22. 发明授权

US4035443A Polyvinyl chloride resin composition having transparency, high gloss, impact and weather resistance 失效
标题翻译：聚氯乙烯树脂组合物具有透明，高光泽，耐冲击和耐候性
公开(公告)号：US4035443A
公开(公告)日：1977-07-12
申请号：US644421
申请日：1975-12-24
申请人： Fumio Ide , Kazuo Kishida , Jinpee Kobayashi
发明人： Fumio Ide , Kazuo Kishida , Jinpee Kobayashi
IPC分类号： C08L27/00 , C08F265/00 , C08F265/04 , C08F265/06 , C08F279/00 , C08F285/00 , C08L1/00 , C08L27/06 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L51/06 , A43B13/04 , C08F6/24
CPC分类号： C08F285/00 , C08F265/04 , C08F265/06 , C08L27/06 , C08L51/003
摘要： A transparent vinyl chloride resin composition excellent in surface gloss and resistant to weathering and impact, comprising 97 to 60 parts by weight of a vinyl-chloride polymer and 3 to 40 parts by weight of a graft copolymer (B) obtained by emulsion-polymerizing a mixture of an aromatic vinyl monomer and a polyfunctional crosslinking agent having at least one allyl group, then polymerizing, in the presence of the resulting polymer latex, a mixture of an alkyl acrylate having 2 to 10 carbon atoms in the alkyl group and a polyfunctional crosslinking agent having at least one allyl group to form an acrylic elastomer (A) in the first stage the proportions of said alkyl acrylate and said aromatic vinyl monomer being 50 to 70% by weight and 50 to 30% by weight, respectively, and the amount of said crosslinking agent used being 0.1 to 5 parts by weight in total per 100 parts by weight of the sum of said alkyl acrylate and said aromatic vinyl monomer; and graft-polymerizing, in the presence of the resulting acrylic elastomer (A), first methyl methacrylate and subsequently an aromatic vinyl monomer in the second stage, the proportions of said methyl methacrylate and said aromatic vinyl monomer being 30 to 80% by weight and 70 to 20% by weight, respectively, and the total amount of said methyl methacrylate and said aromatic vinyl monomer used being 70 to 20 parts by weight per 30 to 80 parts by weight of said acrylic elastomer (A).
摘要翻译：一种透明的氯乙烯树脂组合物，具有优异的表面光泽度和耐候性和耐冲击性，其包含97-60重量份氯乙烯聚合物和3-40重量份通过乳液聚合反应获得的接枝共聚物（B）芳族乙烯基单体和具有至少一个烯丙基的多官能交联剂的混合物，然后在所得聚合物胶乳存在下，在烷基中具有2至10个碳原子的丙烯酸烷基酯与多官能交联剂具有至少一个烯丙基的试剂在第一阶段中形成丙烯酸弹性体（A），所述丙烯酸烷基酯和所述芳族乙烯基单体的比例分别为50至70重量％和50至30重量％，并且其量的所述交联剂的总和为每100重量份所述丙烯酸烷基酯和所述芳族乙烯基单体的总量为0.1至5重量份; 在第二阶段中，在得到的丙烯酸类弹性体（A），第一甲基丙烯酸甲酯和随后的芳香族乙烯基单体的存在下接枝聚合，所述甲基丙烯酸甲酯和所述芳族乙烯基单体的比例为30〜80重量％，和 70〜20重量％，所使用的所述甲基丙烯酸甲酯和所述芳族乙烯基单体的总量相对于所述丙烯酸系弹性体（A）为30〜80重量份为70〜20重量份。

23. 发明授权

US08123882B2 Process for producing ceramic substrate 有权
标题翻译：陶瓷基板的制造方法
公开(公告)号：US08123882B2
公开(公告)日：2012-02-28
申请号：US12888450
申请日：2010-09-23
申请人： Kazuo Kishida , Hiroaki Yamada
发明人： Kazuo Kishida , Hiroaki Yamada
IPC分类号： B29C65/00 , C03B29/00
CPC分类号： H05K3/4611 , B32B18/00 , C04B2237/34 , C04B2237/341 , C04B2237/343 , C04B2237/348 , C04B2237/561 , C04B2237/562 , C04B2237/565 , C04B2237/62 , C04B2237/66 , C04B2237/68 , C04B2237/702 , H05K1/0306 , H05K3/1291 , H05K3/4629 , H05K2201/0116 , H05K2201/0212 , H05K2203/1126 , H05K2203/308
摘要： A shrinkage suppression layer used in the production of a ceramic substrate according to a non-shrinkage process provides favorable removal performance while sufficiently ensuring the restraining performance of the shrinkage suppression layer. Resin beads, which disappear at a temperature lower than the sintering temperature of a low-temperature sintering ceramic material of a base material layer to form open bores in a shrinkage suppression layer, are added to the shrinkage suppression layer and dispersed uniformly at least in a principal surface direction. The shrinkage suppression layer provides sufficient restraining performance to the base material layer in the step of firing, and after the firing, forms open bores, thereby improving the removal performance of the shrinkage suppression layer.
摘要翻译：根据非收缩方法用于制造陶瓷基板的收缩抑制层在充分确保收缩抑制层的约束性能的同时提供了良好的去除性能。在低于烧结温度的基材层的烧结温度下消失的树脂珠在收缩抑制层中加入到收缩抑制层中，并至少均匀地分散在主表面方向。收缩抑制层在烧成工序中对基材层提供足够的抑制性能，烧成后形成开口孔，从而提高收缩抑制层的除去性能。

24. 发明授权

US06448195B2 Composition for ceramic substrate and ceramic circuit component 有权
标题翻译：陶瓷基板和陶瓷电路元件的组成
公开(公告)号：US06448195B2
公开(公告)日：2002-09-10
申请号：US09930010
申请日：2001-08-15
申请人： Kazuo Kishida , Akira Shiratori , Osamu Yokokura , Hiroshi Takagi
发明人： Kazuo Kishida , Akira Shiratori , Osamu Yokokura , Hiroshi Takagi
IPC分类号： C03C100
CPC分类号： C04B35/111 , C03C8/14 , C03C14/004 , H01L23/15 , H01L2924/0002 , H01L2924/09701 , H05K1/0306 , Y10S428/901 , Y10T428/24917 , Y10T428/24926 , H01L2924/00
摘要： There is disclosed a composition for a ceramic substrate comprising a mixture of: powdered borosilicate-based glass comprising about 5% to 17.5% by weight of B2O3, about 28% to 44% by weight of SiO2, 0% to about 20% by weight of Al2O3, and about 36% to 50% by weight of MO (where MO is at least one selected from the group consisting of CaO, MgO, and BaO), and a powdered ceramic; in which the amount of the powdered borosilicate-based glass is about 40% to 49% by weight based on the total amount of the composition for a ceramic substrate, and the amount of the powdered ceramic is about 60% to 51% by weight based on the total amount of the composition for a ceramic substrate.
摘要翻译：公开了一种用于陶瓷基材的组合物，其包含以下混合物：粉末状硼硅酸盐玻璃，其包含约5％至17.5％重量的B 2 O 3，约28％至44％重量的SiO 2，0重量％至约20重量％的Al 2 O 3和约36〜50重量％的MO（其中MO是选自CaO，MgO和BaO中的至少一种）和陶瓷粉末; 其中基于陶瓷基材的组合物的总量，硼硅酸玻璃粉末的量为约40重量％至49重量％，并且粉末状陶瓷的量为约60重量％至51重量％关于陶瓷基材的组合物的总量。

25. 发明授权

US06265090B1 Electrically conductive paste ceramic multi-layered substrate 有权
标题翻译：导电胶陶瓷多层基板
公开(公告)号：US06265090B1
公开(公告)日：2001-07-24
申请号：US09326496
申请日：1999-06-04
申请人： Mitsuyoshi Nishide , Kazuo Kishida
发明人： Mitsuyoshi Nishide , Kazuo Kishida
IPC分类号： B32B900
CPC分类号： H01L23/49883 , B22F1/02 , H01L2924/0002 , H01L2924/09701 , H01L2924/15192 , H05K1/092 , H05K3/4629 , Y10T428/2991 , H01L2924/00
摘要： Provided is an electrically conductive paste adapted to be sintered at the same time when a ceramic body is being sintered, wherein said paste has a contraction starting temperature that is higher than the contraction ending temperature of said ceramic body during the sintering treatment. Also provided is an electrically conductive paste comprising an electrically conductive component and an organic vehicle component, wherein said electrically conductive component comprises an electrically conductive powder mainly comprising silver, the particles of said electrically conductive powder being coated with a metal oxide having a melting point higher than that of silver.
摘要翻译：本发明提供一种适于在烧结陶瓷体的同时烧结的导电膏，其中所述糊料的收缩起始温度高于烧结处理期间所述陶瓷体的收缩结束温度。还提供了包含导电组分和有机载体组分的导电糊，其中所述导电组分包括主要包含银的导电粉末，所述导电粉末的颗粒被熔点高的金属氧化物涂覆比银。

26. 发明授权

US5132362A Thermoplastic resin composition 失效
公开(公告)号：US5132362A
公开(公告)日：1992-07-21
申请号：US500462
申请日：1990-03-28
申请人： Kazuo Kishida , Kohji Matsumoto , Masaaki Mohri
发明人： Kazuo Kishida , Kohji Matsumoto , Masaaki Mohri
IPC分类号： C08L51/04 , C08F279/02 , C08L67/02 , C08L69/00 , C08L101/00
CPC分类号： C08F279/02 , C08L101/00 , C08L67/02 , C08L69/00
摘要： Disclosed is a thermoplastic resin composition of an enhanced impact strength comprising 100 parts by weight of a thermoplastic resin and 2 to 50 parts by weight of a graft copolymer (A) obtained by emulsion-graft-polymerizing a monomer mixture comprised of a major amount of an acrylic monomer and a minor amount of a monomer selected from aromatic vinyl monomers and vinyl cyanide monomers in the presence of 60 to 90% by weight (as solids), based on the weight of the graft copolymer (A), of a diene type rubber latex containing more than 50% by weight of a diene type rubber polymer having a weight average particle diameter of at least 0.3 .mu.m.

27. 发明授权

US5064906A Thermoplastic resin compositions having excellent impact resistance, weather resistance and moldability, and process for preparing the same 失效
标题翻译：具有优异的耐冲击性，耐候性和可塑性的热塑性树脂组合物及其制备方法
公开(公告)号：US5064906A
公开(公告)日：1991-11-12
申请号：US405428
申请日：1989-08-28
申请人： Kazuo Kishida , Yutaka Toyooka , Haruyoshi Kitahara
发明人： Kazuo Kishida , Yutaka Toyooka , Haruyoshi Kitahara
IPC分类号： C08F285/00 , C08L51/00
CPC分类号： C08L51/00 , Y10S525/902
摘要： Disclosed is a graft copolymer resin prepared by graft polymerizing a vinyl compound onto a composite-structured acrylic rubber whose particles are composed of a core consisting of a diene rubber enlarged by treatment with an acid group-containing copolymer latex, and an outer layer consisting of an acrylate polymer having a crosslinked structure formed by the combined use of a graft-linking agent and a cross-linking agent. This graft copolymer resin may be blended with a rigid thermoplastic resin in a specific proportion. This resin composition imparts a good gloss to the molded articles formed therefrom, while retaining excellent impact resistance and weather resistance.

28. 发明授权

US4755559A Thermoplastic resin composition of a polycarbonate and a vinyl aromatic-vinyl cyanide monomers/diene rubber graft copolymer 失效
标题翻译：聚碳酸酯和乙烯基芳族 - 乙烯基氰单体/二烯橡胶接枝共聚物的热塑性树脂组合物
公开(公告)号：US4755559A
公开(公告)日：1988-07-05
申请号：US806467
申请日：1985-12-09
申请人： Kazuo Kishida , Hiroshi Kawasaki , Hideyuki Shigemitsu
发明人： Kazuo Kishida , Hiroshi Kawasaki , Hideyuki Shigemitsu
IPC分类号： C08L51/00 , C08F279/02 , C08L7/00 , C08L21/00 , C08L25/00 , C08L25/12 , C08L33/00 , C08L33/02 , C08L51/02 , C08L51/04 , C08L55/02 , C08L69/00
CPC分类号： C08L51/04 , C08L25/12 , C08L55/02 , C08L69/00
摘要： A thermoplastic resin composition comrpising:(A) from 5 to 50 parts by weight of a graft copolymer obtained by graft polymerizing from 20 to less than 40 parts by weight of monomers comprising from 20 to 80% by weight of an .alpha.-alkyl aromatic vinyl monomer, from 3 to 40% by weight of an aromatic vinyl monomer containing no .alpha.-alkyl aromatic vinyl monomer, from 15 to 40% by weight of a vinyl cyanide monomer and from 0 to 35% by weight of a vinyl monomer copolymerizable with these monomers, to from more than 60 to 80 parts by weight of a diene rubber-like polymer, the total amount of the monomers and the rubber-like polymer being 100 parts by weight;(B) from 0 to 60 parts by weight of a copolymer obtained by polymerizing from 60 to 90% by weight of an aromatic vinyl monomer, from 10 to 40% by weight of a vinyl cyanide monomer and from 0 to 30% by weight of a vinyl monomer copolymerizable with these monomers; and(C) from 15 to 80 parts by weight of a polycarbonate resin;the total amount of components (A), (B) and (C) being 100 parts by weight. The composition is useful for making molded products.
摘要翻译：一种热塑性树脂组合物，其包括：（A）5至50重量份的接枝共聚物，所述接枝共聚物通过接枝聚合20至少于40重量份的包含20至80重量％的α-烷基芳族乙烯基单体，3至40重量％的不含α-烷基芳族乙烯基单体的芳族乙烯基单体，15至40重量％的乙烯基氰单体和0至35重量％可与其共聚的乙烯基单体单体，从多于60〜80重量份的二烯橡胶状聚合物，单体和橡胶状聚合物的总量为100重量份; （B）0至60重量份通过聚合60至90重量％的芳族乙烯基单体，10至40重量％的乙烯基氰单体和0至30重量％可与这些单体共聚的乙烯基单体; 和（C）15〜80重量份的聚碳酸酯树脂; 组分（A），（B）和（C）的总量为100重量份。该组合物可用于制备模塑产品。

29. 发明授权

US4556692A Thermoplastic resin composition having excellent impact resistance and heat resistance 失效
标题翻译：热塑性树脂组合物具有优良的耐冲击性和耐热性
公开(公告)号：US4556692A
公开(公告)日：1985-12-03
申请号：US676810
申请日：1984-11-30
申请人： Kazuo Kishida , Naoki Yamamoto , Yasumasa Sato
发明人： Kazuo Kishida , Naoki Yamamoto , Yasumasa Sato
IPC分类号： C08L25/16 , C08L51/00 , C08L51/04 , C08F265/02
CPC分类号： C08L25/16 , C08L51/003 , C08L51/04
摘要： A thermoplastic resin composition having excellent impact resistance and heat resistance which comprises 5 to 95% by weight of a graft copolymer (I) obtained by polymerizing 93 to 30 parts by weight of a monomer or a monomer mixture for grafting comprising 30 to 100% by weight of at least one monomer selected from the group consisting of styrene, .alpha.-methylstyrene, acrylonitrile and methyl methacrylate and 0 to 70% by weight of at least one copolymerizable monomer having CH.sub.2 .dbd.C
摘要翻译：具有优异的耐冲击性和耐热性的热塑性树脂组合物包含5至95重量％的通过将93至30重量份的单体或用于接枝的单体混合物聚合而获得的接枝共聚物（I），其包含30至100％至少一种选自苯乙烯，α-甲基苯乙烯，丙烯腈和甲基丙烯酸甲酯的单体的重量和0-70％重量的至少一种可共聚的单体，其中R 2为C < 通过加入0.1至5重量份（以固体计）含酸基共聚物（B）胶乳获得的粒径为至少0.2μm的附聚颗粒的橡胶胶乳的重量（以固体计）得自3至30重量％的含酸基单体，97至35重量％的至少一种在烷基中具有1至12个碳原子的丙烯酸烷基酯和0至48重量％的至少一种单乙烯基单体可共聚（100重量％）相对于100重量份（以固体计）的100重量份（重量）固体成分的100〜50重量％丁二烯和0至50重量％的其它可共聚的CH 2 = C <基团的单体（总共100重量％）; 95〜5重量％的通过聚合α-甲基苯乙烯和至少一种其它可共聚的CH 2 = C <基团的单体获得的热塑性树脂（II）; 和0〜50重量％的不含α-甲基苯乙烯单元的其它热塑性树脂（III），所述组分（I），（II）和（III）配混以使所述丁二烯橡胶（A）的含量在整个组合物的总重量为3〜40重量％，α-甲基苯乙烯单元的含量为10〜75重量％。

30. 发明授权

US4528330A Resin composition usable without being coated 失效
标题翻译：可涂覆的树脂组合物
公开(公告)号：US4528330A
公开(公告)日：1985-07-09
申请号：US438264
申请日：1982-11-01
申请人： Kazuo Kishida , Akira Hasegawa , Yasunori Kawachi , Hiroshi Kawasaki , Hiroshi Mizukoshi
发明人： Kazuo Kishida , Akira Hasegawa , Yasunori Kawachi , Hiroshi Kawasaki , Hiroshi Mizukoshi
IPC分类号： C08F285/00 , C08L7/00 , C08L21/00 , C08L33/00 , C08L33/02 , C08L33/04 , C08L33/06 , C08L51/00 , C08L51/02 , C08L51/06
CPC分类号： C08L33/06 , C08F285/00 , C08L51/003 , C08L51/00 , Y10S525/902
摘要： Disclosed is a resin composition which is usable for an exterior article without being coated on its surface when molded into the article and is excellent in the color tone and has good impact resistance and weatherability, said composition comprising (I) 10 to 70% by weight of a high-rubber-content graft polymer obtained by polymerizing 50 to 10% by weight of a monomer mixture (C) comprising 10 to 90% by weight of at least one aromatic vinyl monomer and 90 to 10% by weight of at least one ethylenically unsaturated monomer represented by the following general formula:CH.sub.2 .dbd.CRXwherein R stands for a hydrogen atom or methyl group, and X stands for a group --CN or --COOR.sub.1 in which R.sub.1 stands for an alkyl group having 1 to 8 carbon atoms,in the presence of a latex of a multi-layer crosslinked acrylic rubber particles containing 5 to 30% by weight of a rigid crosslinked resin (A) having a core particle size of 0.15 to 0.45.mu. in the interior of the rubber particles and 45 to 85% by weight of a crosslinked acrylic acid ester polymer (B) comprising an acrylic acid ester as the main component in the outer layer of the rubber particles, so that the total amount of the components (A), (B) and (C) is 100% by weight, (II) 90 to 30% by weight of a thermoplastic resin obtained by polymerizing at least one alkyl acrylate or methacrylate represented by the following general formula:CH.sub.2 .dbd.CRCOOR.sub.1wherein R stands for a hydrogen atom or methyl group, and R.sub.1 stands for an alkyl group having 1 to 8 carbon atoms,in an amount of at least 90% by weight, and (III) 0 to 50% by weight of a diene type rubber-containing thermoplastic resin, the sum of the amounts of the components (I), (II) and (III) being 100% by weight.

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