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    • 22. 发明授权
    • System and method for adsorbing contaminants and regenerating the
adsorber
    • 用于吸附污染物和再生吸附剂的系统和方法
    • US5658372A
    • 1997-08-19
    • US500078
    • 1995-07-10
    • Kishor P. Gadkaree
    • Kishor P. Gadkaree
    • B01D53/04
    • B01D53/02B01D2253/102B01D2253/308B01D2253/342B01D2253/3425B01D2257/108B01D2257/504B01D2257/70B01D2257/7022B01D2257/7027B01D2259/40086B01D2259/41Y02C10/08
    • A system for adsorbing a plurality of contaminants from a workstream composed of a first stage open-ended activated carbon monolith adsorber, a second stage open ended activated carbon monolith adsorber downstream of the first stage. The first stage activated carbon has an average pore size that is larger than the average pore size of the second stage activated carbon. A method for removing more than one contaminant from a workstream which involves passing a workstream containing more than one contaminant through a first open ended activated carbon monolith adsorber having a pore size suitable for adsorbing the major portion of the larger size contaminant and for allowing the smaller size contaminant to pass through the monolith, to cause adsorption of the major portion of the larger size contaminant by the activated carbon, while allowing the smaller size contaminant to pass through the first monolith, and thereafter passing the effluent from the first adsorber through a second open ended activated carbon monolith adsorber having a pore size suitable for adsorbing the smaller size contaminant to cause adsorption of the major portion of the smaller size contaminant by the second monolith activated carbon. The adsorbed contaminants can then be desorbed by passing a regenerating stream(s) through the respective monoliths.
    • 一种用于从由第一级开放式活性炭整料吸附器,第二级开放式活性炭整体式吸附器组成的工作流中吸附多种污染物的系统。 第一级活性炭的平均孔径大于第二级活性炭的平均孔径。 一种用于从工作流中除去多于一种污染物的方法,其涉及使含有多于一种污染物的工作流通过具有适于吸附较大尺寸污染物的主要部分的孔径的第一开放式活性炭整料吸附器,并允许较小的 尺寸的污染物通过整料,以引起活性炭对较大尺寸污染物的主要部分的吸附,同时允许较小尺寸的污染物通过第一整料,然后使来自第一吸附器的流出物通过第二 开放式活性炭整体式吸附器具有适于吸附较小尺寸污染物的孔径,以引起较小尺寸污染物主要部分被第二整体活性炭吸附。 然后可以通过将再生流通过相应的整料来解吸吸附的污染物。
    • 27. 发明授权
    • Dehydroxylation and purification of calcium fluoride materials using a halogen containing plasma
    • 使用含卤素等离子体对氟化钙材料进行脱羟基化和纯化
    • US06982001B2
    • 2006-01-03
    • US10856633
    • 2004-05-28
    • Robert A. BellmanDana C. BookbinderKishor P. GadkareeCynthia B. Giroux
    • Robert A. BellmanDana C. BookbinderKishor P. GadkareeCynthia B. Giroux
    • C30B11/00C30B11/12
    • C01B9/08C01F11/22C30B11/00C30B29/12
    • The invention is directed to a process of purifying metal fluoride materials used to make metal fluoride single crystals suitable for making optical elements used in the transmission of wavelengths below 200 nm, and in particular to a process of purifying such materials by the use of a halogen containing plasma to convert metal oxygenates contaminating the feedstocks used in the preparation of the crystals to metal fluorides. The invention also is directed to a process of growing a metal fluoride single crystal using a crystal growth furnace to carry out the foregoing purification procedure followed by the steps of melting the purified material and cooling it using s selected time and temperature cycle to from a metal fluoride single crystal. The plasmas used in practicing the invention can be derived from a variety of halogenated materials including, for example, fluorocarbons, chlorocarbons, boron trihalides, chlorine, fluorine, xenon difluoride and other gaseous or easily volatilized halogenated substances known in the art.
    • 本发明涉及一种净化金属氟化物材料的方法,所述金属氟化物材料用于制备适于制造用于波长低于200nm的透射体的光学元件的金属氟化物单晶,并且特别涉及一种通过使用卤素 将等离子体转化成金属氧化物,将用于制备晶体的原料污染成金属氟化物。 本发明还涉及使用晶体生长炉生长金属氟化物单晶的方法,以执行上述纯化程序,然后是将精制材料熔化并使用选定的时间和温度循环冷却至金属 氟化物单晶。 用于实施本发明的等离子体可以衍生自各种卤化物质,包括例如碳氟化合物,氯代烃,三卤化硼,氯,氟,氙二氟化物以及本领域已知的其它气态或易挥发的卤化物质。
    • 30. 发明授权
    • Method of making activated carbon bodies having improved adsorption properties
    • 制备具有改善吸附性能的活性炭体的方法
    • US06187713B1
    • 2001-02-13
    • US09231860
    • 1999-01-14
    • Kishor P. Gadkaree
    • Kishor P. Gadkaree
    • C01B3112
    • B01J20/3234B01J20/0266B01J20/20B01J2220/42C01B32/336C01B32/382
    • An activated carbon body and method of making the body which involves providing an inorganic substrate, thermosetting resin, and an adsorption enhancing additive which can be sulfur and/or oil which is non-miscible with and non-reactive with the carbon precursor, contacting the inorganic substrate with the carbon precursor and the adsorption enhancing additive to coat the substrate therewith, curing and carbonizing the carbon precursor, and activating the carbon to produce a coating of activated carbon on the substrate and form the activated carbon body. Another method involves forming a mixture of thermosetting resin, adsorption enhancing additive, which can be sulfur, phosphoric acid, and/or the oil, temporary organic binder, optional forming aid, and fillers, shaping the mixture into a body, followed by curing, carbonizing, and activating to produce a shaped body of activated carbon. When sulfur is utilized, a sulfur-carbon bond forms that is characterized by a peak at 165.9 eV when analyzed by Electron Spectroscopy for Chemical Analysis.
    • 一种活性炭体及其制造方法,其包括提供无机基质,热固性树脂和吸附增强添加剂,其可以是与碳前体不可混溶且不与碳前体反应的硫和/或油, 无机底物与碳前体和吸附增强添加剂一起涂覆底物,固化和碳化碳前体,并活化碳以在基材上生成活性炭涂层并形成活性炭体。 另一种方法包括形成热固性树脂,吸附增强添加剂,其可以是硫,磷酸和/或油,临时有机粘合剂,任选的成型助剂和填料的混合物,将混合物成型成体,然后固化, 碳化和活化以产生活性炭的成形体。 当使用硫时,形成硫 - 碳键,其特征在于在165.9eV的峰值,当通过电子能谱化学分析进行分析时。