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21. 发明授权

US07268196B2 Process for producing cycloolefin addition polymer 有权
标题翻译：制备环烯加成聚合物的方法
公开(公告)号：US07268196B2
公开(公告)日：2007-09-11
申请号：US11620202
申请日：2007-01-05
申请人： Noboru Oshima , Michitaka Kaizu , Satoshi Ebata , Takashi Imamura
发明人： Noboru Oshima , Michitaka Kaizu , Satoshi Ebata , Takashi Imamura
IPC分类号： C08F4/70 , C08F32/00
CPC分类号： C08F232/08 , C08F32/08
摘要： A process for producing a cycloolefin addition polymer in which one or more cycloolefin monomers can be (co)polymerized by addition polymerization with a small palladium catalyst amount to produce a cycloolefin addition (co)polymer while attaining high catalytic activity. The process for cycloolefin addition polymer production is characterized by addition-polymerizing one or more cycloolefin monomers comprising a cycloolefin compound represented by a specific formula in the presence of a multi-component catalyst comprising (a) a palladium compound and (b) a specific phosphorus compound.
摘要翻译：一种制备环烯加成聚合物的方法，其中一种或多种环烯烃单体可以通过加成聚合以小的钯催化剂量进行（共）聚合，从而产生环烯烃加成（共）聚合物同时达到高催化活性。环烯烃加成聚合物制备方法的特征在于在多组分催化剂存在下，加入聚合一种或多种环烯烃单体，所述环烯烃单体包括由特定式表示的环烯烃化合物，其包含（a）钯化合物和（b）特定磷复合。

22. 发明申请

US20070155922A1 Process for producing cycloolefin addition polymer 审中-公开
标题翻译：制备环烯加成聚合物的方法
公开(公告)号：US20070155922A1
公开(公告)日：2007-07-05
申请号：US10581525
申请日：2004-11-30
申请人： Satoshi Ebata , Michitaka Kaizu , Noboru Oshima
发明人： Satoshi Ebata , Michitaka Kaizu , Noboru Oshima
IPC分类号： C08F4/80
CPC分类号： C08F32/00
摘要： [Means to solve problems] The process for preparing a cycloolefin addition polymer comprises addition-polymerizing monomers containing a specific cycloolefin compound in the presence of ethylene and a multicomponent catalyst containing, as essential components, (a) a palladium compound, (b) a compound selected from an ionic boron compound, an ionic aluminum compound, a Lewis acidic aluminum compound and a Lewis acidic boron compound and (c) a specific phosphine compound or its phosphonium salt. [Effect] A cycloolefin compound is addition-polymerized using a specific palladium catalyst and using ethylene as a molecular weight modifier, whereby a cycloolefin addition polymer having a molecular weight preferable for a sheet or a film used for an optical material can be prepared using small amounts of the molecular weight modifier and the palladium catalyst.
摘要翻译：解决问题的手段制备环烯加成聚合物的方法包括在乙烯存在下加入聚合含有特定环烯烃化合物的单体和含有（a）钯化合物作为必要组分的多组分催化剂，（b）选自离子性硼化合物，离子型铝化合物，路易斯酸性铝化合物和路易斯酸性硼化合物的化合物和（c）特定膦化合物或其鏻盐。 [效果]环烯烃化合物使用特定的钯催化剂进行加成聚合，使用乙烯作为分子量调节剂，由此可以使用小型的用于光学材料的片材或膜的分子量优选的环烯加成聚合物量的分子量调节剂和钯催化剂。

23. 发明授权

US07112460B2 Semiconductor laser device, production method therefor, and jig for use in the production method 有权
标题翻译：半导体激光装置及其制造方法以及用于制造方法的夹具
公开(公告)号：US07112460B2
公开(公告)日：2006-09-26
申请号：US10731081
申请日：2003-12-08
申请人： Noboru Oshima
发明人： Noboru Oshima
IPC分类号： H01L21/00
CPC分类号： H01S5/028 , H01S5/0281 , H01S5/0425 , H01S5/16
摘要： A semiconductor laser device includes a semiconductor substrate on which a semiconductor thin film including an active layer is lamineted, a pair of electrodes respectively provided on opposite faces of the substrate, a light emitting surface defined on a side face of the substrate to which the active layer and an edge of at least one of the electrodes are exposed, and a protective film covering the light emitting surface. The protective film has a smaller thickness on the edge of the electrode than on the active layer. This arrangement makes it possible to suppress diffusion of an electrode material in the protective film and sufficiently protect the light emitting surface.
摘要翻译：半导体激光装置包括：半导体基板，其上层叠有包括有源层的半导体薄膜，分别设置在基板的相对面上的一对电极，限定在基板的侧面上的发光面，活性物质并且暴露出至少一个电极的边缘，以及覆盖发光表面的保护膜。保护膜在电极边缘上比在有源层上具有更小的厚度。由此，能够抑制保护膜内的电极材料的扩散，充分保护发光面。

24. 发明授权

US07015293B2 Cycloolefin addition copolymer and optical transparent material 有权
标题翻译：环烯烃加成共聚物和光学透明材料
公开(公告)号：US07015293B2
公开(公告)日：2006-03-21
申请号：US10515189
申请日：2003-05-14
申请人： Noboru Oshima , Tatsuya Sakai , Kenzo Ohkita , Takashi Tsubouchi
发明人： Noboru Oshima , Tatsuya Sakai , Kenzo Ohkita , Takashi Tsubouchi
IPC分类号： C08F232/08
CPC分类号： C08F232/08 , C08F8/04 , Y10T428/31663 , Y10T428/31938
摘要： A cyclic olefin addition copolymer obtained by copolymerizing a cyclic olefin compound having a side chain substituent group with a ring structure, such as endo-tricyclo[4.3.0.12,5]deca-3,7-diene or endo-tricyclo[4.3.0.12,5]deca-3-ene, with another cyclic olefin compound such as bicyclo[2.2.1]hept-2-ene, and further with a cyclic olefin compound having a hydrolysable silyl group as needed, or hydrogenating after copolymerization; a composition for crosslinking in which a specific crosslinking agent is incorporated; a crosslinked product obtained by crosslinking the composition; an optical material containing the copolymer, the composition or the crosslinked product; and a method for producing the copolymer in which addition polymerization is conducted using a specific nickel catalyst.
摘要翻译：通过使具有侧链取代基的环状烯烃化合物与环结构共聚获得的环状烯烃加成共聚物，例如内三环[4.3.0.1 2,5]癸-3,7-二烯或内三环[4.3.0.1 2,5]癸-3-烯与另一种环状烯烃化合物如双环[2.2.1]庚-2-烯，还有环烯烃需要时具有可水解甲硅烷基的化合物，或共聚后氢化; 其中掺入特定交联剂的交联用组合物; 通过交联组合物获得的交联产物; 含有共聚物，组合物或交联产物的光学材料; 以及使用特定的镍催化剂进行加成聚合的共聚物的制造方法。

25. 发明授权

US06911507B2 Processes for producing cycloolefin addition polymer 有权
标题翻译：制备环烯加成聚合物的方法
公开(公告)号：US06911507B2
公开(公告)日：2005-06-28
申请号：US10466429
申请日：2001-01-23
申请人： Kenzo Ohkita , Noboru Oshima , Takashi Imamura , Takashi Tsubouchi
发明人： Kenzo Ohkita , Noboru Oshima , Takashi Imamura , Takashi Tsubouchi
IPC分类号： C08F2/38 , C08F4/70 , C08F32/00
CPC分类号： C08F32/00 , Y10S526/903
摘要： A cyclic olefin having a specific polar group is polymerized by addition polymerization in a hydrocarbon solvent, using a polymerization catalyst component containing (i) a specific transition metal compound, (ii) a Lewis acid compound and (iii) an alkyl aluminoxane, or the cyclic olefin is polymerized by addition polymerization in the hydrocarbon solvent, using the polymerization catalyst component, by further adding at least one aromatic vinyl compound and at least one cyclic nonconjugated polyene compound, or either one of them as a molecular weight modifier, thereby obtaining a cyclic olefinic addition polymer.
摘要翻译：使用含有（i）特定的过渡金属化合物，（ii）路易斯酸化合物和（iii）烷基铝氧烷的聚合催化剂组分的聚合催化剂组分，通过在烃溶剂中进行加成聚合来使具有特定极性基团的环状烯烃聚合，或通过进一步添加至少一种芳族乙烯基化合物和至少一种环状非共轭多烯化合物或其中任一种作为分子量调节剂，通过在烃溶剂中的加成聚合使用聚合催化剂组分使环烯烃聚合，得到环烯烃加成聚合物。

26. 发明申请

US20050111506A1 Semiconductor laser element and manufacturing method for the same 有权
标题翻译：半导体激光元件及其制造方法相同
公开(公告)号：US20050111506A1
公开(公告)日：2005-05-26
申请号：US10995780
申请日：2004-11-22
申请人： Masayuki Ohta , Takahiro Hashimoto , Yoshinori Ohitsu , Hiroyuki Tsujii , Satofumi Kinei , Noboru Oshima , Shinji Kaneiwa
发明人： Masayuki Ohta , Takahiro Hashimoto , Yoshinori Ohitsu , Hiroyuki Tsujii , Satofumi Kinei , Noboru Oshima , Shinji Kaneiwa
IPC分类号： H01S5/00 , H01S5/042 , H01S5/22 , H01S5/223
CPC分类号： H01S5/2231 , H01S5/0425 , H01S5/2214 , H01S2304/04
摘要： A semiconductor laser element comprising: a clad layer of a first conductivity type; an active layer; a first clad layer of a second conductivity type; a ridge made of a second clad layer of the second conductivity type and a cap layer of the second conductivity type, which are layered on the first clad layer of the second conductivity type, in this order starting from the first clad layer side; a dielectric film formed on ridge sides other than a top portion of the ridge; and a metal electrode layer that covers the ridge, wherein the width of the bottom of the cap layer and the width of the top surface of the second clad layer are approximately equal.
摘要翻译：一种半导体激光元件，包括：第一导电类型的覆层; 活性层第二导电类型的第一覆盖层; 从第一覆盖层侧开始依次层叠在第二导电类型的第一覆盖层上的由第二导电类型的第二包层和第二导电类型的覆盖层制成的脊; 形成在所述脊的顶部以外的脊侧上的电介质膜; 以及覆盖所述脊的金属电极层，其中所述盖层的底部的宽度和所述第二包层的顶表面的宽度近似相等。

27. 发明授权

US06732540B2 Air conditioning plant and control method thereof 有权
标题翻译：空调厂及其控制方法
公开(公告)号：US06732540B2
公开(公告)日：2004-05-11
申请号：US10322606
申请日：2002-12-19
申请人： Yoshibumi Sugihara , Yuuji Miyajima , Takumi Sugiura , Hiroo Sakai , Noboru Oshima , Tadakatsu Nakajima , Hiroshige Kikuchi
发明人： Yoshibumi Sugihara , Yuuji Miyajima , Takumi Sugiura , Hiroo Sakai , Noboru Oshima , Tadakatsu Nakajima , Hiroshige Kikuchi
IPC分类号： F25D1700
CPC分类号： F24F11/30 , F24F11/47 , F24F11/62 , F24F2110/12
摘要： Provided are an air conditioning plant control method by which an air conditioning plant can be operated in a most desirable state, and an air conditioning plant so controlled. An air conditioning plant is controlled, which has at least one air conditioner, a refrigerating machine supplying cold water to the air conditioner and a cooling tower supplying cooling water to the refrigerating machine. Within an extent satisfying set conditions of air conditioning, setpoints of the draft temperature of the at least one air conditioner, the cold water temperature of the refrigerating machine and the temperature of cooling water from the cooling tower are altered and optimized so as to minimize energy consumption, operating cost or carbon dioxide emission of the air conditioning plant.
摘要翻译：提供一种空调设备控制方法，通过该方法可以使空调设备以最理想的状态运行，并且如此控制的空调设备。控制空调设备，其至少有一个空调器，向空调机供应冷水的制冷机和向冷藏机供应冷却水的冷却塔。在满足空调的设定条件的范围内，改变和优化至少一个空调的通风温度设定值，冷冻机的冷水温度和冷却水的冷却水的温度，以使能量最小化空调厂的消耗，运行成本或二氧化碳排放量。

28. 发明授权

US5206301A Hydrogenated block copolymer and composition comprising the same 失效
标题翻译：加氢嵌段共聚物及其组合物
公开(公告)号：US5206301A
公开(公告)日：1993-04-27
申请号：US536564
申请日：1990-07-12
申请人： Iwakazu Hattori , Noboru Oshima , Tooru Shibata , Yasuo Takeuchi
发明人： Iwakazu Hattori , Noboru Oshima , Tooru Shibata , Yasuo Takeuchi
IPC分类号： C08L23/02 , C08F8/04 , C08F8/46 , C08F297/04 , C08L53/00 , C08L53/02 , C08L101/00
CPC分类号： C08L53/025 , C08F297/04 , C08F8/04 , C08L101/00 , Y10S525/904 , Y10S525/914
摘要： A hydrogenated block copolymer having a number-average molecular weight of 40,000-700,000, obtained by hydrogenating at least 80% of the olefinic bonds of a block copolymer having in the molecule at least one each ofa polymer block A composed of 90% by weight or more of a vinyl aromatic compound,a polybutadiene polymer block B having a 1,2-vinyl structure of 30-70%, anda polybutadiene polymer block C having a 1,2-vinyl structure of less than 30%,in which block copolymer the blocks A, B and C are contained at a specific ratio, or a unit of the block copolymer is bonded, via a coupling agent residue, to at least one polymer block unit of the blocks A, B and C and thereby the polymer molecular chain is extended or branched; and a thermoplastic resin composition comprising the hydrogenated block copolymer.
摘要翻译： PCT No.PCT / JP89 / 01157 Sec。 371日期1990年7月12日 102（e）日1990年7月12日PCT 1989年11月14日PCT PCT。 WO90 / 05753 PCT出版物日本1990年5月31日。一种数均分子量为40,000-700,000的氢化嵌段共聚物，其通过氢化至少80％的分子中具有至少一种聚合物嵌段A的嵌段共聚物的烯键由乙烯基芳族化合物的90重量％以上，1,2-乙烯基结构为30〜70摩尔的聚丁二烯聚合物嵌段B和1,2-乙烯基结构的聚丁二烯聚合物嵌段C小于 30％，其中嵌段A，B和C以特定比例包含或嵌段共聚物的单元通过偶联剂残基键合至块A，B的至少一个聚合物嵌段单元和C，从而使聚合物分子链延伸或分支; 和包含氢化嵌段共聚物的热塑性树脂组合物。

29. 发明授权

US5011888A Vulcanized rubber composition 失效
标题翻译：硫化橡胶组合物
公开(公告)号：US5011888A
公开(公告)日：1991-04-30
申请号：US449308
申请日：1989-12-06
申请人： Fumio Tsutsumi , Akihiko Morikawa , Mitsuhiko Sakakibara , Noboru Oshima , Tatsuro Hamada , Tatsuo Fujimaki , Masayuki Ohashi
发明人： Fumio Tsutsumi , Akihiko Morikawa , Mitsuhiko Sakakibara , Noboru Oshima , Tatsuro Hamada , Tatsuo Fujimaki , Masayuki Ohashi
IPC分类号： C08L9/06 , B60C1/00 , C08F297/04 , C08G18/69 , C08L21/00 , C08L53/00 , C08L53/02
CPC分类号： C08L53/02 , B60C1/0016 , C08G18/69 , C08L21/00 , C08G2380/00
摘要： A rubber composition is disclosed which contains not less than 20% by weight in a rubber component of a block copolymer composed of polymer or copolymer block units (A) and a random copolymer block units (B). The polymer or copolymer block units (A) are obtained by singly polymerizing a conjugated diolefine or copolymerizing the conjugated diolefine and a monovinyl aromatic hydrocarbon with use of a lithium initiator and contains not more than 10% by weight of the bound monovinyl aromatic hydrocarbon. The random copolymer block unit (B) are obtained by copolymerizing the conjugated diolefine and the monovinyl aromatic hydrocarbon and contain 15 to 80% by weight of the bound monovinyl aromatic hydrocarbon. In the block copolymer, (i) the block copolymer contains not less than 10% by weight of each of the block units (A) and the block units (B); (ii) the total content of the bound monovinyl aromatic hydrocarbon is from 10 to 40% by weight; (iii) the average content of the vinyl bonds in the conjugated diolefine portions is from 20 to 70%; and (iv) polymerizable terminals of the block copolymer are reacted with an isocyanate compound.
摘要翻译：公开了在由聚合物或共聚物嵌段单元（A）和无规共聚物嵌段单元（B）组成的嵌段共聚物的橡胶组分中不少于20重量％的橡胶组合物。聚合物或共聚物嵌段单元（A）是通过使共轭二烯烃单独聚合或使用锂引发剂共轭共轭二烯和单乙烯基芳族烃而得到的，并且含有不超过10重量％的结合的单乙烯基芳烃。无规共聚物嵌段单元（B）通过使共轭二烯烃和单乙烯基芳族烃共聚而得到，并含有15〜80重量％的结合的单乙烯基芳烃。在嵌段共聚物中，（i）嵌段共聚物含有不少于块单元（A）和嵌段单元（B）的10重量％。（ii）结合的单乙烯基芳烃的总含量为10〜40重量％（iii）共轭二烯烃部分中的乙烯基键的平均含量为20〜70％。和（iv）嵌段共聚物的可聚合端与异氰酸酯化合物反应。

30. 发明授权

US4782119A Rubber composition comprising a styrene-butadiene block copolymer having two kinds of blocks 失效
标题翻译：包含具有两种嵌段的苯乙烯 - 丁二烯嵌段共聚物的橡胶组合物
公开(公告)号：US4782119A
公开(公告)日：1988-11-01
申请号：US769923
申请日：1985-08-27
申请人： Fumio Tsutsumi , Akio Iakashima , Mitsuhiko Sakakibara , Noboru Oshima , Tatsuo Fujimaki , Yoshiyuki Morimoto
发明人： Fumio Tsutsumi , Akio Iakashima , Mitsuhiko Sakakibara , Noboru Oshima , Tatsuo Fujimaki , Yoshiyuki Morimoto
IPC分类号： C08L7/00 , B60C1/00 , C08F297/04 , C08L1/00 , C08L9/06 , C08L21/00 , C08L23/00 , C08L27/00 , C08L51/00 , C08L51/02 , C08L53/00 , C08L53/02 , C08L77/00 , C08L101/00
CPC分类号： B60C1/0016 , C08F297/044 , Y10S525/914
摘要： A rubber composition containing at least 20% by weight of a styrene-butadiene block copolymer consisting of a block (A) and a block (B) characterized in that: (i) the block (A) is a styrene-butadiene copolymer block having the content of styrene of 10-80% by weight and the average content of the vinyl bonds in the butadiene portion of 30-70% by weight; (ii) the block (B) is a polybutadiene block with the average content of the vinyl bonds in the butadiene portion being not more than 60% by weight (iii) the styrene-butadiene block copolymer contains at least 20% by weight of each of the block (A) and the block (B); (iv) the average content of the vinyl bonds in the butadiene portion of the block (A) is greater by at least 5% by weight than that of the block (B); (v) the glass transition temperature of the block (A) is higher by at least 30.degree. C. than that of the block (B); (vi) the whole content of the bound styrene in the above block copolymer is 5-40% by weight; (vii) the ratio Mw/Mn between the weight average molecular weight Mw and the number average molecular weight Mn of the block copolymer is 1.8-5.0 when calculated as polystyrene according to the gel permeation chromatogram; and (viii) the Mooney's viscosity (ML.sub.1+4.sup.100.degree. C.) of the block copolymer is 20-150.
摘要翻译：一种含有至少20重量％由嵌段（A）和嵌段（B）组成的苯乙烯 - 丁二烯嵌段共聚物的橡胶组合物，其特征在于：（i）嵌段（A）是苯乙烯 - 丁二烯共聚物嵌段，其具有苯乙烯含量为10-80重量％，丁二烯部分中乙烯基键的平均含量为30-70重量％; （ii）嵌段（B）是丁二烯部分中乙烯基键的平均含量不大于60重量％的聚丁二烯嵌段（iii）苯乙烯 - 丁二烯嵌段共聚物含有至少20重量％（A）和块（B）; （iv）嵌段（A）的丁二烯部分中的乙烯基键的平均含量比块（B）的平均含量高至少5重量％。（v）嵌段（A）的玻璃化转变温度比嵌段（B）的玻璃化转变温度高至少30℃; （vi）上述嵌段共聚物中的结合苯乙烯的全部含量为5-40重量％（vii）根据凝胶渗透色谱法计算，当以聚苯乙烯计算时，嵌段共聚物的重均分子量Mw与数均分子量Mn之比Mw / Mn为1.8-5.0; 和（viii）嵌段共聚物的门尼粘度（ML1 + 4100℃）为20-150℃。

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