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1. 发明授权

US5206301A Hydrogenated block copolymer and composition comprising the same 失效
标题翻译：加氢嵌段共聚物及其组合物
公开(公告)号：US5206301A
公开(公告)日：1993-04-27
申请号：US536564
申请日：1990-07-12
申请人： Iwakazu Hattori , Noboru Oshima , Tooru Shibata , Yasuo Takeuchi
发明人： Iwakazu Hattori , Noboru Oshima , Tooru Shibata , Yasuo Takeuchi
IPC分类号： C08L23/02 , C08F8/04 , C08F8/46 , C08F297/04 , C08L53/00 , C08L53/02 , C08L101/00
CPC分类号： C08L53/025 , C08F297/04 , C08F8/04 , C08L101/00 , Y10S525/904 , Y10S525/914
摘要： A hydrogenated block copolymer having a number-average molecular weight of 40,000-700,000, obtained by hydrogenating at least 80% of the olefinic bonds of a block copolymer having in the molecule at least one each ofa polymer block A composed of 90% by weight or more of a vinyl aromatic compound,a polybutadiene polymer block B having a 1,2-vinyl structure of 30-70%, anda polybutadiene polymer block C having a 1,2-vinyl structure of less than 30%,in which block copolymer the blocks A, B and C are contained at a specific ratio, or a unit of the block copolymer is bonded, via a coupling agent residue, to at least one polymer block unit of the blocks A, B and C and thereby the polymer molecular chain is extended or branched; and a thermoplastic resin composition comprising the hydrogenated block copolymer.
摘要翻译： PCT No.PCT / JP89 / 01157 Sec。 371日期1990年7月12日 102（e）日1990年7月12日PCT 1989年11月14日PCT PCT。 WO90 / 05753 PCT出版物日本1990年5月31日。一种数均分子量为40,000-700,000的氢化嵌段共聚物，其通过氢化至少80％的分子中具有至少一种聚合物嵌段A的嵌段共聚物的烯键由乙烯基芳族化合物的90重量％以上，1,2-乙烯基结构为30〜70摩尔的聚丁二烯聚合物嵌段B和1,2-乙烯基结构的聚丁二烯聚合物嵌段C小于 30％，其中嵌段A，B和C以特定比例包含或嵌段共聚物的单元通过偶联剂残基键合至块A，B的至少一个聚合物嵌段单元和C，从而使聚合物分子链延伸或分支; 和包含氢化嵌段共聚物的热塑性树脂组合物。

2. 发明授权

US4933401A Catalyst composition for polymerization of conjugated diene and process for producing conjugated diene polymer 失效
标题翻译：用于共轭二烯聚合的催化剂组合物和共轭二烯聚合物的制备方法
公开(公告)号：US4933401A
公开(公告)日：1990-06-12
申请号：US314130
申请日：1989-02-23
申请人： Iwakazu Hattori , Noboru Shimada , Noboru Oshima , Mitsuhiko Sakakibara
发明人： Iwakazu Hattori , Noboru Shimada , Noboru Oshima , Mitsuhiko Sakakibara
IPC分类号： C08F2/06 , C08F4/48 , C08F36/04
CPC分类号： C08F36/04
摘要： A catalyst composition for polymerizing a conjugated diene which comprises the following (a), (b) and (c) components:(a) an organolithium-aluminum compound represented by the formula:LiAlR.sup.1 R.sup.2 R.sup.3 R.sup.4(b) an organobarium-aluminum compound represented by the formula:Ba(AlR.sup.1 R.sup.2 R.sup.3 R.sup.4).sub.2 or Ba[AlR.sup.1 R.sup.2 R.sup.3 (OR.sup.4)].sub.2(c) a lithium alkoxide represented by the formula:LiOR.sup.5 The conjugated diene polymer or copolymer obtained by polymerizing a conjugated diene alone or in combination with other monomer with the above catalyst composition in an inert organic solvent has a high trans-1,4 bond content, a low vinyl bond content and a low cis-1,4 bond content.

3. 发明授权

US5017636A Rubber compositions from modified trans-polybutadiene and rubber for tires 失效
标题翻译：来自改性反式聚丁二烯和轮胎橡胶的橡胶组合物
公开(公告)号：US5017636A
公开(公告)日：1991-05-21
申请号：US521008
申请日：1990-05-10
申请人： Iwakazu Hattori , Noboru Shimada , Noboru Oshima , Mitsuhiko Sakakibara , Hiroshi Mouri , Tatsuo Fujimaki , Tatsuro Hamada
发明人： Iwakazu Hattori , Noboru Shimada , Noboru Oshima , Mitsuhiko Sakakibara , Hiroshi Mouri , Tatsuo Fujimaki , Tatsuro Hamada
IPC分类号： C08C19/44 , C08L15/00
CPC分类号： C08C19/44 , C08L15/00 , C08K3/04 , C08K5/01 , C08K5/09 , C08L7/00 , C08L9/00 , C08L9/06
摘要： A rubber composition for tire having improved processability, wear resistance, rebound resilience and heat build-up comprises 20.about.70 parts by weight of a specified butadiene polymer, 30.about.80 parts by weight of at least one rubber selected from natural rubber, high cis-1,4 polyisoprene rubber and styrene-butadiene copolymer rubber, and 0.about.30 parts by weight of high cis-1,4 polybutadiene and/or low cis-1,4 polybutadiene, and contains 35.about.100 parts by weight of carbon black, 0.about.50 parts by weight of process oil, 0.5.about.5 parts by weight of aliphatic carboxylic acid and 0.1.about.3 parts by weight of sulfur based on 100 parts by weight of the above rubber components.
摘要翻译：具有改善的加工性，耐磨性，回弹性和发热性的轮胎用橡胶组合物包含20重量份指定的丁二烯聚合物，30重量份至少一种选自天然橡胶，高顺式 -1,4-聚异戊二烯橡胶和苯乙烯 - 丁二烯共聚物橡胶，和0分钟30重量份的高顺式-1,4聚丁二烯和/或低顺-1,4聚丁二烯，并含有35重量％的炭黑，0差异基于100重量份的上述橡胶组分，加工油50重量份，0.5重量份脂肪族羧酸和0.1重量份3重量份的硫。

4. 发明授权

US4894409A Rubber composition 失效
标题翻译：橡胶组成
公开(公告)号：US4894409A
公开(公告)日：1990-01-16
申请号：US218797
申请日：1988-07-14
申请人： Noboru Shimada , Iwakazu Hattori , Mitsuhiko Sakakibara , Noboru Oshima , Tatsuro Hamada , Hiromi Fukuoka , Tatsuo Fujimaki
发明人： Noboru Shimada , Iwakazu Hattori , Mitsuhiko Sakakibara , Noboru Oshima , Tatsuro Hamada , Hiromi Fukuoka , Tatsuo Fujimaki
IPC分类号： C08K3/36 , C08C19/44 , C08F4/00 , C08K3/00 , C08L15/00 , C08L21/00
CPC分类号： C08C19/44 , C08L21/00
摘要： A rubber composition comprising not less than 20% by weight of an amino group-containing diene based polymer in a rubber component, and 10 to 100 parts by weight of silica as a filler with respect to 100 parts by weight of the rubber component. The amino group-containing diene based polymer is obtained by polymerizing a monomer or copolymerizing the monomer in an organic solvent in the presence of at least one of an organic alkali metal and an organic alkaline earth metal.
摘要翻译：橡胶组合物，相对于100重量份的橡胶组分，包含不少于20重量％的在橡胶组分中含氨基的二烯基聚合物和10至100重量份作为填料的二氧化硅。含有氨基的二烯系聚合物通过在有机碱金属和有机碱土金属中的至少一种的存在下，使单体聚合或在有机溶剂中共聚而得到。

5. 发明授权

US08362126B2 Functionalized high cis-1,4-polybutadiene prepared using novel functionalizing agents 有权
标题翻译：使用新型官能化剂制备的官能化高顺式-1,4-聚丁二烯
公开(公告)号：US08362126B2
公开(公告)日：2013-01-29
申请号：US12644382
申请日：2009-12-22
申请人： Yoichi Ozawa , H. Jerrold Miller , Koji Masaki , Koichi Morita , Tatsuo Fujimaki , Tetsuya Omura , Takuo Sone , Iwakazu Hattori
发明人： Yoichi Ozawa , H. Jerrold Miller , Koji Masaki , Koichi Morita , Tatsuo Fujimaki , Tetsuya Omura , Takuo Sone , Iwakazu Hattori
IPC分类号： C08K5/13 , C08F36/00
CPC分类号： C08F136/14 , C08C19/00 , C08C19/22 , C08C19/44 , C08F36/04 , C08F136/06 , C08K3/04 , C08K3/045 , C08K3/36 , C08L21/00 , C08L91/00 , C08F4/545 , C08L15/00
摘要： A method for preparing a functionalized polymer comprising the steps of preparing a polymer by polymerizing conjugated diene monomer with a lanthanide-based catalyst, wherein the lanthanide-based catalyst comprises (a) a lanthanide compound, (b) an alkylating agent, and (c) a source of halogen, and reacting the pseudo-living polymer with at least one amide-containing functionalizing agent.
摘要翻译：一种制备官能化聚合物的方法，包括以下步骤：通过使镧系元素基催化剂聚合共轭二烯单体来制备聚合物，其中所述镧系元素基催化剂包含（a）镧系元素化合物，（b）烷基化剂和（c ）卤素源，并使假活性聚合物与至少一种含酰胺官能化试剂反应。

6. 发明授权

US07642322B2 Functionalized high cis-1,4-polybutadiene prepared using novel functionalizing agents 有权
标题翻译：使用新型官能化剂制备的官能化高顺式-1,4-聚丁二烯
公开(公告)号：US07642322B2
公开(公告)日：2010-01-05
申请号：US11216559
申请日：2005-08-31
申请人： Yoichi Ozawa , H. Jerrold Miller , Koji Masaki , Koichi Morita , Tatsuo Fujimaki , Tetsuya Omura , Takuo Sone , Iwakazu Hattori
发明人： Yoichi Ozawa , H. Jerrold Miller , Koji Masaki , Koichi Morita , Tatsuo Fujimaki , Tetsuya Omura , Takuo Sone , Iwakazu Hattori
IPC分类号： C08C19/34 , C08C19/22
CPC分类号： C08F136/14 , C08C19/00 , C08C19/22 , C08C19/44 , C08F36/04 , C08F136/06 , C08K3/04 , C08K3/045 , C08K3/36 , C08L21/00 , C08L91/00 , C08F4/545 , C08L15/00
摘要： A functionalized polymer prepared by a process comprising the steps of preparing a pseudo-living polymer by polymerizing conjugated monomer with a lanthanide-based catalyst, and reacting the pseudo-living polymer with a functionalizing agent defined by the formula (I) A-R1-Z (I) where R1 is a divalent bond or divalent organic group comprising from 0 to about 20 carbon atoms, A is a substituent that will undergo an addition reaction with a pseudo-living polymer, and Z is a substituent that will react or interact with silica or carbon black reinforcing fillers, with the proviso that A, R1, and Z are substituents that will not protonate a pseudo-living polymer.
摘要翻译：通过包括以下步骤制备的官能化聚合物的方法，所述方法包括通过使镧系元素类催化剂与共轭单体聚合制备假活性聚合物，并使假活性聚合物与式（I）A-R1- Z（I）其中R1是二价键或包含0至约20个碳原子的二价有机基团，A是将与假活性聚合物进行加成反应的取代基，Z是将反应或相互作用的取代基具有二氧化硅或炭黑增强填料，条件是A，R 1和Z是不会使假活性聚合物质子化的取代基。

7. 发明申请

US20060106150A1 Block copolymer, rubber composition containing the same and molded product 审中-公开
标题翻译：嵌段共聚物，含有它们的橡胶组合物和模塑产品
公开(公告)号：US20060106150A1
公开(公告)日：2006-05-18
申请号：US11260204
申请日：2005-10-28
申请人： Toshihiro Tadaki , Naokazu Kobayashi , Iwakazu Hattori
发明人： Toshihiro Tadaki , Naokazu Kobayashi , Iwakazu Hattori
IPC分类号： C08K3/34
CPC分类号： C08F297/046 , C08F8/04 , C08F297/04
摘要： An objective of the present invention is to provide a block copolymer which is excellent in processability at the time of preparing a rubber composition and leads to a cross-linked rubber composition excellent in tensile property, wearing resistance, weatherability, ozone resistance and heat aging resistance when it is cross-linked, a rubber composition containing the block copolymer and a molded product. The block copolymer of the present invention comprises two polymer blocks each having an ethylenic unsaturated bond and other polymer block which is interposed between two polymer blocks, has a uniform weight average molecular weight in the range from 5,000 to 100,000. The weight average molecular weight of the polymer block having the ethylenic unsaturated bond is preferably in the range from 1,000 to 20,000.
摘要翻译：本发明的目的是提供一种在制备橡胶组合物时加工性优异并导致拉伸性，耐磨性，耐候性，耐臭氧性和耐热老化性优异的交联橡胶组合物的嵌段共聚物当交联时，含有嵌段共聚物的橡胶组合物和模塑产品。本发明的嵌段共聚物包含两个具有烯属不饱和键的聚合物嵌段和介于两个聚合物嵌段之间的其它聚合物嵌段，其重均分子量均匀分布在5,000至100,000的范围内。具有烯属不饱和键的聚合物嵌段的重均分子量优选为1,000〜20,000。

8. 发明授权

US06887929B2 Resin composition and golf ball 有权
标题翻译：树脂组成和高尔夫球
公开(公告)号：US06887929B2
公开(公告)日：2005-05-03
申请号：US10232610
申请日：2002-09-03
申请人： Motokazu Takeuchi , Masashi Shimakage , Takashi Toyoizumi , Iwakazu Hattori
发明人： Motokazu Takeuchi , Masashi Shimakage , Takashi Toyoizumi , Iwakazu Hattori
IPC分类号： C08L19/00 , C08L53/02 , A63B37/12 , C08L33/02
CPC分类号： C08L53/02 , C08L19/006 , C08L53/025 , C08L2666/02 , C08L2666/24
摘要： An objective of the present invention is to provide a resin composition which gives a molding excellent in flexibility, impact resilience and mechanical properties and a golf ball having the better shot feel, a long carry, and the excellent cutting resistance when used in a golf ball cover. The resin composition of the present invention is characterized in comprising an ionomer resin, an alkoxysilyl group-containing hydrogenated conjugated diene-based polymer and/or an amino group-containing hydrogenated conjugated diene-based polymer. Alkoxysilyl group content and amino group content in the above-mentioned polymers are preferably 0.0001 to 5 mmol/g, respectively. The golf ball of the invention is characterized in that core is covered with a cover material using the above-mentioned resin composition.
摘要翻译：本发明的目的是提供一种树脂组合物，其在柔软性，冲击弹性和机械性能方面具有优异的成型性，并且当用于高尔夫球时，具有更好的拍摄感觉，较长的携带性和优异的切割阻力的高尔夫球盖。本发明的树脂组合物的特征在于，包含离聚物树脂，含烷氧基甲硅烷基的氢化共轭二烯系聚合物和/或含氨基的氢化共轭二烯系聚合物。上述聚合物中的烷氧基甲硅烷基含量和氨基含量分别优选为0.0001〜5mmol / g。本发明的高尔夫球的特征在于，使用上述树脂组合物用覆盖材料覆盖芯。

9. 发明授权

US06838526B1 Modified conjugated diene polymer and method of producing the same and rubber composition 有权
标题翻译：改性共轭二烯聚合物及其制备方法和橡胶组合物
公开(公告)号：US06838526B1
公开(公告)日：2005-01-04
申请号：US09709563
申请日：2000-11-13
申请人： Takuo Sone , Ryouji Tanaka , Kouichirou Tani , Iwakazu Hattori , Hiroshi Akema , Atsushi Nakayama
发明人： Takuo Sone , Ryouji Tanaka , Kouichirou Tani , Iwakazu Hattori , Hiroshi Akema , Atsushi Nakayama
IPC分类号： B60C1/00 , C08C19/00 , C08C19/44 , C08L19/00 , C08F8/34
CPC分类号： C08L19/006 , B60C1/0016 , B60C1/0025 , C08C19/00 , C08C19/44 , C08K3/04 , C08L7/00 , C08L9/00 , C08L9/02 , C08L9/06 , C08L11/00 , C08L23/0815 , C08L23/16 , C08L23/283 , C08L2666/08 , C08L2666/06
摘要： A novel modified conjugated diene polymer is obtained by polymerizing a conjugated diene compound with a specified catalyst consisting of components (a)-(c) and then reacting with at least one specified compound selected from the group consisting of components (d)-(l), and has a content of cis-1,4-bond of not less than 85% and a ratio of weight average molecular weight to number average molecular weight of not more than 4. And also, a rubber composition comprises the modified conjugated diene polymer a rubber ingredient.
摘要翻译：通过将共轭二烯化合物与由组分（a） - （c）组成的特定催化剂聚合，然后与至少一种选自组分（d） - （I））的特定化合物反应获得新的改性共轭二烯聚合物），并且具有不小于85％的顺式-1,4-键含量，重均分子量与数均分子量之比不大于4.另外，橡胶组合物包含改性共轭二烯聚合橡胶成分。

10. 发明申请

US20070112158A1 Novel (co)polymer, process for producing the same, and process for producing carboxylated (co)polymer 审中-公开
标题翻译：新型（共）聚合物，其制备方法，以及生产羧化（共）聚合物的方法
公开(公告)号：US20070112158A1
公开(公告)日：2007-05-17
申请号：US10578138
申请日：2004-11-15
申请人： Toshiyuki Hayakawa , Iwakazu Hattori , Akihiko Ookubo
发明人： Toshiyuki Hayakawa , Iwakazu Hattori , Akihiko Ookubo
IPC分类号： C08F230/08
CPC分类号： C08F32/08 , C08G61/06
摘要： Disclosed herein are a novel (co)polymer having a silyl carboxylate residue, a production process thereof and a production process of a carboxyl group-containing (co) polymer. A (co)polymer of the invention comprises a structural unit represented by the following general formula (1). Another (co)polymer of the invention comprises a structural unit represented by the following general formula (2). wherein n is 0 or 1, R1, R2, R3 and R4 mean, independently of one another, a hydrogen atom, halogen atom or monovalent organic group, and X denotes an ethylene or vinylene group.
摘要翻译：本文公开了具有甲硅烷基羧酸盐残基的新型（共）聚合物，其制备方法和含羧基（共）聚合物的制备方法。本发明的（共）聚合物包含由以下通式（1）表示的结构单元。本发明的另一（共）聚合物包含由以下通式（2）表示的结构单元。其中n为0或1，R 1，R 2，R 3和R 4均为独立地为氢原子，卤原子或一价有机基团，X表示乙烯或亚乙烯基。

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