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    • 20. 发明授权
    • Process for the production of carbon fibers
    • 生产碳纤维的工艺
    • US3723609A
    • 1973-03-27
    • US3723609D
    • 1970-10-07
    • BAYER AG
    • MANSMANN MWINTER GPAMPUS GSCHON N
    • D01F9/16D01F9/17D01F9/18D01F9/21D01F9/24D01F9/26D01F9/28C01B31/07
    • D01F9/18D01F9/16D01F9/17D01F9/21D01F9/24D01F9/245D01F9/26D01F9/28Y10S264/19
    • In the production of carbon fibers wherein a carbon-containing fiber-forming material is spun as a solution, the spun-filaments are converted to solid fibrous material, and the fibrous material is carbonized, the improvement which comprises including in said solution at least one fiber-forming high polymer at a concentration of about 0.001 to 10 percent by weight and a greater amount of a carbon source comprising at least one carboncontaining organic material having a softening or melting point in excess of about 80* C., whereby the solution of said carbon containing material is rendered spinnable by addition of said fiber-forming high polymer, said carbon containing organic material serving as the source of carbon for the carbon fiber; the fiber may thereafter be graphitized. The spinning solution used for fiber production is preferably a solution in a volatile solvent so that it may be dry spun. The carbon source in said solvent by itself would not be spinnable and may be a monomer or low polymer.
    • 在其中将含碳纤维形成材料作为溶液纺丝的碳纤维的生产中,纺丝长丝被转化为固体纤维材料,并且纤维材料被碳化,其改进包括在所述溶液中包含至少一种 浓度为约0.001至10重量%的纤维形成高聚物和更大量的包含至少一种软化点或熔点超过约80℃的含碳有机材料的碳源,由此, 所述含碳材料的溶液通过加入所述形成纤维的高分子,所述含碳有机材料作为碳纤维的碳源,使其可纺丝; 之后纤维可被石墨化。 用于纤维生产的纺丝溶液优选是挥发性溶剂中的溶液,使其可以是干纺的。 所述溶剂中的碳源本身不可纺,可以是单体或低聚物。