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11. 发明授权

US06235856B1 Polymerization of dicyclopentadiene 失效
标题翻译：二环戊二烯的聚合
公开(公告)号：US06235856B1
公开(公告)日：2001-05-22
申请号：US08860268
申请日：1997-06-19
申请人： Andreas Hafner , Paul Adriaan Van Der Schaaf , Andreas Mühlebach
发明人： Andreas Hafner , Paul Adriaan Van Der Schaaf , Andreas Mühlebach
IPC分类号： C08F480
CPC分类号： C08G61/08 , B33Y70/00
摘要： Composition of (a) dicyclopentadiene, by itself or in a mixture with a strained cycloolefin, and (b) a catalytic amount of at least one carbene-free, divalent-cationic ruthenium or osmium compound as a single-component catalyst, which contains at least one phosphine group and a total of 2 to 5 ligands bonded to the metal atom, and which contains acid anions for charge balancing. The compositions can be polymerized by means of heat (metathesis polymerization) and are suitable for the production of shaped articles and coatings.
摘要翻译：（a）二环戊二烯本身或与应变环烯烃的混合物的组成，和（b）催化量的至少一种不含有无碳原子的二价阳离子钌或锇化合物作为单组分催化剂，其含有至少一个膦基和总共2至5个与金属原子键合的配体，并且其含有用于电荷平衡的酸阴离子。组合物可以通过热（易位聚合）聚合，并且适用于成型制品和涂料的生产。

12. 发明授权

US06232417B1 Photoresist compositions comprising polycyclic polymers with acid labile pendant groups 失效
标题翻译：包含具有酸不稳定侧基的多环聚合物的光致抗蚀剂组合物
公开(公告)号：US06232417B1
公开(公告)日：2001-05-15
申请号：US08928573
申请日：1997-09-12
申请人： Larry F Rhodes , Andrew Bell , Saikumar Jayaraman , John-Henry Lipian , Brian L. Goodall , Robert A. Shick
发明人： Larry F Rhodes , Andrew Bell , Saikumar Jayaraman , John-Henry Lipian , Brian L. Goodall , Robert A. Shick
IPC分类号： C08F480
CPC分类号： G03F7/0045 , C08G61/08 , G03F7/038 , G03F7/039 , Y10S430/109 , Y10S430/111 , Y10S430/115
摘要： The present invention relates to a radiation sensitive photoresist composition comprising a photoacid initiator and a polycyclic polymer comprising repeating units that contain pendant acid labile groups. Upon exposure to an imaging radiation source the photoacid initiator generates an acid which cleaves the pendant acid labile groups effecting a polarity change in the polymer. The polymer is rendered soluble in an aqueous base in the areas exposed to the imaging source. The polymer repeating units are polymerized from polycyclic monomers in the presence of single or multicomponent catalyst systems containing a Group VIII metal
摘要翻译：本发明涉及包含光酸引发剂和包含含有酸不稳定基团的重复单元的多环聚合物的辐射敏感性光致抗蚀剂组合物。在暴露于成像辐射源时，光酸引发剂产生酸，该酸切割引起聚合物极性变化的侧链酸不稳定基团。聚合物在暴露于成像源的区域中变得可溶于碱性水溶液。聚合物重复单元在含有VIII族金属的单组分或多组分催化剂体系存在下由多环单体聚合

13. 发明授权

US06407190B1 Ruthenium and osmium carbene catalysts 有权
标题翻译：钌和铯卡因催化剂
公开(公告)号：US06407190B1
公开(公告)日：2002-06-18
申请号：US09445909
申请日：1999-12-15
申请人： Paul Adriaan Van Der Schaaf , Andreas Hafner , Andreas Mühlebach
发明人： Paul Adriaan Van Der Schaaf , Andreas Hafner , Andreas Mühlebach
IPC分类号： C08F480
CPC分类号： B01J31/2404 , B01J31/182 , B01J31/2204 , B01J31/2265 , B01J31/24 , B01J2231/14 , B01J2231/543 , B01J2531/821 , B01J2531/825 , C07F15/002 , C07F15/0046 , C08G61/02
摘要： The invention relates to penta- and hexacoordinated ruthenium and osmium carbene catalysts, in which a sulfur, oxygen or nitrogen atom is attached to the carbene group which is coordinated with the central ruthenium or osmium atom, to their preparation and to their use for synthesizing polymers, for ring-closing metathesis of olefins and for isomerizing olefins.
摘要翻译：本发明涉及五价和六配位的钌和锇卡宾催化剂，其中硫，氧或氮原子连接至与中心钌或锇原子配位的卡宾基团，其制备及其用于合成聚合物，用于烯烃的闭合复分解和异构化烯烃。

14. 发明授权

US06399732B2 Preparation of conjugated diene polymers by using an iron-based catalayst system 有权
标题翻译：通过使用铁基催化剂体系制备共轭二烯聚合物
公开(公告)号：US06399732B2
公开(公告)日：2002-06-04
申请号：US09475343
申请日：1999-12-30
申请人： Steven Luo
发明人： Steven Luo
IPC分类号： C08F480
CPC分类号： C08L9/00 , C08F4/70 , C08F136/04 , C08F136/06
摘要： A process for preparing conjugated diene polymers by polymerizing conjugated diene monomers in the presence of a catalyst composition that is formed by combining an iron-containing compound, a hydrogen phosphite, and an organoaluminum compound.
摘要翻译：在通过组合含铁化合物，亚磷酸氢盐和有机铝化合物形成的催化剂组合物存在下，通过使共轭二烯单体聚合来制备共轭二烯聚合物的方法。

15. 发明授权

US06395851B1 Copolymerization of norbornene and functional norbornene monomers 失效
公开(公告)号：US06395851B1
公开(公告)日：2002-05-28
申请号：US09591571
申请日：2000-06-09
申请人： Gino Georges Lavoie , Peter Borden Mackenzie
发明人： Gino Georges Lavoie , Peter Borden Mackenzie
IPC分类号： C08F480
CPC分类号： C08G61/08 , C08F232/08
摘要： The present invention is directed to copolymers of norbornene and functional group containing norbornene comonomers and processes for the preparation thereof. These polymers may be random, alternating or block copolymers or terpolymers, etc.

16. 发明授权

US06350832B1 Mold addition polymerization of norbornene-type monomers using group 10 metal complexes 有权
标题翻译：使用第10族金属络合物对降冰片烯型单体进行加模聚合
公开(公告)号：US06350832B1
公开(公告)日：2002-02-26
申请号：US09456780
申请日：1999-12-08
申请人： Andrew Bell , Larry F. Rhodes , Brian L. Goodall , John C. Fondran
发明人： Andrew Bell , Larry F. Rhodes , Brian L. Goodall , John C. Fondran
IPC分类号： C08F480
CPC分类号： C08F232/08 , C08F32/00 , C08F232/00
摘要： A catalyst system and a process for the bulk addition polymerization or of polycyclic olefins, such as norbornene, methylnorbornene, ethylnorbornene, butylnorbornene or hexylnorbornene, 1,2,3,4,4a,5,8,8a-octahydro-1,4:5,8-dimethanonapthalene, 5,5′-(1,2-ethanediyl)bisbicyclo[2.2.1]hept-2-ene, and 1,4,4a,4b,5,8,8a,8b-octahydro-1,4:5,8-dimethanobiphenylene are disclosed. The catalyst includes an organonickel or organopalladium transition metal procatalyst and an activator compound. Polymerization can be carried out in a reaction injection molding process to yield thermoplastic and thermoset molded polymeric articles possessing high glass transition temperatures.
摘要翻译：催化剂体系和本体加成聚合方法或降冰片烯，甲基降冰片烯，乙基降冰片烯，丁基降冰片烯或己基降冰片烯等多环烯烃，1,2,3,4,4a，5,8,8a-八氢-1,4： 5,8-二甲基萘，5,5' - （1,2-乙二基）双双环[2.2.1]庚-2-烯和1,4,4a，4b，5,8,8a，8b-八氢-1 ，4：5,8-二甲基亚二苯基。催化剂包括有机金属或有机钯过渡金属前催化剂和活化剂化合物。可以在反应注射成型工艺中进行聚合以产生具有高玻璃化转变温度的热塑性和热固性模塑聚合物制品。

17. 发明授权

US06281307B1 Polymerizable composition, process for producing cross linked polymers, and cross-linkable polymers 失效
标题翻译：可聚合组合物，交联聚合物的生产方法和可交联聚合物
公开(公告)号：US06281307B1
公开(公告)日：2001-08-28
申请号：US08875529
申请日：1997-07-31
申请人： Andreas Mühlebach , Andreas Hafner , Paul Adriaan Van Der Schaaf
发明人： Andreas Mühlebach , Andreas Hafner , Paul Adriaan Van Der Schaaf
IPC分类号： C08F480
CPC分类号： C08G18/6204 , B33Y70/00 , C08G61/00
摘要： Composition comprising (a) catalytic amounts of a one-component catalyst for metathesis polymerization and (b) at least one polymer with strained cycloalkenylene radicals bonded in the polymer backbone, alone or as a mixture with strained cycloolefins. The composition can be polymerized thermally or photochemically by metathesis polymerization and is suitable for the production of shaped articles, coatings and relief images. The catalyst is selected from Ruthenium and Osmium compounds.
摘要翻译：组合物，其包含（a）催化量的用于复分解聚合的单组分催化剂和（b）至少一种具有结合在聚合物主链中的应变亚链烯基的聚合物，单独或作为与应变环烯烃的混合物。组合物可以通过复分解聚合进行热或光化学聚合，并且适用于生产成形制品，涂层和浮雕图像。催化剂选自钌和锇化合物。

18. 发明授权

US06265506B1 Method for the preparation of copolymers of ethylene/norbornene-type monomers with cationic palladium catalysts 失效
标题翻译：乙烯/降冰片烯型单体与阳离子钯催化剂的共聚物的制备方法
公开(公告)号：US06265506B1
公开(公告)日：2001-07-24
申请号：US09094349
申请日：1998-06-09
申请人： Brian Leslie Goodall , Lester Howard McIntosh, III
发明人： Brian Leslie Goodall , Lester Howard McIntosh, III
IPC分类号： C08F480
CPC分类号： C08F232/08 , C08F10/00 , C08F210/02 , C08F232/00 , C08F4/7006 , C08F4/7016 , C08F4/7014 , C08F4/7032 , C08F4/7018
摘要： A method of preparing generally amorphous copolymers of ethylene and at least one norbornene (NB)-type comonomer. These polymers may be random or alternating, depending on the choice of catalyst and/or the relative ratio of the monomers used. This method comprises polymerizing said monomers in a diluent or in bulk in the presence of a cationic palladium catalyst resulting from reacting a chelating ligand with a palladium (II) compound. The catalysts employed in this invention may be represented by the formula: wherein X and Y each independently is a donor heteroatom selected from P, N, O, S and As or an organic group containing said heteroatoms, and the heteroatoms are bonded to the bridging group A; A is a divalent group selected from an organic group and phosphorus forming together with X, Y and Pd a 4, 5, 6, or 7-membered ring, and preferably a 5-membered ring; R is a hydrocarbyl group; and CA is a weakly coordinating anion.
摘要翻译：通常制备乙烯和至少一种降冰片烯（NB）型共聚单体的无定形共聚物的方法。这些聚合物可以是随机的或交替的，这取决于催化剂的选择和/或所用单体的相对比例。该方法包括在由螯合配体与钯（II）化合物反应得到的阳离子钯催化剂的存在下，以稀释剂或本体聚合所述单体。本发明中使用的催化剂可以由下式表示：其中X和Y各自独立地是选自P，N，O，S和As的供体杂原子或含有所述杂原子的有机基团，并且杂原子与桥连基团键合 A; A是选自有机基团的二价基团和与X，Y和Pd一起形成的磷，4,5,6或7元环，优选为5元环; R为烃基; 而CA是弱配位阴离子。

19. 发明授权

US06812306B2 Metallic compounds and the use thereof in the polymerization of olefins 失效
标题翻译：金属化合物及其在烯烃聚合中的应用
公开(公告)号：US06812306B2
公开(公告)日：2004-11-02
申请号：US10312880
申请日：2003-01-02
申请人： Marc Oliver Kristen , Peter Hofmann , Frank Eisenträger
发明人： Marc Oliver Kristen , Peter Hofmann , Frank Eisenträger
IPC分类号： C08F480
CPC分类号： C08F110/02 , C07F15/006 , C07F15/04 , C08F10/00 , C08F4/80 , C08F2500/03 , C08F4/7016
摘要： Metal compounds of the formula I, where M is selected from among Ni and Pd in the oxidation state +II can be used for the polymerization or copolymerization of olefins. Supported catalysts for the polymerization and copolymerization of olefins can be obtained by application of one or more of the above-described ionic metal compounds to a support.
摘要翻译：式I的金属化合物，其中M选自氧化态+ II的Ni和Pd可用于烯烃的聚合或共聚。用于烯烃聚合和共聚的载体催化剂可以通过将一种或多种上述离子金属化合物应用于载体来获得。

20. 发明授权

US06787620B2 Homobimetallic and heterobimetallic alkylidene complexes of ruthenium containing N-heterocyclic carbene ligands 失效
标题翻译：含有N-杂环卡宾配体的钌的同双金属和异双金属亚烷基络合物
公开(公告)号：US06787620B2
公开(公告)日：2004-09-07
申请号：US10371955
申请日：2003-02-20
申请人： Wolfgang Anton Herrmann , Florian J. Kohl , Thomas Weskamp
发明人： Wolfgang Anton Herrmann , Florian J. Kohl , Thomas Weskamp
IPC分类号： C08F480
CPC分类号： C07C6/04 , C07C2527/1213 , C07C2527/122 , C07C2527/138 , C07C2531/22 , C07C2531/26 , C07C2531/30 , C07F15/0046
摘要： The invention relates to complexes of ruthenium of the structural formula I where X is an anionic ligand, Z is a monodentate to tridentate ligand which contains a metal and is nonionically bound to the ruthenium center, R1 and R2 are identical or different and are each hydrogen or/and a hydrocarbon group, but may also form a ring, and Ligand L is an N-heterocyclic carbene, and also to a process for preparing acyclic olefins having two or more carbon atoms or/and cyclic olefins having three or more carbon atoms and the use of at least one complex of the formula I in olefin metathesis.
摘要翻译：本发明涉及结构式I的钌络合物，其中X是阴离子配位体，Z是含有金属并且与钌中心非离子键合的三齿配体的单齿配位体，R 1和R 2是相同或不同的并且各自为氢或/和烃基，但也可以形成环，并且L是N-杂环卡宾，并且还涉及制备具有两个或更多个碳原子的非环烯烃或/或具有三个或更多个碳原子的环烯烃的方法，更多的碳原子和在烯烃复分解中使用至少一种式I的络合物。

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