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11. 发明授权

US5094990A Iron-antimony-phosphorus-containing metal oxide catalyst for oxidation 失效
标题翻译：用于氧化的含抗氧化磷的金属氧化物催化剂
公开(公告)号：US5094990A
公开(公告)日：1992-03-10
申请号：US540729
申请日：1990-06-20
申请人： Yutaka Sasaki , Masato Otani , Hiroshi Utsumi , Kazuo Morishita
发明人： Yutaka Sasaki , Masato Otani , Hiroshi Utsumi , Kazuo Morishita
IPC分类号： B01J27/18 , B01J27/182 , B01J27/185 , B01J27/186 , B01J27/188 , B01J27/19 , B01J27/192 , B01J27/198 , B01J27/199 , C01B35/12 , C01C3/02 , C07B61/00 , C07C253/24 , C07C255/06
CPC分类号： C01C3/0216 , B01J23/002 , B01J27/1853 , B01J27/188 , B01J27/198 , C01C3/0241 , C07C253/26 , B01J2523/00 , Y02P20/52
摘要： An iron-antimony-phosphorus-containing metal oxide catalyst for the catalytic oxidation, comprising a crystalline iron antimonate, the catalyst being represented by the following empirical formula:Fe.sub.a Sb.sub.b P.sub.c X.sub.d Q.sub.e R.sub.f O.sub.g (SiO.sub.2).sub.hwherein X represents at least one element selected from the group consisting of V, Mo and W; Q represents at least one element selected from the group consisting of Li, Na, K, Rb, Cs, Be, Mg, Ca, Sr, Ba, Sc, Y, La, Ce, Pr, Nd, Sm, Th, U, Ti, Zr, Hf, Nb, Ta, Cr, Mn, Re, Co, Ni, Ru, Rh, Pd, Os, Ir, Pt, Cu, Ag, Au, Zn, Cd, Hg, Al, Ga, In, Tl, Ge, Sn and Pb; R represents at least one element selected from the group consisting of B, As, Bi, Se and Te; a, b, c, d, e, f, g and h each is an atomic ratio as follows:a=about 5 to 15b=about 5 to 100c=about 1 to 30d=about 0 to 10e=about 0 to 15f=about 0 to 10h=about 0 to 300g is a number of oxygen atom as determined corresponding to the oxides formed by combining the above-mentioned components; the atomic ratio of P/Fe is at least 0.3; the atomic ratio of P/Sb is at least 0.1; and the atomic ratio of P/X is at least 1 when d>0.

12. 发明授权

US4482503A Process for producing aliphatic nitriles 失效
标题翻译：生产脂肪腈的方法
公开(公告)号：US4482503A
公开(公告)日：1984-11-13
申请号：US400026
申请日：1982-07-20
申请人： Peter Hofmann
发明人： Peter Hofmann
IPC分类号： C07B61/00 , B01J23/00 , B01J23/74 , C07C67/00 , C07C253/00 , C07C255/02 , C07C255/06 , C07C120/00 , C07C120/08
CPC分类号： C07C253/22
摘要： A process for producing aliphatic nitriles by reacting the corresponding carboxylic acids or carboxylic alkylesters with ammonia in the liquid phase and in the presence of a metal-containing catalyst, the reaction being carried out at a temperature between about 150.degree. and 290.degree. C. in the presence of iron or an iron compound as the catalyst.
摘要翻译：通过使相应的羧酸或羧酸烷基酯与氨在液相中和在含金属的催化剂存在下反应来生产脂族腈的方法，该反应在约150℃和290℃之间的温度下进行，铁或铁化合物作为催化剂的存在。

13. 发明授权

US3966798A Catalytic coupling of allylic compounds to substituted olefins 失效
标题翻译：烯丙基化合物与取代烯烃的催化偶联
公开(公告)号：US3966798A
公开(公告)日：1976-06-29
申请号：US529674
申请日：1974-12-04
申请人： George M. Intille , Gary R. Beck
发明人： George M. Intille , Gary R. Beck
IPC分类号： C07C69/587 , B01J21/00 , B01J31/00 , B01J31/24 , C07B61/00 , C07C41/00 , C07C43/30 , C07C43/303 , C07C45/00 , C07C49/203 , C07C51/00 , C07C57/03 , C07C57/10 , C07C57/44 , C07C67/00 , C07C67/343 , C07C69/025 , C07C231/00 , C07C231/12 , C07C233/09 , C07C235/28 , C07C253/00 , C07C255/06 , C07D309/38 , C07C69/52
CPC分类号： B01J31/18 , B01J31/24 , B01J31/2404 , C07C57/10 , C07C57/44 , C07C67/343 , C07D309/38 , B01J2231/4205 , B01J2531/80 , B01J2531/824
摘要： Allylic compounds are carbon-to-carbon coupled to substituted olefins by contacting the two compounds in the presence of a catalyst system comprising a Group VIII metal component, a bromine or iodine component, and a Group VA component. The foregoing catalytic process also promotes the intra-molecular, carbon-carbon coupling of allylic and substituted olefin groups wherein both processes provide a method for producing sorbates and related compounds.
摘要翻译：烯属化合物是通过在包含VIII族金属组分，溴或碘组分和VA族组分的催化剂体系的存在下使两种化合物接触而与取代的烯烃偶合的碳 - 碳。上述催化方法还促进烯丙基和取代的烯烃基团的分子内，碳 - 碳偶联，其中两种方法提供了一种生产山梨酸盐和相关化合物的方法。

14. 发明授权

US09029587B2 Method for producing aqueous acrylamide solution 有权
公开(公告)号：US09029587B2
公开(公告)日：2015-05-12
申请号：US14117754
申请日：2012-05-21
申请人： Makoto Kanou , Norifumi Hagiya
发明人： Makoto Kanou , Norifumi Hagiya
IPC分类号： C07C255/06 , C07C231/00 , C12P13/02 , C07C231/06
摘要： There is provided a method for producing an aqueous acrylamide solution by reacting a composition including acrylonitrile with water to produce acrylamide, in which the composition including acrylonitrile includes 3 to 15 mg of propionitrile per 1 kg of the total weight of the composition including acrylonitrile. According to the present invention, a production method with which it is possible to suppress acrylamide polymerization without lowering quality and thereby obtain a stable aqueous acrylamide solution can be provided.

15. 发明授权

US08785675B2 Mixed catalyst 有权
标题翻译：混合催化剂
公开(公告)号：US08785675B2
公开(公告)日：2014-07-22
申请号：US13697053
申请日：2011-03-23
申请人： Takaaki Kato , Minoru Kadowaki
发明人： Takaaki Kato , Minoru Kadowaki
IPC分类号： C07C255/06 , C07C255/07
CPC分类号： C07C51/215 , B01J23/002 , B01J37/0045 , B01J37/038 , B01J37/04 , B01J37/12 , B01J2523/00 , B01J2523/36 , B01J2523/3706 , B01J2523/3712 , B01J2523/53 , B01J2523/55 , B01J2523/56 , B01J2523/68 , B01J2523/69 , C07C253/24 , Y02P20/52 , C07C57/04 , C07C255/08 , B01J2523/41 , B01J2523/3718 , B01J2523/3787 , B01J2523/51 , B01J2523/845
摘要： It is an object of the present invention to provide a mixed catalyst for a vapor-phase catalytic oxidation or a vapor-phase catalytic ammoxidation reaction of propane, or isobutene, capable of providing a corresponding unsaturated acid or unsaturated nitrile at high yield from propane or isobutene.
摘要翻译：本发明的目的是提供一种用于丙烷或异丁烯的气相催化氧化或气相催化氨氧化反应的混合催化剂，其能够以高产率从丙烷或丙烷提供相应的不饱和酸或不饱和腈异丁烯

16. 发明申请

US20100137178A1 PERFUME SYSTEMS 审中-公开
标题翻译： PERFUME系统
公开(公告)号：US20100137178A1
公开(公告)日：2010-06-03
申请号：US12628255
申请日：2009-12-01
申请人： Johan Smets , Hugo Robert Germain Denutte , An Pintens , David Thomas Stanton , Koen Van Aken , Inge Helena Hubert Laureyn , Bram Denolf , Freek Annie Camiel Vrielynck
发明人： Johan Smets , Hugo Robert Germain Denutte , An Pintens , David Thomas Stanton , Koen Van Aken , Inge Helena Hubert Laureyn , Bram Denolf , Freek Annie Camiel Vrielynck
IPC分类号： A61K8/11 , C07C49/00 , C07C49/20 , C07C49/213 , C07C49/21 , C07C69/74 , C07C69/52 , C07C255/06 , C07C255/33 , C07C255/00 , C07C35/04 , A61K8/34 , A61K8/35 , A61K8/36 , A61K8/37 , A61K8/40 , C11D3/50
CPC分类号： C11D3/50 , A61K8/732 , A61K8/84 , A61Q5/02 , A61Q13/00 , C07C33/05 , C07C33/14 , C07C49/203 , C07C49/213 , C07C49/217 , C07C49/225 , C07C49/255 , C07C49/293 , C07C49/557 , C07C49/792 , C07C49/794 , C07C57/03 , C07C69/007 , C07C255/07 , C07C255/33 , C07C2601/04 , C07C2601/16 , C11B9/003 , C11B9/0034 , C11B9/0061 , C11B9/0065
摘要： The present application relates to perfume raw materials, perfume delivery systems and consumer products comprising such perfume raw materials and/or such perfume delivery systems, as well as processes for making and using such perfume raw materials, perfume delivery systems and consumer products. Such perfume raw materials and compositions, including the delivery systems, disclosed herein expand the perfume communities options as such perfume raw materials can provide variations on character and such compositions can provide desired odor profiles.
摘要翻译：本申请涉及香水原料，香水输送系统和包含这种香料原料和/或这种香料输送系统的消费品，以及制造和使用这种香料原料，香水输送系统和消费品的方法。本文公开的这种香料原料和组合物，包括递送系统，扩展了香水社区的选择，因为这样的香料原料可以提供特性的变化，并且这样的组合物可提供所需的气味分布。

17. 发明申请

US20070155979A1 Process for the hydrocyanation of unsaturated compounds 有权
标题翻译：不饱和化合物的氢化方法
公开(公告)号：US20070155979A1
公开(公告)日：2007-07-05
申请号：US10556628
申请日：2004-05-07
申请人： Cécile Rosier , Philippe Leconte , Damien Bourgeois
发明人： Cécile Rosier , Philippe Leconte , Damien Bourgeois
IPC分类号： C07C255/06 , C07C253/10
CPC分类号： C07C253/34 , C07C255/04
摘要： The present invention relates to a process for the hydrocyanation of unsaturated compounds to unsaturated mononitrile compounds or to dinitrile compounds; It relates more particularly to a process for the manufacture of dinitriles by double hydrocyanation of diolefins, such as butadiene, comprising a recovery and separation of the catalytic system. The process for the manufacture of dinitriles of the invention by hydrocyanation of unsaturated compounds, comprising at least one stage of hydrocyanation in the presence of a catalytic system comprising an organometallic complex formed by one or more monodentate organophosphite ligands and one or more bidentate organophosphorus ligands and optionally a promoter of Lewis acid type, comprises at least one stage of separation by distillation of a reactant used in the process or of a compound formed by the reaction from a medium comprising the said catalytic system.
摘要翻译：本发明涉及不饱和化合物氢化成不饱和单腈化合物或二腈化合物的方法; 更具体地涉及通过二烯烃如丁二烯的双氢氰化制备二腈的方法，其包括催化体系的回收和分离。通过氢化不饱和化合物的方法制备本发明的二腈的方法，该方法在包含由一个或多个单齿有机亚磷酸酯配体和一个或多个二齿有机磷配体形成的有机金属络合物的催化体系存在下包含至少一个氢化氰化阶段，以及任选的路易斯酸型助催化剂包括通过蒸馏在该方法中使用的反应物或由包含所述催化体系的介质通过反应形成的化合物的至少一个阶段进行分离。

18. 发明申请

US20050159634A1 Polymerizable higher diamondoid derivatives 失效
公开(公告)号：US20050159634A1
公开(公告)日：2005-07-21
申请号：US11013638
申请日：2004-12-17
申请人： Jeremy Dahl , Robert Carlson , Shenggao Liu
发明人： Jeremy Dahl , Robert Carlson , Shenggao Liu
IPC分类号： C07C4/00 , C07C7/04 , C07C7/12 , C07C7/135 , C07C13/64 , C07C17/10 , C07C17/16 , C07C17/383 , C07C17/395 , C07C23/20 , C07C23/46 , C07C35/44 , C07C39/17 , C07C47/347 , C07C49/423 , C07C61/29 , C07C69/00 , C07C69/08 , C07C69/753 , C07C205/05 , C07C211/19 , C07C211/50 , C07C217/90 , C07C233/06 , C07C255/06 , C08G61/00 , C08G61/02 , C08G83/00 , C08G85/00 , C08L65/00 , C07C13/00
CPC分类号： B82Y30/00 , B82Y10/00 , C07C4/00 , C07C7/04 , C07C7/12 , C07C7/135 , C07C13/64 , C07C17/10 , C07C17/16 , C07C17/383 , C07C17/395 , C07C23/20 , C07C29/124 , C07C29/143 , C07C29/149 , C07C29/48 , C07C31/137 , C07C31/278 , C07C37/20 , C07C39/17 , C07C41/16 , C07C43/188 , C07C45/28 , C07C47/347 , C07C49/423 , C07C51/353 , C07C67/08 , C07C67/14 , C07C69/08 , C07C69/38 , C07C69/54 , C07C69/604 , C07C205/05 , C07C211/38 , C07C211/50 , C07C217/90 , C07C233/58 , C07C2603/54 , C07C2603/90 , C08G61/00 , C08G61/02 , C08G83/00 , C08L65/00 , C07C69/608 , C07C61/125
摘要： Higher diamondoid derivatives capable of taking part in polymerization reactions are disclosed as well as intermediates to these derivatives, polymers formed from these derivatives and methods for preparing the polymers.

19. 发明授权

US4419297A Preparation of nitriles from formamides 失效
标题翻译：从甲酰胺制备腈
公开(公告)号：US4419297A
公开(公告)日：1983-12-06
申请号：US340902
申请日：1982-01-20
申请人： Dieter Arlt , Gerhard Klein
发明人： Dieter Arlt , Gerhard Klein
IPC分类号： C07C255/03 , A01N43/64 , C07C20060101 , C07C67/00 , C07C253/00 , C07C253/06 , C07C255/02 , C07C255/06 , C07C255/32 , C07C255/33 , C07C255/49 , C07C255/50 , C07C120/00 , C07C120/10
CPC分类号： C07C253/20
摘要： Aliphatic, araliphatic or aromatic nitriles of the formula R--CN are obtained by reacting N-substituted formamides of the formula R--NHCHO with at least the stoichiometric quantity of an acylating agent (generally a carboxylic acid anhydride, such as acetic anhydride, or ketene) in the gas phase at temperatures above 250.degree. C., without using a catalyst. The process is especially useful in the preparation of nitriles wherein the connecting carbon of R is a tertiary carbon atom. The nitriles are important intermediate products, for example for the preparation of herbicides, surface-active agents and anti-corrosive agents.
摘要翻译：式R-CN的脂族，芳脂族或芳族腈通过使式R-NHCHO的N-取代甲酰胺与至少化学计量量的酰化剂（通常为羧酸酐，例如乙酸酐或乙烯酮）反应而获得）在高于250℃的温度下在气相中，而不使用催化剂。该方法在制备其中R的连接碳是叔碳原子的腈中是特别有用的。腈是重要的中间产物，例如用于制备除草剂，表面活性剂和抗腐蚀剂。

20. 发明授权

US3923832A Insecticidal substituted alkenes 失效
标题翻译：杀虫剂取代烯烃
公开(公告)号：US3923832A
公开(公告)日：1975-12-02
申请号：US35497073
申请日：1973-04-27
申请人： LILLY CO ELI
发明人： LEOPOLD ERIC JAN
IPC分类号： C07C69/767 , A01N29/02 , A01N43/08 , A01N43/30 , A01N49/00 , C07B31/00 , C07B35/06 , C07C1/00 , C07C1/24 , C07C1/32 , C07C15/40 , C07C17/00 , C07C17/26 , C07C22/02 , C07C22/04 , C07C25/02 , C07C25/24 , C07C41/00 , C07C43/20 , C07C43/215 , C07C67/00 , C07C69/618 , C07C201/00 , C07C205/11 , C07C209/00 , C07C211/21 , C07C211/44 , C07C211/48 , C07C253/00 , C07C255/06 , C07C255/50 , C07C255/62 , C07D307/36 , C07D317/50 , C07D333/06 , C07D333/08 , C07D333/12 , C07F9/40 , C07D319/18
CPC分类号： C07F9/4056 , C07C17/2635 , C07D317/50 , C07D333/08 , C07D333/12 , C07C25/24
摘要： wherein each of R1, R2 and R3 can be hydrogen or C1-C3 alkyl, and Z1 and Z2 separately can be hydrogen or halogen or together can be a carbon to carbon bond, and Y is thienyl, furyl, naphthyl, phenyl or phenyl substituted by one or two substituents selected from chloro, bromo, fluoro, carboethoxy, cyano, C1-C4 alkyl, C1-C3 alkoxy, nitro, methylenedioxy, ethylenedioxy, dimethylamino or diethylamino. A compound exemplary of my invention is 4,8-dimethyl-1-(3,4-methylenedioxyphenyl)-1,7nonadiene.

Novel 1,7-dienes and addition products thereof possessing juvenile hormone-like activity have been prepared. Such a compound is one having the formula
摘要翻译：已经制备出具有幼体激素样活性的新颖的1,7-二烯及其加成产物。这种化合物是具有式Z1Z2 || Y-CH = CH-CH2CHCH2CH2CH-C-R3 || R1R2的化合物，其中R1，R2和R3各自可以是氢或C1-C3烷基，Z1和Z2可以分别是氢或卤素或一起可以是碳 - 碳键，Y是噻吩基，呋喃基，萘基，苯基或被一个或两个选自氯，溴，氟，乙酰乙氧基，氰基，C 1 -C 4烷基，C 1 -C 3 烷氧基，硝基，亚甲二氧基，亚乙二氧基，二甲基氨基或二乙基氨基。本发明的化合物是4,8-二甲基-1-（3,4-亚甲二氧基苯基）-1,7-壬二烯。

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