会员体验
专利管家(专利管理)
工作空间(专利管理)
风险监控(情报监控)
数据分析(专利分析)
侵权分析(诉讼无效)
联系我们
交流群
官方交流:
QQ群: 891211   
微信请扫码    >>>
现在联系顾问~
热词
    • 14. 发明授权
    • High apparent bulk density gamma alumina carrier and method of
manufacture of same
    • 高表观堆积密度γ氧化铝载体及其制造方法
    • US4301033A
    • 1981-11-17
    • US87267
    • 1979-10-22
    • Shizuo TakumiToshio HashimotoFumio Akimoto
    • Shizuo TakumiToshio HashimotoFumio Akimoto
    • C01F7/02B01J21/04B01J35/10B01J37/00B01J35/08C01F7/22
    • B01J37/0072B01J21/04B01J35/10B01J35/1019B01J35/1042B01J35/1061B01J35/1085
    • A catalyst carrier comprising gamma alumina wherein the apparent bulk density is in the range of from 0.65 g/cc to 0.71 g/cc, the total pore volume is in the range of from 0.55 cc/g to 0.65 cc/g, the content of pores having a diameter in the range of from 60A to 110A occupies at least 75% of the total pore volume, the surface area is in the range of from 210 m.sup.2 /g to 250 m.sup.2 /g and the attrition loss is less than 0.5 wt. %. This sort of catalyst carrier can be namufactured through a series of steps of: (a) preparing a first alumina hydrosol having an aluminum concentration in the range of from 9.8 wt. % to 14.4 wt. % and a weight ratio of aluminum to chloride in the range of from 0.95 to 1.20, (b) preparing a second alumina hydrosol having an aluminum concentration in the range of from 9.5 wt. % to 13.0 wt. % and a weight ratio of aluminum to chloride in the range of from 0.85 to 0.95 by adding hydrochloric acid to said first hydrosol, (c) preparing an alumina precursor having an aluminum concentration in the range of from 6.0 wt. % to 7.0 wt. % by commingling said second hydrosol with a suitable gelling agent in an amount of from 1.65 to 1.85 times the chemical equivalent necessary to neutralize the chloride contained in the second hydrosol and (d) dispersing this precursor as droplets in a suspending medium thereby forming hydrogel particles, ageing the thus obtained hydrogel particles in said suspending medium and then in an aqueous ammonia, washing the aged particles in water, drying and calcining thereafter.
    • 包含γ氧化铝的催化剂载体,其中表观堆积密度在0.65g / cc至0.71g / cc的范围内,总孔体积在0.55cc / g至0.65cc / g的范围内, 直径在60A至110A范围内的孔占总孔体积的至少75%,表面积在210m 2 / g至250m 2 / g的范围内,并且磨损损失小于0.5wt 。 %。 这种催化剂载体可以通过以下一系列步骤进行制造:(a)制备铝浓度在9.8重量%范围内的第一氧化铝水溶胶, %〜14.4重量% 铝和氯化铝的重量比在0.95至1.20的范围内,(b)制备铝浓度在9.5重量%范围内的第二氧化铝水溶胶。 %〜13.0重量% 通过向所述第一水溶胶中加入盐酸,铝和氯化物的重量比在0.85至0.95的范围内,(c)制备铝浓度在6.0重量%范围内的氧化铝前体。 %〜7.0重量% 通过用合适的胶凝剂混合所述第二水溶胶,其量为中和第二水溶胶中所含氯化物所需的化学当量的1.65至1.85倍,和(d)将该前体作为液滴分散在悬浮介质中,从而形成水凝胶颗粒 将如此得到的水凝胶颗粒在所述悬浮介质中老化,然后在氨水中老化,在水中洗涤老化的颗粒,然后干燥和煅烧。