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    • 2. 发明授权
    • Process for preparation of mesoporous silica and organosilica materials
    • 介孔二氧化硅和有机硅材料的制备工艺
    • US09296618B2
    • 2016-03-29
    • US14115663
    • 2012-05-11
    • Mark John MacLachlanKevin Eric ShopsowitzWadood Yasser Hamad
    • Mark John MacLachlanKevin Eric ShopsowitzWadood Yasser Hamad
    • B01D53/56C01B33/12B01J20/10B01J20/28B01J20/283C09K19/02C09K19/38C09K19/52B01J20/24B01J20/30
    • C01B33/126B01J20/10B01J20/103B01J20/24B01J20/28083B01J20/283B01J20/305B01J20/3078C01B33/124C01P2006/16C09K19/02C09K19/3819C09K19/52C09K2019/521
    • In this invention, we disclose a method as well as silica and/or organosilica mesoporous materials obtained by templating using nanocrystalline cellulose and removal of the latter using acidic conditions. The resultant mesoporous silica materials are characterized by having high surface area with tunable iridescence resulting from the long-range chiral nematic organization. This invention is an improvement over the formation of composite materials formed with nanocrystalline cellulose (NCC) and silica, where the calcination of the materials led to removal of the cellulose and formation of a mesoporous silica material. Characteristically, the removal of the NCC template using acidic conditions differentiates the silica materials thus obtained in two ways: (1) It does not lead to as significant contraction of the materials as from calcination thereby giving access to materials with larger mesopores; and (2) it allows the formation of mesoporous chiral nematic compositions that include heat-sensitive components. This approach may be used to prepare the first example of a mesoporous organosilica material with a chiral nematic pore structure. Examples of possible applications of this material include optical filters, adsorbents, chiral stationary phases for chromatography, sensors, composite materials, membranes, and templates for creating other chiral materials.
    • 在本发明中,我们公开了一种方法以及通过使用纳米晶纤维素模板化和通过酸性条件去除后者而获得的二氧化硅和/或有机二氧化硅介孔材料。 所得的介孔二氧化硅材料的特征在于具有高的表面积,并且由长程手性向列组织引起可调谐的虹彩。 本发明是对由纳米晶体纤维素(NCC)和二氧化硅形成的复合材料的形成的改进,其中材料的煅烧导致去除纤维素和形成介孔二氧化硅材料。 特征上,使用酸性条件去除NCC模板可以通过两种方式区分由此获得的二氧化硅材料:(1)它不会导致材料与煅烧显着的收缩,从而进入具有较大介孔的材料; 和(2)它允许形成包括热敏组分的介孔手性向列组合物。 该方法可用于制备具有手性向列孔结构的介孔有机硅材料的第一实例。 这种材料的可能应用的实例包括光学过滤器,吸附剂,用于色谱的手性固定相,传感器,复合材料,膜和用于产生其它手性材料的模板。
    • 5. 发明申请
    • METHOD FOR SYNTHESIZING ONE-DIMENSIONAL HELICAL NANOPOROUS STRUCTURES AND METHOD FOR SYNTHESIZING GLYCINE-DERIVED SURFACTANT FOR SYNTHESIZING HELICAL NANOPOROUS STRUCTURES
    • 用于合成一维螺旋纳米结构的方法和用于合成甘氨酸衍生的表面活性剂以合成螺旋形纳米结构的方法
    • US20110039682A1
    • 2011-02-17
    • US12921457
    • 2009-04-10
    • Sang Cheol HanYang KimChung Kwon Park
    • Sang Cheol HanYang KimChung Kwon Park
    • C04B38/00C07C237/04
    • C07C237/06C01B33/124C01B37/02
    • Disclosed herein are a method for synthesizing one-dimensional helical mesoporous structure, in which a self-assembled structure of a glycine-derived surfactant is used as a template at room temperature to synthesize the one-dimensional helical mesoporous silica structures having a uniform pore size and a method for synthesizing a glycine-derived surfactant for synthesizing the helical nanoporous structures, in which relatively expensive surfactant can be easily recovered using an organic solvent and reused, which provides economical and environment friendly effects and the glycine-derived surfactant is synthesized by homogeneously heating a reaction product of glycine and phthalic anhydride by dielectric heating with irradiation of microwave, whereby it is possible to realize high yield of the glycine-derived surfactant, shortened synthesis time and increase in energy efficiency, leading to improvement in productivity and reduction in production cost.
    • 本文公开了一种用于合成一维螺旋介孔结构的方法,其中在室温下将甘氨酸衍生的表面活性剂的自组装结构用作模板以合成具有均匀孔径的一维螺旋介孔二氧化硅结构 以及用于合成用于合成螺旋纳米孔结构的甘氨酸衍生的表面活性剂的方法,其中相对昂贵的表面活性剂可以使用有机溶剂容易地回收并重复使用,这提供了经济和环境友好的作用,并且甘氨酸衍生的表面活性剂通过均匀合成 通过微波照射的电介质加热加热甘氨酸和邻苯二甲酸酐的反应产物,从而可以实现甘氨酸衍生的表面活性剂的高产率,缩短合成时间和提高能量效率,从而提高生产率和降低生产 成本。
    • 7. 发明申请
    • Closed-cell foam silica
    • 闭孔泡沫二氧化硅
    • US20080286555A1
    • 2008-11-20
    • US11798976
    • 2007-05-18
    • Alan HustonBrian I. Justus
    • Alan HustonBrian I. Justus
    • C03B19/08B32B3/26C01B33/12
    • C03B19/08C01B33/124C03C11/007Y10T428/249969Y10T428/249977
    • A method of making a closed-cell silica foam glass is provided which can include diffusing a substance into a porous glass substrate to form an impregnated substrate, sealing the impregnated glass substrate and heating to a first temperature, wherein the pressure is greater than one atmosphere, heating the container to a second temperature, wherein the second temperature is higher than first temperature, removing the solid glass, non-porous substrate, and heating the solid glass, non-porous substrate to a third temperature to soften the solid glass, non-porous substrate and thereby expand the solid glass, non-porous substrate. A closed-cell silica foam product is provided which can have a closed-cell structure and high temperature insulating property.
    • 提供一种制造闭孔二氧化硅泡沫玻璃的方法,其可以包括将物质扩散到多孔玻璃基板中以形成浸渍的基材,密封浸渍的玻璃基板并加热至第一温度,其中压力大于一个大气压 将容器加热至第二温度,其中第二温度高于第一温度,除去固体玻璃,无孔基材,并将固体玻璃,无孔基材加热至第三温度以软化固体玻璃,非 从而膨胀固体玻璃,无孔基材。 提供了可以具有闭孔结构和高温绝缘性的闭孔硅石泡沫产品。