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    • 14. 发明授权
    • Process for processing spent photographic baths
    • 处理用过的摄影浴的过程
    • US5863442A
    • 1999-01-26
    • US857203
    • 1997-05-15
    • Roger Noero
    • Roger Noero
    • G03C5/00C01B17/05C01B17/50C01C1/02C02F1/58C02F1/62C02F1/64C02F1/72C02F9/00C02F1/20
    • C02F1/20C01B17/05C01B17/508C01C1/026C02F1/66C02F9/00C02F2101/101C02F2101/20C02F2103/40C02F2209/06C02F2301/063
    • A process for the processing of spent photographic baths of black and white processes, namely developing baths with a preponderant content of alkali sulphite, particularly sodium sulphite, and fixing baths with a preponderant content of thiosulphates, particularly ammonium thiosulphate and/or sodium thiosulphate is proposed and is characterized in that following the deposition of the silver contained in the baths, the spent fixing baths are brought to a pH of approximately 0.5 with concentrated HCl and the elementary sulphur resulting from the decomposition of the thiosulphates is separated, whilst the remaining sulphurous acid intermediate solution is mixed with the spent developing baths and adjusted to a pH of approximately 2 and the resulting, SO.sub.2 -supersaturated solution is heated and pure SO.sub.2 is drawn off in a vacuum. Finally, the residual solution is adjusted to a pH of approximately 10 with Ca(OH).sub.2 and the liberated ammonia is drawn off.
    • 提出了一种处理黑色和白色工艺用过的照相浴的方法,即开发具有碱金属亚硫酸盐,特别是亚硫酸钠的主要含量的洗浴,以及含硫代硫酸盐,特别是硫代硫酸钠和/或硫代硫酸钠的重要含量的固定浴。 并且其特征在于,在沉积包含在浴中的银之后,用浓HCl将废定影液的pH调至约为0.5,并且由硫代硫酸盐分解产生的元素硫被分离,而其余的亚硫酸 将中间溶液与废显影浴混合并调节至约2的pH,并且将所得的SO 2过饱和溶液加热并在真空中抽出纯的SO 2。 最后,用Ca(OH)2将残余溶液调节至约10左右,释放出的氨被排出。
    • 20. 发明授权
    • Method of removing sulphur dioxide from a gaseous stream
    • 从气流中除去二氧化硫的方法
    • US4867961A
    • 1989-09-19
    • US160699
    • 1988-02-26
    • Joseph Palmer
    • Joseph Palmer
    • B01D53/50C01B17/50C01B17/74C01D5/00C01F5/08C01F5/30C01F5/40C01F11/24
    • C01F11/24B01D53/501C01B17/501C01B17/74C01D5/00C01F5/08C01F5/30C01F5/40
    • Capture-fixation of SO.sub.2 from flue and non-ferrous smelter gases is achieved with the use of MgO aqueous slurry as an absorbing medium. During the absorption, most of the MgO is converted to MgSO.sub.4 and the rest is solubilized as MgSO.sub.3 and Mg(HSO.sub.3).sub.2. The clear solution obtained at the end of the absorption is brought to about 40.degree. C. and is treated with sulphuric acid in an amount representing at least 5% in excess of the stoichiometric requirement whereby sulphite and bisulphite of magnesium are converted to magnesium sulphate. The magnesium sulphate obtained above can be used in a two stage addition of potassium chloride to obtain magnesium chloride, and calcined dolomite added to the remainder whereby magnesium hydroxide is precipitated and may be filtered off from the resulting CaCl.sub.2 solution. The process provides a means of removing SO.sub.2 from flue and smelter gases and at the same time produces industrially important chemical products (SO.sub.2, H.sub.2 SO.sub.4, K.sub.2 SO.sub.4, MgO, CaCl.sub.2).
    • 通过使用MgO含水浆料作为吸收介质,可以实现烟道和有色金属冶炼气体SO2捕集固定。 在吸收过程中,大部分的MgO被转化为MgSO 4,其余的以硫酸镁和Mg(HSO3)2的形式溶解。 在吸收结束时获得的澄清溶液达到约40℃,并且用超过化学计量要求的至少5%的量的硫酸处理,从而将亚硫酸盐和亚硫酸氢盐转化成硫酸镁。 得到的硫酸镁可以两步加入氯化钾,得到氯化镁,煅烧后的白云石加入其中,由此使氢氧化镁沉淀,并从所得的CaCl 2溶液中滤出。 该方法提供了从烟道和冶炼气体中除去SO2的方法,同时产生工业上重要的化学产物(SO2,H2SO4,K2SO4,MgO,CaCl2)。