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    • 13. 发明申请
    • Method and system for electrolyzer diagnosis based on curve fitting analysis and efficiency optimization
    • 基于曲线拟合分析和效率优化的电解槽诊断方法与系统
    • US20060289312A1
    • 2006-12-28
    • US11454669
    • 2006-06-16
    • Gilles TremblaySaid BerriahMichel Veillette
    • Gilles TremblaySaid BerriahMichel Veillette
    • C25B15/02G01N27/26C25D21/12B23H3/02
    • H01M8/186C25B1/26C25B9/08C25B15/02H01M10/42H01M10/48Y02E60/528
    • The present invention provides a method and system for electrolyzer diagnosis based on curve fitting analysis and efficiency optimization. The present invention relates to monitoring the electrochemical cell components by using curve fitting and estimating the overall electrolyzer performance by using predictive models. The system according to the present invention comprises an extraction unit for selecting suitable operation zones, a filtering unit, a curve fitting unit performing linear or non-linear regression by using user-defined equations applied to current-voltage data points and a curve fitting goodness analysis unit. The zones are defined as start-up zones, shutdown zones and load change zones. The system further comprises a curve fitting parameters characterization unit for classifying curve fitting parameters by respect to the electrolyzer cells components technology and reference values, and a characterization database for storing fitting coefficients and their characterization.
    • 本发明提供了一种基于曲线拟合分析和效率优化的电解槽诊断方法和系统。 本发明涉及通过使用曲线拟合来监测电化学电池元件,并且通过使用预测模型来估计整个电解槽性能。 根据本发明的系统包括用于选择合适的操作区域的提取单元,过滤单元,通过使用应用于电流 - 电压数据点的用户定义的方程和曲线拟合优度来执行线性或非线性回归的曲线拟合单元 分析单位。 区域被定义为启动区域,关闭区域和负载变化区域。 该系统还包括用于根据电解槽组件技术和参考值分类曲线拟合参数的曲线拟合参数表征单元,以及用于存储拟合系数及其表征的表征数据库。
    • 18. 发明授权
    • Electrochemical machining method and electrochemical machining equipment
    • 电化学加工方法和电化学加工设备
    • US6059954A
    • 2000-05-09
    • US47855
    • 1998-03-25
    • Masayuki SudaToshihiko SakuharaTatsuaki Ataka
    • Masayuki SudaToshihiko SakuharaTatsuaki Ataka
    • B23H3/00B23H3/02B81C99/00C25B15/00
    • B23H3/02
    • An electrochemical machining method in which a work piece and a machining electrode are opposed to each other and dipped in an electrolyte solution, and a surface of the work piece is machined by causing an electrolytic reaction between the surface of the work piece and a tip of the machining electrode in a state where a separating distance between the surface of the work piece and the tip of the machining electrode is adjusted and a desired separating distance is maintained, wherein a zero contact reference position where the surface of the work piece and the tip of the machining electrode are brought into contact with each other and the separating distance between the work piece and the machining electrode is nullified is electrically detected, moving distances of the work piece and the machining electrode from the zero contact reference position are detected, a relative separating distance between the surface of the work piece and the tip of the machining electrode is calculated based on a result of the detection and the work piece is machined in a state where the desired separating distance is maintained.
    • 一种电化学加工方法,其中工件和加工电极彼此相对并浸入电解质溶液中,并且通过使工件的表面和工件的表面之间的电解反应来加工工件的表面 在工件表面与加工用电极的前端之间的分离距离被调整并保持期望的分离距离的状态下的加工电极,其中,零接触基准位置,其中工件的表面和尖端 使电极检测到加工用电极彼此接触并且使工件与加工电极之间的分离距离无效,检测出工件和加工电极与零接触基准位置的移动距离,相对 计算工件表面与加工电极前端之间的距离 并且在保持期望的分离距离的状态下加工工件。
    • 19. 发明授权
    • Method and apparatus for electrochemical machining by bipolar current
pulses
    • 双极电流脉冲进行电化学加工的方法和装置
    • US5833835A
    • 1998-11-10
    • US679025
    • 1996-07-12
    • Nasich Z. GimaevAleksandr N. ZajcevAleksandr L. BelogorskijIgor L. AgafonovNaila A. AmirchanovaViktor N. KucenkoRafail R. Muchutdinov
    • Nasich Z. GimaevAleksandr N. ZajcevAleksandr L. BelogorskijIgor L. AgafonovNaila A. AmirchanovaViktor N. KucenkoRafail R. Muchutdinov
    • B23H3/02B23H3/00B23H7/32
    • B23H3/02B23H2300/10B23H2300/12Y10S204/09
    • Method of electrochemically machining an electrically conductive workpiece (2) in an electrolyte by applying bipolar electric pulses between the workpiece (2) and an electrically conductive electrode (6), one or more current pulses of normal polarity alternating with voltage pulses of opposite polarity. The amplitude (Un) of the voltage pulses is adjusted between two predetermined values (Un1, Un2) derived from the occurrence of a given surface quality of the workpiece (2) and the occurrence of wear of the electrode (6). The derivation is effected by means of at least one test which precedes the machining of the workpiece (2). During the test the amplitude (Un) of the voltage pulses is increased gradually from an initial value to a final value. The two predetermined values (Un1, Un2) are determined upon the occurrence of a sign reversal in the difference between successive values of a parameter which is representative of a property of a gap (5) between the electrode (6) and the workpiece (2). The parameter may be the amplitude (Umin) of a global minimum in the voltage across the gap (5) during the current pulses, which global minimum results from an oscillatory movement of the workpiece (2) and the electrode (6) relative to one another. The parameter may also be the integral (Qn) of the current across the gap (5) during the voltage pulses; or the integral (Fp) of the voltage across the gap (5) during the current pulses; or the resistance across the gap (5); or the size (St) of the gap (5).
    • 通过在工件(2)和导电电极(6)之间施加双极电脉冲来对电解质中的导电工件(2)进行电化学加工的方法,一个或多个正极性的电流脉冲与相反极性的电压脉冲交替。 电压脉冲的振幅(Un)在从工件(2)的给定表面质量的出现和电极(6)的磨损的发生导出的两个预定值(Un1,Un2)之间调节。 通过在加工工件(2)之前的至少一个测试来实现推导。 在测试期间,电压脉冲的振幅(Un)从初始值逐渐增加到最终值。 在表示电极(6)和工件(2)之间的间隙(5)的性质的参数的连续值之间的差异中出现符号反转时,确定两个预定值(Un1,Un2) )。 参数可以是当前脉冲期间跨越间隙(5)的电压中的全局最小值的幅度(Umin),其中工件(2)和电极(6)相对于一个的振荡运动产生的全局最小值 另一个。 该参数还可以是在电压脉冲期间跨越间隙(5)的电流的积分(Qn); 或在电流脉冲期间跨越间隙(5)的电压的积分(Fp); 或跨越间隙的电阻(5); 或间隙(5)的尺寸(St)。