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11. 发明授权

US4722875A Electrochemical cell 失效
标题翻译：电化学电池
公开(公告)号：US4722875A
公开(公告)日：1988-02-02
申请号：US908571
申请日：1986-09-18
申请人： Michael L. Wright
发明人： Michael L. Wright
IPC分类号： H01M4/02 , H01M10/38 , H01M10/39 , H01M10/36
CPC分类号： H01M10/39 , Y10T29/49108
摘要： This invention provides a method of making a cathode for a high temperature rechargeable electrochemical cell. A mixture is formed in particulate form of an alkali metal chloride such as sodium chloride and a substance comprising a transition metal such as iron, and the mixture is impregnated with a chloride ion-containing alkali metal aluminium halide molten salt liquid electrolyte such as molten sodium aluminium chloride. The impregnated mixture is then subjected to at least one charge cycle in a high temperature cell in which it forms the cathode and is separated from an alkali metal anode by a solid electrolyte separator.
摘要翻译：本发明提供了制造用于高温可再充电电化学电池的阴极的方法。混合物形成为碱金属氯化物的颗粒形式，例如氯化钠和包含过渡金属如铁的物质，并将混合物用含氯离子的碱金属铝卤化物熔融盐液体电解质如熔融钠氯化铝。然后将浸渍的混合物在其形成阴极的高温电池中进行至少一个充电循环，并通过固体电解质分离器与碱金属阳极分离。

12. 发明授权

US5458868A Method of making analogues of .beta.-alumina 失效
标题翻译：制造β-氧化铝类似物的方法
公开(公告)号：US5458868A
公开(公告)日：1995-10-17
申请号：US375043
申请日：1995-01-17
申请人： Peter Barrow
发明人： Peter Barrow
IPC分类号： C01F7/02 , C01F7/00 , C01F7/04
CPC分类号： C01F7/028 , C01P2002/32 , C01P2002/72 , C01P2002/78 , C01P2004/62
摘要： The invention provides a method of making an analogue of .beta."-alumina, the analogue having a layered .beta."-alumina spinel-type structure in which ate least some of the Na ions in the layers of Na ions separated by layers of Al and O ions in said .beta."-alumina spinel-type structure are replaced by substitute metal cations. The substitute metal cations are mono-, d- and/or trivalent. The method comprises dispersing in a boehmite having a well developed and highly ordered crystal structure at least one oxide of the substitute metal cations or a precursor thereof to form a starting mixture, and heating the mixture to a conversion temperature at which it is converted to the analogue.
摘要翻译：本发明提供了制备β“ - 氧化铝类似物的方法，该类似物具有层状β” - 氧化铝尖晶石型结构，其中Na离子层中的至少一些Na离子被Al层分离并且所述β“ - 氧化铝尖晶石型结构中的O离子被替代的金属阳离子代替。替代金属阳离子是单，二和/或三价。该方法包括将具有良好显影和高度有序晶体结构的勃姆石分散在至少一种替代金属阳离子或其前体的氧化物上以形成起始混合物，并将该混合物加热至转化温度类似物。

13. 发明授权

US5009357A Joining of ceramic components to metal components 失效
标题翻译：将陶瓷部件连接到金属部件
公开(公告)号：US5009357A
公开(公告)日：1991-04-23
申请号：US385323
申请日：1989-07-25
申请人： Derrick J. Baker , Walter G. Bugden , Peter R. Smith
发明人： Derrick J. Baker , Walter G. Bugden , Peter R. Smith
IPC分类号： B23K20/00 , C04B37/02 , H01M10/39
CPC分类号： C04B37/026 , C04B2235/6567 , C04B2237/122 , C04B2237/343 , C04B2237/404 , C04B2237/405 , C04B2237/406 , C04B2237/407 , C04B2237/61 , C04B2237/708 , C04B2237/765 , C04B2237/78
摘要： The invention provides a method of joining together a ceramic component and a metal component. According to the invention a surface of the ceramic component is metallized with a metallizing metal to form a metallized layer thereon. The metal component is then thermocompression bonded to the metallized layer, optionally after the metallized layer is plated with a continuous metal layer. For electrochemical cell applications, the ceramic component is typically alpha-alumina, the metal of the metallized layer is typically selected from tantalum, titanium, vanadium, tungsten and molybdenum, and the metal component typically comprises, in metallic or alloy form, at least one of iron, nickel, cobalt, chromium, manganese or copper.
摘要翻译：本发明提供了一种将陶瓷组分和金属组分接合在一起的方法。根据本发明，陶瓷部件的表面用金属化金属金属化以在其上形成金属化层。然后将金属组分热压粘合到金属化层，任选地在金属化层被镀上连续的金属层之后。对于电化学电池应用，陶瓷组分通常是α-氧化铝，金属化层的金属通常选自钽，钛，钒，钨和钼，并且金属组分通常包含金属或合金形式的至少一种的铁，镍，钴，铬，锰或铜。

14. 发明授权

US4975343A Electrochemical cell 失效
标题翻译：电化学电池
公开(公告)号：US4975343A
公开(公告)日：1990-12-04
申请号：US357519
申请日：1989-05-24
申请人： Johan Coetzer
发明人： Johan Coetzer
IPC分类号： H01M10/39
CPC分类号： H01M10/39 , H01M10/399 , Y10T29/49108
摘要： An electrochemical cell has a molten alkali metal anode separated by a separator which is a conductor of anode ions from an alkali metal aluminium halide molten electrolyte which couples the anode to a cathode having an active material comprising Fe, Ni, Co, Cr and/or Mn. The molten electrolyte is doped by a dopant M.sub.2 X, MY or M.sub.A Z in which M is the anode metal, X, Y and Z are respectively anions which are divalent, monovalent and polyvalent. The dopant acts to reduce the Lewis acidity of the molten electrolyte.
摘要翻译：电化学电池具有通过分离器分离的熔融碱金属阳极，隔板是来自碱金属铝卤化物熔融电解质的阳极离子的导体，其将阳极耦合到具有包含Fe，Ni，Co，Cr和/或 Mn。熔融电解质由掺杂剂M2X，MY或MAZ掺杂，其中M是阳极金属，X，Y和Z分别是二价，一价和多价的阴离子。掺杂剂用于降低熔融电解质的路易斯酸度。

15. 发明授权

US4795685A Electrochemical cell 失效
标题翻译：电化学电池
公开(公告)号：US4795685A
公开(公告)日：1989-01-03
申请号：US873168
申请日：1986-06-11
申请人： Roger J. Bones , Roy C. Galloway , Johan Coetzer , David A. Teagle
发明人： Roger J. Bones , Roy C. Galloway , Johan Coetzer , David A. Teagle
IPC分类号： H01M4/52 , H01M10/39 , H01M10/42
CPC分类号： H01M10/39 , H01M10/4235
摘要： The invention provides a method of protecting an electrochemical cell which has a molten sodium anode, a chloride-ion containing sodium aluminum halide molten salt electrolyte, an iron-containing cathode in contact with the electrolyte and a solid conductor of sodium ions which separates the anode from the electrolyte, from the adverse effects of overcharging. The method comprises operating the cell, to prevent oxidation of iron to FeCl.sub.3 in the cathode, by connecting it in parallel with a protective cell having an open circuit charging plateau at a voltage less than the open circuit voltage of the Fe/FeCl.sub.3 //Na plateau of the cell being protected, and greater than the open circuit voltage, in its fully charged state, of the cell being protected. The invention also provides a cell of this type protected in this fashion, a battery including one or more such protected cells, and a cathode for such cells.
摘要翻译：本发明提供了一种保护电化学电池的方法，该电化学电池具有熔融的钠阳极，含氯化钠的卤化钠熔融盐电解质，与电解质接触的含铁阴极和钠离子的固体导体，其分离阳极从电解液，过度充电的不利影响。该方法包括操作电池，以防止铁在阴极中氧化成FeCl 3，通过将其与具有低于Fe / FeCl 3 // Na的开路电压的开路充电平台的保护电池并联连接电池的高原被保护，并且大于被保护的电池的处于其完全充电状态的开路电压。本发明还提供以这种方式保护的这种类型的电池，包括一个或多个这种受保护的电池的电池和用于这种电池的阴极。

16. 发明授权

US4772293A Manufacture of electrochemical cells 失效
标题翻译：电化学电池的制造
公开(公告)号：US4772293A
公开(公告)日：1988-09-20
申请号：US40925
申请日：1987-04-21
申请人： Walter G. Bugden , Peter R. Smith
发明人： Walter G. Bugden , Peter R. Smith
IPC分类号： H01M2/02 , C04B37/02 , H01M2/04 , H01M10/39 , H01M2/00 , B23K31/02
CPC分类号： H01M2/0447 , H01M10/39 , Y10T29/49108
摘要： The invention provides a method of manufacturing an electrochemical cell housing wherein a beta-alumina tube has an open end attached to a casing via an alpha-alumina ring. In the method the alpha-alumina ring is thermocompression bonded to a metal ring by hot isostatic pressing, the alpha-alumina ring is then glass welded to the open end of the tube, and the metal ring is metal welded to the casing. The invention also provides a cell housing wherein a beta-alumina tube is located in spaced relationship within a metal casing. The tube is glass welded to an alpha-alumina ring which is thermocompression bonded on a curved radially facing surface thereof to a metal ring, the metal ring being metal welded to the casing.
摘要翻译：本发明提供了一种制造电化学电池壳体的方法，其中β-氧化铝管具有通过α-氧化铝环连接到壳体的开口端。在该方法中，通过热等静压将α-氧化铝环热压接合到金属环上，然后将α-氧化铝环玻璃焊接到管的开口端，金属环被金属焊接到壳体上。本发明还提供了一种电池壳体，其中β-氧化铝管在金属壳体内以间隔的关系定位。该管被玻璃焊接到α-氧化铝环上，该α-氧化铝环在其弯曲的径向对置的表面上被热压粘合到金属环上，金属环被金属焊接到壳体上。

17. 发明授权

US4612266A Electrochemical cell 失效
标题翻译：电化学电池
公开(公告)号：US4612266A
公开(公告)日：1986-09-16
申请号：US765122
申请日：1985-08-13
申请人： Roger J. Bones , Roy C. Galloway , Johan Coetzer , David A. Teagle
发明人： Roger J. Bones , Roy C. Galloway , Johan Coetzer , David A. Teagle
IPC分类号： H01M4/52 , H01M10/39 , H01M10/42 , H01M4/36
CPC分类号： H01M10/39 , H01M10/4235
摘要： The invention provides a method of protecting an electrochemical cell which has a molten sodium anode, a chloride-ion containing sodium aluminum halide molten salt electrolyte, an iron-containing cathode in contact with the electrolyte and a solid conductor of sodium ions which separates the anode from the electrolyte, from the adverse effects of overcharging. The method comprises operating the cell, to prevent oxidation of iron to FeCl.sub.3 in the cathode, by connecting it in parallel with a protective cell having an open circuit charging plateau at a voltage less than the open circuit voltage of the Fe/FeCl.sub.3 //Na plateau of the cell being protected, and greater than the open circuit voltage, in its fully charged state, of the cell being protected. The invention also provides a cell of this type protected in this fashion, a battery including one or more such protected cells, and a cathode for such cells.
摘要翻译：本发明提供了一种保护电化学电池的方法，该电化学电池具有熔融的钠阳极，含氯化钠的卤化钠熔融盐电解质，与电解质接触的含铁阴极和钠离子的固体导体，其分离阳极从电解液，过度充电的不利影响。该方法包括操作电池，以防止铁在阴极中氧化成FeCl 3，通过将其与具有低于Fe / FeCl 3 // Na的开路电压的开路充电平台的保护电池并联连接电池的高原被保护，并且大于被保护的电池的处于其完全充电状态的开路电压。本发明还提供以这种方式保护的这种类型的电池，包括一个或多个这种受保护的电池的电池和用于这种电池的阴极。

18. 发明授权

US4585712A Battery comprising high temperature rechargeable electrochemical cells and support means 失效
标题翻译：电池包括高温可充电电化学电池和支撑装置
公开(公告)号：US4585712A
公开(公告)日：1986-04-29
申请号：US692233
申请日：1985-01-17
申请人： Roger J. Wedlake
发明人： Roger J. Wedlake
IPC分类号： H01M10/50
CPC分类号： B60L11/1875 , B60L11/1879 , F28D15/0275 , H01M10/615 , H01M10/625 , H01M10/6552 , H01M10/6556 , H01M10/6563 , H01M10/6595 , H01M10/613 , H01M10/653 , H01M10/6551 , H01M10/6555 , H01M10/6571 , Y02T10/7005 , Y02T10/705
摘要： A battery of interconnected high-temperature rechargeable electrochemical cells, a method of operating the battery and support means for supporting and heating the battery are provided. The support means acts to carry the cells and to heat the cells from below. Heating the cells from below is electrical and/or by circulating heated gas through a plinth on which the cells rest, the gases being derived from the catalytic conversion of a hydrocarbon fuel.
摘要翻译：提供了一组互连的高温可再充电电化学电池，一种操作电池的方法和用于支撑和加热电池的支撑装置。支撑装置用于携带细胞并从下方加热细胞。从下面加热电池是电的和/或通过循环加热的气体通过细胞搁置的底座，气体源自烃燃料的催化转化。

19. 发明授权

US4560627A Electrochemical cell 失效
公开(公告)号：US4560627A
公开(公告)日：1985-12-24
申请号：US631905
申请日：1984-07-18
申请人： Roger J. Bones , Roy C. Galloway , Johan Coetzer , David A. Teagle
发明人： Roger J. Bones , Roy C. Galloway , Johan Coetzer , David A. Teagle
IPC分类号： H01M4/52 , H01M10/39 , H01M10/42 , H01M4/36
CPC分类号： H01M10/39 , H01M10/4235
摘要： The invention provides a method of protecting an electrochemical cell which has a molten sodium anode, a chloride-ion containing sodium aluminum halide molten salt electrolyte, an iron-containing cathode in contact with the electrolyte and a solid conductor of sodium ions which separates the anode from the electrolyte, from the adverse effects of overcharging. The method comprises operating the cell, to prevent oxidation of iron to FeCl.sub.3 in the cathode, by connecting it in parallel with a protective cell having an open circuit charging plateau at a voltage less than the open circuit voltage of the Fe/FeCl.sub.3 //Na plateau of the cell being protected, and greater than the open circuit voltage, in its fully charged state, of the cell being protected. The invention also provides a cell of this type protected in this fashion, a battery including one or more such protected cells, and a cathode for such cells.

20. 发明授权

US4895773A Electrochemical cell 失效
标题翻译：电化学电池
公开(公告)号：US4895773A
公开(公告)日：1990-01-23
申请号：US253267
申请日：1988-10-04
申请人： Roger J. Bones , James L. Sudworth
发明人： Roger J. Bones , James L. Sudworth
IPC分类号： H01M10/39 , H01M10/42
CPC分类号： H01M10/39 , H01M10/42
摘要： The invention provides a rechargeable electrochemical power storage cell. The cell has an anode compartment defined between a cell casing and a separator, the anode compartment containing active anode material which is liquid at the operating temperature of the cell. The separator defines a cathode compartment containing an electrolyte which is liquid at the operating temperature of the cell, and an active cathode material. The separator separates said compartments from each other and during discharge of the cell the active anode material passes from the anode compartment to the cathode compartment through the separator, to enter the cathode compartment in ionic form. The active anode material passes through the separator from the cathode compartment to the anode compartment during charging of the cell. At least one of said compartments is sealed and is provided with switch means, which switch means is operative in response to an excursion, past a threshold value, of pressure in the sealed compartment arising from passage of active anode material through the separator during operation of the cell while it is connected to an external circuit, to prevent further operation of the cell while said pressure remains past said threshold value.
摘要翻译：本发明提供一种可再充电电化学蓄电池。该电池具有限定在电池壳体和隔板之间的阳极室，阳极室包含在电池工作温度下为液态的活性阳极材料。分离器限定了包含在电池的工作温度下为液体的电解质的阴极室和活性阴极材料。隔板将隔间彼此隔开，并且在电池放电期间，活性阳极材料通过隔板从阳极隔室通过阴极隔室，以离子形式进入阴极室。活性阳极材料在电池充电期间通过分离器从阴极室传递到阳极室。所述隔间中的至少一个是密封的，并且设置有开关装置，该开关装置响应于在活动阳极材料通过隔离件期间在密封隔室中的偏移超过阈值的偏移而操作，该单元在连接到外部电路时，以防止在所述压力保持超过所述阈值时电池的进一步操作。

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