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11. 发明授权

US06812316B2 Powder coating compositions and powder slurry coating compositions containing monomeric difunctional compounds 失效
标题翻译：含有单体双官能化合物的粉末涂料组合物和粉末浆料涂料组合物
公开(公告)号：US06812316B2
公开(公告)日：2004-11-02
申请号：US10261427
申请日：2002-09-30
申请人： Walter H. Ohrbom , David J. Law , Robert D. Weise
发明人： Walter H. Ohrbom , David J. Law , Robert D. Weise
IPC分类号： C08G1881
CPC分类号： C09D133/14 , C09D5/02 , C09D5/033 , C09D201/00 , C09D201/02 , C09D201/025 , Y10S525/934
摘要： The curable coating compositions of the invention comprise a particulate component having at least one binder component (a) which is a solid at 75° F./24° C., and an additive component (b). The curable coating compositions further comprise a crosslinking component (c) reactive with the at least one binder component (a). Additive component (b) has from 12 to 72 carbon atoms, is substantially free of any heteroatoms, is not a crystalline solid at 75° F./24° C. and comprises a mixture of two or more structures selected from the group consisting of aliphatic structures for additive component (b), aromatic-containing structures for additive component (b), cycloaliphatic-containing structures for additive component (b), and mixtures thereof, wherein at least one of the two or more structures is either a cycloaliphatic-containing structure or an aromatic-containing structure. The curable coating compositions are useful as powder coating compositions and powder slurry coating compositions having improved application and/or performance properties.
摘要翻译：本发明的可固化涂料组合物包含具有至少一种在75°F / 24℃下为固体的粘合剂组分（a）和添加剂组分（b）的颗粒组分。可固化涂料组合物还包含与至少一种粘合剂组分（a）反应的交联组分（c）。添加剂组分（b）具有12至72个碳原子，基本上不含任何杂原子，在75°F / 24℃下不是结晶固体，并且包含两种或更多种选自以下的结构的混合物：用于添加剂组分（b）的脂族结构，用于添加剂组分（b）的含芳族化合物结构，用于添加剂组分（b）的含脂环族基团的结构）及其混合物，其中两种或多种结构中的至少一种是脂环族 - 含有结构或含芳香族结构。可固化涂料组合物可用作具有改进的应用和/或性能特性的粉末涂料组合物和粉末淤浆涂料组合物。

12. 发明授权

US06777495B2 Powder coating with tris(hydroxyethyl) isocyanurate-anhydride reaction product crosslinker 失效
标题翻译：粉末涂料用三（羟乙基）异氰脲酸酐 - 酐反应产物交联剂
公开(公告)号：US06777495B2
公开(公告)日：2004-08-17
申请号：US10191643
申请日：2002-07-09
申请人： Walter H. Ohrbom , David J. Law , Robert D. Weise
发明人： Walter H. Ohrbom , David J. Law , Robert D. Weise
IPC分类号： C08K322
CPC分类号： C08G59/4238 , C08G18/4661 , C08G2150/20 , C09D163/00
摘要： Powder coating composition for automotive exterior coatings with compatibility with other coatings and resistance to yellowing include a film-forming material such as a polyepoxide and an acid-functional crosslinker that is a reaction product of 1,3,5-tris(2-hdyroxyethyl)isocyanurate and a cyclic anhydride.
摘要翻译：用于汽车外涂层的粉末涂料组合物与其它涂料的相容性和耐黄变性包括成膜材料如聚环氧化物和酸官能交联剂，其是1,3,5-三（2-羟乙基）异氰脲酸酯和环状酸酐。

13. 发明授权

US07163984B2 Waterborne coating compositions containing monomeric difunctional compounds 失效
标题翻译：含有单体双官能化合物的水性涂料组合物
公开(公告)号：US07163984B2
公开(公告)日：2007-01-16
申请号：US10261428
申请日：2002-09-30
申请人： Walter H. Ohrbom , Sergio E. Balatan , David J. Law , Robert D. Weise
发明人： Walter H. Ohrbom , Sergio E. Balatan , David J. Law , Robert D. Weise
IPC分类号： C08G18/00
CPC分类号： C09D5/02 , C09D133/14 , C09D201/00 , C09D201/02 , C09D201/025
摘要： The invention provides curable waterborne coating compositions comprising an aqueous dispersion (A) comprising an organic binder component (A1) comprising at least 5% by weight of a reactive component (a), based on the total weight of organic binder component (A1), and at least one crosslinking component (B). The reactive component (a) is substantially free of any heteratoms and is a not a crystalline solid at room temperature and comprises from (i) 12 to 72 carbon atoms, and (ii) at least two functional groups.The curable waterborne coating compositions of the invention show significantly improved pop resistance while also providing improved chip resistance, weathering resistance, flexibility, and/or scratch & mar resistance.
摘要翻译：本发明提供可固化的水性涂料组合物，其包含基于有机粘合剂组分（A1）的总重量的包含至少5重量％的反应性组分（a）的有机粘合剂组分（A1）的水性分散体（A）和至少一种交联组分（B）。反应性组分（a）基本上不含任何杂原子，并且在室温下不是结晶固体，并且包含（i）12至72个碳原子，和（ii）至少两个官能团。本发明的可固化水性涂料组合物显示出显着改善的弹性阻力，同时还提供改善的耐碎屑性，耐候性，柔韧性和/或抗划痕性。

14. 发明授权

US07205029B2 Method of providing cured coating films free of popping defects 有权
标题翻译：提供没有突出缺陷的固化涂膜的方法
公开(公告)号：US07205029B2
公开(公告)日：2007-04-17
申请号：US10261888
申请日：2002-09-30
申请人： Walter H. Ohrbom , Sergio E. Balatan , David J. Law , Robert D. Weise
发明人： Walter H. Ohrbom , Sergio E. Balatan , David J. Law , Robert D. Weise
IPC分类号： B05D3/00
CPC分类号： C09D201/00 , C08F212/14 , C08K5/205 , C09D5/002 , C09D5/033 , C09D7/63 , C09D133/08 , C09D201/02 , C08L2666/28 , C08L2666/36
摘要： A method for providing cured coating films free of popping defects. The method requires the application to a substrate of at least 2.0 mils/50.8 microns of a uncured curable coating composition comprising an anti-popping component (a), a film-forming component (b), and a crosslinking component (c), wherein anti-popping component (a) has from 12 to 72 carbon atoms, is substantially free of any heteroatoms, is not a crystalline solid at room temperature and comprises a mixture of two or more structures selected from the group consisting of aliphatic structures for anti-popping component (a), aromatic-containing structures for anti-popping component (a), cycloaliphatic-containing structures for anti-popping component (a), and mixtures thereof, at least one of the two or more structures being a cycloaliphatic-containing structure or an aromatic-containing structure. The coated uncured substrate is cured to provide a cured film free of popping defects with an average film build of at least 2.0 mils/50.8 microns.
摘要翻译：提供没有突出缺陷的固化涂膜的方法。该方法需要施用至少2.0密耳/ 50.8微米的包含抗爆组分（a），成膜组分（b）和交联组分（c）的未固化的可固化涂料组合物的基材，其中抗突起组分（a）具有12至72个碳原子，基本上不含任何杂原子，在室温下不是结晶固体，并且包含两种或更多种选自以下的结构的混合物：脂肪族结构，弹性组分（a），用于抗爆组分（a）的含芳族化合物的结构，用于抗爆组分（a）的含脂环族的结构及其混合物，所述两种或多种结构中的至少一种是含脂环族的结构或含芳族结构。固化涂覆的未固化基底以提供没有突出缺陷的固化膜，其平均膜构成为至少2.0密耳/ 50.8微米。

15. 发明授权

US07060357B2 Powder coatings containing symmetrical additives 失效
标题翻译：包含对称添加剂的粉末涂料
公开(公告)号：US07060357B2
公开(公告)日：2006-06-13
申请号：US10265036
申请日：2002-10-04
申请人： Walter H. Ohrbom , David J. Law , Robert D. Weise , James A. Laugal
发明人： Walter H. Ohrbom , David J. Law , Robert D. Weise , James A. Laugal
IPC分类号： B32B27/40 , B32B27/42 , C08L75/04
CPC分类号： C09D5/037 , C08G2150/20 , C09D161/20 , Y10S525/934 , Y10T428/31551 , C08L2666/02
摘要： A coating composition contains solid particulates of a mixture of an aminoplast crosslinking agent, a solid polymer having functionality reactive with the aminoplast crosslinking agent, and a crystalline, carbamate-functional additive. The crystalline, carbamate-functional additive has a melting point of at least about 30° C. and is up to about 15% by weight of the powder coating composition.
摘要翻译：涂料组合物含有氨基塑料交联剂，具有与氨基塑料交联剂反应的官能团的固体聚合物和结晶的氨基甲酸酯官能添加剂的混合物的固体颗粒。结晶的氨基甲酸酯官能添加剂具有至少约30℃的熔点并且高达粉末涂料组合物的约15重量％。

16. 发明授权

US06822040B2 Basecoat composition with improved repair properties 失效
标题翻译：底漆组合物具有改进的修复性能
公开(公告)号：US06822040B2
公开(公告)日：2004-11-23
申请号：US09962700
申请日：2001-09-25
申请人： Leslie G. Baugh , David K. K. Lau , Thomas C. Balch , Sergio E. Balatan , Walter H. Ohrbom , James A. Laugal , David J. Law
发明人： Leslie G. Baugh , David K. K. Lau , Thomas C. Balch , Sergio E. Balatan , Walter H. Ohrbom , James A. Laugal , David J. Law
IPC分类号： C08L5100
CPC分类号： B05D7/536 , B05D7/577 , C09D133/08 , Y10T428/2982 , Y10T428/31529 , C08L2666/54 , C08L2666/14
摘要： A basecoat composition includes an acrylic polymer prepared from a combination of monomers including at least about 30% by weight ethyl acrylate, methyl acrylate, methyl methacrylate, or a combination of these. The basecoat composition also includes methylated melamine-formaldehyde resin and up to about 10% by weight of a butylated melamine-formaldehyde resin, based on the weight of the basecoat composition vehicle and butylated melamine resin. An at least partially cured layer of the basecoat composition offers improved adhesion with a coating composition layer applied over it and cured, whether the coating composition layer applied over it is another layer of the basecoat composition itself or a layer of a clearcoat composition.
摘要翻译：底漆组合物包括由包含至少约30重量％的丙烯酸乙酯，丙烯酸甲酯，甲基丙烯酸甲酯或它们的组合的单体组合组合制备的丙烯酸聚合物。底漆组合物还包括甲基化三聚氰胺甲醛树脂和最多约10重量％的丁基化三聚氰胺 - 甲醛树脂，基于底漆组合物载体和丁基化三聚氰胺树脂的重量。底涂层组合物的至少部分固化的层提供与涂覆在其上并且固化的涂料组合物层的改善的粘合性，涂覆在其上的涂料组合物层是否是底涂层组合物本身的另一层或透明涂层组合物层。

17. 发明授权

US08008416B2 Curable alkoxycarbonylamino compositions, coatings, and methods 有权
标题翻译：可固化的烷氧基羰基氨基组合物，涂料和方法
公开(公告)号：US08008416B2
公开(公告)日：2011-08-30
申请号：US12345237
申请日：2008-12-29
申请人： Walter H. Ohrbom
发明人： Walter H. Ohrbom
IPC分类号： C08F26/02
CPC分类号： C07C271/16 , C07C271/64
摘要： A compound, oligomer, or polymer having a functional group of formula (I) wherein R is a group having 1 to 12 carbons and optionally including one or more heteroatoms selected from oxygen, nitrogen, and sulfur is useful in curable compositions having active hydrogen functional groups reactive with group (I). The functional groups of formula (I) and active hydrogen functional groups may be part of the same material or different materials. In some embodiments a filler is surface modified to have a functional group of formula (I). Also disclosed is a method of making a material having a functional group of formula (I).
摘要翻译：具有式（I）官能团的化合物，低聚物或聚合物可用于具有活性氢官能团的可固化组合物中，其中R是具有1至12个碳原子并且任选地包含一个或多个选自氧，氮和硫的杂原子的基团组与组（I）反应。式（I）和活性氢官能团的官能团可以是相同材料或不同材料的一部分。在一些实施方案中，填料被表面改性以具有式（I）的官能团。还公开了制备具有式（I）的官能团的材料的方法。

18. 发明授权

US07772304B2 Plasticizing component and a curable coating composition including the same 有权
标题翻译：增塑组分和包含其的可固化涂料组合物
公开(公告)号：US07772304B2
公开(公告)日：2010-08-10
申请号：US11560932
申请日：2006-11-17
申请人： Walter H. Ohrbom , John E. Boisseau
发明人： Walter H. Ohrbom , John E. Boisseau
IPC分类号： C08K5/3492 , C07D251/30
CPC分类号： C09D133/066 , C09D133/14
摘要： A curable coating composition includes a plasticizing component. The plasticizing component includes an isocyanurate core and at least one low surface tension group pending from the isocyanurate core. The low surface tension group may be a) a fatty chain includes at least 6 carbon atoms, b) a silicon-containing group having at least 1 silicon atom, c) a fluorocarbon, and combinations thereof. The low surface tension group may have cross-linkable functional groups pending therefrom. In addition to the plasticizing component, the curable coating composition further includes a resin component and a crosslinking agent that is reactive with the resin component. The curable coating composition including the plasticizing component is capable of forming a cured film that has resistance to both cracking and etching that, to date, has not been achieved with known plasticizing components.
摘要翻译：可固化涂料组合物包括增塑组分。增塑组分包括异氰脲酸酯芯和至少一种从异氰脲酸酯芯悬浮的低表面张力组。低表面张力基团可以是a）脂肪链包含至少6个碳原子，b）具有至少1个硅原子的含硅基团，c）碳氟化合物及其组合。低表面张力组可能具有可交联的官能团。除了增塑组分之外，可固化涂料组合物还包括树脂组分和与树脂组分反应的交联剂。包含增塑组分的可固化涂料组合物能够形成耐开裂和蚀刻的固化膜，迄今为止，已知的增塑组分尚未实现。

19. 发明申请

US20080119592A1 PLASTICIZING COMPONENT AND A CURABLE COATING COMPOSITION INCLUDING THE SAME 有权
标题翻译：塑化组分和可固化的涂料组合物，包括它们
公开(公告)号：US20080119592A1
公开(公告)日：2008-05-22
申请号：US11560932
申请日：2006-11-17
申请人： Walter H. Ohrbom , John E. Boisseau
发明人： Walter H. Ohrbom , John E. Boisseau
IPC分类号： C08K5/3492 , C07D251/30
CPC分类号： C09D133/066 , C09D133/14
摘要： A curable coating composition includes a plasticizing component. The plasticizing component includes an isocyanurate core and at least one low surface tension group pending from the isocyanurate core. The low surface tension group may be a) a fatty chain includes at least 6 carbon atoms, b) a silicon-containing group having at least 1 silicon atom, c) a fluorocarbon, and combinations thereof. The low surface tension group may have cross-linkable functional groups pending therefrom. In addition to the plasticizing component, the curable coating composition further includes a resin component and a crosslinking agent that is reactive with the resin component. The curable coating composition including the plasticizing component is capable of forming a cured film that has resistance to both cracking and etching that, to date, has not been achieved with known plasticizing components.
摘要翻译：可固化涂料组合物包括增塑组分。增塑组分包括异氰脲酸酯芯和至少一种从异氰脲酸酯芯悬浮的低表面张力组。低表面张力基团可以是a）脂肪链包含至少6个碳原子，b）具有至少1个硅原子的含硅基团，c）碳氟化合物及其组合。低表面张力组可能具有可交联的官能团。除了增塑组分之外，可固化涂料组合物还包括树脂组分和与树脂组分反应的交联剂。包含增塑组分的可固化涂料组合物能够形成耐开裂和蚀刻的固化膜，迄今为止，已知的增塑组分尚未实现。

20. 发明授权

US07297749B2 Asymmetric polyisocyanate monomers in urethane polymers and oligomers to reduce crystallinity 失效
标题翻译：聚氨酯聚合物和低聚物中的不对称多异氰酸酯单体，以降低结晶度
公开(公告)号：US07297749B2
公开(公告)日：2007-11-20
申请号：US10965346
申请日：2004-10-14
申请人： Craig S. Schang , Walter H. Ohrbom , Joanne Casale , Thaddeus J. Lepkowski
发明人： Craig S. Schang , Walter H. Ohrbom , Joanne Casale , Thaddeus J. Lepkowski
IPC分类号： C08G18/70
CPC分类号： C09D175/04 , C08G18/8016 , C08G18/8058 , C08L2666/16
摘要： Compositions comprising a reaction product of a) an asymmetrical, saturated polyisocyanate that is non-cyclic, non-aromatic, and has at least 3 carbon atoms in the polyisocyanate per isocyanate group, b) a material that is at least one of i) a primary carbamate material having at least one functional group reactive with an isocyanate and at least one primary carbamate group or a group convertible to a primary carbamate group and ii) a reaction product of the primary carbamate material and an extending agent, and c) optionally, a chain extension agent that has at least difunctional reactivity with an isocyanate. Also, methods of making these compositions.
摘要翻译：包含a）不对称饱和多异氰酸酯的反应产物的组合物，其是非环状的，非芳族的，并且在每个异氰酸酯基团的多异氰酸酯中具有至少3个碳原子，b）至少一种i）具有至少一个与异氰酸酯和至少一个伯氨基甲酸酯基团或可转换成伯氨基甲酸酯基团的基团反应的官能团的主要氨基甲酸酯材料和ii）主要氨基甲酸酯材料和延伸剂的反应产物，和c）任选地，与异氰酸酯具有至少双官能反应性的扩链剂。而且，制备这些组合物的方法。

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