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11. 发明授权

US4438060A Process for producing cross-sectionally stable, hygroscopic fibers and filaments having a core-jacket structure 失效
标题翻译：用于生产横截面稳定的吸湿纤维和具有芯 - 夹套结构的细丝的方法
公开(公告)号：US4438060A
公开(公告)日：1984-03-20
申请号：US210467
申请日：1980-11-24
申请人： Ulrich Reinehr , Toni Herbertz , Hermann-Josef Jungverdorben
发明人： Ulrich Reinehr , Toni Herbertz , Hermann-Josef Jungverdorben
IPC分类号： D01D5/247 , D01D5/34 , D01F1/08 , D01F6/18 , D01F6/54
CPC分类号： D01F6/18 , D01D5/247 , D01D5/34 , D01F1/08 , Y10T428/2975
摘要： Hygroscopic filaments or fibers with a core-jacket structure of hydrophobic, filament-forming synthetic polymers having a water retention capacity of at least 10% and having uniform round to oval cross-sectional profiles are obtained by a dry-spinning process which comprises addition of a substance to the spinning solvent which(a) has a higher boiling point than the spinning solvent used,(b) is readily miscible with the spinning solvent and with water,(c) is a non-solvent for the polymer to be spun,and addition of another substance which(a) is soluble in the non-solvent for the polymer to be spun,(b) is soluble in the solvent for the polymer(c) remains dissolved in the non-solvent for the polymer during solidification of the filaments,(d) is insoluble in water, and(e) does not evaporate to any significant extent during the spinning process,to the system in quantities of at least 1% by weight, based on polymer solids/spinning solvent/non-solvent carrying out the spinning process in such a way that the non-solvent does not evaporate to any significant extent in the spinning duct and washing out the non-solvent from the solidified filaments.
摘要翻译：通过干纺丝方法获得吸水性长丝或具有疏水的长丝形成合成聚合物的芯 - 夹层结构的纤维，其具有至少10％的保水能力并且具有均匀的圆形至椭圆形横截面轮廓，其包括添加（a）沸点比所使用的纺丝溶剂高的纺丝溶剂的物质，（b）易与纺丝溶剂和水混溶，（c）是纺丝聚合物的非溶剂，和（a）可溶于用于纺丝聚合物的非溶剂中的另一物质，（b）可溶于聚合物（c）的溶剂中，溶于固化的聚合物的非溶剂中长丝（d）不溶于水，（e）在纺丝过程中不会以至少1重量％的量以体积计，以聚合物固体/纺丝溶剂/非纺丝方式蒸发至体系，溶剂进行纺丝过程 ss，使得非溶剂在纺丝管中不会蒸发到任何显着程度，并从固化的丝中洗出非溶剂。

12. 发明授权

US4332765A Process for spinning hydrophilic acrylic fibres of low density 失效
标题翻译：低密度亲水丙烯酸纤维纺丝方法
公开(公告)号：US4332765A
公开(公告)日：1982-06-01
申请号：US82449
申请日：1979-10-09
申请人： Ulrich Reinehr , Toni Herbertz , Hermann-Josef Jungverdorben
发明人： Ulrich Reinehr , Toni Herbertz , Hermann-Josef Jungverdorben
IPC分类号： D01F6/18 , D01D5/04 , D01D5/247 , D01D5/26 , D01F6/38 , D01F6/54 , D01F8/08 , D02G3/00
CPC分类号： D01D5/247 , D01F6/54 , D01F8/08
摘要： The invention relates to dry-spun hydrophilic core-jacket filaments or fibres of a hydrophobic filament forming synthetic polymer. The filaments or fibres having a porosity of at least 50%, a water-retention capacity of at least 100% and a mercury density of at most 0.7 g/cm.sup.3. The invention also relates to a process for the production of these fibres and filaments.
摘要翻译：本发明涉及干纺亲水性芯 - 夹芯长丝或疏水长丝形成合成聚合物的纤维。长丝或纤维具有至少50％的孔隙率，至少100％的保水能力和至多0.7g / cm 3的汞密度。本发明还涉及生产这些纤维和长丝的方法。

13. 发明授权

US4224269A Process for spinning hygroscopic filaments and fibers 失效
标题翻译：纺丝吸湿丝和纤维的方法
公开(公告)号：US4224269A
公开(公告)日：1980-09-23
申请号：US887212
申请日：1978-03-16
申请人： Ulrich Reinehr , Toni Herbertz , Hermann-Josef Jungverdorben
发明人： Ulrich Reinehr , Toni Herbertz , Hermann-Josef Jungverdorben
IPC分类号： D01F6/18 , D01D5/04 , D01F6/38 , D01F8/08 , B29F3/10
CPC分类号： D01F6/38 , D01D5/04 , Y10T428/2929 , Y10T428/2935
摘要： The invention relates to a process for the production of hygroscopic filaments or fibers by dry-spinning a polymer solution wherein immediately they issue from the spinning jet or at the latest at a time when their solidification is still not complete, the filaments are brought into contact with water-vapour or with the vapour of another liquid which coagulates filaments.
摘要翻译：本发明涉及一种通过干式纺丝聚合物溶液来生产吸湿丝或纤维的方法，其中立即从纺丝射流发出，或者在最后凝固仍然不完全的时候，丝被接触与水蒸气或与另一种液体的蒸气凝结细丝。

14. 发明授权

US5013504A Dry spinning process with hot air and with spinning cell outputs greater than 20 kg per cell per hour 失效
标题翻译：干燥纺丝过程用热空气和纺丝细胞输出大于每公斤每小时20公斤
公开(公告)号：US5013504A
公开(公告)日：1991-05-07
申请号：US411078
申请日：1989-09-22
申请人： Ulrich Reinehr , Gunter Turck , Rolf B. Hirsch , Hermann-Josef Jungverdorben
发明人： Ulrich Reinehr , Gunter Turck , Rolf B. Hirsch , Hermann-Josef Jungverdorben
IPC分类号： D01D5/04 , D01F6/18 , D01F6/38 , D01F11/06
CPC分类号： D01D5/04 , D01F6/18
摘要： A process for the dry spinning of synthetic polymers, in particular polyacylonitrile fibres, from solutions in high polar solvents, such as dimethylformamide, which are heated to 100.degree.-150.degree. C. shortly upstream of the spinneret and spun there by spinnerets having a certain shape, and in the spinning cell the specific energy supply is at least 0.090 kWh per m.sup.2 of heated cell area, the cell is charged with at least 70 m.sup.3 (S.T.P.) of hot air per hour, and the filaments are treated in the lower part of the cell with water or aqueous preparations, so that the temperature of the filaments which leave the cell is decreased below 110.degree. C. Under these conditions, the unexpectedly high spinning cell outputs of at least 20 kg of PAN solid per spinning cell per hour can be achieved without yellowing or self-ignition of the filaments occurring.
摘要翻译：合成聚合物特别是聚腈腈纤维从高极性溶剂如二甲基甲酰胺中的溶液干燥的方法，其在喷丝头上游短时间内加热至100-150℃，并通过喷丝头旋转，形状，并且在纺丝电池中，比能量供应量为每平方米加热池面积至少为0.090kWh，电池每小时充入至少70m 3（STP）的热空气，并且灯丝在下部处理的细胞，使得离开细胞的细丝的温度降低到110℃以下。在这些条件下，出乎意料的高纺丝细胞每小时纺丝细胞产生至少20kg的PAN固体可以实现不发生黄丝或自发点火的灯丝。

15. 发明授权

US5013502A Continuous production of acrylonitrile filaments and fibers from spinning material of low residual solvent content 失效
标题翻译：由纺丝材料连续生产丙烯腈长丝和纤维，残留溶剂含量低
公开(公告)号：US5013502A
公开(公告)日：1991-05-07
申请号：US409550
申请日：1989-09-19
申请人： Ulrich Reinehr , Rolf-Burkhard Hirsch , Hermann Josef Jungverdorben , Joachim Dross
发明人： Ulrich Reinehr , Rolf-Burkhard Hirsch , Hermann Josef Jungverdorben , Joachim Dross
IPC分类号： D01D5/04 , D01F6/18 , D01F6/38 , D01F11/06 , D02G1/16 , D02J1/22
CPC分类号： D01F6/18 , D01D5/04
摘要： A process for the production of crimped filaments and fibers of acrylonitrile polymers of copolymers containing at least 40% by weight acrylonitrile units, by dry spinning from highly polar solvents, where the filaments are brought to extremely low solvent contents in the actual spinning tube by a minimum of superheated steam prepared in the absence of water at very high spinning tube temperatures and spinning gas temperatures, but are cooled to low filament temperatures in the spinning tube by application of water or aqueous finishes in a quantity equivalent to more than 10% by weight moisture. In this way, spun PAN filaments of good natural color are safely obtained, in which there is no washing stage and no drying stage. Acrylic fibers and filaments combining a vacuolestable structure with a very high degree of whiteness and gloss are thus obtained with densities of at least 1.180 g/cm.sup.3, giving shrinkage-free to high-shrinkage fibers, depending on the aftertreatment applied.
摘要翻译：一种制备卷曲长丝的纤维和含有至少40重量％丙烯腈单元的共聚物的丙烯腈聚合物的方法，通过从极性极性溶剂中干燥纺丝，其中丝线在实际纺丝管中达到极低的溶剂含量在纺丝管温度和纺丝气体温度非常高的条件下，在不存在水的情况下制备的最小过热蒸汽，但是通过施加相当于10重量％以上的水或水性表面处理，在纺丝管中冷却至低丝温度湿气。以这种方式，可以安全地获得具有良好天然色彩的纺丝PAN丝，其中没有洗涤阶段并且没有干燥阶段。因此，获得具有至少1.180g / cm 3的密度的具有非常高的白度和光泽度的可空泡结构的丙烯酸纤维和长丝，根据所施加的后处理，使高收缩纤维无收缩。

16. 发明授权

US4185059A Process for the preparation of hydrophilic fibres and filaments from synthetic polymers 失效
标题翻译：从合成聚合物制备亲水性纤维和长丝的方法
公开(公告)号：US4185059A
公开(公告)日：1980-01-22
申请号：US775574
申请日：1977-03-08
申请人： Ulrich Reinehr , Hermann-Josef Jungverdorben
发明人： Ulrich Reinehr , Hermann-Josef Jungverdorben
IPC分类号： D01F6/18 , D01F1/10 , D01F6/38 , D01F6/54 , B29H7/20
CPC分类号： D01F1/10 , D01F6/54 , Y10T428/2935
摘要： The invention relates to a process for the production of hydrophilic filaments and fibers which comprises wet- or dry-spinning a fibre-forming synthetic polymer from a spinning solvent containing from 5 to 50% of a substance which has a higher melting or boiling point than the spinning solvent which is miscible with the spinning solvent and with a liquid suitable for use as a washing liquid and which is a non-solvent for the polymer to be spun and from 0,1 to 20% by weight of at least one substance which decomposes into a gas under heating.
摘要翻译：本发明涉及一种生产亲水长丝和纤维的方法，其包括将纤维形成合成聚合物从含有5至50％具有较高熔点或沸点的物质的纺丝溶剂中湿纺或干纺丝与纺丝溶剂和适合用作洗涤液体的液体混合的纺丝溶剂，其是用于待纺的聚合物的非溶剂和0.1至20重量％的至少一种物质，其中在加热下分解成气体。

17. 发明授权

US4854021A Stufferbox crimper and process for preparing crimped synthetic fibers 失效
标题翻译：卷边机卷边机和卷曲合成纤维的制备方法
公开(公告)号：US4854021A
公开(公告)日：1989-08-08
申请号：US93735
申请日：1987-09-08
申请人： Ulrich Reinehr , Christian Pieper , Rolf-Burkhard Hirsch , Hermann-Josef Jungverdorben , Jakob Breuer
发明人： Ulrich Reinehr , Christian Pieper , Rolf-Burkhard Hirsch , Hermann-Josef Jungverdorben , Jakob Breuer
IPC分类号： D02G1/12
CPC分类号： D02G1/12
摘要： In an improved crimping process, use is made of a stufferbox where(a) lid and/or floor are arranged movably and(b) in the working position, the distance between lid and floor at the inlet opening is smaller than the distance between lid and floor at the outlet opening.
摘要翻译：在改进的压接过程中，使用填塞箱，其中（a）盖和/或地板被可移动地布置，并且（b）在工作位置，入口处的盖和地板之间的距离小于盖和出口处的地板。

18. 发明授权

US4842793A Process for wetting thread bundles with liquids 失效
标题翻译：用液体润湿螺纹束的方法
公开(公告)号：US4842793A
公开(公告)日：1989-06-27
申请号：US94966
申请日：1987-09-09
申请人： Ulrich Reinehr , Rolf-Burkhard Hirsch , Joachim Dross , Hermann-Josef Jungverdorben
发明人： Ulrich Reinehr , Rolf-Burkhard Hirsch , Joachim Dross , Hermann-Josef Jungverdorben
IPC分类号： D06B1/02 , B05C5/02 , D06B1/10
CPC分类号： B05C5/0241 , D06B1/10
摘要： Thread bundles which are transported from top to bottom, can be wetted with liquids by means of a device consisting of a system releasing the liquid, conduits and a storage container as well as suitable transporting means for the liquid, whereby the system releasing the liquid has at least two slotted nozzles positioned one above the other and opposite each other, having a horizontal slot and whereby rods are attached at the slot ends which, seen from above, form an angle with the slot of from 100 to 170.degree., preferably from 115 to 160.degree..
摘要翻译：从顶部向底部输送的螺纹束可以通过由释放液体，管道和储存容器的系统组成的装置以及用于液体的合适的输送装置而用液体润湿，由此释放液体的系统具有至少两个开槽的喷嘴一个位于另一个上并且彼此相对设置，具有水平的狭槽，并且其中杆在狭缝端处附接，其从上方观察到与槽的角度为100至170°，优选为115° 至160°。

19. 发明授权

US4714045A Device for wetting threads, films or thread bundles with liquids 失效
标题翻译：润湿螺纹，薄膜或带有液体的螺纹束的装置
公开(公告)号：US4714045A
公开(公告)日：1987-12-22
申请号：US851064
申请日：1986-04-11
申请人： Ulrich Reinehr , Rolf-Burkhard Hirsch , Joachim Dross , Hermann-Josef Jungverdorben
发明人： Ulrich Reinehr , Rolf-Burkhard Hirsch , Joachim Dross , Hermann-Josef Jungverdorben
IPC分类号： D06B1/02 , B05C5/02 , D06B1/10 , B05C3/12
CPC分类号： B05C5/0241 , D06B1/10
摘要： Threads, films or thread bundles which are transported from top to bottom, can be wetted with liquids by means of a device consisting of a system releasing the liquid, conduits and a storage container as well as suitable transporting means for the liquid, whereby the system releasing the liquid has at least two slotted nozzles positioned one above the other and opposite each other, having a horizontal slot and whereby rods are attached at the slot ends which, seen from above, form an angle with the slot of from 100.degree. to 170.degree., preferably from 115.degree. to 160.degree..
摘要翻译：从顶部向底部输送的螺纹，胶片或线束可以用液体通过由释放液体，导管和存储容器的系统组成的装置以及用于液体的合适的输送装置来润湿，由此系统释放液体具有至少两个定位成一个彼此上下并且相对彼此的开槽喷嘴，其具有水平狭槽，并且由此杆在狭缝端部附接，其从上方观察到与槽的角度为100°至170° DEG，优选115°至160°。

20. 发明授权

US5015428A Pan dry spinning process of increased spinning chimney capacity using superheated steam as the spinning gas medium 失效
标题翻译：采用过热蒸汽作为纺丝气体介质，提高了纺丝烟囱容量的泛干纺工艺
公开(公告)号：US5015428A
公开(公告)日：1991-05-14
申请号：US408861
申请日：1989-09-18
申请人： Ulrich Reinehr , Gunter Turck , Rolf B. Hirsch , Hermann-Josef Jungverdorben
发明人： Ulrich Reinehr , Gunter Turck , Rolf B. Hirsch , Hermann-Josef Jungverdorben
IPC分类号： D01D4/02 , D01D5/04 , D01F6/18 , D01F6/38
CPC分类号： D01F6/18 , D01D4/02 , D01D5/04
摘要： A process for dry spinning of synthetic polymers, in particular PAN threads containing more than 85 wt. % acrylonitrile in the PAN (co)polymer, with high spinning chimney capacities of at least 20 kg PAN solid per spinning chimney and hour, using superheated steam as the spinning gas and with in-chimney finishing with water or aqueous finishes.
摘要翻译：合成聚合物的干法纺丝方法，特别是包含超过85wt。％丙烯腈在PAN（共）聚合物中，具有高纺丝烟囱容量，每个纺丝烟囱至少20公斤PAN固体和小时，使用过热蒸汽作为纺丝气体，并在烟囱中用水或水性表面处理。

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