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11. 发明授权

US08618018B2 Catalytically active component for thermal ionization detectors for the detection of halogen-containing compounds and process for producing an oxide-ceramic material for the component 有权
标题翻译：用于检测含卤素化合物的热电离检测器的催化活性组分和用于制备用于组分的氧化物 - 陶瓷材料的方法
公开(公告)号：US08618018B2
公开(公告)日：2013-12-31
申请号：US12439264
申请日：2007-07-30
申请人： Viktar Sauchuk , Peter Otschik , Klaus Eichler , Mihails Kusnezoff
发明人： Viktar Sauchuk , Peter Otschik , Klaus Eichler , Mihails Kusnezoff
IPC分类号： B01J23/04 , B01J23/58 , G01N27/00
CPC分类号： C04B33/24 , B01J23/04 , B01J23/58 , C04B2235/3201 , C04B2235/3217 , C04B2235/3418 , C04B2235/3463 , C04B2235/408 , C04B2235/80 , G01N27/626 , G01N33/0049 , G01N2030/025 , G01N2030/647
摘要： The invention relates to catalytically active components for thermal ionization detectors for the detection of compounds containing halogen which have an improved structure as well as to a manufacturing method for an oxide ceramic sintering material for the components. It is the object of the invention to manufacture catalytically active components for thermal ionization detectors for gas chromatographic applications which are thermally, mechanically and chemically stable in the long term and which have increased sensitivity to the materials to be detected. In this respect, the sintering material should be adjustable in a controllable manner in the ideal parameter required for the detector. It is proposed in accordance with the invention to use an oxide ceramic sintering material for the components which comprises a crystalline phase and an amorphous glass phase, with it being essential to the invention that the amorphous glass phase is formed with 0.1 to 20% by weight of a cesium compound.
摘要翻译：本发明涉及用于检测具有改进结构的卤素化合物的热电离检测器的催化活性组分以及用于组分的氧化物陶瓷烧结材料的制造方法。本发明的目的是制造用于气相色谱应用的热离子化检测器的催化活性组分，其在长期内是热的，机械的和化学上稳定的，并且对待检测的材料具有增加的敏感性。在这方面，烧结材料应该以可控的方式在检测器所需的理想参数中调节。根据本发明提出，为了包含结晶相和无定形玻璃相的组分使用氧化物陶瓷烧结材料，对于本发明，非晶玻璃相的形成必须为0.1-20重量％的铯化合物。

12. 发明授权

US08368411B2 Method for determining diffusion and/or transfer coefficients of a material 失效
标题翻译：用于确定材料的扩散和/或传递系数的方法
公开(公告)号：US08368411B2
公开(公告)日：2013-02-05
申请号：US12452994
申请日：2008-07-28
申请人： Mihails Kusnezoff , Steffen Ziesche , Anne Paepke
发明人： Mihails Kusnezoff , Steffen Ziesche , Anne Paepke
IPC分类号： G01R27/08 , G01N27/02
CPC分类号： G01N27/407 , G01N7/10 , G01N27/041 , G01N27/4074 , G01N2013/003
摘要： The invention relates to a method for the determination of diffusion coefficients and/or exchange coefficient of a material having electronic and ionic conductivity. The material is permeable to at least one gas. It is the object of the invention to provide a cost-effective, accurate method for the determination of the diffusion coefficient and of the surface exchange coefficient which can be carried out in a short time and can thus be used for a screening of materials, in particular for application in the field of permeation membranes. The procedure is followed in accordance with the invention such that a sample of the material is arranged in a measurement chamber and has an electric current passed through it for a determination of the electric resistance. In this respect, a gas mixture in which the respective gas is contained is conducted through the measurement chamber as a gas flow and the partial pressure of the respective gas in the gas mixture is changed periodically at regular intervals. The change in the electric resistance of the sample is measured and a diffusion coefficient and/or exchange coefficient of the material can be determined for the respective gas from the determined change in the electric resistance.
摘要翻译：本发明涉及一种用于确定具有电子和离子电导率的材料的扩散系数和/或交换系数的方法。该材料对至少一种气体是可渗透的。本发明的目的是提供一种用于确定扩散系数和表面交换系数的成本有效的精确方法，该方法可在短时间内进行，因此可用于材料的筛选特别适用于渗透膜领域。按照本发明，遵循本发明的方法，将材料样品布置在测量室中，并且具有通过它的电流以确定电阻。在这方面，其中容纳有各自气体的气体混合物作为气流被传导通过测量室，并且气体混合物中的各个气体的分压以规则的间隔周期性地改变。测量样品的电阻的变化，并且可以根据确定的电阻变化来确定各气体的材料的扩散系数和/或交换系数。

13. 发明申请

US20100108953A1 MATERIAL FOR PROTECTIVE COATINGS ON HIGH TEMPERATURE-RESISTANT CHROMIUM OXIDE-FORMING SUBSTRATES, METHOD FOR THE PRODUCTION THEREOF, AND USE THEREOF 有权
标题翻译：用于耐高温氧化铬形成基材的保护涂料的材料，其生产方法及其用途
公开(公告)号：US20100108953A1
公开(公告)日：2010-05-06
申请号：US12595257
申请日：2008-04-11
申请人： Mihails Kusnezoff , Viktar Sauchuk , Nikolai Trofimenko
发明人： Mihails Kusnezoff , Viktar Sauchuk , Nikolai Trofimenko
IPC分类号： C04B35/443 , H01B1/08 , C04B35/26
CPC分类号： C04B35/016 , C01G45/006 , C01G45/1221 , C01G45/1235 , C01G49/009 , C01G53/006 , C01P2002/32 , C01P2002/72 , C01P2002/85 , C01P2002/88 , C01P2004/80 , C04B35/265 , C04B35/6261 , C04B35/6264 , C04B35/62675 , C04B2235/3265 , C04B2235/3272 , C04B2235/3279 , C04B2235/3281 , C04B2235/763 , C04B2235/764 , C04B2235/80 , C04B2235/9607 , H01M8/0208 , H01M8/0228 , H01M2008/1293 , Y02P70/56
摘要： The invention relates to a material for the formation of protective layers resistant to high temperatures on chromium oxide forming substrates, to a manufacturing method and to a use of these materials. It is suitable for a use as a chromium evaporation layer for metallic alloys containing chromium in the high temperature range. It is the object of the invention to provide a material for applications as a protective layer for chromium oxide forming alloys of high temperature resistance which is thermally and mechanically permanently stable and ensures a high electrical conductivity at the operating temperature of the fuel cell. In accordance with the invention, the material is formed from a spinel phase and an oxidic secondary phase which is preferably formed with an oxidic compound containing manganese.
摘要翻译：本发明涉及一种用于形成耐氧化铬形成衬底的耐高温保护层的材料，涉及这些材料的制造方法和用途。适用于在高温范围内含有铬的金属合金的铬蒸发层。本发明的目的是提供一种用作氧化铬形成合金的保护层的材料，耐热和机械永久稳定的耐热性合金，并确保在燃料电池的工作温度下的高导电性。根据本发明，该材料由尖晶石相和氧化二次相形成，优选由含有锰的氧化化合物形成。

14. 发明授权

US08512901B2 High-temperature fuel cell system 有权
标题翻译：高温燃料电池系统
公开(公告)号：US08512901B2
公开(公告)日：2013-08-20
申请号：US13381568
申请日：2010-06-24
申请人： Mihails Kusnezoff , Sebastian Reuber
发明人： Mihails Kusnezoff , Sebastian Reuber
IPC分类号： H01M8/06
CPC分类号： H01M8/0618 , C01B3/384 , C01B3/386 , C01B2203/0233 , C01B2203/0261 , C01B2203/067 , C01B2203/0805 , H01M8/04007 , H01M8/04097 , H01M8/04365 , H01M8/04619 , H01M8/04753 , H01M8/04761 , H01M8/04776 , H01M8/0625 , H01M8/0637 , H01M8/12 , Y02E60/566 , Y02E70/20
摘要： The invention relates to a high-temperature fuel cell system which can be operated with at least one hydrocarbon compound, preferably with methane or a gas containing methane such as natural gas or biogas. It is the object of the invention to increase the efficiency of high-temperature fuel cell systems and to allow a more flexible operation. In the system in accordance with the invention, individual fuel cells are present which are connected electrically in series and form the stacks. The stacks are flowed through after one another by fuel gas which contains hydrogen and which flows into a first stack of the system from a reformer and a suitable hydrocarbon compound is supplied via further connection lines in the flow direction of the introduced fuel gas sequentially into further stacks to the respective stack for a direct internal reforming of a hydrocarbon compound at anodes of the fuel cells of the stack and air is supplied as an oxidation means at the cathode side to the individual fuel cells of the system.
摘要翻译：本发明涉及一种高温燃料电池系统，其可与至少一种烃化合物一起操作，优选用甲烷或含有天然气或沼气的甲烷的气体操作。本发明的目的是提高高温燃料电池系统的效率并允许更灵活的操作。在根据本发明的系统中，存在单独的燃料电池，它们串联电连接并形成堆叠。堆叠通过包含氢的燃料气体彼此流动，并且从重整器流入系统的第一堆叠中，并且合适的烃化合物通过进一步的连接管线沿引入的燃料气体的流动方向顺序地进一步供给在堆叠和空气的燃料电池的阳极处将碳氢化合物的直接内部重整作为氧化装置在阴极侧供应到各个燃料电池单体的堆叠。

15. 发明授权

US08366972B2 Material for protective coatings on high temperature-resistant chromium oxide-forming substrates, method for the production thereof, and use thereof 有权
标题翻译：耐高温氧化铬形成用基材的保护涂层用材料及其制造方法及其用途
公开(公告)号：US08366972B2
公开(公告)日：2013-02-05
申请号：US12595257
申请日：2008-04-11
申请人： Mihails Kusnezoff , Viktar Sauchuk , Nikolai Trofimenko
发明人： Mihails Kusnezoff , Viktar Sauchuk , Nikolai Trofimenko
IPC分类号： H01B1/02 , H01B1/08 , C04B35/00 , C04B35/04
CPC分类号： C04B35/016 , C01G45/006 , C01G45/1221 , C01G45/1235 , C01G49/009 , C01G53/006 , C01P2002/32 , C01P2002/72 , C01P2002/85 , C01P2002/88 , C01P2004/80 , C04B35/265 , C04B35/6261 , C04B35/6264 , C04B35/62675 , C04B2235/3265 , C04B2235/3272 , C04B2235/3279 , C04B2235/3281 , C04B2235/763 , C04B2235/764 , C04B2235/80 , C04B2235/9607 , H01M8/0208 , H01M8/0228 , H01M2008/1293 , Y02P70/56
摘要： The invention relates to a material for the formation of protective layers resistant to high temperatures on chromium oxide forming substrates, to a manufacturing method and to a use of these materials. It is suitable for a use as a chromium evaporation layer for metallic alloys containing chromium in the high temperature range. It is the object of the invention to provide a material for applications as a protective layer for chromium oxide forming alloys of high temperature resistance which is thermally and mechanically permanently stable and ensures a high electrical conductivity at the operating temperature of the fuel cell. In accordance with the invention, the material is formed from a spinel phase and an oxidic secondary phase which is preferably formed with an oxidic compound containing manganese.
摘要翻译：本发明涉及一种用于形成耐氧化铬形成衬底的耐高温保护层的材料，涉及这些材料的制造方法和用途。适用于在高温范围内含有铬的金属合金的铬蒸发层。本发明的目的是提供一种用作氧化铬形成合金的保护层的材料，耐热和机械永久稳定的耐热性合金，并确保在燃料电池的工作温度下的高导电性。根据本发明，该材料由尖晶石相和氧化二次相形成，优选由含有锰的氧化化合物形成。

16. 发明申请

US20100120611A1 CATALYTICALLY ACTIVE COMPONENT FOR THERMAL IONIZATION DETECTORS FOR THE DETECTION OF HALOGEN-CONTAINING COMPOUNDS AND PROCESS FOR PRODUCING AN OXIDE-CERAMIC MATERIAL FOR THE COMPONENT 有权
标题翻译：用于检测含卤素化合物的热离子检测器的催化活性组分和用于制备用于组分的氧化物 - 陶瓷材料的方法
公开(公告)号：US20100120611A1
公开(公告)日：2010-05-13
申请号：US12439264
申请日：2007-07-30
申请人： Viktar Sauchuk , Peter Otschik , Klaus Eichler , Mihails Kusnezoff
发明人： Viktar Sauchuk , Peter Otschik , Klaus Eichler , Mihails Kusnezoff
IPC分类号： B01J21/06 , B01J23/04 , B01J23/58 , B01J21/02
CPC分类号： C04B33/24 , B01J23/04 , B01J23/58 , C04B2235/3201 , C04B2235/3217 , C04B2235/3418 , C04B2235/3463 , C04B2235/408 , C04B2235/80 , G01N27/626 , G01N33/0049 , G01N2030/025 , G01N2030/647
摘要： The invention relates to catalytically active components for thermal ionization detectors for the detection of compounds containing halogen which have an improved structure as well as to a manufacturing method for an oxide ceramic sintering material for the components. It is the object of the invention to manufacture catalytically active components for thermal ionization detectors for gas chromatographic applications which are thermally, mechanically and chemically stable in the long term and which have increased sensitivity to the materials to be detected. In this respect, the sintering material should be adjustable in a controllable manner in the ideal parameter required for the detector. It is proposed in accordance with the invention to use an oxide ceramic sintering material for the components which comprises a crystalline phase and an amorphous glass phase, with it being essential to the invention that the amorphous glass phase is formed with 0.1 to 20% by weight of a cesium compound.
摘要翻译：本发明涉及用于检测具有改进结构的卤素化合物的热电离检测器的催化活性组分以及用于组分的氧化物陶瓷烧结材料的制造方法。本发明的目的是制造用于气相色谱应用的热离子化检测器的催化活性组分，其在长期内是热的，机械的和化学上稳定的，并且对待检测的材料具有增加的敏感性。在这方面，烧结材料应该以可控的方式在检测器所需的理想参数中调节。根据本发明提出，为了包含结晶相和无定形玻璃相的组分使用氧化物陶瓷烧结材料，对于本发明，非晶玻璃相的形成必须为0.1-20重量％的铯化合物。

17. 发明申请

US20100068602A1 FUEL CELL STACK AND SEAL FOR A FUEL CELL STACK, AS WELL AS A PRODUCTION METHOD FOR IT 审中-公开
标题翻译：用于燃料电池堆的燃料电池堆叠和密封，作为其生产方法
公开(公告)号：US20100068602A1
公开(公告)日：2010-03-18
申请号：US12518465
申请日：2007-11-05
申请人： Christian Wunderlich , Andreas Reinert , Karl-Hermann Bucher , Ralf Otterstedt , Hans-Peter Baldus , Michael Stelter , Axel Rost , Mihails Kusnezoff
发明人： Christian Wunderlich , Andreas Reinert , Karl-Hermann Bucher , Ralf Otterstedt , Hans-Peter Baldus , Michael Stelter , Axel Rost , Mihails Kusnezoff
IPC分类号： H01M2/08
CPC分类号： H01M8/242 , H01M8/0273 , H01M8/0276 , H01M8/0282 , H01M8/0286 , H01M8/2404 , H01M8/2425 , H01M8/2432 , Y02P70/56 , Y10T29/49108
摘要： The invention relates to a sealing for the gas-tight connection of two elements of a fuel cell stack comprising an electrically non-conducting spacer component and at least one solder component solid or viscous over its entire extension at the operating temperature of the fuel cell stack and coupling the spacer component to at least one of the elements to be connected of the fuel cell stack in a gas-tight manner. According to the invention it is envisaged that the spacer component is formed of a ceramic material. The invention further relates to a fuel cell stack in which, according to the invention, it is envisaged that a distribution of forces compressing the fuel cell stack in the axial direction is directly transmitted to at least one of the elements to be connected by the spacer component. The invention further relates to production methods for seals and fuel cell stacks.
摘要翻译：本发明涉及一种用于燃料电池堆的两个元件的气密连接的密封件，其包括不导电的间隔件部件和在燃料电池堆的工作温度下在其整个延伸部上固体或粘性的至少一个焊料部件并且以气密的方式将所述间隔件组件耦合到待连接的燃料电池组的至少一个元件。根据本发明，设想间隔件部件由陶瓷材料形成。本发明还涉及一种燃料电池堆，其中根据本发明，设想将沿轴向压缩燃料电池堆的力的分布直接传递到待间隔件连接的至少一个元件零件。本发明还涉及密封件和燃料电池堆的制造方法。

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