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1. 发明授权

US07087336B2 Process for producing a solid electrolyte layer on a substrate, in a fuel cell, and in a sensor 失效
公开(公告)号：US07087336B2
公开(公告)日：2006-08-08
申请号：US10373322
申请日：2003-02-24
申请人： Robert Fleck , Michael Kuznecov , Peter Otschik , Winfried Schaffrath , Nikolai Trofimenko
发明人： Robert Fleck , Michael Kuznecov , Peter Otschik , Winfried Schaffrath , Nikolai Trofimenko
IPC分类号： H01M8/12 , B05D5/12 , C04B35/64
CPC分类号： G01N27/4073 , C23C24/10 , H01M4/9033 , H01M8/1253 , Y02E60/525 , Y02P70/56
摘要： A method for producing a solid electrolyte layer, of a fully stabilized zirconium oxide layer on a substrate includes adding a sintering additive to a ZrO2-starting material, a liquid phase is formed during a sintering process and liquid phase sintering is possible at a reduced temperature in comparison with the required sintering temperature without the sintering additive. The reduced sintering temperature substantially prevents the formation of a foreign phase layer between the substrate and the gas-tight layer applied thereon, being of fully stabilized ZrO2. The method is particularly suitable for producing a solid electrolyte layer on a cathode of a high temperature fuel cell and in a sensor.

2. 发明授权

US08618018B2 Catalytically active component for thermal ionization detectors for the detection of halogen-containing compounds and process for producing an oxide-ceramic material for the component 有权
标题翻译：用于检测含卤素化合物的热电离检测器的催化活性组分和用于制备用于组分的氧化物 - 陶瓷材料的方法
公开(公告)号：US08618018B2
公开(公告)日：2013-12-31
申请号：US12439264
申请日：2007-07-30
申请人： Viktar Sauchuk , Peter Otschik , Klaus Eichler , Mihails Kusnezoff
发明人： Viktar Sauchuk , Peter Otschik , Klaus Eichler , Mihails Kusnezoff
IPC分类号： B01J23/04 , B01J23/58 , G01N27/00
CPC分类号： C04B33/24 , B01J23/04 , B01J23/58 , C04B2235/3201 , C04B2235/3217 , C04B2235/3418 , C04B2235/3463 , C04B2235/408 , C04B2235/80 , G01N27/626 , G01N33/0049 , G01N2030/025 , G01N2030/647
摘要： The invention relates to catalytically active components for thermal ionization detectors for the detection of compounds containing halogen which have an improved structure as well as to a manufacturing method for an oxide ceramic sintering material for the components. It is the object of the invention to manufacture catalytically active components for thermal ionization detectors for gas chromatographic applications which are thermally, mechanically and chemically stable in the long term and which have increased sensitivity to the materials to be detected. In this respect, the sintering material should be adjustable in a controllable manner in the ideal parameter required for the detector. It is proposed in accordance with the invention to use an oxide ceramic sintering material for the components which comprises a crystalline phase and an amorphous glass phase, with it being essential to the invention that the amorphous glass phase is formed with 0.1 to 20% by weight of a cesium compound.
摘要翻译：本发明涉及用于检测具有改进结构的卤素化合物的热电离检测器的催化活性组分以及用于组分的氧化物陶瓷烧结材料的制造方法。本发明的目的是制造用于气相色谱应用的热离子化检测器的催化活性组分，其在长期内是热的，机械的和化学上稳定的，并且对待检测的材料具有增加的敏感性。在这方面，烧结材料应该以可控的方式在检测器所需的理想参数中调节。根据本发明提出，为了包含结晶相和无定形玻璃相的组分使用氧化物陶瓷烧结材料，对于本发明，非晶玻璃相的形成必须为0.1-20重量％的铯化合物。

3. 发明授权

US07897289B2 Stackable high-temperature fuel cell 失效
标题翻译：可堆叠高温燃料电池
公开(公告)号：US07897289B2
公开(公告)日：2011-03-01
申请号：US10571093
申请日：2004-08-30
申请人： Peter Otschik , Klaus Eichler , Stefan Megel
发明人： Peter Otschik , Klaus Eichler , Stefan Megel
IPC分类号： H01M8/24
CPC分类号： H01M8/0236 , H01M8/0254 , H01M8/0271 , H01M8/2425 , H01M8/2432
摘要： The invention relates to stackable high-temperature fuel cells which are combined to form so-called fuel cell stacks and also can be connected to each other electrically conductively in series and/or in parallel. According to the set object, such high-temperature fuel cells are intended to form an electrically conductive connection between a cathode and an interconnector which, even at temperatures above 800° C. and also in the oxidising atmosphere prevailing during operation of fuel cells, have a sufficiently high electrical conductivity, a chemically and mechanically adequate strength or stability. The high-temperature fuel cells according to the invention are connected, on the anode-side, to a fuel supply and, on the cathode-side, to an oxidant supply. The cathode is connected electrically conductively by means of at least one resilient contact element to an interconnector. The resilient contact element has one or more regions which exert a compression force on regions of the interconnector, the contact element being formed from an electrically conductive ceramic material.
摘要翻译：本发明涉及可堆叠的高温燃料电池，其组合形成所谓的燃料电池堆，并且还可以串联和/或并联地彼此电连接。根据本发明的目的，这种高温燃料电池旨在在阴极和互连器之间形成导电连接，即使在高于800℃的温度以及在燃料电池运行期间的氧化气氛中也具有足够高的导电性，化学和机械上足够的强度或稳定性。根据本发明的高温燃料电池在阳极侧连接到燃料供应器，并且在阴极侧连接到氧化剂源。阴极通过至少一个弹性接触元件导电地连接到互连器。弹性接触元件具有一个或多个在互连器的区域上施加压缩力的区域，该接触元件由导电陶瓷材料形成。

4. 发明申请

US20100120611A1 CATALYTICALLY ACTIVE COMPONENT FOR THERMAL IONIZATION DETECTORS FOR THE DETECTION OF HALOGEN-CONTAINING COMPOUNDS AND PROCESS FOR PRODUCING AN OXIDE-CERAMIC MATERIAL FOR THE COMPONENT 有权
标题翻译：用于检测含卤素化合物的热离子检测器的催化活性组分和用于制备用于组分的氧化物 - 陶瓷材料的方法
公开(公告)号：US20100120611A1
公开(公告)日：2010-05-13
申请号：US12439264
申请日：2007-07-30
申请人： Viktar Sauchuk , Peter Otschik , Klaus Eichler , Mihails Kusnezoff
发明人： Viktar Sauchuk , Peter Otschik , Klaus Eichler , Mihails Kusnezoff
IPC分类号： B01J21/06 , B01J23/04 , B01J23/58 , B01J21/02
CPC分类号： C04B33/24 , B01J23/04 , B01J23/58 , C04B2235/3201 , C04B2235/3217 , C04B2235/3418 , C04B2235/3463 , C04B2235/408 , C04B2235/80 , G01N27/626 , G01N33/0049 , G01N2030/025 , G01N2030/647
摘要： The invention relates to catalytically active components for thermal ionization detectors for the detection of compounds containing halogen which have an improved structure as well as to a manufacturing method for an oxide ceramic sintering material for the components. It is the object of the invention to manufacture catalytically active components for thermal ionization detectors for gas chromatographic applications which are thermally, mechanically and chemically stable in the long term and which have increased sensitivity to the materials to be detected. In this respect, the sintering material should be adjustable in a controllable manner in the ideal parameter required for the detector. It is proposed in accordance with the invention to use an oxide ceramic sintering material for the components which comprises a crystalline phase and an amorphous glass phase, with it being essential to the invention that the amorphous glass phase is formed with 0.1 to 20% by weight of a cesium compound.
摘要翻译：本发明涉及用于检测具有改进结构的卤素化合物的热电离检测器的催化活性组分以及用于组分的氧化物陶瓷烧结材料的制造方法。本发明的目的是制造用于气相色谱应用的热离子化检测器的催化活性组分，其在长期内是热的，机械的和化学上稳定的，并且对待检测的材料具有增加的敏感性。在这方面，烧结材料应该以可控的方式在检测器所需的理想参数中调节。根据本发明提出，为了包含结晶相和无定形玻璃相的组分使用氧化物陶瓷烧结材料，对于本发明，非晶玻璃相的形成必须为0.1-20重量％的铯化合物。

5. 发明授权

US07625658B2 Interconnector for high-temperature fuel cell unit 有权
标题翻译：高温燃料电池单元互连器
公开(公告)号：US07625658B2
公开(公告)日：2009-12-01
申请号：US10571091
申请日：2004-08-24
申请人： Mihail Kuznecov , Klaus Eichler , Peter Otschik
发明人： Mihail Kuznecov , Klaus Eichler , Peter Otschik
IPC分类号： H01M8/10 , H01M8/12 , H01M2/00 , H01M4/00
CPC分类号： H01M8/0271 , H01M8/0202 , H01M8/0206 , H01M8/0228 , H01M8/0232 , H01M8/0247 , H01M8/026
摘要： A planar fuel cell unit on which a cathode-electrolyte-anode unit (CEA unit), a gas distributor element, inner contacting elements, sealing elements, and an interconnector. The interconnector is formed by a CEA mounting element, a base plate, and a gas distributor element. The CEA mounting element and the base plate are embodied as sheet metal parts that form two shells of a housing and enclose the gas distributor element in a gas-tight manner. Webs that are made of an electrically conductive material are applied to/configured on an external surface of the base plate.
摘要翻译：一种平面型燃料电池单元，阴极 - 电解质 - 阳极单元（CEA单元），气体分配器元件，内部接触元件，密封元件和互连器。互连器由CEA安装元件，基板和气体分布器元件形成。 CEA安装元件和底板被实施为形成壳体的两个壳体并以气密方式封闭气体分配器元件的钣金零件。由导电材料制成的网被施加到/构造在基板的外表面上。

6. 发明授权

US07569799B2 Compound body and method for manufacturing it 有权
标题翻译：复合体及其制造方法
公开(公告)号：US07569799B2
公开(公告)日：2009-08-04
申请号：US10531185
申请日：2003-10-13
申请人： Herbert Gunther , Christel Kretschmar , Uwe Partsch , Peter Otschik
发明人： Herbert Gunther , Christel Kretschmar , Uwe Partsch , Peter Otschik
IPC分类号： H05B3/58 , B05D3/02
CPC分类号： H05B3/46 , Y10T428/31678
摘要： A compound body comprises a steel base element on which is deposited a heater layer. The base element is made of a precipitation hardening steel. In the form of a manifold or material feed tube in a hot duct system, said base element comprises a round or convex surface receiving the heater layer. This heater layer is a compound layer having several strata and/or strata elements which are thick film pastes or sheets and in such form are consecutively deposited, dried and baked-on. The pre-compression generated in this process in the heater layer is increased in controlled manner by precipitation hardening the base element.
摘要翻译：复合体包括钢基体元件，在其上沉积加热器层。基体由沉淀硬化钢制成。在热管道系统中以歧管或材料供给管的形式，所述基座元件包括容纳加热器层的圆形或凸形表面。该加热器层是具有多个层状和/或层状元素的复合层，其是厚膜糊状物，并且以这种形式连续沉积，干燥和烘烤。在加热器层中在该过程中产生的预压缩以受控的方式通过沉淀硬化基体元素而增加。

7. 发明申请

US20060165901A1 Composite body and method for production thereof 有权
标题翻译：复合体及其制造方法
公开(公告)号：US20060165901A1
公开(公告)日：2006-07-27
申请号：US10531185
申请日：2003-10-13
申请人： Herbert Gunther , Christel Kretschmar , Uwe Partsch , Peter Otschik
发明人： Herbert Gunther , Christel Kretschmar , Uwe Partsch , Peter Otschik
IPC分类号： B05D3/02
CPC分类号： H05B3/46 , Y10T428/31678
摘要： A compound body comprises a steel base element on which is deposited a heater layer. The base element is made of a precipitation hardening steel. In the form of a manifold or material feed tube in a hot duct system, said base element comprises a round or convex surface receiving the heater layer. This heater layer is a compound layer having several strata and/or strata elements which are thick film pastes or sheets and in such form are consecutively deposited, dried and baked-on. The pre-compression generated in this process in the heater layer is increased in controlled manner by precipitation hardening the base element.
摘要翻译：复合体包括钢基体元件，在其上沉积加热器层。基体由沉淀硬化钢制成。在热管道系统中以歧管或材料供给管的形式，所述基座元件包括容纳加热器层的圆形或凸形表面。该加热器层是具有多个层状和/或层状元素的复合层，它们是厚膜糊状物，并以这种形式连续沉积，干燥和烘烤。在加热器层中在该过程中产生的预压缩以受控的方式通过沉淀硬化基体元素而增加。

8. 发明授权

US06797925B1 Electric heating element for hot runner systems and a method for producing a heating element of this type 有权
标题翻译：用于热流道系统的电加热元件和这种类型的加热元件的制造方法
公开(公告)号：US06797925B1
公开(公告)日：2004-09-28
申请号：US10069498
申请日：2002-02-27
申请人： Herbert Günther , Christel Kretschmab , Peter Otschik
发明人： Herbert Günther , Christel Kretschmab , Peter Otschik
IPC分类号： H05B348
CPC分类号： B29C45/2737 , B29C2045/274 , B29C2045/2745 , B29C2045/2746 , B29C2045/2748 , H05B3/42
摘要： An electric surface heating element is installed by direct application to the periphery of a cylindrical material pipe (13) of a hot runner nozzle (12). Said surface heating element consists of a ceramic dielectric layer (20) which is directly applied to the metal pipe (13) or to the wall (16) thereof, at least one layer (22) consisting of heating conductor strips (23) and an electrically insulating ceramic covering layer (24) which is applied on top of the latter. Film, or thick-coat screen printing technology are suitable as coating processes. However, thick-coat technology using round printing is preferably used for the layer construction as a whole. Alternatively, the ceramic dielectric layer (20) can be fixed to the periphery of the hot runner pipe (13) in the form of a prefabricated green film and subsequently baked.
摘要翻译：电热表面加热元件通过直接施加到热流道喷嘴（12）的圆柱形材料管（13）的周边而被安装。所述表面加热元件由直接施加到金属管（13）或其壁（16）的陶瓷电介质层（20）组成，至少一层（22）由加热导体条（23）和电绝缘陶瓷覆盖层（24），其被施加在后者的顶部。薄膜或厚涂层丝网印刷技术适合作为涂层工艺。然而，作为整体，优选使用使用圆形印刷的厚涂层技术用于层结构。或者，陶瓷电介质层（20）可以以预制的绿色膜的形式固定到热流道管（13）的周边，并随后烘烤。

9. 发明申请

US20070190391A1 Stackable high-temperature fuel cell 失效
标题翻译：可堆叠高温燃料电池
公开(公告)号：US20070190391A1
公开(公告)日：2007-08-16
申请号：US10571093
申请日：2004-08-30
申请人： Peter Otschik , Klaus Eichler , Stefan Megel
发明人： Peter Otschik , Klaus Eichler , Stefan Megel
IPC分类号： H01M8/02 , H01M8/24 , H01M8/12
CPC分类号： H01M8/0236 , H01M8/0254 , H01M8/0271 , H01M8/2425 , H01M8/2432
摘要： The invention relates to stackable high-temperature fuel cells which are combined to form so-called fuel cell stacks and also can be connected to each other electrically conductively in series and/or in parallel. According to the set object, such high-temperature fuel cells are intended to form an electrically conductive connection between a cathode and an interconnector which, even at temperatures above 800° C. and also in the oxidising atmosphere prevailing during operation of fuel cells, have a sufficiently high electrical conductivity, a chemically and mechanically adequate strength or stability. The high-temperature fuel cells according to the invention are connected, on the anode-side, to a fuel supply and, on the cathode-side, to an oxidant supply. The cathode is connected electrically conductively by means of at least one resilient contact element to an interconnector. The resilient contact element has one or more regions which exert a compression force on regions of the interconnector, the contact element being formed from an electrically conductive ceramic material.
摘要翻译：本发明涉及可堆叠的高温燃料电池，其组合形成所谓的燃料电池堆，并且还可以串联和/或并联地彼此电连接。根据本发明的目的，这种高温燃料电池旨在在阴极和互连器之间形成导电连接，即使在高于800℃的温度以及在燃料电池运行期间的氧化气氛中也具有足够高的导电性，化学和机械上足够的强度或稳定性。根据本发明的高温燃料电池在阳极侧连接到燃料供应器，并且在阴极侧连接到氧化剂源。阴极通过至少一个弹性接触元件导电地连接到互连器。弹性接触元件具有一个或多个在互连器的区域上施加压缩力的区域，该接触元件由导电陶瓷材料形成。

10. 发明申请

US20070116998A1 Interconnector for high-temperature fuel cell unit 有权
标题翻译：高温燃料电池单元互连器
公开(公告)号：US20070116998A1
公开(公告)日：2007-05-24
申请号：US10571091
申请日：2004-08-24
申请人： Mihail Kuznecov , Klaus Eichler , Peter Otschik
发明人： Mihail Kuznecov , Klaus Eichler , Peter Otschik
IPC分类号： H01M4/00
CPC分类号： H01M8/0271 , H01M8/0202 , H01M8/0206 , H01M8/0228 , H01M8/0232 , H01M8/0247 , H01M8/026
摘要： The invention relates to a planar fuel cell unit comprising a cathode-electrolyte-anode unit (KEA unit, 100), a gas distributor element (400), inner contacting elements, sealing elements (600, 700), and an interconnector. The interconnector is formed by a KEA fixing element (200), a base plate (300), and a gas distributor element (400). The KEA fixing element (200) and the base plate (300) are embodied as sheet metal parts that form two shells of a housing and enclose the gas distributor element (400) in a gas-tight manner. Webs (500) that are made of an electrically conductive material are applied to/configured on an external surface of the base plate.
摘要翻译：本发明涉及一种包括阴极 - 电解质 - 阳极单元（KEA单元，100），气体分配器元件（400），内部接触元件，密封元件（600,700）和互连器的平面型燃料电池单元。互连器由KEA固定元件（200），基板（300）和气体分配器元件（400）形成。 KEA固定元件（200）和基板（300）被实施为形成壳体的两个壳体并以气密方式封闭气体分配器元件（400）的钣金零件。由导电材料制成的网（500）施加到/构造在基板的外表面上。

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