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11. 发明申请

US20090069497A1 Polyurethane/Urea Containing Pendant Alkoxysilane Groups 失效
标题翻译：聚氨酯/尿素含有侧链烷氧基硅烷组
公开(公告)号：US20090069497A1
公开(公告)日：2009-03-12
申请号：US11920390
申请日：2005-05-18
申请人： Richard R. Roesler , Lyubov K. Gindin
发明人： Richard R. Roesler , Lyubov K. Gindin
IPC分类号： C08L83/08 , C08G77/26
CPC分类号： C08G18/12 , C08G18/0823 , C08G18/0866 , C08G18/283 , C08G18/3275 , C08G18/4238 , C08G18/6659 , C08G18/718 , C08J3/03 , C08J2375/00 , C09D175/04 , C08G18/3893 , C08G18/3228
摘要： The present invention relates to polyurethane/ureas wherein the polyurethane/ureas contain 0.5 to 6% by weight, based on the weight of the polyurethane/ureas, of alkoxysilane groups (calculated as Si, MW 28), which have been incorporated by the reaction of isocyanate groups with a dihydroxy compound containing urea and alkoxysilane groups, and wherein the polyurethane/ureas optionally contain hydrophilic groups and are optionally dispersed in an aqueous medium.The present invention also relates to a process for preparing these polyurethane/urea and to their use for preparing coatings.
摘要翻译：本发明涉及聚氨酯/尿素，其中聚氨酯/尿素基于聚氨酯/脲的重量计含有0.5至6重量％的烷氧基硅烷基团（以Si计，MW 28计），其通过反应引入的异氰酸酯基团与含有脲和烷氧基硅烷基团的二羟基化合物反应，并且其中所述聚氨酯/脲包含任选地含有亲水基团并且任选地分散在水性介质中。本发明还涉及一种制备这些聚氨酯/尿素的方法及其用于制备涂料的方法。

12. 发明授权

US07115696B2 Moisture-curable, polyether urethanes with reactive silane groups and their use as sealants, adhesives and coatings 有权
公开(公告)号：US07115696B2
公开(公告)日：2006-10-03
申请号：US10690751
申请日：2003-10-22
申请人： Richard R. Roesler , Derek L. Crawford , Kurt C. Frisch , Dinesh Pethiyagoda , Karsten Danielmeier
发明人： Richard R. Roesler , Derek L. Crawford , Kurt C. Frisch , Dinesh Pethiyagoda , Karsten Danielmeier
IPC分类号： C08G77/24
CPC分类号： C09J175/08 , C08G18/10 , C08G18/283 , C08G18/4866 , C08G2190/00 , C08G18/289
摘要： A moisture-curable, alkoxysilane-functional polyether urethanes containing a) 20 to 90% by weight, of a polyether urethane containing two or more reactive silane groups and one or more polyether segments, where the polyether segments have a number average molecular weight (Mn) of at least 3000 and a degree of unsaturation of less than 0.04 milliequivalents/g, and the sum of Mn of all of the polyether segments per molecule averages 6000 to 20,000, and the reactive silane groups are incorporated by the reaction of an isocyanate group with a compound of formula and b) 10 to 80% by weight, of a polyether urethane containing one reactive silane group and one or more polyether segments having Mn of 1000 to 15,000.

13. 发明授权

US07057000B2 Two-component coating compositions containing silane adhesion promoters 有权
公开(公告)号：US07057000B2
公开(公告)日：2006-06-06
申请号：US10217923
申请日：2002-08-13
申请人： Richard R. Roesler , P. Richard Hergenrother
发明人： Richard R. Roesler , P. Richard Hergenrother
IPC分类号： C08L77/04
CPC分类号： C08G18/003 , C08G18/0885 , C08G18/12 , C08G18/409 , C08G18/482 , C09D175/08 , Y10T428/31663 , C08G18/6674 , C08G18/7664
摘要： The present invention relates to two-component coating compositions containing a) a polyisocyanate component, b) an isocyanate-reactive component that contains less than 3% by weight, based on the weight of component b), of an aromatic polyamine and c) 0.1 to 1.8 wt. %, based on the weight of components a) and b), of a compound containing at least one epoxy group and at least one alkoxysilane group. The present invention also relates to substrates coated with these coating compositions, in particular metal substrates.

14. 发明授权

US06809170B2 Moisture-curable, polyether urethanes with reactive silane groups and their use as sealants, adhesive and coatings 失效
标题翻译：具有反应性硅烷基团的水分固化型聚醚聚氨酯及其作为密封剂，粘合剂和涂料的用途
公开(公告)号：US06809170B2
公开(公告)日：2004-10-26
申请号：US10690953
申请日：2003-10-22
申请人： Richard R. Roesler , Derek L. Crawford , Kurt C. Frisch , Karsten Danielmeier , Dinesh Pethiyagoda , Gerhard Ruttmann
发明人： Richard R. Roesler , Derek L. Crawford , Kurt C. Frisch , Karsten Danielmeier , Dinesh Pethiyagoda , Gerhard Ruttmann
IPC分类号： C08G7726
CPC分类号： C08G18/4866 , C08G18/0885 , C08G18/283 , C08G18/289 , C08G18/4825 , C08G2190/00
摘要： Preparation of moisture-curable, alkoxysilane-functional polyether urethanes by reacting at an NCO:OH equivalent ratio of 1.5:1 to 2.5:1 a) a hydroxyl component containing i) 20 to 100 wt. %, of a polyether diol and other polyether segments, where the polyether segments have Mn of at least 3000 and degree of unsaturation of less than 0.04 meq/g, where the sum of Mn of polyether segments per molecule averages 6000 to 20,000, and ii) 0 to 80 wt. % of a polyether monool and other polyether segments having Mn of 1000 to 15,000, with b) an isocyanate component containing i) 20 to 100 wt. % of a diisocyanate, and ii) 0 to 80 wt. % of a monoisocyanate, forming an isocyanate-containing reaction product reacted at an equivalent ratio of 0.8:1 to 1.1:1 with c) a compound containing an isocyanate-reactive group and reactive silane groups where at least 10 mole % is a compound of formula

15. 发明授权

US06355829B2 Aspartate-terminated urea/urethane prepolymers and their use in coating compositions 有权
标题翻译：天冬氨酸封端的脲/氨基甲酸酯预聚物及其在涂料组合物中的用途
公开(公告)号：US06355829B2
公开(公告)日：2002-03-12
申请号：US09389686
申请日：1999-09-02
申请人： Richard R. Roesler , Lyubov K. Gindin , P. Richard Hergenrother
发明人： Richard R. Roesler , Lyubov K. Gindin , P. Richard Hergenrother
IPC分类号： C07C22506
CPC分类号： C09D175/02 , C08G18/10 , C08G18/12 , C08G18/3821 , C08G18/3829
摘要： The present invention relates to aspartate-terminated urea/urethane prepolymers that are based on the reaction products of NCO prepolymers with compounds corresponding to the formula wherein X represents an organic group which has a valency of n and is inert towards isocyanate groups at a temperature of 100° C. or less, R1 and R2 may be identical or different and represent organic groups which are inert towards isocyanate groups at a temperature of 100° C. or less, R3 and R4 may be identical or different and represent hydrogen or organic groups which are inert towards isocyanate groups at a temperature of 100° C. or less and n represents an integer with a value of at least 2, at an equivalent ratio of aspartate groups to isocyanate groups of 1.5:1 to 20:1. The present invention also relates to coating compositions containing the aspartate-terminated urea/urethane prepolymers and a polyisocyanate.
摘要翻译：本发明涉及基于NCO预聚物与对映体的相应化合物的反应产物的天冬氨酸酯封端的脲/氨基甲酸酯预聚物，X表示在100℃的温度下具有n价并且对异氰酸酯基呈惰性的有机基团 C或更少，R 1和R 2可以相同或不同，并且表示在100℃或更低的温度下对异氰酸酯基团呈惰性的有机基团，R 3和R 4可以相同或不同，表示氢或有机基团，在100℃或更低的温度下对异氰酸酯基团是惰性的，并且n代表值为至少2的整数，天冬氨酸基团与异氰酸酯基团的当量比为1.5:1至20:1。本发明还涉及包含天冬氨酸封端的脲/氨基甲酸酯预聚物和多异氰酸酯的涂料组合物。

16. 发明授权

US6057415A Water dispersible polyisocyanates containing alkoxysilane groups 失效
标题翻译：含有烷氧基硅烷基团的水分散性多异氰酸酯
公开(公告)号：US6057415A
公开(公告)日：2000-05-02
申请号：US58072
申请日：1998-04-09
申请人： Richard R. Roesler , Myron W. Shaffer , Poli Yu , Lutz Schmalstieg
发明人： Richard R. Roesler , Myron W. Shaffer , Poli Yu , Lutz Schmalstieg
IPC分类号： C09K3/10 , C07F7/18 , C08G18/00 , C08G18/28 , C08G18/38 , C08G18/70 , C08G18/77 , C08G18/79 , C08G18/80 , C08G77/26 , C09D175/04 , C09J175/04 , C08G77/04 , C07F7/04
CPC分类号： C08G18/289 , C08G18/706 , C08G18/809
摘要： The present invention relates to compounds having an isocyanate group content (calculated as NCO, MW 42) of 0.2 to 20% by weight and an alkoxysilane group content (calculated as Si, MW 28) of 0.2 to 4.5% by weight, wherein the preceding percentages are the weight of the compounds, and containing sufficient chemically incorporated hydrophilic groups to form a stable dispersion in water, wherein the alkoxysilane groups are incorporated as the reaction product ofi) a polyisocyanate component having a minimum average functionality of 2.4 and containing at least 50% by weight of polyisocyanate adducts andii) compounds containing secondary amino groups and alkoxysilane groups.The present invention is also directed to the use of these compounds in admixture with isocyanate-reactive resins in aqueous, two-component coating, adhesive and sealant compositions.
摘要翻译：本发明涉及0.2〜4.5重量％的异氰酸酯基含量（按NCO计，MW 42计）为0.2〜20重量％，烷氧基硅烷基含量（按Si，MW28计算）的化合物，其中前述百分比是化合物的重量，并且含有足够化学引入的亲水基团以在水中形成稳定的分散体，其中所述烷氧基硅烷基团作为i）至少平均官能度为2.4的至少包含至少的多异氰酸酯组分的反应产物 50重量％的多异氰酸酯加合物和ii）含有仲氨基和烷氧基硅烷基的化合物。本发明还涉及这些化合物与水性双组分涂料，粘合剂和密封剂组合物中异氰酸酯反应性树脂的混合物的用途。

17. 发明授权

US5847195A Process for the production of compounds containing aspartate and aldimine groups 失效
标题翻译：用于生产含有天冬氨酸和亚胺基的化合物的方法
公开(公告)号：US5847195A
公开(公告)日：1998-12-08
申请号：US33259
申请日：1998-03-02
申请人： Richard R. Roesler
发明人： Richard R. Roesler
IPC分类号： C07C249/02 , C07C251/08 , C07C229/00
CPC分类号： C07C249/02 , C07C2101/14
摘要： The present invention relates to a process for preparing compounds containing aspartate and aldimine groups corresponding to the formula ##STR1## by a) reacting 50 to 95 mole % of the primary amino groups present in a polyamine containing 2 to 6 primary amino groups with a maleic or fumaric acid ester until at least 98% of the unsaturated groups have reacted and b) subsequently reacting the remaining primary amino groups with an aldehyde.
摘要翻译：本发明涉及一种制备含有对应于下式的天冬氨酸和醛亚胺基团的化合物的方法：a）使存在于含2-6个伯氨基的多胺中的50-95摩尔％的伯氨基与马来酸或富马酸酯，直到至少98％的不饱和基团已经反应并且b）随后使剩余的伯氨基与醛反应。

18. 发明授权

US07759447B2 Low surface energy, ethylenically unsaturated polyisocyanate addition compounds and their use in coating compositions 失效
标题翻译：低表面能，烯键式不饱和多异氰酸酯加成化合物及其在涂料组合物中的应用
公开(公告)号：US07759447B2
公开(公告)日：2010-07-20
申请号：US11281079
申请日：2005-11-17
申请人： Carol L. Kinney , Richard R. Roesler , James T. Garrett , Aaron Lockhart
发明人： Carol L. Kinney , Richard R. Roesler , James T. Garrett , Aaron Lockhart
IPC分类号： C08G18/67 , C08G18/28 , C08G18/10 , C08F2/46
CPC分类号： C08G18/2885 , C08G18/672 , C08G18/791 , C08G18/798 , C09D175/16
摘要： The present invention is directed to polyisocyanate addition compounds which i) are substantially free from isocyanate groups and are prepared from one or more a) polyisocyanate adducts and/or b) NCO prepolymers, ii) contain urethane groups, iii) contain fluorine in an amount of 0.01 to 50% by weight, and iv) contain ethylenically unsaturated groups in an amount of 2 to 40% by weight, wherein the preceding percentages are based on the solids content of the polyisocyanate addition compounds. The fluorine is incorporated by reacting an isocyanate group with a compound containing two or more carbon atoms, one or more hydroxyl groups and one or more fluorine atoms to form urethane and optionally allophanate groups. More than 50 mole % of the groups that incorporate fluorine into the addition compounds are urethane groups. The polyisocyanate addition compounds are useful in coating compositions that are curable by free radical polymerization.
摘要翻译：本发明涉及多异氰酸酯加成化合物，其i）基本上不含异氰酸酯基团，并且由一种或多种a）多异氰酸酯加合物和/或b）NCO预聚物制备，ii）含有氨基甲酸酯基团，iii）含有一定量的氟为0.01〜50重量％，iv）含有2〜40重量％的烯键式不饱和基团，其中前述百分数是基于多异氰酸酯加成化合物的固体含量。通过使异氰酸酯基团与含有两个或更多个碳原子，一个或多个羟基和一个或多个氟原子的化合物反应来形成氟，以形成氨基甲酸酯和任选的脲基甲酸酯基。将氟加入加成化合物的基团的50摩尔％以上是氨基甲酸酯基。多异氰酸酯加成化合物可用于通过自由基聚合可固化的涂料组合物。

19. 发明申请

US20090292036A1 TRIMER AND ALLOPHANATE MODIFIED ISOCYANATES, A PROCESS FOR THEIR PRODUCTION, FOAMS COMPRISING THESE MODIFIED ISOCYANATES, AND A PROCESS FOR THE PRODUCTION OF THESE FOAMS 审中-公开
标题翻译： TRIMER和ALLOPHANATE改性异氰酸酯，其生产工艺，包含这些改性异氰酸酯的方法，以及生产这些改性异氰酸酯的方法
公开(公告)号：US20090292036A1
公开(公告)日：2009-11-26
申请号：US12509515
申请日：2009-07-27
申请人： James Garrett , Richard R. Roesler , Jan L. Clatty , Rick V. Starcher , John R. Sebroski , Jason W. Miller , Micheal A. Blaskiewicz , Michael A. Masciantonio , Michael T. Wellman
发明人： James Garrett , Richard R. Roesler , Jan L. Clatty , Rick V. Starcher , John R. Sebroski , Jason W. Miller , Micheal A. Blaskiewicz , Michael A. Masciantonio , Michael T. Wellman
IPC分类号： C08G18/10 , C07C249/00
CPC分类号： C08G18/7837 , C08G18/794 , C08G2101/00
摘要： This invention relates to stable liquid, trimer and allophanate-modified isocyanates, a process for the production of these isocyanates, foams prepared from these isocyanates and a process for the production of these foams.
摘要翻译：本发明涉及稳定的液体，三聚体和脲基甲酸酯改性的异氰酸酯，一种制备这些异氰酸酯的方法，由这些异氰酸酯制备的泡沫以及制备这些泡沫的方法。

20. 发明申请

US20080227878A1 Trimer and allophanate modified isocyanates, a process for their production, foams comprising these modified isocyanates, and a process for the production of these foams 审中-公开
标题翻译：三聚体和脲基甲酸酯改性的异氰酸酯，其生产方法，包含这些改性的异氰酸酯的泡沫体，以及这些泡沫体的生产方法
公开(公告)号：US20080227878A1
公开(公告)日：2008-09-18
申请号：US11717907
申请日：2007-03-14
申请人： James Garrett , Richard R. Roesler , Bryan D. Kaushiva , Jan L. Clatty , Rick V. Starcher , John R. Sebroski , Jason W. Miller , Michael A. Blaszkiewicz , Michael A. Masciantonio , Michael T. Wellman
发明人： James Garrett , Richard R. Roesler , Bryan D. Kaushiva , Jan L. Clatty , Rick V. Starcher , John R. Sebroski , Jason W. Miller , Michael A. Blaszkiewicz , Michael A. Masciantonio , Michael T. Wellman
IPC分类号： C08G18/02 , C08G18/10 , C08G18/18 , C08G18/22 , C08G18/24
CPC分类号： C08G18/7837 , C08G18/794 , C08G2101/00
摘要： This invention relates to stable liquid, trimer and allophanate-modified isocyanates, a process for the production of these isocyanates, foams prepared from these isocyanates and a process for the production of these foams.
摘要翻译：本发明涉及稳定的液体，三聚体和脲基甲酸酯改性的异氰酸酯，一种制备这些异氰酸酯的方法，由这些异氰酸酯制备的泡沫以及制备这些泡沫的方法。

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