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1. 发明申请

US20080227878A1 Trimer and allophanate modified isocyanates, a process for their production, foams comprising these modified isocyanates, and a process for the production of these foams 审中-公开
标题翻译：三聚体和脲基甲酸酯改性的异氰酸酯，其生产方法，包含这些改性的异氰酸酯的泡沫体，以及这些泡沫体的生产方法
公开(公告)号：US20080227878A1
公开(公告)日：2008-09-18
申请号：US11717907
申请日：2007-03-14
申请人： James Garrett , Richard R. Roesler , Bryan D. Kaushiva , Jan L. Clatty , Rick V. Starcher , John R. Sebroski , Jason W. Miller , Michael A. Blaszkiewicz , Michael A. Masciantonio , Michael T. Wellman
发明人： James Garrett , Richard R. Roesler , Bryan D. Kaushiva , Jan L. Clatty , Rick V. Starcher , John R. Sebroski , Jason W. Miller , Michael A. Blaszkiewicz , Michael A. Masciantonio , Michael T. Wellman
IPC分类号： C08G18/02 , C08G18/10 , C08G18/18 , C08G18/22 , C08G18/24
CPC分类号： C08G18/7837 , C08G18/794 , C08G2101/00
摘要： This invention relates to stable liquid, trimer and allophanate-modified isocyanates, a process for the production of these isocyanates, foams prepared from these isocyanates and a process for the production of these foams.
摘要翻译：本发明涉及稳定的液体，三聚体和脲基甲酸酯改性的异氰酸酯，一种制备这些异氰酸酯的方法，由这些异氰酸酯制备的泡沫以及制备这些泡沫的方法。

2. 发明申请

US20090292036A1 TRIMER AND ALLOPHANATE MODIFIED ISOCYANATES, A PROCESS FOR THEIR PRODUCTION, FOAMS COMPRISING THESE MODIFIED ISOCYANATES, AND A PROCESS FOR THE PRODUCTION OF THESE FOAMS 审中-公开
标题翻译： TRIMER和ALLOPHANATE改性异氰酸酯，其生产工艺，包含这些改性异氰酸酯的方法，以及生产这些改性异氰酸酯的方法
公开(公告)号：US20090292036A1
公开(公告)日：2009-11-26
申请号：US12509515
申请日：2009-07-27
申请人： James Garrett , Richard R. Roesler , Jan L. Clatty , Rick V. Starcher , John R. Sebroski , Jason W. Miller , Micheal A. Blaskiewicz , Michael A. Masciantonio , Michael T. Wellman
发明人： James Garrett , Richard R. Roesler , Jan L. Clatty , Rick V. Starcher , John R. Sebroski , Jason W. Miller , Micheal A. Blaskiewicz , Michael A. Masciantonio , Michael T. Wellman
IPC分类号： C08G18/10 , C07C249/00
CPC分类号： C08G18/7837 , C08G18/794 , C08G2101/00
摘要： This invention relates to stable liquid, trimer and allophanate-modified isocyanates, a process for the production of these isocyanates, foams prepared from these isocyanates and a process for the production of these foams.
摘要翻译：本发明涉及稳定的液体，三聚体和脲基甲酸酯改性的异氰酸酯，一种制备这些异氰酸酯的方法，由这些异氰酸酯制备的泡沫以及制备这些泡沫的方法。

3. 发明申请

US20080207784A1 Polyvinylchloride/polyurethane hybrid foams with improved burn properties and reduced after-glow 失效
标题翻译：聚氯乙烯/聚氨酯混合泡沫具有改善的燃烧性能和减少的余辉
公开(公告)号：US20080207784A1
公开(公告)日：2008-08-28
申请号：US11881603
申请日：2007-07-27
申请人： Jan L. Clatty , Michael T. Wellman , Michael A. Masciantonio
发明人： Jan L. Clatty , Michael T. Wellman , Michael A. Masciantonio
IPC分类号： C08J9/00
CPC分类号： C08J9/0066 , C08G18/4812 , C08G18/4866 , C08G2101/0025 , C08G2101/005 , C08G2101/0083 , C08J9/0061 , C08J2375/04 , C08J2427/00
摘要： The present invention provides a rigid polyurethane foam comprising the reaction product, at an isocyanate index of from about 90 to about 400, of a polyisocyanate and a polyol component comprising, about 20 wt. % to about 80 wt. %, based on the weight of the polyol component, of a double metal cyamide (DMC)-catalyzed polyether polyol having a number average molecular weight of greater than about 1,000 Daltons (Da), about 80 wt. % to about 20 wt. %, based on the weight of the polyol component, of a sucrose-based polyol having a functionality of from about 2.5 to about 6 and a number average molecular weight of from about 350 Da to less than about 1,000 Da, and about 0 wt. % to about 40 wt. %, based on the weight of the polyol component, of a low molecular weight organic compound having a number average molecular weight of less than about 600 Da in the presence of water, polyvinylchloride (PVC) particles having a diameter of from about 0.1 microns to about 200 microns, glass beads having a diameter of from about 40 microns to about 400 microns, and about 1 wt. % to about 30 wt. %, based on the weight of the polyol component, of expanded graphite, optionally, in the presence of at least one of carbon dioxide, surfactants, flame retardants other than expanded graphite, crosslinking agents, pigments and catalysts, wherein the rigid polyurethane foam with a density of about 10 pcf to about 25 pcf has a heat sag measured at 102 mm overhang at 121° C. and one hour of less than about 5 mm and an average after-glow time of less than about 35 seconds. The inventive rigid polyurethane foams exhibit improved burn properties and reduced after-glow while maintaining improved heat sag performance over commercial materials.
摘要翻译：本发明提供一种硬质聚氨酯泡沫，其包含异氰酸酯指数为约90至约400的多异氰酸酯和多元醇组分的反应产物，其包含约20重量％％至约80wt。基于多元醇组分的重量，数均分子量大于约1,000道尔顿（Da）的双金属环酰胺（DMC）催化的聚醚多元醇，约80wt。％至约20wt。基于多元醇组分的重量，官能度为约2.5至约6，数均分子量为约350Da至小于约1,000Da的蔗糖基多元醇和约0wt。％至约40wt。基于多元醇组分的重量，在水存在下具有数均分子量小于约600Da的低分子量有机化合物，直径为约0.1微米的聚氯乙烯（PVC）颗粒至约200微米，直径约40微米至约400微米的玻璃珠和约1重量％％至约30wt。任选地，在二氧化碳，表面活性剂，膨胀石墨以外的阻燃剂，交联剂，颜料和催化剂中的至少一种的存在下，膨胀石墨的重量基于多元醇组分的重量％，其中硬质聚氨酯泡沫与约10 pcf至约25 pcf的密度在121℃悬伸时测量的热下垂和小于约5mm的1小时以及小于约35秒的平均余辉时间。本发明的刚性聚氨酯泡沫具有改进的燃烧性能和减少的余辉，同时保持与商业材料相比改善的热下垂性能。

4. 发明授权

US07601762B2 Polyvinylchloride/polyurethane hybrid foams with improved burn properties and reduced after-glow 失效
标题翻译：聚氯乙烯/聚氨酯混合泡沫具有改善的燃烧性能和减少的余辉
公开(公告)号：US07601762B2
公开(公告)日：2009-10-13
申请号：US11881603
申请日：2007-07-27
申请人： Jan L. Clatty , Michael T. Wellman , Michael A. Masciantonio
发明人： Jan L. Clatty , Michael T. Wellman , Michael A. Masciantonio
IPC分类号： C08L75/04
CPC分类号： C08J9/0066 , C08G18/4812 , C08G18/4866 , C08G2101/0025 , C08G2101/005 , C08G2101/0083 , C08J9/0061 , C08J2375/04 , C08J2427/00
摘要： The present invention provides a rigid polyurethane foam comprising the reaction product, at an isocyanate index of from about 90 to about 400, of a polyisocyanate and a polyol component comprising, about 20 wt. % to about 80 wt. %, based on the weight of the polyol component, of a double metal cyanide (DMC)-catalyzed polyether polyol having a number average molecular weight of greater than about 1,000 Daltons (Da), about 80 wt. % to about 20 wt. %, based on the weight of the polyol component, of a sucrose-based polyol having a functionality of from about 2.5 to about 6 and a number average molecular weight of from about 350 Da to less than about 1,000 Da, and about 0 wt. % to about 40 wt. %, based on the weight of the polyol component, of a low molecular weight organic compound having a number average molecular weight of less than about 600 Da in the presence of water, polyvinylchloride (PVC) particles having a diameter of from about 0.1 microns to about 200 microns, glass beads having a diameter of from about 40 microns to about 400 microns, and about 1 wt. % to about 30 wt. %, based on the weight of the polyol component, of expanded graphite, optionally, in the presence of at least one of carbon dioxide, surfactants, flame retardants other than expanded graphite, crosslinking agents, pigments and catalysts, wherein the rigid polyurethane foam with a density of about 10 pcf to about 25 pcf has a heat sag measured at 102 mm overhang at 121° C. and one hour of less than about 5 mm and an average after-glow time of less than about 35 seconds. The inventive rigid polyurethane foams exhibit improved burn properties and reduced after-glow while maintaining improved heat sag performance over commercial materials.
摘要翻译：本发明提供一种硬质聚氨酯泡沫，其包含异氰酸酯指数为约90至约400的多异氰酸酯和多元醇组分的反应产物，其包含约20重量％％至约80wt。基于多元醇组分的重量，数均分子量大于约1,000道尔顿（Da）的双金属氰化物（DMC）催化的聚醚多元醇，约80wt。％至约20wt。基于多元醇组分的重量，官能度为约2.5至约6，数均分子量为约350Da至小于约1,000Da的蔗糖基多元醇和约0wt。％至约40wt。基于多元醇组分的重量，在水存在下具有数均分子量小于约600Da的低分子量有机化合物，直径为约0.1微米的聚氯乙烯（PVC）颗粒至约200微米，直径约40微米至约400微米的玻璃珠和约1重量％％至约30wt。任选地，在二氧化碳，表面活性剂，膨胀石墨以外的阻燃剂，交联剂，颜料和催化剂中的至少一种的存在下，膨胀石墨的重量基于多元醇组分的重量％，其中硬质聚氨酯泡沫与约10 pcf至约25 pcf的密度在121℃悬伸时测量的热下垂和小于约5mm的1小时以及小于约35秒的平均余辉时间。本发明的刚性聚氨酯泡沫具有改进的燃烧性能和减少的余辉，同时保持与商业材料相比改善的热下垂性能。

5. 发明授权

US07601761B2 Rigid polyurethane foams with increased heat performance 失效
标题翻译：坚固的聚氨酯泡沫具有增加的热性能
公开(公告)号：US07601761B2
公开(公告)日：2009-10-13
申请号：US11710788
申请日：2007-02-26
申请人： Jan L. Clatty , Timothy R. Whelan , Susanne Whelan, legal representative , Michael T. Wellman , John W. Liddle , Marie W. Urick
发明人： Jan L. Clatty , Timothy R. Whelan , Michael T. Wellman , John W. Liddle , Marie W. Urick
IPC分类号： C08L75/04
CPC分类号： C08G18/4018 , C08G18/4812 , C08G18/4829 , C08G18/7664 , C08G2101/0025 , C08G2101/0066 , C08G2101/0083 , C08L27/04
摘要： The present invention provides a rigid polyurethane foam made from the reaction product, at an isocyanate index of from about 90 to about 400, of a polyisocyanate, and a polyol component containing about 20 to about 80 wt. %, based on the weight of the polyol component, of a double metal cyanide (DMC)-catalyzed polyether polyol having a number average molecular weight of greater than about 1000 Daltons (Da), about 80 to about 20 wt. %, based on the weight of the polyol component, of a sucrose-based polyol having a functionality of from about 2.5 to about 6 and a molecular weight of from about 350 to less than about 1,000, and about 0 to about 40 wt. %, based on the weight of the polyol component, of a low molecular weight organic compound having a number average molecular weight of less than about 600 Da, in the presence of water, polyvinylchloride (PVC) particles having a diameter of from about 0.1 to about 200 microns, and glass beads having a diameter of from about 40 to about 400 microns (about 270 to about 45 mesh), and optionally, in the presence of at least one of carbon dioxide, surfactants, flame retardants, pigments and catalysts, wherein the rigid polyurethane foam with a density of about 10 to about 25 pcf has a heat sag measured at 102 mm overhang at 121° C. and one hour of less than about 8 mm. The inventive rigid polyurethane foams exhibit increased heat performance (decreased heat sag) while also maintaining impact and rebound strengths.
摘要翻译：本发明提供由异氰酸酯指数为约90至约400的反应产物制成的多异氰酸酯和包含约20至约80重量％的多元醇组分的多元醇组分的硬质聚氨酯泡沫。基于多元醇组分的重量，数均分子量大于约1000道尔顿（Da）的双金属氰化物（DMC）催化的聚醚多元醇的含量为约80至约20wt。基于多元醇组分的重量，官能度为约2.5至约6，分子量为约350至小于约1,000，约0至约40重量％的蔗糖基多元醇。在数均分子量小于约600Da的低分子量有机化合物的基础上，基于多元醇组分的重量％，在水的存在下，直径为约0.1〜约200微米的玻璃珠和直径为约40至约400微米（约270至约45目）的玻璃珠，以及任选在二氧化碳，表面活性剂，阻燃剂，颜料和催化剂中的至少一种存在下，其中密度为约10至约25pff的硬质聚氨酯泡沫具有在121℃突出的102mm处测量的热下垂和小于约8mm的1小时。本发明的刚性聚氨酯泡沫体表现出增加的热性能（减少热量下垂），同时还保持冲击和回弹强度。

6. 发明申请

US20080207787A1 Rigid polyurethane foams with increased heat performance 失效
标题翻译：坚固的聚氨酯泡沫具有增加的热性能
公开(公告)号：US20080207787A1
公开(公告)日：2008-08-28
申请号：US11710788
申请日：2007-02-26
申请人： Jan L. Clatty , Timothy R. Whelan , Michael T. Wellman , John W. Liddle , Marie W. Urick , Susanne Whelan
发明人： Jan L. Clatty , Timothy R. Whelan , Michael T. Wellman , John W. Liddle , Marie W. Urick , Susanne Whelan
IPC分类号： C08G18/48
CPC分类号： C08G18/4018 , C08G18/4812 , C08G18/4829 , C08G18/7664 , C08G2101/0025 , C08G2101/0066 , C08G2101/0083 , C08L27/04
摘要： The present invention provides a rigid polyurethane foam made from the reaction product, at an isocyanate index of from about 90 to about 400, of a polyisocyanate, and a polyol component containing about 20 to about 80 wt. %, based on the weight of the polyol component, of a double metal cyanide (DMC)-catalyzed polyether polyol having a number average molecular weight of greater than about 1000 Daltons (Da), about 80 to about 20 wt. %, based on the weight of the polyol component, of a sucrose-based polyol having a functionality of from about 2.5 to about 6 and a molecular weight of from about 350 to less than about 1,000, and about 0 to about 40 wt. %, based on the weight of the polyol component, of a low molecular weight organic compound having a number average molecular weight of less than about 600 Da, in the presence of water, polyvinylchloride (PVC) particles having a diameter of from about 0.1 to about 200 microns, and glass beads having a diameter of from about 40 to about 400 microns (about 270 to about 45 mesh), and optionally, in the presence of at least one of carbon dioxide, surfactants, flame retardants, pigments and catalysts, wherein the rigid polyurethane foam with a density of about 10 to about 25 pcf has a heat sag measured at 102 mm overhang at 121° C. and one hour of less than about 8 mm. The inventive rigid polyurethane foams exhibit increased heat performance (decreased heat sag) while also maintaining impact and rebound strengths.
摘要翻译：本发明提供由异氰酸酯指数为约90至约400的反应产物制成的多异氰酸酯和包含约20至约80重量％的多元醇组分的多元醇组分的硬质聚氨酯泡沫。基于多元醇组分的重量，数均分子量大于约1000道尔顿（Da）的双金属氰化物（DMC）催化的聚醚多元醇的含量为约80至约20wt。基于多元醇组分的重量，官能度为约2.5至约6，分子量为约350至小于约1,000，约0至约40重量％的蔗糖基多元醇。在数均分子量小于约600Da的低分子量有机化合物的基础上，基于多元醇组分的重量％，在水的存在下，直径为约0.1〜约200微米的玻璃珠和直径为约40至约400微米（约270至约45目）的玻璃珠，以及任选在二氧化碳，表面活性剂，阻燃剂，颜料和催化剂中的至少一种存在下，其中密度为约10至约25pff的硬质聚氨酯泡沫具有在121℃突出的102mm处测量的热下垂和小于约8mm的1小时。本发明的刚性聚氨酯泡沫体表现出增加的热性能（减少热量下垂），同时还保持冲击和回弹强度。

7. 发明申请

US20100260941A1 REINFORCED UV-A CURABLE COMPOSITE COMPOSITIONS AND METHODS 有权
标题翻译：增强UV-A可固化复合材料组合物和方法
公开(公告)号：US20100260941A1
公开(公告)日：2010-10-14
申请号：US12420112
申请日：2009-04-08
申请人： Alan D. Bushmire , Jan L. Clatty , Michael J. Dvorchak , Charles A. Gambino , Christine Mebane
发明人： Alan D. Bushmire , Jan L. Clatty , Michael J. Dvorchak , Charles A. Gambino , Christine Mebane
IPC分类号： B05D3/06 , C08F4/32 , C08J7/04 , C08J3/28 , C08F2/48 , C08F2/46
CPC分类号： C08J5/24 , B29C2035/0827 , C08J7/123 , C08J2375/16
摘要： The present disclosure is directed to a process for forming a reinforced ultraviolet (UV) radiation-curable composite. The composite may be formed by applying reinforcing layers and resin layers to a substrate. The resin composition may include an aliphatic urethane acrylate oligomer, a polyfunctional acrylate monomer, and a photoinitiator. The composite formed on the substrate may be exposed to UV radiation to cure the composite on the substrate. The composite may be characterized in that it is cured within 10 minutes of exposure to UV radiation and does not exhibit oxygen inhibition effects, such as, for example, surface tack. The reinforced UV-curable composite may find utility, for example, as a rapid field repair patch in aerospace applications, among others.
摘要翻译：本公开涉及形成增强的紫外线（UV）可辐射固化复合材料的方法。可以通过将增强层和树脂层施加到基底上来形成复合材料。树脂组合物可以包括脂肪族聚氨酯丙烯酸酯低聚物，多官能丙烯酸酯单体和光引发剂。形成在基底上的复合物可以暴露于UV辐射以固化基底上的复合物。该复合材料的特征在于其在暴露于UV辐射的10分钟内固化，并且不显示出氧抑制作用，例如表面粘性。增强的可UV固化复合材料可以用于例如航空航天应用中的快速现场修补补片。

8. 发明授权

US06649667B2 Polyurethane foams having improved heat sag and a process for their production 失效
公开(公告)号：US06649667B2
公开(公告)日：2003-11-18
申请号：US10336111
申请日：2003-03-04
申请人： Jan L. Clatty
发明人： Jan L. Clatty
IPC分类号： C08G1810
CPC分类号： C08G18/6696 , C08G18/36 , C08G18/4816 , C08G2101/0025 , C08J9/00 , C08J2201/022 , C08J2205/052 , C08J2205/10 , C08J2375/04
摘要： Rigid, closed-cell polyurethane foams are produced by a RIM process by reacting an organic polyisocyanate with an isocyanate-reactive mixture in which a significant amount of a bio-based polyol is present. The foams produced by this process are characterized by improved heat sag and heat distortion temperature.

9. 发明授权

US09701802B2 Reinforced UV-A curable composite compositions and methods 有权
公开(公告)号：US09701802B2
公开(公告)日：2017-07-11
申请号：US12420112
申请日：2009-04-08
申请人： Alan D. Bushmire , Jan L. Clatty , Michael J. Dvorchak , Charles A. Gambino , Christine Mebane
发明人： Alan D. Bushmire , Jan L. Clatty , Michael J. Dvorchak , Charles A. Gambino , Christine Mebane
IPC分类号： C08J7/04 , C08J5/24 , C08J7/12 , B29C35/08
CPC分类号： C08J5/24 , B29C2035/0827 , C08J7/123 , C08J2375/16
摘要： The present disclosure is directed to a process for forming a reinforced ultraviolet (UV) radiation-curable composite. The composite may be formed by applying reinforcing layers and resin layers to a substrate. The resin composition may include an aliphatic urethane acrylate oligomer, a polyfunctional acrylate monomer, and a photoinitiator. The composite formed on the substrate may be exposed to UV radiation to cure the composite on the substrate. The composite may be characterized in that it is cured within 10 minutes of exposure to UV radiation and does not exhibit oxygen inhibition effects, such as, for example, surface tack. The reinforced UV-curable composite may find utility, for example, as a rapid field repair patch in aerospace applications, among others.

10. 发明授权

US08552079B2 Water-blown, flame retardant rigid polyurethane foam 有权
标题翻译：水吹，阻燃硬质聚氨酯泡沫
公开(公告)号：US08552079B2
公开(公告)日：2013-10-08
申请号：US11292193
申请日：2005-12-01
申请人： Jan L. Clatty , Donald L. McCalmon
发明人： Jan L. Clatty , Donald L. McCalmon
IPC分类号： C08G18/00
CPC分类号： C08G18/4018 , C08G18/4883 , C08G2101/0025 , C08G2101/0058 , C08G2101/0083 , C08G2130/00 , C08J2205/10 , C08K3/22 , C08K5/12 , C08K5/52 , C08K5/5333 , C08L75/04
摘要： The present invention provides a flame-retardant polyurethane foam made with non chlorofluorocarbon/hydrogenated chlorofluorocarbon-containing blowing agents and without trimethylolpropane-based polyols that achieves a Class I rating as determined by a modification of the ASTM E-84 tunnel test and may find application in electronic cabinetry, architectural decorative moldings, and interior transportation vehicle walls.
摘要翻译：本发明提供一种由不含氯氟烃/氢化含氯氟烃的发泡剂制成的阻燃聚氨酯泡沫，并且不具有通过ASTM E-84隧道试验的改进确定的达到Class I等级的三羟甲基丙烷基多元醇，并且可以找到应用在电子橱柜，建筑装饰模具和室内运输车辆墙壁。

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