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11. 发明申请

US20060046924A1 Process for regeneration of a catalyst that contains an EUO-structural-type zeolite 有权
标题翻译：含有EUO结构型沸石的催化剂的再生方法
公开(公告)号：US20060046924A1
公开(公告)日：2006-03-02
申请号：US11216098
申请日：2005-09-01
申请人： Sylvie Lacombe , Julia Magne-Drisch , Eric Sanchez
发明人： Sylvie Lacombe , Julia Magne-Drisch , Eric Sanchez
IPC分类号： B01J20/34 , B01J29/06 , B01J38/04
CPC分类号： C07C5/2737 , B01J29/74 , B01J29/76 , B01J29/78 , B01J29/90 , B01J38/44 , B01J2229/42 , C07C5/2775 , Y02P20/52 , Y02P20/584 , C07C15/08
摘要： A process for regeneration of a catalyst that comprises at least one EUO-structural-type zeolite in acid form and at least one hydro-dehydrogenating metal, used in a process for isomerization of a hydrocarbon feedstock that comprises aromatic compounds with eight carbon atoms, comprising at least a) a stage for eliminating a majority of the coke, deposited on said catalyst, by combustion in the presence of a gas that contains oxygen at a temperature that is less than or equal to 600° C., and b) a stage for oxychlorination of the product that is obtained from stage a), carried out between 200 and 550° C. in the presence of at least one gas mixture that contains at least oxygen, water and chlorine and/or at least one chlorinated compound, is described.
摘要翻译：一种催化剂再生方法，该催化剂包含至少一种酸形式的EUO结构型沸石和至少一种加氢脱氢金属，其用于包含具有8个碳原子的芳族化合物的烃原料异构化方法，包括至少a）通过在小于或等于600℃的温度下含有氧的气体存在下通过燃烧除去沉积在所述催化剂上的大部分焦炭的阶段，以及b）阶段在至少一种至少含有氧，水和氯的气体混合物和/或至少一种氯化化合物的存在下，在200-550℃之间进行从a）阶段获得的产物的氧氯化，是描述。

12. 发明授权

US06514479B1 EUO zeolite comprising crystals and aggregates of crystals with specific granulometrys and its use as a catalyst in the isomerisation of C8 aromatic compounds 有权
标题翻译：包含具有特定粒度的晶体和晶体聚集体的EUO沸石及其作为C8芳族化合物异构化中的催化剂的用途
公开(公告)号：US06514479B1
公开(公告)日：2003-02-04
申请号：US09471323
申请日：1999-12-23
申请人： Elisabeth Merlen , Fabio Alario , Olivia Martin , Nathalie Ferrer , Sylvie Lacombe , Loïc Rouleau , Julia Magne-Drisch
发明人： Elisabeth Merlen , Fabio Alario , Olivia Martin , Nathalie Ferrer , Sylvie Lacombe , Loïc Rouleau , Julia Magne-Drisch
IPC分类号： C01B3904
CPC分类号： B01J29/7023 , B01J29/7446 , B01J35/023 , C07C5/2708 , C07C2529/70 , C10G45/64 , C10G2300/1096 , C10G2300/4018 , C10G2400/30 , C07C15/067
摘要： The invention concerns a zeolite with structure type EUO comprising EUO zeolite crystals with a size of less than 5 &mgr;m, at least a portion of the EUO zeolite crystals being in the form of EUO zeolite aggregates, characterized in that the granulometry of the aggregates is such that Dv,90 is 500 &mgr;m or less. The invention also concerns the preparation of the zeolite and the use of the zeolite as a catalyst, for example in a process for isomerising aromatic compounds containing 8 carbon atoms per molecule.
摘要翻译：本发明涉及结构类型为EUO的沸石，其包含尺寸小于5um的EUO沸石晶体，至少一部分EUO沸石晶体为EUO沸石聚集体形式，其特征在于聚集体的粒度为那么Dv，90是500mam以下。本发明还涉及沸石的制备和沸石作为催化剂的用途，例如在每分子含有8个碳原子的芳族化合物的异构化方法中。

13. 发明授权

US06333289B1 Process for activating catalysts for isomerizing aromatic compounds containing eight carbon atoms 有权
标题翻译：用于活化用于异构化含有8个碳原子的芳族化合物的催化剂的方法
公开(公告)号：US06333289B1
公开(公告)日：2001-12-25
申请号：US09288676
申请日：1999-04-09
申请人： Jean-François Joly , Julia Magne-Drisch , Fabio Alario , Elisabeth Merlen , Eric Benazzi , Sylvie Lacombe
发明人： Jean-François Joly , Julia Magne-Drisch , Fabio Alario , Elisabeth Merlen , Eric Benazzi , Sylvie Lacombe
IPC分类号： B01J2100
CPC分类号： B01J29/7446 , B01J29/18 , B01J29/22 , B01J29/7246 , B01J33/00 , B01J37/20 , B01J2229/26 , B01J2229/42 , C07C5/2724 , C07C2529/72 , C07C15/067
摘要： The present invention relates to a process for activating catalysts for isomerizing aromatic compounds containing 8 carbon atoms, the catalysts containing at least one group VIII metal, comprising at least one sulfurization and at least one passivation using ammonia.
摘要翻译：本发明涉及一种用于使含有8个碳原子的芳族化合物异构化的催化剂的活化方法，含有至少一种第Ⅷ族金属的催化剂，包括至少一种硫化和至少一种使用氨的钝化。

14. 发明授权

US6147269A Isomerization with an EUO-type catalyst of aromatic compounds with eight carbon atoms followed by a dehydrogenation stage 有权
标题翻译：与具有八个碳原子的芳族化合物的EUO型催化剂异化，随后脱氢阶段
公开(公告)号：US6147269A
公开(公告)日：2000-11-14
申请号：US289662
申请日：1999-04-12
申请人： Jean-Fran.cedilla.ois Joly , Vincent Coupard , Julia Magne-Drisch , Fabio Alario , Elisabeth Merlen , Sylvie Lacombe , Eric Benazzi
发明人： Jean-Fran.cedilla.ois Joly , Vincent Coupard , Julia Magne-Drisch , Fabio Alario , Elisabeth Merlen , Sylvie Lacombe , Eric Benazzi
IPC分类号： B01J29/04 , C07C5/27 , C07C15/067 , C07C5/00 , C07C5/22
CPC分类号： C07C15/067 , B01J29/04 , C07C5/2724 , C07C2529/72 , Y02P20/52
摘要： A C.sub.8 aromatic feedstock is isomerized by an isomerization stage conducted at 320-380.degree. C. with a catalyst containing at least one EUO-structure-type zeolite and at least one metal of group VIII, to obtain an effluent containing isomerized alkyl aromatics and about 10-30% by weight of naphthenes. The effluent is then subjected to a dehydrogenation stage so as to convert the naphthenes to additional alkyl aromatics.
摘要翻译： C8芳族原料通过在320-380℃下进行的异构化异构化，使用含有至少一种EUO结构型沸石和至少一种第Ⅷ族金属的催化剂，得到含异构化烷基芳族化合物和约 10-30重量％的环烷烃。然后将流出物进行脱氢阶段，以将环烷烃转化为另外的烷基芳族化合物。

15. 发明授权

US5608103A Preparation of alkanesulphonic acids by photooxidation of sulpher-containing derivatives 失效
标题翻译：通过含硫醇衍生物的光氧化制备烷基磺酸
公开(公告)号：US5608103A
公开(公告)日：1997-03-04
申请号：US565613
申请日：1995-11-29
申请人： Evelyne Banchereau , Sylvie Lacombe , Jean Ollivier
发明人： Evelyne Banchereau , Sylvie Lacombe , Jean Ollivier
IPC分类号： C07B61/00 , C07C303/16 , C07C309/04
CPC分类号： C07C303/16
摘要： The invention relates to the preparation of alkanesulphonic acids by photooxidation of sulphur-containing derivatives (thiols, sulphides, disulphides).The operation is carried out in solution in aqueous or alcoholic acetonitrile, with a light source irradiating between 200 and 400 nm.
摘要翻译：本发明涉及通过含硫衍生物（硫醇，硫化物，二硫化物）的光氧化制备烷基磺酸。操作在水溶液或乙腈乙腈溶液中进行，光源照射在200和400nm之间。

16. 发明申请

US20100081852A1 MULTI-ZONE FIXED-BED OR MOVING-BED REACTOR WITH AN INTEGRATED HEAT EXCHANGER 有权
标题翻译：多功能固定床或移动式反应器与集成热交换器
公开(公告)号：US20100081852A1
公开(公告)日：2010-04-01
申请号：US12572827
申请日：2009-10-02
申请人： Sylvain Louret , Patrice Font , Sylvie Lacombe , Eric Sanchez , Laurent Simon
发明人： Sylvain Louret , Patrice Font , Sylvie Lacombe , Eric Sanchez , Laurent Simon
IPC分类号： C07C2/04
CPC分类号： B01J8/125 , B01J8/0453 , B01J8/0492 , B01J8/0496 , B01J8/085 , B01J8/087 , B01J2208/00168 , B01J2208/00203 , C10G50/00 , C10G2300/1088 , C10G2400/04
摘要： This invention relates to a staged-zone reactor of the axial-flow type that makes it possible to implement strongly endothermic or exothermic reactions. The reactor comprises a constriction of the catalytic bed between an upper zone (3a) and a lower zone (3b), making it possible to house in the reactor a heat exchanger for the intermediate heating or cooling of the effluents. Process of chemical conversion using this reactor for exothermic or endothermic reactions in the gas and/or liquid phase, and in particular for the oligomerization reaction of C2 to C12 fractions for the purpose of producing a diesel fraction.
摘要翻译：本发明涉及一种能够实现强吸热或放热反应的轴流式分级反应器。反应器包括上部区域（3a）和下部区域（3b）之间的催化床的收缩部，使得可以在反应器中容纳用于中间加热或冷却流出物的热交换器。用于在气体和/或液相中使用该反应器进行放热或吸热反应的化学转化方法，特别是用于生产柴油馏分的C2至C12馏分的低聚反应的方法。

17. 发明授权

US07572946B2 Process for oligomerizing olefins using a silica-alumina based catalyst 有权
标题翻译：使用二氧化硅 - 氧化铝基催化剂使烯烃低聚的方法
公开(公告)号：US07572946B2
公开(公告)日：2009-08-11
申请号：US11182021
申请日：2005-07-15
申请人： Sylvie Lacombe , Renaud Revel , Patrick Briot , Eric Llido , Patrick Euzen , Carole Bobin
发明人： Sylvie Lacombe , Renaud Revel , Patrick Briot , Eric Llido , Patrick Euzen , Carole Bobin
IPC分类号： C07C2/08
CPC分类号： C10G69/126 , C07C2/10 , C07C2521/12 , C10G50/00 , C10G2300/1092 , C10G2300/301 , C10G2300/4018 , C10G2300/802 , C10G2400/02 , C07C11/02
摘要： An olefin oligomerization process employs a particular silica-alumina catalyst which comprises a non zeolitic support based on silica-alumina containing a quantity of more than 5% by weight and 95% by weight or less of silica (SiO2) and has the following characteristics: a mean pore diameter, measured by mercury porosimetry, in the range 20 to 140 Å; a total pore volume, measured by mercury porosimetry, in the range 0.1 ml/g to 0.6 ml/g; a total pore volume, measured by nitrogen porosimetry, in the range 0.1 ml/g to 0.6 ml/g; a BET specific surface area in the range 100 to 550 m2/g; a pore volume, measured by mercury porosimetry, included in pores with a diameter of more than 140 Å, of less than 0.1 ml/g; a pore volume, measured by mercury porosimetry, included in pores with a diameter of more than 160 Å, of less than 0.1 ml/g; a pore volume, measured by mercury porosimetry, included in pores with a diameter of more than 200 Å, of less than 0.1 ml/g; a pore volume, measured by mercury porosimetry, included in pores with a diameter of more than 500 Å, of less than 0.1 ml/g; and an X ray diffraction diagram containing at least the principal characteristic peaks of at least one of the transition aluminas included in the group composed of alpha, rho, khi, eta, gamma, kappa, theta and delta aluminas.
摘要翻译：烯烃低聚方法使用特定的二氧化硅 - 氧化铝催化剂，其包含基于二氧化硅 - 氧化铝的非沸石载体，其含有大于5重量％且95重量％以下的二氧化硅（SiO 2），并具有以下特征：通过水银孔率法测量的平均孔径在20至140埃的范围内; 通过水银孔率法测量的总孔体积在0.1ml / g至0.6ml / g的范围内; 通过氮气孔率法测量的总孔体积在0.1ml / g至0.6ml / g的范围内; 100-550m2 / g范围内的BET比表面积; 通过水银孔率法测定的孔体积，其直径大于140埃，小于0.1ml / g; 通过水银孔率法测量的孔体积，其直径大于160埃的孔隙小于0.1ml / g; 包含在直径大于200埃的孔中，通过水银孔率法测量的孔体积小于0.1ml / g; 通过水银孔率法测量的孔体积包含在直径大于500埃的小于0.1ml / g的孔中; 以及X射线衍射图，其至少包含由α，rho，khi，eta，γ，κ，θ和δ氧化铝组成的组中的至少一种过渡氧化铝的主要特征峰。

18. 发明授权

US07431913B2 EUO-structural-type zeolite that contains the N,N-dimethyl-N,N-di(3,3-dimethylbutyl)ammonium cation and its process for preparation 有权
标题翻译：含有N，N-二甲基-N，N-二（3,3-二甲基丁基）铵阳离子的EUO结构型沸石及其制备方法
公开(公告)号：US07431913B2
公开(公告)日：2008-10-07
申请号：US11638352
申请日：2006-12-14
申请人： Philippe Caullet , Sylvie Lacombe , Jean-Louis Paillaud , Nicolas Bats , Loic Rouleau
发明人： Philippe Caullet , Sylvie Lacombe , Jean-Louis Paillaud , Nicolas Bats , Loic Rouleau
IPC分类号： C01B33/36 , C01B39/04 , C01F7/00 , B01J29/06 , B01J21/00 , B01J29/00
CPC分类号： C01B37/02 , B01J20/18 , B01J29/7023 , B01J29/7446 , C01B39/48
摘要： A new EUO-structural-type zeolite that comprises at least one tetravalent element X that is selected from among silicon, tin, titanium and germanium and optionally at least one trivalent element T that is selected from among aluminum, iron, boron, indium and gallium is described. This new zeolite is characterized in that it contains, in its crude synthesis form, the nitrogen-containing organic cation of formula N,N-dimethyl-N,N-di(3,3-dimethylbutyl)ammonium. A method for the preparation of this zeolite is also described.
摘要翻译：包含至少一种选自硅，锡，钛和锗中的四价元素X和选自铝，铁，硼，铟和镓中的至少一种三价元素T的EUO结构型沸石被描述。该新沸石的特征在于，其粗制合成形式含有式N，N-二甲基-N，N-二（3,3-二甲基丁基）铵的含氮有机阳离子。还描述了制备该沸石的方法。

19. 发明申请

US20080221376A1 PROCESS FOR ISOMERIZING AROMATIC C8 COMPOUNDS IN THE PRESENCE OF A CATALYST COMPRISING A MODIFIED EUO ZEOLITE 有权
标题翻译：在包含改性的EUO ZEOLITE的催化剂存在下异构化芳族C8化合物的方法
公开(公告)号：US20080221376A1
公开(公告)日：2008-09-11
申请号：US11955825
申请日：2007-12-13
申请人： NGI SUOR GNEP , Emmanuelle Guillon , Sylvie Lacombe , Laurent Simon , Pierre Moreau , Patrick Magnoux
发明人： NGI SUOR GNEP , Emmanuelle Guillon , Sylvie Lacombe , Laurent Simon , Pierre Moreau , Patrick Magnoux
IPC分类号： C07C5/22
CPC分类号： B01J29/7446 , B01J29/7246 , B01J29/7646 , B01J29/7846 , B01J2229/123 , B01J2229/20 , B01J2229/32 , B01J2229/42 , C07C5/2775 , Y02P20/52 , C07C15/08
摘要： A process for isomerizing a feed comprising at least one aromatic compound containing eight carbon atoms per molecule is carried out in the presence of a catalyst comprising at least one modified zeolite with structure type EUO, at least one binder and at least one metal from group VIII of the periodic table, said catalyst having been prepared using a process which comprises the following in succession: a) a step for treatment of a zeolite with structure type EUO in the presence of at least one molecular compound containing at least one silicon atom, during which said compound, with a diameter greater than the maximum pore opening diameter in said zeolite, is deposited in the gas phase on the outer surface of said zeolite; b) at least one heat treatment step; c) forming said zeolite with a binder; d) at least one step for introducing at least one metal from group VIII of the periodic table onto a support based on said modified and formed zeolite.
摘要翻译：在包含至少一种结构类型为EUO的改性沸石，至少一种粘合剂和至少一种来自VIII族的金属的催化剂的存在下，进行包含至少一种每分子含有8个碳原子的芳族化合物的进料异构化的方法所述催化剂已经使用以下方法制备的催化剂：a）在存在至少一种含有至少一个硅原子的分子化合物的存在下，处理具有结构型EUO的沸石的步骤，在其中所述化合物的直径大于所述沸石中的最大孔开口直径在气相中沉积在所述沸石的外表面上; b）至少一个热处理步骤; c）用粘合剂形成所述沸石; d）至少一个步骤，用于将基于所述改性和形成的沸石的元素周期表第Ⅷ族中的至少一种金属引入到载体上。

20. 发明申请

US20060079704A1 Process for co-producing olefins and esters by ethenolysis of unsaturated fats in non-aqueous ionic liquids 失效
标题翻译：通过非水性离子液体中不饱和脂肪的乙烯分解共同生产烯烃和酯的方法
公开(公告)号：US20060079704A1
公开(公告)日：2006-04-13
申请号：US11286351
申请日：2005-11-25
申请人： Sylvie Lacombe , Renaud Revel , Patrick Briot , Eric Llido , Patrick Euzen , Carole Bobin
发明人： Sylvie Lacombe , Renaud Revel , Patrick Briot , Eric Llido , Patrick Euzen , Carole Bobin
IPC分类号： C07C67/00 , C07C5/00
CPC分类号： C07C6/04 , C07C2/10 , C07C67/333 , C07C2521/12 , C10G50/00 , C10G69/126 , C10G2300/1014 , C10G2400/22 , C11C3/00 , C07C11/02 , C07C69/533
摘要： A process is described in which an unsaturated fat is reacted with ethylene in a metathesis reaction in the presence of at least one non-aqueous ionic liquid to produce both an olefinic fraction and a composition of monoalcohol or polyol esters. Particular application to an oleic sunflower seed oil, an oleic rapeseed oil or to a mixture of monoalcohol esters of said oils, the process producing both an olefinic fraction and a monoalcohol or glycerol esters composition generally having more than half of its chains constituted by unsaturated C10 chains.
摘要翻译：描述了一种方法，其中不饱和脂肪在复分解反应中在至少一种非水离子液体存在下与乙烯反应，以产生烯属馏分和一元醇或多元醇酯的组合物。特别应用于油酸向日葵籽油，油菜菜籽油或所述油的一元醇酯的混合物，该方法生产烯烃级分和一元醇或甘油酯组合物，其通常具有由不饱和C构成的链的一半以上 10个链。

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