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1. 发明授权

US07431913B2 EUO-structural-type zeolite that contains the N,N-dimethyl-N,N-di(3,3-dimethylbutyl)ammonium cation and its process for preparation 有权
标题翻译：含有N，N-二甲基-N，N-二（3,3-二甲基丁基）铵阳离子的EUO结构型沸石及其制备方法
公开(公告)号：US07431913B2
公开(公告)日：2008-10-07
申请号：US11638352
申请日：2006-12-14
申请人： Philippe Caullet , Sylvie Lacombe , Jean-Louis Paillaud , Nicolas Bats , Loic Rouleau
发明人： Philippe Caullet , Sylvie Lacombe , Jean-Louis Paillaud , Nicolas Bats , Loic Rouleau
IPC分类号： C01B33/36 , C01B39/04 , C01F7/00 , B01J29/06 , B01J21/00 , B01J29/00
CPC分类号： C01B37/02 , B01J20/18 , B01J29/7023 , B01J29/7446 , C01B39/48
摘要： A new EUO-structural-type zeolite that comprises at least one tetravalent element X that is selected from among silicon, tin, titanium and germanium and optionally at least one trivalent element T that is selected from among aluminum, iron, boron, indium and gallium is described. This new zeolite is characterized in that it contains, in its crude synthesis form, the nitrogen-containing organic cation of formula N,N-dimethyl-N,N-di(3,3-dimethylbutyl)ammonium. A method for the preparation of this zeolite is also described.
摘要翻译：包含至少一种选自硅，锡，钛和锗中的四价元素X和选自铝，铁，硼，铟和镓中的至少一种三价元素T的EUO结构型沸石被描述。该新沸石的特征在于，其粗制合成形式含有式N，N-二甲基-N，N-二（3,3-二甲基丁基）铵的含氮有机阳离子。还描述了制备该沸石的方法。

2. 发明申请

US20070117711A1 EUO-structural-type zeolite that contains the N,N-dimethyl-N,N-di(3,3-dimethylbutyl)Ammonium cation and its process for preparation 有权
标题翻译：含有N，N-二甲基-N，N-二（3,3-二甲基丁基）铵阳离子的EUO结构型沸石及其制备方法
公开(公告)号：US20070117711A1
公开(公告)日：2007-05-24
申请号：US11638352
申请日：2006-12-14
申请人： Philippe Caullet , Sylvie Lacombe , Jean-Louis Paillaud , Nicolas Bats , Loic Rouleau
发明人： Philippe Caullet , Sylvie Lacombe , Jean-Louis Paillaud , Nicolas Bats , Loic Rouleau
IPC分类号： B01J29/04 , C01B39/00
CPC分类号： C01B37/02 , B01J20/18 , B01J29/7023 , B01J29/7446 , C01B39/48
摘要： A new EUO-structural-type zeolite that comprises at least one tetravalent element X that is selected from among silicon, tin, titanium and germanium and optionally at least one trivalent element T that is selected from among aluminum, iron, boron, indium and gallium is described. This new zeolite is characterized in that it contains, in its crude synthesis form, the nitrogen-containing organic cation of formula N,N-dimethyl-N,N-di(3,3-dimethylbutyl)ammonium. A method for the preparation of this zeolite is also described.
摘要翻译：包含至少一种选自硅，锡，钛和锗中的四价元素X和选自铝，铁，硼，铟和镓中的至少一种三价元素T的EUO结构型沸石被描述。该新沸石的特征在于，其粗制合成形式含有式N，N-二甲基-N，N-二（3,3-二甲基丁基）铵的含氮有机阳离子。还描述了制备该沸石的方法。

3. 发明授权

US07622099B2 Process for preparation of ZBM-30-type zeolites using a diammonium ether-type compound as an organic structuring agent 失效
标题翻译：使用二铵醚型化合物作为有机结构剂制备ZBM-30型沸石的方法
公开(公告)号：US07622099B2
公开(公告)日：2009-11-24
申请号：US11592326
申请日：2006-11-03
申请人： Philippe Caullet , Sylvie Lacombe , Jean-Louis Paillaud , Nicolas Bais , Loic Rouleau
发明人： Philippe Caullet , Sylvie Lacombe , Jean-Louis Paillaud , Nicolas Bais , Loic Rouleau
IPC分类号： C01B39/00 , C01B33/00 , C01B21/00 , C01B21/06 , C01B21/064 , C01B21/072 , C01B21/076
CPC分类号： B01J29/70 , B01J29/703 , C01B37/02 , C01B39/48
摘要： The invention relates to a process for preparation of a zeolite that is selected from among the ZBM-30, ZSM-48, EU-2 and EU-11 zeolites, comprising the mixing in an aqueous medium of at least one source of at least one element X (Si and/or Ge) and at least one nitrogen-containing organic compound Q. Said nitrogen-containing organic compound Q is selected from among the compounds comprising at least one ether group and two terminal ammonium groups and their precursors.
摘要翻译：本发明涉及一种选自ZBM-30，ZSM-48，EU-2和EU-11沸石的沸石的制备方法，其包括在含水介质中混合至少一种至少一种元素X（Si和/或Ge）和至少一种含氮有机化合物Q.所述含氮有机化合物Q选自包含至少一个醚基和两个末端铵基团的化合物及其前体。

4. 发明申请

US20070134152A1 Process for preparation of ZBM-30-type zeolites using a diammonium ether-type compound as an organic structuring agent 失效
标题翻译：使用二铵醚型化合物作为有机结构剂制备ZBM-30型沸石的方法
公开(公告)号：US20070134152A1
公开(公告)日：2007-06-14
申请号：US11592326
申请日：2006-11-03
申请人： Philippe Caullet , Sylvie Lacombe , Jean-Louis Paillaud , Nicolas Bais , Loic Rouleau
发明人： Philippe Caullet , Sylvie Lacombe , Jean-Louis Paillaud , Nicolas Bais , Loic Rouleau
IPC分类号： C01B39/00 , C01B39/02
CPC分类号： B01J29/70 , B01J29/703 , C01B37/02 , C01B39/48
摘要： The invention relates to a process for preparation of a zeolite that is selected from among the ZBM-30, ZSM-48, EU-2 and EU-11 zeolites, comprising the mixing in an aqueous medium of at least one source of at least one element X (Si and/or Ge) and at least one nitrogen-containing organic compound Q. Said nitrogen-containing organic compound Q is selected from among the compounds comprising at least one ether group and two terminal ammonium groups and their precursors.
摘要翻译：本发明涉及一种选自ZBM-30，ZSM-48，EU-2和EU-11沸石的沸石的制备方法，其包括在含水介质中混合至少一种至少一种元素X（Si和/或Ge）和至少一种含氮有机化合物Q.所述含氮有机化合物Q选自包含至少一个醚基和两个末端铵基团的化合物及其前体。

5. 发明授权

US06942847B2 Solid crystalline IM-9, and a process for its preparation 有权
标题翻译：固体结晶IM-9及其制备方法
公开(公告)号：US06942847B2
公开(公告)日：2005-09-13
申请号：US10758290
申请日：2004-01-16
申请人： Bogdan Harbuzaru , Jean-Louis Paillaud , Joel Patarin , Nicolas Bats , Loic Rouleau
发明人： Bogdan Harbuzaru , Jean-Louis Paillaud , Joel Patarin , Nicolas Bats , Loic Rouleau
IPC分类号： B01J20/18 , B01J29/035 , B01J29/04 , B01J29/70 , C01B39/06 , C01B39/48 , C10G47/14
CPC分类号： C01B39/06 , B01J20/18 , B01J29/035 , B01J29/04 , B01J29/70 , C01B39/48 , C10G47/14
摘要： A zeolite crystalline solid, designated IM-9, having an X ray diffraction diagram according to FIG. 1, has a chemical composition, expressed as the anhydrous base, in terms of moles of oxides, in accordance with the formula XO2: mYO2: pZ2O3: qR2/nO: sF, in which R represents one or more cation(s) with valency n, X represents one or more tetravalent element(s) other than germanium, Y represents germanium, Z represents at least one trivalent element and F is fluorine. The solid is useable, for example as an adsorbent or catalyst.
摘要翻译：具有根据图1的X射线衍射图的称为IM-9的沸石结晶固体。 1，具有根据式XO 2：mYO 2：pZ 2的氧化物的摩尔数表示为无水碱的化学组成其中R表示一个或多个具有化合价n的阳离子，X表示一个或多个四价基团除锗以外的元素，Y表示锗，Z表示至少一个三价元素，F表示氟。固体可用，例如作为吸附剂或催化剂。

6. 发明授权

US08038982B2 EUO-structural-type zeolite containing the alkyl quinuclidinium structuring agent, process for preparation and use as catalyst 失效
标题翻译：含有烷基奎宁环结构剂的EUO结构型沸石，其制备方法和用作催化剂
公开(公告)号：US08038982B2
公开(公告)日：2011-10-18
申请号：US10579205
申请日：2004-11-09
申请人： Loic Rouleau , Sylvie Lacombe
发明人： Loic Rouleau , Sylvie Lacombe
IPC分类号： C01B39/04 , C07C5/27
CPC分类号： B01J29/7446 , B01J29/7023 , B01J2229/18 , C01B39/48 , C07C5/2775 , C07C9/14
摘要： An EUO-structural-type zeolite that comprises at least one element X that is selected from among silicon and germanium and at least one element T that is selected from among aluminum, iron, gallium, vanadium, zirconium, molybdenum, arsenic, antimony, chromium and manganese is described. It contains at least one alkyl quinuclidinium cation in its intracrystalline pores and has an N/X atomic ratio of more than 0.065, whereby N represents the nitrogen element. This invention also relates to a process for preparation of said zeolite and the use of the latter as an acidic solid in a process for conversion of hydrocarbon feedstocks.
摘要翻译：包含选自硅和锗中的至少一种元素X和选自铝，铁，镓，钒，锆，钼，砷，锑，铬中的至少一种元素T的EUO结构型沸石并描述了锰。它在其晶内孔中含有至少一个烷基奎宁环鎓阳离子，其N / X原子比大于0.065，由此N代表氮元素。本发明还涉及一种制备所述沸石的方法以及后者在烃原料转化方法中作为酸性固体的用途。

7. 发明授权

US06342200B1 Process for preparing a zeolite with structure type EUO 有权
标题翻译：制备结构型EUO的沸石的方法
公开(公告)号：US06342200B1
公开(公告)日：2002-01-29
申请号：US09432120
申请日：1999-11-02
申请人： Loic Rouleau , Sylvie Lacombe , Fabio Alario , Elisabeth Merlen , Frédéric Kolenda , Julia Magne-Drisch
发明人： Loic Rouleau , Sylvie Lacombe , Fabio Alario , Elisabeth Merlen , Frédéric Kolenda , Julia Magne-Drisch
IPC分类号： C01B3904
CPC分类号： B01J29/7023 , B01J20/18 , B01J29/04 , B01J2229/62 , C01B39/48 , C07C5/2708 , C07C2529/70 , C10G35/095 , C10G45/64 , Y02P20/588 , C07C15/067
摘要： The present invention concerns a process for preparing a zeolite with structure type EUO comprising at least one element X selected from silicon and germanium and at least one element T selected from iron, aluminium, gallium, boron, titanium, vanadium, zirconium, molybdenum, arsenic, antimony, chromium and manganese, characterized in that seeds of at least one zeolitic material are used comprising at least one element X′ selected from silicon and germanium and at least one element T′ selected from iron, aluminium, gallium, boron, titanium, vanadium, zirconium, molybdenum, arsenic, antimony, chromium and manganese with a ratio X′/T′ of less than 200, said seeds being different from the zeolite with structure type EUO being prepared. The present invention also concerns the use of the zeolite obtained as a catalyst in a process for converting hydrocarbon-containing feeds, as an adsorbent to control pollution and as a molecular sieve for separation, and more particularly as a catalyst in a process for isomerizing aromatic compounds containing 8 carbon atoms.
摘要翻译：本发明涉及一种制备具有结构型EUO的沸石的方法，该方法包括至少一种选自硅和锗的元素X和选自铁，铝，镓，硼，钛，钒，锆，钼，砷中的至少一种元素T ，锑，铬和锰，其特征在于使用至少一种沸石材料的种子，其包含至少一种选自硅和锗的元素X'和至少一种选自铁，铝，镓，硼，钛，钒，锆，钼，砷，锑，铬和锰，其比例X'/ T'小于200，所述种子与制备具有结构类型EUO的沸石不同。本发明还涉及在烃类进料转化方法中作为催化剂使用的沸石，作为用于控制污染的吸附剂和用于分离的分子筛，更特别地，作为用于异构化芳族化合物的方法中的催化剂含有8个碳原子的化合物。

8. 发明申请

US20090043145A1 Euo-structural-type zeolite containing the alkyl quinuclidinium structuring agent, process for preparation and use as catalyst 失效
标题翻译：含有烷基奎宁环结构剂的Eu-结构型沸石，其制备方法和用作催化剂
公开(公告)号：US20090043145A1
公开(公告)日：2009-02-12
申请号：US10579205
申请日：2004-11-09
申请人： Loic Rouleau , Sylvie Lacombe
发明人： Loic Rouleau , Sylvie Lacombe
IPC分类号： C07C5/13
CPC分类号： B01J29/7446 , B01J29/7023 , B01J2229/18 , C01B39/48 , C07C5/2775 , C07C9/14
摘要： An EUO-structural-type zeolite that comprises at least one element X that is selected from among silicon and germanium and at least one element T that is selected from among aluminum, iron, gallium, vanadium, zirconium, molybdenum, arsenic, antimony, chromium and manganese is described. It contains at least one alkyl quinuclidinium cation in its intracrystalline pores and has an N/X atomic ratio of more than 0.065, whereby N represents the nitrogen element. This invention also relates to a process for preparation of said zeolite and the use of the latter as an acidic solid in a process for conversion of hydrocarbon feedstocks.
摘要翻译：包含选自硅和锗中的至少一种元素X和选自铝，铁，镓，钒，锆，钼，砷，锑，铬中的至少一种元素T的EUO结构型沸石并描述了锰。它在其晶内孔中含有至少一个烷基奎宁环鎓阳离子，其N / X原子比大于0.065，由此N代表氮元素。本发明还涉及一种制备所述沸石的方法以及后者在烃原料转化方法中作为酸性固体的用途。

9. 发明授权

US6136290A IM-5 zeolite, a process for its preparation and catalytic applications thereof 失效
标题翻译： IM-5沸石，其制备方法和催化应用
公开(公告)号：US6136290A
公开(公告)日：2000-10-24
申请号：US955117
申请日：1997-10-21
申请人： Eric Benazzi , Jean-Louis Guth , Loic Rouleau
发明人： Eric Benazzi , Jean-Louis Guth , Loic Rouleau
IPC分类号： B01J29/70 , B01J29/00 , B01J29/04 , C01B39/46 , C01B39/48 , C10G49/08 , B01J29/06 , C10G11/05
CPC分类号： C10G49/08 , B01J29/04 , C01B39/48
摘要： The invention concerns IM-5 zeolite with a chemical composition with the following formula, expressed in terms of the mole ratios of the oxides for the anhydrous state: 100XO.sub.2,mY.sub.2 O.sub.3, pR.sub.2/n O where m is 10 or less; p is in the range 0 to 20; R represents one or more cations with valency n; X represents silicon and/or germanium; Y represents one or more of the following elements: aluminum, iron, gallium, boron and titanium. The zeolite is characterized by an Xray diffraction diagram, in its as synthesized state, which comprises the results shown in Table 1 of the description. The invention also concerns the preparation of the zeolite, any catalyst containing the zeolite and any catalytic process using such a catalyst.
摘要翻译：本发明涉及具有下式的化学组成的IM-5沸石，以无水状态的氧化物的摩尔比表示：100XO2，mY2O3，pR2 / nO，其中m为10或更小; p在0到20之间; R表示一个或多个价数为n的阳离子; X表示硅和/或锗; Y表示以下元素中的一种或多种：铝，铁，镓，硼和钛。沸石的特征在于XRD衍射图，其合成状态包括说明书的表1所示的结果。本发明还涉及沸石的制备，含有沸石的任何催化剂以及使用这种催化剂的任何催化方法。

10. 发明申请

US20090029845A1 FAU-structural-type supported zeolite membranes, their process for preparation and their applications 失效
标题翻译： FAU结构型支撑沸石膜，其制备方法及其应用
公开(公告)号：US20090029845A1
公开(公告)日：2009-01-29
申请号：US12219541
申请日：2008-07-23
申请人： Florent Guillou , Gerhard Pirngruber , Loic Rouleau , Valentin Valtchev
发明人： Florent Guillou , Gerhard Pirngruber , Loic Rouleau , Valentin Valtchev
IPC分类号： B01J20/18
CPC分类号： B01D71/028 , B01D67/0051 , B01D69/10 , B01D2325/04 , B01J20/183 , B01J20/28035
摘要： The invention relates to a FAU-type zeolite membrane that comprises a FAU-type zeolite crystal layer incorporated in the surface porosity of at least one selected face of a porous substrate, in which the ratio between the thickness of said zeolite layer incorporated in the surface porosity of said selected face of the substrate and the total thickness of said zeolite layer is at least 70%. It also relates to processes for preparation and application of these membranes.
摘要翻译：本发明涉及一种FAU型沸石膜，其包括结合在多孔基材的至少一个选择面的表面孔隙率中的FAU型沸石结晶层，其中所述沸石层的结合在表面中的厚度之比所述基材的所述选择面的孔隙率和所述沸石层的总厚度为至少70％。它还涉及这些膜的制备和应用的方法。

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