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1. 发明授权

US06514479B1 EUO zeolite comprising crystals and aggregates of crystals with specific granulometrys and its use as a catalyst in the isomerisation of C8 aromatic compounds 有权
标题翻译：包含具有特定粒度的晶体和晶体聚集体的EUO沸石及其作为C8芳族化合物异构化中的催化剂的用途
公开(公告)号：US06514479B1
公开(公告)日：2003-02-04
申请号：US09471323
申请日：1999-12-23
申请人： Elisabeth Merlen , Fabio Alario , Olivia Martin , Nathalie Ferrer , Sylvie Lacombe , Loïc Rouleau , Julia Magne-Drisch
发明人： Elisabeth Merlen , Fabio Alario , Olivia Martin , Nathalie Ferrer , Sylvie Lacombe , Loïc Rouleau , Julia Magne-Drisch
IPC分类号： C01B3904
CPC分类号： B01J29/7023 , B01J29/7446 , B01J35/023 , C07C5/2708 , C07C2529/70 , C10G45/64 , C10G2300/1096 , C10G2300/4018 , C10G2400/30 , C07C15/067
摘要： The invention concerns a zeolite with structure type EUO comprising EUO zeolite crystals with a size of less than 5 &mgr;m, at least a portion of the EUO zeolite crystals being in the form of EUO zeolite aggregates, characterized in that the granulometry of the aggregates is such that Dv,90 is 500 &mgr;m or less. The invention also concerns the preparation of the zeolite and the use of the zeolite as a catalyst, for example in a process for isomerising aromatic compounds containing 8 carbon atoms per molecule.
摘要翻译：本发明涉及结构类型为EUO的沸石，其包含尺寸小于5um的EUO沸石晶体，至少一部分EUO沸石晶体为EUO沸石聚集体形式，其特征在于聚集体的粒度为那么Dv，90是500mam以下。本发明还涉及沸石的制备和沸石作为催化剂的用途，例如在每分子含有8个碳原子的芳族化合物的异构化方法中。

2. 发明授权

US06613709B1 Catalyst comprising at least one zeolite with structure type NES and rhenium, and its use for transalkylation of alkylaromatic hydrocarbons 有权
标题翻译：包含至少一种结构类型为NES和铼的沸石的催化剂及其用于烷基芳烃的烷基转移的用途
公开(公告)号：US06613709B1
公开(公告)日：2003-09-02
申请号：US09642020
申请日：2000-08-21
申请人： Elisabeth Merlen , Fabio Alario , Nathalie Ferrer , Olivia Martin
发明人： Elisabeth Merlen , Fabio Alario , Nathalie Ferrer , Olivia Martin
IPC分类号： B01J2906
CPC分类号： C07C6/126 , B01J29/74 , B01J29/78 , B01J2229/16 , B01J2229/26 , B01J2229/36 , B01J2229/40 , B01J2229/42 , C07C2529/70
摘要： The present invention concerns a catalyst which contain at least one zeolite with structure type NES, preferably NU-87, comprising silicon and at least one element T selected from the group formed by aluminium, iron, gallium and boron. Preferably, element T has been extracted so that the overall Si/T atomic ratio is more than 20. This zeolite is at least partially in its acid form. The binder is preferably alumina. The catalyst also contains at least one metal selected from the group formed by group VIIB, group VIB and iridium, preferably rhenium. Finally, the catalyst optionally also contains at least one metal selected from the group formed by elements from groups III and IV of the periodic table, preferably indium or tin. The present invention also concerns the use of the catalyst in a process for transalkylating alkylaromatic hydrocarbons such as toluene and alkylaromatic compounds containing at least 9 carbon atoms. In particular, this catalyst is highly effective in treating C9+ aromatic feeds containing more than 5% by weight of aromatic olefins containing 10 carbon atoms and more, this feed possibly also containing benzene.
摘要翻译：本发明涉及含有至少一种结构类型为NES，优选为NU-87的沸石的催化剂，其包含硅和选自由铝，铁，镓和硼形成的基团中的至少一种元素T. 优选地，提取元素T使得总Si / T原子比大于20.该沸石至少部分为其酸形式。粘合剂优选为氧化铝。该催化剂还含有选自由ⅦB族，ⅥB族和铱族，优选铼形成的族中的至少一种金属。最后，催化剂任选地还含有至少一种选自元素周期表III和IV族的元素形成的金属，优选为铟或锡。本发明还涉及催化剂在烷基化烷基芳烃如甲苯和含有至少9个碳原子的烷基芳族化合物的方法中的用途。特别地，该催化剂在处理含有大于5重量％的含有10个碳原子的芳族烯烃和更多的芳族烯烃的C9 +芳族原料方面是非常有效的，该进料还可能含有苯。

3. 发明申请

US20050256355A1 Catalyst comprising at least one zeolite with structure type NES and rhenium, and its use for transalkylation of alkylaromatic hydrocarbons 审中-公开
标题翻译：包含至少一种结构类型为NES和铼的沸石的催化剂及其用于烷基芳烃的烷基转移的用途
公开(公告)号：US20050256355A1
公开(公告)日：2005-11-17
申请号：US11048751
申请日：2005-02-03
申请人： Elisabeth Merlen , Fabio Alario , Nathalie Ferrer , Olivia Martin
发明人： Elisabeth Merlen , Fabio Alario , Nathalie Ferrer , Olivia Martin
IPC分类号： B01J29/06 , B01J29/78 , C07C6/12 , C10G45/64
CPC分类号： B01J29/78 , B01J2229/42 , C07C6/126 , C07C2523/28 , C07C2529/70 , C07C2529/78 , C10G45/64
摘要： The present invention concerns catalysts which contain at least one zeolite with structure type NES, preferably NU-87, comprising silicon and at least one element T selected from the group formed by aluminium, iron, gallium and boron. Preferably, element T has been extracted so that the overall Si/T atomic ratio is more than 20. This zeolite is at least partially in its acid form. The binder is preferably alumina. The catalyst also contains at least one metal selected from the group formed by group VIIB, group VIB and iridium, preferably molybdenum. Finally, the catalyst optionally also contains at least one metal selected from the group formed by elements from groups IIIA and IVA of the periodic table, preferably indium or tin. The present invention also concerns the use of the catalyst in a process for transalkylating alkylaromatic hydrocarbons such as toluene and alkylaromatic compounds containing at least 9 carbon atoms. In particular, this catalyst is highly effective in treating C9+ aromatic feeds containing more than 5% by weight of aromatic olefins containing 10 carbon atoms and more, this feed possibly also containing benzene.
摘要翻译：本发明涉及含有至少一种结构类型NES，优选NU-87的沸石的催化剂，其包含硅和至少一种选自由铝，铁，镓和硼形成的基团的元素T. 优选地，提取元素T使得总Si / T原子比大于20.该沸石至少部分为其酸形式。粘合剂优选为氧化铝。该催化剂还含有至少一种选自由ⅦB族，ⅥB族和铱族化合物形成的金属，优选为钼。最后，催化剂任选地还含有选自元素周期表IIIA和IVA族元素形成的族中的至少一种金属，优选为铟或锡。本发明还涉及催化剂在烷基化烷基芳烃如甲苯和含有至少9个碳原子的烷基芳族化合物的方法中的用途。特别地，该催化剂在处理含有大于5重量％的含有10个碳原子的芳族烯烃和更多的芳族烯烃的C9 +芳族原料方面是非常有效的，该进料还可能含有苯。

4. 发明授权

US06864400B2 Catalyst comprising at least one zeolite with structure type NES and rhenium, and its use for transalkylation of alkylaromatic hydrocarbons 失效
标题翻译：包含至少一种结构类型为NES和铼的沸石的催化剂及其用于烷基芳烃的烷基转移的用途
公开(公告)号：US06864400B2
公开(公告)日：2005-03-08
申请号：US10428033
申请日：2003-05-02
申请人： Elisabeth Merlen , Fabio Alario , Nathalie Ferrer , Olivia Martin
发明人： Elisabeth Merlen , Fabio Alario , Nathalie Ferrer , Olivia Martin
IPC分类号： B01J29/076 , B01J23/16 , B01J23/46 , B01J29/06 , B01J29/74 , B01J29/78 , C07B61/00 , C07C5/22 , C07C5/52 , C07C6/06 , C07C6/12 , C07C15/08
CPC分类号： C07C6/126 , B01J29/74 , B01J29/78 , B01J2229/16 , B01J2229/26 , B01J2229/36 , B01J2229/40 , B01J2229/42 , C07C2529/70
摘要： The present invention concerns a catalyst which contain at least one zeolite with structure type NES, preferably NU-87, comprising silicon and at least one element T selected from the group formed by aluminium, iron, gallium and boron. Preferably, element T has been extracted so that the overall Si/T atomic ratio is more than 20. This zeolite is at least partially in its acid form. The binder is preferably alumina. The catalyst also contains at least one metal selected from the group formed by group VIIB, group VIB and iridium, preferably rhenium. Finally, the catalyst optionally also contains at least one metal selected from the group formed by elements from groups III and IV of the periodic table, preferably indium or tin. The present invention also concerns the use of the catalyst in a process for transalkylating alkylaromatic hydrocarbons such as toluene and alkylaromatic compounds containing at least 9 carbon atoms. In particular, this catalyst is highly effective in treating C9+ aromatic feeds containing more than 5% by weight of aromatic olefins containing 10 carbon atoms and more, this feed possibly also containing benzene.
摘要翻译：本发明涉及含有至少一种结构类型为NES，优选为NU-87的沸石的催化剂，其包含硅和选自由铝，铁，镓和硼形成的基团中的至少一种元素T. 优选地，提取元素T使得总Si / T原子比大于20.该沸石至少部分为其酸形式。粘合剂优选为氧化铝。该催化剂还含有选自由ⅦB族，ⅥB族和铱族，优选铼形成的族中的至少一种金属。最后，催化剂任选地还含有至少一种选自元素周期表III和IV族的元素形成的金属，优选为铟或锡。本发明还涉及催化剂在烷基化烷基芳烃如甲苯和含有至少9个碳原子的烷基芳族化合物的方法中的用途。特别地，该催化剂在处理含有大于5重量％的含有10个碳原子的芳族烯烃和更多的芳族烯烃的C9 +芳族原料方面是非常有效的，该进料还可能含有苯。

5. 发明授权

US6096939A Aliphatic alkylation utilizing a liquid catalyst 失效
标题翻译：使用液体催化剂的脂肪族烷基化
公开(公告)号：US6096939A
公开(公告)日：2000-08-01
申请号：US115546
申请日：1998-07-15
申请人： Eric Benazzi , Jean-Francois Joly , Nathalie Ferrer , Bernard Torck
发明人： Eric Benazzi , Jean-Francois Joly , Nathalie Ferrer , Bernard Torck
IPC分类号： B01J31/02 , B01J31/30 , C07B61/00 , C07C2/62 , C07C9/16 , C10G35/04
CPC分类号： C07C2/62 , C07C2527/03 , C07C2531/025
摘要： The invention concerns the catalytic alkylation of at least one isoparaffin selected from the group formed by isobutane and isopentane in the presence of at least one olefin containing 3 to 6 carbon atoms per molecule, using a catalyst comprising 40% to 99% by weight of an acid selected from acids with formula R--SO.sub.3 H where R is fluorine or an alkyl group or a fluorinated alkyl group, R preferably being F or CF.sub.3, and more preferably CF.sub.3, and 1% to 60% by weight of a solvent selected from the group formed by sulpholane, dimethylsulphoxide and dioxanes, preferably sulpholane.
摘要翻译：本发明涉及至少一种选自异丁烷和异戊烷的异构烷烃在至少一种含有3至6个碳原子的烯烃存在下，每分子的催化烷基化，使用包含40-99％（重量）选自具有式R-SO 3 H的酸的酸，其中R是氟或烷基或氟化烷基，R优选为F或CF 3，更优选为CF 3，和1至60重量％的选自以下的溶剂：由环丁烷，二甲基亚砜和二恶烷形成，优选为环丁烷。

6. 发明授权

US5475184A Paraffin alkylation catalyst 失效
标题翻译：石蜡烷基化催化剂
公开(公告)号：US5475184A
公开(公告)日：1995-12-12
申请号：US230467
申请日：1994-04-20
申请人： Jean-Francois Joly , Nathalie Ferrer , Jean-Yves Bernhard , Eric Benazzi
发明人： Jean-Francois Joly , Nathalie Ferrer , Jean-Yves Bernhard , Eric Benazzi
IPC分类号： B01J29/04 , B01J21/08 , B01J27/053 , B01J31/02 , B01J35/02 , B01J35/08 , B01J35/10 , B01J37/02 , C07B61/00 , C07C2/62 , C07C9/16
CPC分类号： B01J31/0227 , B01J21/08 , B01J27/053 , B01J35/08 , C07C2/62 , B01J2231/323 , B01J35/023 , B01J35/1014 , B01J35/1047 , B01J37/0203 , C07C2521/08 , C07C2527/054 , C07C2531/025
摘要： Catalyst comprising a porous mineral or organic support and a mixture constituted by sulphuric acid, trifluoromethanesulphonic acid and, optionally, water. The invention also relates to a method for the preparation of the catalyst and its use in catalytic alkylation of isobutane and/or isopentane in the presence of at least one olefin comprising 3 to 6 carbon atoms per molecule.
摘要翻译：包含多孔矿物或有机载体的催化剂和由硫酸，三氟甲磺酸和任选的水构成的混合物。本发明还涉及一种制备催化剂的方法及其在异丁烷和/或异戊烷的催化烷基化存在下，每分子含有至少一个含有3-6个碳原子的烯烃的用途。

7. 发明授权

US5849978A Liquid catalyst for aliphatic alkylation 失效
标题翻译：用于脂肪族烷基化的液体催化剂
公开(公告)号：US5849978A
公开(公告)日：1998-12-15
申请号：US684441
申请日：1996-07-19
申请人： Eric Benazzi , Jean-Francois Joly , Nathalie Ferrer , Bernard Torck
发明人： Eric Benazzi , Jean-Francois Joly , Nathalie Ferrer , Bernard Torck
IPC分类号： B01J31/02 , B01J31/30 , C07B61/00 , C07C2/62 , C07C9/16 , C10G35/04
CPC分类号： C07C2/62 , C07C2527/03 , C07C2531/025
摘要： The invention concerns the catalytic alkylation of at least one isoparaffin selected from the group formed by isobutane and isopentane in the presence of at least one olefin containing 3 to 6 carbon atoms per molecule, using a catalyst comprising 40% to 99% by weight of an acid selected from acids with formula R--SO.sub.3 H where R is fluorine or an alkyl group or a fluorinated alkyl group, R preferably being F or CF.sub.3, and more preferably CF.sub.3, and 1% to 60% by weight of a solvent selected from the group formed by sulpholane, dimethylsulphoxide and dioxanes, preferably sulpholane.
摘要翻译：本发明涉及至少一种选自异丁烷和异戊烷的异构烷烃在至少一种含有3至6个碳原子的烯烃存在下，每分子的催化烷基化，使用包含40-99％（重量）选自具有式R-SO 3 H的酸的酸，其中R是氟或烷基或氟化烷基，R优选为F或CF 3，更优选为CF 3，和1至60重量％的选自以下的溶剂：由环丁烷，二甲基亚砜和二恶烷形成，优选为环丁烷。

8. 发明授权

US5693585A Aliphatic alkylation catalyst comprising an active phase containing a cuprous compound on a support 失效
标题翻译：脂肪族烷基化催化剂包含在载体上含有亚铜化合物的活性相
公开(公告)号：US5693585A
公开(公告)日：1997-12-02
申请号：US664538
申请日：1996-06-17
申请人： Eric Benazzi , Yves Chauvin , Andre Hirschauer , Nathalie Ferrer , Helene Olivier , Jean-Yves Bernhard
发明人： Eric Benazzi , Yves Chauvin , Andre Hirschauer , Nathalie Ferrer , Helene Olivier , Jean-Yves Bernhard
IPC分类号： B01J21/08 , B01J27/125 , B01J31/02 , B01J31/26 , B01J31/28 , B01J32/00 , B01J35/02 , B01J35/10 , C07B61/00 , C07C2/58 , C07C2/60 , C07C9/16 , B01J27/122 , B01J27/25 , B01J31/00
CPC分类号： C07C2/60 , B01J31/0294 , B01J31/26 , B01J31/28 , B01J31/30 , B01J21/08 , B01J2231/323 , B01J35/023 , B01J35/1019 , B01J35/1047 , C07C2521/08 , C07C2527/053 , C07C2527/122 , C07C2527/125 , C07C2527/126 , C07C2527/24 , C07C2531/02 , C07C2531/04 , Y02P20/584
摘要： A catalyst containing a porous organic or mineral support and at least one active phase having at least one aluminum halide, at least one compound selected for quaternary ammonium halides and amine hydrohalides, and at least one cuprous compound, the support having been impregnated with the active phase, the catalyst essentially constituted by particles with an average diameter in the range 0.1 .mu.m to 150 .mu.m, and the support, before impregnation with the active phase, has a total pore volume in the range 0.1 cm.sup.3 /g and 6 cm.sup.3 /g.
摘要翻译：含有多孔有机或矿物载体和至少一种具有至少一种卤化铝，至少一种选自季铵卤化物和胺氢卤化物的化合物和至少一种亚铜化合物的活性相的催化剂，该载体已经浸渍有活性相，催化剂基本上由平均直径在0.1μm至150μm的颗粒构成，并且在用活性相浸渍之前，载体的总孔体积在0.1cm 3 / g和6cm 3 / G。

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