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11. 发明授权

US06908660B2 Shaped body made of fiber-reinforced composites having a segmented covering layer, its production and its use 有权
标题翻译：由具有分段覆盖层的纤维增强复合材料制成的成形体，其生产及其用途
公开(公告)号：US06908660B2
公开(公告)日：2005-06-21
申请号：US10301941
申请日：2002-11-22
申请人： Moritz Bauer , Nadine Hander , Andreas Kienzle , Rainer Zimmermann-Chopin
发明人： Moritz Bauer , Nadine Hander , Andreas Kienzle , Rainer Zimmermann-Chopin
IPC分类号： C04B35/573 , C04B41/50 , C04B41/87 , F16D65/12 , F16D69/02 , B32B3/28 , B05D3/02 , C01B31/00 , C04B33/34 , F16D11/00 , F16D65/00 , F41H5/02
CPC分类号： C04B41/87 , C04B35/573 , C04B41/009 , C04B41/5059 , C04B2111/00362 , C04B2235/3826 , C04B2235/48 , F16D65/12 , F16D69/02 , F16D69/023 , Y10T428/24537 , Y10T428/24612 , C04B41/455 , C04B41/4576 , C04B35/565
摘要： The present invention relates to shaped bodies made of fiber-reinforced ceramic composites and comprising a core zone and at least one covering layer which has a coefficient of thermal expansion which is higher than that of the core zone. The covering layer is an SiC-rich covering layer and is divided into segments which are separated from the adjacent segments by gaps or bridging zones of a material which is different from the material of the segments. The invention also relates to a process for producing such shaped bodies by infiltration of an intermediate body with molten silicon and their use for friction disks, in vehicle construction or as protective plates.
摘要翻译：本发明涉及由纤维增强陶瓷复合材料制成的成型体，其包括芯区和至少一层具有高于芯区的热膨胀系数的覆盖层。覆盖层是富SiC的覆盖层，并且被分成通过不同于段的材料的材料的间隙或桥接区与相邻段分离的段。本发明还涉及通过熔融硅浸入中间体及其在摩擦盘，车辆结构或保护板中的用途来制造这种成型体的方法。

12. 发明授权

US07138190B2 Composite containing reinforcing fibers comprising carbon 有权
标题翻译：含有包含碳的增强纤维的复合材料
公开(公告)号：US07138190B2
公开(公告)日：2006-11-21
申请号：US10391868
申请日：2003-03-19
申请人： Moritz Bauer , Martin Christ , Ronald Huener , Andreas Kienzle , Rainer Zimmermann-Chopin
发明人： Moritz Bauer , Martin Christ , Ronald Huener , Andreas Kienzle , Rainer Zimmermann-Chopin
IPC分类号： B32B5/02 , B32B15/14 , B32B15/20
CPC分类号： C04B41/009 , C04B35/573 , C04B35/83 , C04B41/5059 , C04B41/87 , C04B2111/00362 , C04B2235/3217 , C04B2235/3244 , C04B2235/3248 , C04B2235/3272 , C04B2235/3275 , C04B2235/3279 , C04B2235/3418 , C04B2235/3817 , C04B2235/3821 , C04B2235/3826 , C04B2235/3839 , C04B2235/3843 , C04B2235/3873 , C04B2235/3891 , C04B2235/40 , C04B2235/402 , C04B2235/404 , C04B2235/405 , C04B2235/407 , C04B2235/421 , C04B2235/428 , C04B2235/80 , F16D69/02 , F16D69/023 , Y10T428/12035 , Y10T428/12063 , Y10T428/12486 , Y10T428/12576 , Y10T428/12903 , Y10T428/25 , C04B41/4523 , C04B41/4556 , C04B41/5127
摘要： Composite which contains reinforcing fibers comprising carbon and whose matrix comprises silicon carbide, silicon and copper, with the mass fraction of copper in the composite being up to 55%, processes for producing it, in particular by liquid infiltration of C/C intermediate bodies with melts comprising Si and/or Cu and Si, and also its use as friction lining in a friction pairing with ceramic brake discs or clutch discs comprising C/SiC.
摘要翻译：复合材料，其含有包含碳的增强纤维，其基质包括碳化硅，硅和铜，复合材料中铜的质量分数高达55％，其制备方法，特别是通过C / C中间体的液体渗透包含Si和/或Cu和Si的熔体，以及其用作与陶瓷制动盘或包含C / SiC的离合器盘的摩擦配对中的摩擦衬里的用途。

13. 发明授权

US06908667B2 Fiber-reinforced material composed, at least in a surface region, of a metal/ceramic composite, molding composed of the fiber-reinforced material and method of producing the fiber-reinforced material 失效
标题翻译：至少在表面区域中由金属/陶瓷复合材料构成的纤维增强材料，由纤维增强材料构成的成型体和制造纤维增强材料的方法
公开(公告)号：US06908667B2
公开(公告)日：2005-06-21
申请号：US10179481
申请日：2002-06-25
申请人： Martin Christ , Michael Heine , Andreas Kienzle , Rainer Zimmermann-Chopin
发明人： Martin Christ , Michael Heine , Andreas Kienzle , Rainer Zimmermann-Chopin
IPC分类号： C04B35/571 , C04B35/573 , C04B35/628 , C04B35/80 , C04B35/83 , C04B41/51 , C04B41/52 , C04B41/88 , C04B41/89 , F16D69/02 , D04H1/00
CPC分类号： C04B35/62884 , C04B35/565 , C04B35/571 , C04B35/573 , C04B35/62863 , C04B35/62873 , C04B35/806 , C04B35/83 , C04B41/009 , C04B41/4564 , C04B41/51 , C04B41/5127 , C04B41/52 , C04B41/88 , C04B41/89 , C04B2111/00362 , C04B2235/3272 , C04B2235/3275 , C04B2235/3279 , C04B2235/40 , C04B2235/404 , C04B2235/405 , C04B2235/407 , C04B2235/408 , C04B2235/422 , C04B2235/428 , C04B2235/5224 , C04B2235/5232 , C04B2235/5236 , C04B2235/5244 , C04B2235/728 , C04B2235/75 , C04B2235/80 , F16D69/02 , Y10T428/213 , Y10T428/24273 , Y10T428/249924 , Y10T428/249927 , Y10T428/249951 , Y10T428/252 , Y10T428/2918 , Y10T428/2949 , Y10T428/31 , C04B41/5144 , C04B41/5133 , C04B41/522 , C04B41/5027 , C04B41/5022 , C04B38/00
摘要： A method is provided for producing a fiber-reinforced material which is composed, at least in a region of a surface layer, of a ceramic composite and has carbon-containing fibers reaction-bonded to a matrix containing the elements Si and C. In particular a method of producing fiber-reinforced silicon carbide is provided in which a structure of a matrix contains cracks and/or pores, at least at ambient temperature, because of a high thermal expansion coefficient compared with that of the fibers. Metals are selectively electrodeposited in the open pores and cracks of the matrix and, in particular, in a region of the electrically conductive reinforcing fibers. As a result, the open pores and cracks are filled and, in addition, metallic top layers are optionally formed that are firmly keyed to the ceramic composite and that may serve as an interlayer for glass top layers or ceramic top layers. A fiber-reinforced composite material, as well as moldings, in particular brake discs, brake linings or clutch plates, composed of such a composite material, are also provided.
摘要翻译：提供一种制造纤维增强材料的方法，所述纤维增强材料至少在陶瓷复合材料的表面层的区域中形成并具有与包含元素Si和C的基体反应结合的含碳纤维。特别地，提供了一种生产纤维增强碳化硅的方法，其中由于与纤维相比具有高的热膨胀系数，至少在环境温度下，基质的结构含有裂纹和/或孔。金属选择性地电沉积在基体的开孔和裂纹中，特别是在导电增强纤维的区域中。结果，填充了开放的孔和裂纹，此外，任选地形成金属顶层，其牢固地键合到陶瓷复合材料上，并且可以用作玻璃顶层或陶瓷顶层的中间层。还提供了由这种复合材料组成的纤维增强复合材料以及模制品，特别是制动盘，制动衬片或离合器片。

14. 发明授权

US07708805B2 Method of producing carbon fibers, and methods of making protective clothing and a filter module 失效
标题翻译：生产碳纤维的方法，以及制作防护服的方法和过滤器模块
公开(公告)号：US07708805B2
公开(公告)日：2010-05-04
申请号：US11656259
申请日：2007-01-22
申请人： Michael Heine , Richard Neuert , Rainer Zimmermann-Chopin
发明人： Michael Heine , Richard Neuert , Rainer Zimmermann-Chopin
IPC分类号： D01F9/12
CPC分类号： D01F9/22
摘要： Porous carbon fibers, whose active centers are formed by pores that are filled at least in part by carbon and/or metal and/or metal carbide, obtainable by carbonization of organic or inorganic polymers, the use thereof for the adsorption or separation of gaseous substances, in particular of CO2, and also a method for the production thereof. First, a spinning mixture containing polyacrylonitrile-based polymer A and an organic or metallo-organic polymer B is produced. Next, the spinning mixture is spun to form mixed fibers of polymer A and polymer B. The mixed fiber is stabilized by oxidation. This is followed by carbonization or graphitization of the mixed fiber under non-oxidizing conditions in such a way that the polymer B forms a carbon and/or metal and/or metal carbide residue of at least 22 wt %, the residue forming active centers.
摘要翻译：多孔碳纤维，其活性中心由至少部分由碳和/或金属和/或金属碳化物填充的孔形成，可通过有机或无机聚合物的碳化获得，其用于吸附或分离气态物质，特别是二氧化碳，以及其制备方法。首先，制备含有聚丙烯腈类聚合物A和有机或金属有机聚合物B的纺丝混合物。接下来，将纺丝混合物纺丝以形成聚合物A和聚合物B的混合纤维。混合纤维通过氧化而稳定。接着在非氧化条件下使混合纤维碳化或石墨化，使得聚合物B形成至少22重量％的碳和/或金属和/或金属碳化物残余物，残余物形成活性中心。

15. 发明授权

US07238414B2 Fiber-reinforced composite for protective armor, and method for producing the fiber-reinforced composition and protective armor 失效
标题翻译：用于防护装甲的纤维增强复合材料，以及生产纤维增强组合物和防护装甲的方法
公开(公告)号：US07238414B2
公开(公告)日：2007-07-03
申请号：US10852960
申请日：2004-05-24
申请人： Bodo Benitsch , Michael Heine , Sven Schweizer , Rainer Zimmermann-Chopin
发明人： Bodo Benitsch , Michael Heine , Sven Schweizer , Rainer Zimmermann-Chopin
IPC分类号： B32B17/12 , B32B3/14
CPC分类号： F41H5/0428 , B32B18/00 , B32B2315/02 , C04B35/522 , C04B35/573 , C04B35/83 , C04B2235/38 , C04B2235/3821 , C04B2235/3826 , C04B2235/3843 , C04B2235/3847 , C04B2235/386 , C04B2235/3873 , C04B2235/48 , C04B2235/5248 , C04B2235/526 , C04B2235/5264 , C04B2235/5272 , C04B2237/365 , C04B2237/38 , C04B2237/385 , C04B2237/584 , C04B2237/61 , Y10T428/166 , Y10T428/249924 , Y10T428/249928
摘要： A fiber-reinforced composite body containing a first zone made of a ceramic matrix, which predominantly contains silicon carbide and, optionally, silicon and/or carbon and/or compounds thereof, and containing a second zone, which is located on a surface of the ceramic matrix zone and formed form a fiber-reinforced C/SiC ceramic. The fiber length decreases from the exterior of the fiber-reinforced ceramic zone up to the first zone and, optionally, up to one or more other zones that are arranged on the second zone. A method for producing the composite body is characterized by involving a joint infiltration at least of the first zone and of the second zone with liquid silicon and by the carrying out of a siliconization. A composite body of this type can be used, in particular, as armoring in the civil or military sectors.
摘要翻译：一种纤维增强复合体，其包含由陶瓷基体制成的第一区域，该第一区域主要含有碳化硅和任选的硅和/或碳和/或其化合物，并且包含第二区，其位于陶瓷基体区并形成纤维增强C / SiC陶瓷。纤维长度从纤维增强陶瓷区域的外部直到第一区域，并且可选地，直到布置在第二区域上的一个或多个其它区域减小。复合体的制造方法的特征在于，至少使第一区域和第二区域与液态硅进行接合渗透，并且进行硅化。这种复合体可以用于民用或军事部门的装甲。

16. 发明申请

US20070116939A1 FIBER-REINFORCED COMPOSITE FOR PROTECTIVE ARMOR, AND METHOD FOR PRODUCING THE FIBER-REINFORCED COMPOSITION AND PROTECTIVE ARMOR 失效
标题翻译：用于保护性铠装的纤维增强复合材料，以及用于生产纤维增强组合物和保护性铠甲的方法
公开(公告)号：US20070116939A1
公开(公告)日：2007-05-24
申请号：US10852960
申请日：2004-05-24
申请人： Bodo Benitsch , Michael Heine , Sven Schweizer , Rainer Zimmermann-Chopin
发明人： Bodo Benitsch , Michael Heine , Sven Schweizer , Rainer Zimmermann-Chopin
IPC分类号： D04H13/00 , D04H5/00
CPC分类号： F41H5/0428 , B32B18/00 , B32B2315/02 , C04B35/522 , C04B35/573 , C04B35/83 , C04B2235/38 , C04B2235/3821 , C04B2235/3826 , C04B2235/3843 , C04B2235/3847 , C04B2235/386 , C04B2235/3873 , C04B2235/48 , C04B2235/5248 , C04B2235/526 , C04B2235/5264 , C04B2235/5272 , C04B2237/365 , C04B2237/38 , C04B2237/385 , C04B2237/584 , C04B2237/61 , Y10T428/166 , Y10T428/249924 , Y10T428/249928
摘要： A fiber-reinforced composite body containing a first zone made of a ceramic matrix, which predominantly contains silicon carbide and, optionally, silicon and/or carbon and/or compounds thereof, and containing a second zone, which is located on a surface of the ceramic matrix zone and formed form a fiber-reinforced C/SiC ceramic. The fiber length decreases from the exterior of the fiber-reinforced ceramic zone up to the first zone and, optionally, up to one or more other zones that are arranged on the second zone. A method for producing the composite body is characterized by involving a joint infiltration at least of the first zone and of the second zone with liquid silicon and by the carrying out of a siliconization. A composite body of this type can be used, in particular, as armoring in the civil or military sectors.
摘要翻译：一种纤维增强复合体，其包含由陶瓷基体制成的第一区域，该第一区域主要含有碳化硅和任选的硅和/或碳和/或其化合物，并且包含第二区，其位于陶瓷基体区并形成纤维增强C / SiC陶瓷。纤维长度从纤维增强陶瓷区域的外部直到第一区域，并且可选地，直到布置在第二区域上的一个或多个其它区域减小。复合体的制造方法的特征在于，至少使第一区域和第二区域与液态硅进行接合渗透，并进行硅化。这种复合体可以用于民用或军事部门的装甲。

17. 发明申请

US20070132128A1 Method of producing carbon fibers, and methods of making protective clothing and a filter module 失效
标题翻译：生产碳纤维的方法，以及制作防护服的方法和过滤器模块
公开(公告)号：US20070132128A1
公开(公告)日：2007-06-14
申请号：US11656259
申请日：2007-01-22
申请人： Michael Heine , Richard Neuert , Rainer Zimmermann-Chopin
发明人： Michael Heine , Richard Neuert , Rainer Zimmermann-Chopin
IPC分类号： D01F8/00
CPC分类号： D01F9/22
摘要： Porous carbon fibers, whose active centers are formed by pores that are filled at least in part by carbon and/or metal and/or metal carbide, obtainable by carbonization of organic or inorganic polymers, the use thereof for the adsorption or separation of gaseous substances, in particular of CO2, and also a method for the production thereof. First, a spinning mixture containing polyacrylonitrile-based polymer A and an organic or metallo-organic polymer B is produced. Next, the spinning mixture is spun to form mixed fibers of polymer A and polymer B. The mixed fiber is stabilized by oxidation. This is followed by carbonization or graphitization of the mixed fiber under non-oxidizing conditions in such a way that the polymer B forms a carbon and/or metal and/or metal carbide residue of at least 22 wt %, the residue forming active centers.
摘要翻译：多孔碳纤维，其活性中心由至少部分由碳和/或金属和/或金属碳化物填充的孔形成，可通过有机或无机聚合物的碳化获得，其用于吸附或分离气态物质，特别是CO 2 2，以及其制备方法。首先，制备含有聚丙烯腈类聚合物A和有机或金属有机聚合物B的纺丝混合物。接下来，将纺丝混合物纺丝以形成聚合物A和聚合物B的混合纤维。混合纤维通过氧化而稳定。接着在非氧化条件下使混合纤维碳化或石墨化，使得聚合物B形成至少22重量％的碳和/或金属和/或金属碳化物残余物，残余物形成活性中心。

18. 发明授权

US06193928B1 Process for manufacturing ceramic metal composite bodies, the ceramic metal composite bodies and their use 失效
标题翻译：制造陶瓷金属复合体的方法，陶瓷金属复合体及其用途
公开(公告)号：US06193928B1
公开(公告)日：2001-02-27
申请号：US09026548
申请日：1998-02-20
申请人： Steffen Rauscher , Michael Scheydecker , Karl Weisskopf , Tanja Tschirge , Rainer Zimmermann-Chopin
发明人： Steffen Rauscher , Michael Scheydecker , Karl Weisskopf , Tanja Tschirge , Rainer Zimmermann-Chopin
IPC分类号： B22F326
CPC分类号： C04B35/58092 , C04B35/56 , C04B35/58 , C04B35/5805 , C04B35/58085 , C04B35/806 , C04B41/88 , C22C1/058
摘要： A process for manufacturing ceramic metal composite bodies, the ceramic metal composite bodies and their use. The process is based on molten infiltration and the simultaneous or delayed exchange reaction of ceramic or metal ceramic un-fired bodies or sintered bodies which may consist of nitrides or carbides as well as metals, with molten metal of additional metals, whereby new nitride, carbide and intermetallic phases are formed which have improved wear and high-temperature characteristics. These ceramic metal composite bodies can be used for tribological applications.
摘要翻译：陶瓷金属复合体的制造方法，陶瓷金属复合体及其用途。该方法基于熔融渗透以及可能由氮化物或碳化物以及金属组成的陶瓷或金属陶瓷烧结体或烧结体同时或延迟的交换反应与附加金属的熔融金属，由此新的氮化物，碳化物并且形成具有改善的耐磨性和高温特性的金属间相。这些陶瓷金属复合体可用于摩擦学应用。

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