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11. 发明授权

US5326742A Recording medium for sublimation type heat-sensitive transfer recording process 失效
标题翻译：用于升华型热敏转印记录工艺的记录介质
公开(公告)号：US5326742A
公开(公告)日：1994-07-05
申请号：US22298
申请日：1993-02-25
申请人： Kenji Kushi , Takayuki Iseki , Tadayuki Fujiwara , Kazuhiko Jufuku , Akifumi Ueda
发明人： Kenji Kushi , Takayuki Iseki , Tadayuki Fujiwara , Kazuhiko Jufuku , Akifumi Ueda
IPC分类号： B41M5/52 , B41M5/035 , B41M5/38
CPC分类号： B41M5/5227 , Y10S428/913 , Y10S428/914 , Y10T428/31786
摘要： A recording medium for sublimation type heat-sensitive transfer recording process is disclosed in which an image receiving layer constituting a resin composition containing a dyeable resin and at least one compound shown in Formula (1) is formed on a substrate surface. This recording medium for sublimation type heat-sensitive transfer recording process has extremely superior light resistance, and the image recorded on this recording medium suffers little fade out or discoloration as a result of exposure to light, so that this recording medium is expected to contribute greatly to the spread of video printers and the like. ##STR1## (In Formula (1), R.sub.1 represents an alkyl group having a number of carbon atoms within a range of 1-20, and A represents a substituted or unsubstituted phenylene group or naphthalene group.)
摘要翻译：公开了一种用于升华型热敏转印记录方法的记录介质，其中在基板表面上形成了构成包含可染树脂和式（1）所示的至少一种化合物的树脂组合物的图像接收层。用于升华型热敏转印记录方法的记录介质具有非常优异的耐光性，并且记录在该记录介质上的图像由于曝光而遭受很少的淡出或变色，从而预期该记录介质有很大的贡献视频打印机等的传播。（1）（式（1）中，R 1表示碳原子数为1〜20的烷基，A表示取代或未取代的亚苯基或萘基。

12. 发明授权

US5322762A Photopolymerizable composition 失效
标题翻译：可光聚合组合物
公开(公告)号：US5322762A
公开(公告)日：1994-06-21
申请号：US45250
申请日：1993-04-13
申请人： Kenji Kushi , Chiho Tokuhara
发明人： Kenji Kushi , Chiho Tokuhara
IPC分类号： C08F2/50 , G03F7/029 , G03F7/105 , C08F20/20 , G03F7/031
CPC分类号： G03F7/029 , G03F7/105 , Y10S430/116 , Y10S430/146 , Y10S430/148
摘要： A highly stable photopolymerizable composition which is highly photosensitive to visible light, which can be hardened using a visible light laser, such as an argon laser, which provides excellent contrast between non-irradiated portions and the substrate under red light, and, moreover, which provides excellent contrast between the portions irradiated by the laser and the portions not irradiated. The photopolymerizable composition consists of 100 parts by weight of a resin which is hardenable under visible light having an irradiation energy mainly consisting of light rays in the 400 nm to 700 nm visible light region; 0.02 to 0.5 parts by weight of at least one dye selected from the group consisting of Victoria Pure Blue, anthraquinone dyes, monoazo dyes, and merocyanine dyes, these dyes having maximum absorption wavelengths from 550 to 700 nm; 0.1 to 5 parts by weight of the leuco dye 4,4'-(phenylmethylene bis[N,N-diethylbenzene amine]; and 0.1 to 5 parts by weight of tribromomethylphenyl sulphone.
摘要翻译：对可见光高度感光的高度稳定的光聚合性组合物，其可以使用诸如氩激光器的可见光激光进行硬化，其在红光下提供非照射部分和基板之间的优异对比度，此外，在由激光照射的部分和未被照射的部分之间提供优异的对比度。可光聚合组合物由100重量份在可见光下可硬化的树脂组成，其具有主要由400nm至700nm可见光区域中的光线组成的照射能量; 0.02至0.5重量份的至少一种选自维多利亚纯蓝，蒽醌染料，单偶氮染料和部花青染料的染料，这些染料的最大吸收波长为550-700nm; 0.1〜5重量份的无色染料4,4' - （苯基亚甲基双[N，N-二乙基苯胺]）和0.1〜5重量份的三溴甲基苯基砜。

13. 发明授权

US4291097A Scratch-resistant, dyeable coating compositions for synthetic resin articles 失效
标题翻译：用于合成树脂制品的耐刮擦可染色涂料组合物
公开(公告)号：US4291097A
公开(公告)日：1981-09-22
申请号：US103625
申请日：1979-12-14
申请人： Kazumasa Kamada , Isao Sasaki , Kenji Kushi
发明人： Kazumasa Kamada , Isao Sasaki , Kenji Kushi
IPC分类号： C08F2/00 , C08F2/48 , C08F20/00 , C08F20/10 , C08F20/20 , C08F20/28 , C08F30/00 , C08F30/02 , C08F220/00 , C08F220/26 , C08F290/00 , C08F299/00 , C09D4/00 , C09D5/00 , C09D171/00 , B05D3/06
CPC分类号： C09D4/00 , Y10T428/31507 , Y10T428/31928
摘要： Coating compositions comprising a polyfunctional monomer of a mono or polypentaerythritol poly(meth)acrylate, a bifunctional (meth)acrylate having specific monomer structure, an additional (meth)acrylate containing not more than 2 (meth)acryloyloxy groups, a phosphoric acid ester and an ethanolamine all blended together in a suitable organic solvent system together with a photosensitizer are disclosed. The compositions provide a scratch-resistant, hard cross-linked film surface that is dyeable and resists static and fogging to a synthetic resin article, such as polymethyl methacrylate, to which they are applied.
摘要翻译：包含单或多季戊四醇聚（甲基）丙烯酸酯，具有特定单体结构的双官能（甲基）丙烯酸酯，另外的（甲基）丙烯酸酯含有不多于2个（甲基）丙烯酰氧基的多官能单体，磷酸酯和公开了在合适的有机溶剂系统中与光敏剂一起共混的乙醇胺。所述组合物提供耐刮擦，硬交联的膜表面，其可染色并且抵抗其所施用的合成树脂制品（例如聚甲基丙烯酸甲酯）的静电和起雾。

14. 发明授权

US4287227A Coating composition and process for producing synthetic resin moldings by using the same 失效
标题翻译：用于制造合成树脂模制品的涂料组合物和方法
公开(公告)号：US4287227A
公开(公告)日：1981-09-01
申请号：US109245
申请日：1980-01-03
申请人： Kazumasa Kamada , Isao Sasaki , Kenji Kushi
发明人： Kazumasa Kamada , Isao Sasaki , Kenji Kushi
IPC分类号： C08F2/00 , C08F2/44 , C08F2/48 , C08F2/50 , C08F20/00 , C08F20/10 , C08F20/26 , C08F220/00 , C08F220/20 , C08F283/00 , C08F290/00 , C08F299/00 , C08F299/02 , C08J3/28 , C08J7/04 , C08K5/5419 , C09D4/00 , C09D4/06 , C09D5/00 , C09D7/12 , C09D171/00 , B05D3/06
CPC分类号： C09D4/00 , C09D4/06 , Y10T428/31507 , Y10T428/31649 , Y10T428/31855
摘要： A coating composition comprising a monomer mixture of mono- or polypentaerythritol hving at least three (meth) acryloyloxy groups and at least one monofunctional acrylate or methacrylate having at least one ether bond in the molecule, a boiling point above 150.degree. C. under normal pressure and a viscosity below 20 centipoises at 20.degree. C., a photosensitizing agent, at least one silicon containing surface active agent and at least one organic solvent capable of forming a uniform solution upon mixing with the vinyl monomer mixture. Also disclosed is a process of coating surfaces with the coating compositions.
摘要翻译：一种涂料组合物，其包含具有至少三个（甲基）丙烯酰氧基的单 - 或多季戊四醇和至少一个在分子中具有至少一个醚键的单官能丙烯酸酯或甲基丙烯酸酯的单体混合物，在常压下高于150℃的沸点 20℃下的粘度低于20厘泊，光敏剂，至少一种含硅表面活性剂和至少一种能够与乙烯基单体混合物混合时形成均匀溶液的有机溶剂。还公开了用涂料组合物涂覆表面的方法。

15. 发明授权

US4689243A Heat-resistant resin molded article with excellent abrasion resistance and process for producing the same 失效
标题翻译：具有优异耐磨性的耐热树脂成型体及其制造方法
公开(公告)号：US4689243A
公开(公告)日：1987-08-25
申请号：US783227
申请日：1985-09-24
申请人： Isao Sasaki , Kozi Nishida , Masaru Morimoto , Kenji Kushi
发明人： Isao Sasaki , Kozi Nishida , Masaru Morimoto , Kenji Kushi
IPC分类号： C08J7/04 , C08L33/24 , C09D4/00 , B05D3/06
CPC分类号： C08L33/24 , C08J7/047 , C09D4/00 , C08J2423/00 , C08J2433/00 , Y10T428/261 , Y10T428/264 , Y10T428/265 , Y10T428/269 , Y10T428/31721 , Y10T428/31928
摘要： A heat-resistant resin molded article excellent in abrasion resistance, surface smoothness, solvent resistance, durability and adhesiveness between base material and cured film, consisting of (1) a resin molded article composed of 2% by weight or more of a structural unit represented by the following structural formula ##STR1## (wherein R is a hydrogen atom, an alkyl group, an aryl group or an alicyclic group of 1 to 20 carbon atoms) and 98% by weight or less of an ethylenic monomer unit and (2) a cured film formed on the surface of said resin molded article by curing a crosslinking-curable resin material containing 30% by weight or more of at least one monomer having three or more (meth)acryloyloxy groups in one molecule, as well as a process for producing said heat-resistant resin molded article.
摘要翻译： PCT No.PCT / JP85 / 00071 Sec。 371日期：1985年9月24日 102（e）1985年9月24日PCT 1985年2月20日PCT PCT。出版物WO85 / 03670 日本1985年8月29日。耐磨性，表面平滑性，耐溶剂性，耐久性和基材与固化膜之间的粘合性优异的耐热性树脂成型体，由（1）由2重量％以下结构式表示的结构单元，其中R为氢原子，烷基，芳基或碳原子数为1〜20的脂环族基），98重量％以下的结构单元乙烯性单体单元和（2）通过将包含30重量％以上的至少一种具有三个以上（甲基）丙烯酰氧基的单体的交联固化性树脂材料固化在一个上形成在所述树脂成型体的表面上的固化膜分子，以及制造所述耐热树脂模塑制品的方法。

16. 发明授权

US4518472A Delustering coating composition excellent in abrasion resistance 失效
标题翻译：具有优异耐磨性的清漆涂料组合物
公开(公告)号：US4518472A
公开(公告)日：1985-05-21
申请号：US525895
申请日：1983-08-24
申请人： Kazuo Kishida , Isao Sasaki , Kenji Kushi , Masahiro Sugimori
发明人： Kazuo Kishida , Isao Sasaki , Kenji Kushi , Masahiro Sugimori
IPC分类号： C08F2/48 , C08F285/00 , C08J7/04 , C09D4/06 , C08F220/00 , C09D3/00
CPC分类号： C08J7/047 , C08F285/00 , C09D4/06 , C08J2333/06 , C08J2433/00
摘要： A coating composition curable by an activation energy ray, which comprises (a) 100 parts by weight of a monomer mixture (A) comprising at least 30% by weight of a compound having at least 3 acryloyloxy and/or methacryloyloxy groups in the molecule and up to 70% by weight of a compound having 1 to 2 .alpha.,.beta.-ethylenically unsaturated bonds in the molecule, (b) 0.01 to 6.0 parts by weight of at least one photosensitizer and (c) 0.5 to 30 parts by weight of an emulsion type crosslinked polymer or copolymer of a reactive monomer having one .alpha.,.beta.-ethylenically unsaturated bond in the molecule and a reactive monomer having at least two .alpha.,.beta.-ethylenically unsaturated bonds in the molecule.
摘要翻译：一种由活化能射线固化的涂料组合物，其包含（a）100重量份的包含至少30重量％的分子中具有至少3个丙烯酰氧基和/或甲基丙烯酰氧基的化合物的单体混合物（A），和至多70重量％的分子中具有1至2个α，β-烯属不饱和键的化合物，（b）0.01至6.0重量份的至少一种光敏剂和（c）0.5至30重量份的分子中具有一个α，β-烯属不饱和键的反应性单体的乳液型交联聚合物或共聚物，以及在分子中具有至少两个α，β-烯属不饱和键的反应性单体。

17. 发明授权

US4418641A Dip-coating apparatus 失效
标题翻译：浸涂装置
公开(公告)号：US4418641A
公开(公告)日：1983-12-06
申请号：US365761
申请日：1982-04-05
申请人： Atushi Nakashima , Michisuke Edamatu , Kenji Kushi
发明人： Atushi Nakashima , Michisuke Edamatu , Kenji Kushi
IPC分类号： B01D19/00 , B05C3/05 , B05D1/18 , B05C3/00
CPC分类号： B05D1/18 , B01D19/0021 , B01D19/0078 , B05C3/05
摘要： A dip-coating method for forming a smooth coated film on the surface of an article by dipping the article in a coating solution while making ultrasonic waves act on the coating solution and forming a uniform liquid flow on the surface of the coating solution. An apparatus for practicing the method is also disclosed.

18. 发明授权

US4367245A Coating composition and process for preparing synthetic resin shaped articles by using same 失效
标题翻译：涂料组合物及其制备方法
公开(公告)号：US4367245A
公开(公告)日：1983-01-04
申请号：US246942
申请日：1981-03-24
申请人： Kazuo Kishida , Isao Sasaki , Kenji Kushi , Misao Tamura
发明人： Kazuo Kishida , Isao Sasaki , Kenji Kushi , Misao Tamura
IPC分类号： C08F20/00 , B05D3/06 , B05D7/02 , C08F2/48 , C08F20/10 , C08F20/26 , C08F22/10 , C08F220/28 , C08F290/00 , C08F299/02 , C08J7/04 , C09D4/00 , C09D133/04
CPC分类号： C08F22/105 , C09D4/00
摘要： A coating composition for the preparation of synthetic resin shaped articles excellent in abrasion resistance and weatherability is described. This composition comprises (a) a polyfunctional monomer mixture comprising (i) 25-75 wt. % of at least one polyfunctional monomer of the formula (I): ##STR1## wherein at least three of X.sub.11, X.sub.12, X.sub.13, X.sub.22, X.sub.23 -X.sub.n2, X.sub.n3 and X.sub.14 are CH.sub.2 .dbd.CH.C00-- and the remaining groups are --OH, and n is an integer of 1-5, (ii) 25-75 wt. % of at least one polyfunctional monomer of the formula (II): ##STR2## wherein at least three of the R groups are CH.sub.2 .dbd.CH COO-- and each of the remaining is H or --OH, n.sub.1, n.sub.2, n.sub.3, n.sub.4, m.sub.1, m.sub.2, m.sub.3 and m.sub.4 are integers of 0, 1 or 2, and X is an integer of 1 to 10 and (iii) 0 to 50 wt. % of a monomer containing one acryloyloxy group and having a boiling point of at least 150.degree. C. at normal pressure and a viscosity of not higher than 20 cps/20.degree. C., and (b) 0.01-6.0 wt. parts, based on 100 wt. parts of the polyfunctional monomer mixture, of at least one photosensitizer. The coating composition is coated on a synthetic resin shaped article and then, irradiated with utraviolet rays in air to form a crosslinked coating film having a thickness of 1-30 microns.
摘要翻译：描述了用于制备耐磨性和耐候性优异的合成树脂成型制品的涂料组合物。该组合物包含（a）多官能单体混合物，其包含（i）25-75wt。％的至少一种式（I）的多官能单体：其中X11，X12，X13，X22，X23-Xn2，Xn3和X14中的至少三个是CH2 = CH。 C00-，其余基团为-OH，n为1-5的整数，（ii）25-75wt。％的至少一种式（II）的多官能单体：其中至少三个R基团是CH 2 = CH COO-，并且其中每一个是H或-OH， n1，n2，n3，n4，m1，m2，m3和m4为0,1或2的整数，X为1〜10的整数，（iii）0〜50重量％％的含有1个丙烯酰氧基的单体，沸点在常压下为至少150℃，粘度不高于20cps / 20℃，（b）0.01-6.0wt。基于100wt。部分多官能单体混合物，至少一种光敏剂。将涂料组合物涂布在合成树脂成型制品上，然后在空气中用紫外线照射，形成厚度为1-30微米的交联涂膜。

19. 发明授权

US5218019A Sublimation disperson dye receptive resin compositions 失效
标题翻译：升华分散染料接受树脂组合物
公开(公告)号：US5218019A
公开(公告)日：1993-06-08
申请号：US895443
申请日：1992-06-08
申请人： Kenji Kushi , Tadayuki Fujiwara
发明人： Kenji Kushi , Tadayuki Fujiwara
IPC分类号： B41M5/52
CPC分类号： B41M5/529
摘要： A sublimation dispersion dye receptive resin composition which comprises a polyester resin, a cross- linking agent obtained by curing by activating energy, and a releasing agent which can effect the cross-linked construction of at least one selected from the group of silicon functional groups and functional groups containing fluorine. This resin composition is especially applicable to image-receiving paper or image-receiving film for sublimation-type thermal dye transfer methods; it has superior anti-blocking and heat-resistant characteristics. Furthermore, by means of the addition of benzotriazol ultraviolet stabilizer or hindered amine photostabilizer, the fading characteristics are improved.
摘要翻译：升华分散染料接受树脂组合物，其包含聚酯树脂，通过活化能量固化获得的交联剂和可以实现选自硅官能团中的至少一种的交联结构的脱模剂和含氟的官能团。该树脂组合物特别适用于用于升华型热染料转印方法的图像接收纸或图像接收膜; 它具有优异的防粘连和耐热特性。此外，通过加入苯并三唑紫外线稳定剂或受阻胺光稳定剂，可以提高褪色特性。

20. 发明授权

US4877922A Composition easily dyeable with sublimable desperse dye 失效
标题翻译：组合物易于染色，具有可升华的分散染料
公开(公告)号：US4877922A
公开(公告)日：1989-10-31
申请号：US330936
申请日：1989-03-27
申请人： Isao Sasaki , Kenji Kushi , Nobuyoshi Taguchi
发明人： Isao Sasaki , Kenji Kushi , Nobuyoshi Taguchi
IPC分类号： B41M5/382 , B41M5/00 , B41M5/50 , B41M5/52 , C08F299/04 , C08L67/00 , C08L67/06
CPC分类号： B41M5/52 , C08F299/0428 , C08L67/00 , B41M5/5209 , B41M5/5227 , B41M5/5272 , B41M5/529 , Y10S528/901 , Y10T428/29 , Y10T428/31786
摘要： Disclosed is an easily-dyeable resin composition used in a sublimation type heat-sensitive transfer process. The composition comprises 100 parts by weight of a mixture composed of 40 to 95% by weight of a polyester resin and 5 to 60% of a crosslinking agent curable with active energy rays, and 0.01 to 12 parts by weight of a surface active agent selected from silicon-containing surface active agents and fluorine-containing surface active agents.
摘要翻译：公开了一种用于升华型热敏转印方法中的易染色树脂组合物。该组合物包含100重量份由40至95重量％的聚酯树脂和5至60％的可活化能量射线固化的交联剂组成的混合物和0.01至12重量份的选自下列的表面活性剂来自含硅表面活性剂和含氟表面活性剂。

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