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    • 11. 发明申请
    • Rinsing Liquid for Lithography and Method for Resist Pattern Formation
    • 用于光刻的冲洗液和抗蚀剂图案形成方法
    • US20080193876A1
    • 2008-08-14
    • US11661426
    • 2005-08-29
    • Yoshihiro SawadaKazumasa WakiyaJun KoshiyamaAtsushi MiyamotoHidekazu Tajima
    • Yoshihiro SawadaKazumasa WakiyaJun KoshiyamaAtsushi MiyamotoHidekazu Tajima
    • G03F7/004G03F7/30
    • H01L21/0273G03F7/32
    • This invention provides a novel rinsing liquid for lithography, which, for a photoresist pattern, can reduce surface defects, the so-called defects, without sacrificing the quality of the product, and, at the same time, can impart resistance to electron beam irradiation to suppress the shrinkage of the resist pattern, and a method for resist pattern formation using the same. A resist pattern is formed by preparing a rinsing liquid for lithography comprising an aqueous solution containing (A) a water-soluble and/or alkali-soluble polymer having a nitrogen atom in its molecular structure and (B) at least one member selected from aliphatic alcohols and alkyletherification products thereof, and then carrying out (1) the step of providing a photoresist film on a substrate, (2) the step of selectively exposing the photoresist film thorough a mask pattern, (3) the step of heat-treating the exposed photoresist film, (4) the step of carrying out alkali development, and (5) the step of treating the developed film with the rinsing liquid for lithography.
    • 本发明提供了一种新颖的光刻冲洗液,其中光致抗蚀剂图案可以减少表面缺陷,即所谓的缺陷,而不会牺牲产品的质量,并且同时可赋予电子束照射 以抑制抗蚀剂图案的收缩,以及使用其的抗蚀剂图案形成方法。 通过制备用于光刻的冲洗液,通过制备含有(A)在其分子结构中具有氮原子的水溶性和/或碱溶性聚合物的水溶液形成抗蚀剂图案,(B)至少一种选自脂肪族 醇和烷基醚化产物,然后进行(1)在基板上提供光致抗蚀剂膜的步骤,(2)通过掩模图案选择性地曝光光致抗蚀剂膜的步骤,(3)热处理 暴露的光致抗蚀剂膜,(4)进行碱显影的步骤,(5)用用于光刻的冲洗液处理显影膜的步骤。
    • 15. 发明授权
    • Cleaning liquid for lithography and a cleaning method using it for photoexposure devices
    • 用于光刻的清洁液和使用其进行曝光装置的清洁方法
    • US08058220B2
    • 2011-11-15
    • US12801529
    • 2010-06-14
    • Jun KoshiyamaYoshihiro SawadaJiro YokoyaTomoyuki Hirano
    • Jun KoshiyamaYoshihiro SawadaJiro YokoyaTomoyuki Hirano
    • C11D7/50
    • C11D3/43C11D1/66C11D1/667C11D1/72C11D3/18C11D3/181C11D3/182C11D3/184C11D3/188G03F7/2041G03F7/70341G03F7/70925G03F7/70983
    • Problem: To provide a cleaning liquid for lithography and a cleaning method using it for photoexposure devices. In a process of liquid immersion lithography, the cleaning liquid may efficiently clean the photoexposure device site (especially optical lens member) contaminated with the component released from photoresist and remove the contaminant, and in addition, the waste treatment for the cleaning liquid is easy, the efficiency in substitution with the cleaning liquid for the medium for liquid immersion lithography is high, and the cleaning liquid does not detract from the throughput in semiconductor production.Means for Solution: A cleaning liquid for photolithography to be used for cleaning a photoexposure device in a process of liquid immersion lithography that comprises filling the space between the optical lens member of a photoexposure device and an object for photoexposure mounted on the wafer stage, with a medium for liquid immersion lithography, the cleaning liquid comprising (a) a surfactant, (b) a hydrocarbon solvent, and (c) water; and a cleaning method using it for photoexposure devices.
    • 问题:提供用于光刻的清洗液和使用其进行曝光的清洁装置。 在液浸式光刻工序中,清洗液可以有效地清除被光致抗蚀剂除去的成分所污染的光曝光装置部位(特别是光学透镜部件),除去污染物,另外清洗液的废弃处理容易, 用于液浸光刻介质的清洁液的替代效率高,并且清洁液体不会降低半导体生产中的生产量。 解决方案:一种用于在液浸光刻工艺中用于清洁曝光装置的光刻用清洁液体,其包括填充曝光装置的光学透镜部件和安装在晶片台上的光曝光对象之间的空间,用 用于液浸光刻的介质,所述清洗液包含(a)表面活性剂,(b)烃溶剂和(c)水; 以及将其用于曝光装置的清洁方法。