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    • 13. 发明授权
    • Process of preparing high chloride {100} tabular grain emulsions
    • 制备高氯化物{100}片状颗粒乳剂的方法
    • US5879874A
    • 1999-03-09
    • US961962
    • 1997-10-31
    • Joe E. MaskaskyVictor P. ScacciaSamuel Chen
    • Joe E. MaskaskyVictor P. ScacciaSamuel Chen
    • G03C1/015G03C1/005G03C1/035
    • G03C1/0053
    • A process is disclosed for preparing high chloride {100} tabular grain emulsions containing crystal lattice dislocations in peripheral regions of the tabular grains. In the initial step of the process a radiation-sensitive high chloride {100} tabular grain emulsion is produced to provide host grains. Lateral growth lateral growth of the {100} major surfaces of the tabular grains is extended by precipitating a high chloride peripheral region onto the host tabular grains. After the host grains have been provided an iodide ion source compound with a maximum second order reaction rate constant within the dispersing medium of less than 1.times.10.sup.3 mole.sup.-1 sec.sup.-1 is introduced into the host emulsion to release iodide ions for incorporation into the tabular grains at their peripheral edges by chloride ion displacement. In the resulting emulsion 10 or more crystal lattice dislocations extending inwardly from the peripheral edges of the {100} tabular grains are observed. The dislocations in the peripheral and, particularly, corner regions of the tabular grains increase their sensitivity.
    • 公开了一种用于制备在片状颗粒的周边区域中含有晶格位错的高氯化物{100}片状颗粒乳剂的方法。 在该方法的初始步骤中,产生辐射敏感的高氯酸盐{100}片状颗粒乳剂以提供主体颗粒。 片状颗粒的{100}主表面的横向生长横向生长通过将高氯化物周边区域沉淀到主体平片状晶粒上而延长。 在提供主体颗粒之后,将在分散介质中具有小于1×10 3摩尔-1秒-1的最大二级反应速率常数的碘离子源化合物引入主体乳液中以释放碘离子以掺入片状颗粒 在其外围边缘被氯离子置换。 在所得到的乳液中观察到从{100}片状颗粒的周缘向内延伸的10个或更多个晶格位错。 周边的,特别是片状晶粒的角落区域中的位错增加了它们的灵敏度。
    • 14. 发明授权
    • Process for the preparation of a grain stabilized high chloride tabular
grain photographic emulsion (III)
    • 用于制备颗粒稳定的高氯化物片状颗粒照相乳剂(III)的方法
    • US5298388A
    • 1994-03-29
    • US935806
    • 1992-08-27
    • Joe E. Maskasky
    • Joe E. Maskasky
    • G03C1/015G03C1/005G03C1/035G03C1/18G03C1/07G03C1/12
    • G03C1/0053G03C1/015G03C1/07G03C1/12G03C1/18G03C2200/03
    • A process is disclosed of preparing an emulsion for photographic use comprised of silver halide grains and a gelatino-peptizer dispersing medium in which morphologically unstable tabular grains having {111} major faces account for greater than 50 percent of total grain projected area and contain at least 50 mole percent chloride, based on silver. The emulsion additionally contains at least one 2-hydroaminoazine adsorbed to and morphologically stabilizing the tabular grains. Protonation releases 2-hydroaminoazine from the tabular grain surfaces into the dispersing medium. Released 2-hydroaminoazine is replaced on the tabular grain surfaces by adsorption of a photographically useful benzimidazolium dye, thereby concurrently morphologically stabilizing the tabular grains and enhancing their photographic utility, and the released 2-hydroaminoazine is removed from the dispersing medium.
    • 公开了一种制备用于照相用途的乳液,其包括卤化银颗粒和明胶胶溶剂分散介质,其中具有(111)主面的形态不稳定的片状颗粒占总颗粒投影面积的大于50%,并且至少含有 基于银的50摩尔%氯化物。 该乳液还含有至少一种吸附并形成稳定片状颗粒的2-氨基亚氨基。 质子离子将2-氨基丙嗪从片状颗粒表面释放到分散介质中。 通过吸附摄影有用的苯并咪唑鎓染料,在片状颗粒表面上释放出的2-氨基丙嗪被同时形态地稳定片状颗粒并提高其照相效用,从分散介质中除去释放的2-氨基丙嗪。
    • 18. 发明授权
    • Photoconductive material imaging element
    • 光导材料成像元件
    • US06753121B2
    • 2004-06-22
    • US10295510
    • 2002-11-15
    • Lillian M. KelloggJoe E. MaskaskyDale E. Hamilton
    • Lillian M. KelloggJoe E. MaskaskyDale E. Hamilton
    • G03C1035
    • G03C1/08G03C1/0051G03C7/30Y10S430/141
    • A photoconductive material imaging element is described comprising a support and a silver halide emulsion imaging layer comprising silver halide grains which have not been chemically sensitized to optimize formation of latent image Agno, centers upon imagewise exposure and which are doped with at least 500 deep electron trapping agent dopant centers per grain. In accordance with a preferred embodiment, the photoconductive material imaging element includes a planar support and the non-chemically sensitized, deep electron trapping agent doped silver halide grains comprise tabular grains, preferably with an average grain size equivalent circular diameter of greater than 2 &mgr;m, with the long dimensions of the tabular grains primarily oriented parallel to the plane of the support.
    • 描述了一种光电导材料成像元件,其包括载体和卤化银乳剂成像层,其包含尚未化学增感以卤化银颗粒以优化潜像Agn的形成,成像曝光为中心,并且掺杂有至少500 深度电子捕获剂掺杂剂中心每颗粒。 根据优选实施例,光电导材料成像元件包括平面支撑体,掺杂的卤化银颗粒的非化学敏化的深电子捕获剂包括片状颗粒,优选具有大于2μm的平均粒径当量圆直径, 其中片状颗粒的长尺寸主要取向为平行于支撑体的平面。