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11. 发明申请

US20120082892A1 LITHIUM SECONDARY BATTERY 审中-公开
标题翻译：锂二次电池
公开(公告)号：US20120082892A1
公开(公告)日：2012-04-05
申请号：US13242514
申请日：2011-09-23
申请人： Kei Kobayashi , Atsushi Fukui , Taizou Sunano , Maruo Kamino
发明人： Kei Kobayashi , Atsushi Fukui , Taizou Sunano , Maruo Kamino
IPC分类号： H01M10/052
CPC分类号： H01M4/661 , H01M4/0404 , H01M4/0435 , H01M4/134 , H01M4/1395 , H01M4/662 , H01M4/667 , H01M10/052 , H01M2004/027
摘要： A lithium secondary battery has a positive electrode, a separator, and a negative electrode having a negative electrode current collector and a negative electrode mixture layer formed on a surface of the negative electrode current collector. The negative electrode mixture layer contains a negative electrode active material including a metal element capable of alloying with lithium. The negative electrode current collector includes a substrate made of a Cu—Fe—P alloy foil, and a surface layer provided on both surfaces of the substrate and made of pure copper. The surface layer has a Vickers hardness of 120 and less than that of the substrate. The negative electrode current collector has a proof stress of 308 MPa.
摘要翻译：锂二次电池具有在负极集电体的表面上形成有负极集电体和负极混合层的正极，隔膜和负极。负极合剂层含有负极活性物质，其包含能够与锂合金化的金属元素。负极集电体包括由Cu-Fe-P合金箔制成的基板和设置在基板的两面上并由纯铜制成的表面层。表面层的维氏硬度为120以下，小于基材的维氏硬度。负极集电体的抗张强度为308MPa。

12. 发明授权

US07682744B2 Lithium secondary battery 有权
标题翻译：锂二次电池
公开(公告)号：US07682744B2
公开(公告)日：2010-03-23
申请号：US11231982
申请日：2005-09-22
申请人： Shouichirou Sawa , Hiroshi Minami , Atsushi Fukui , Taizou Sunano , Takuya Sunagawa , Maruo Kamino , Toshio Yanagida
发明人： Shouichirou Sawa , Hiroshi Minami , Atsushi Fukui , Taizou Sunano , Takuya Sunagawa , Maruo Kamino , Toshio Yanagida
IPC分类号： H01M4/00 , H01M4/58 , H01M4/50 , H01M6/04
CPC分类号： C01G51/42 , C01G45/1228 , C01G51/50 , C01G53/42 , C01G53/50 , C01P2002/52 , C01P2002/54 , C01P2004/61 , C01P2006/12 , C01P2006/40 , H01M4/0404 , H01M4/386 , H01M4/485 , H01M4/505 , H01M4/525 , H01M10/052 , H01M2004/021
摘要： A lithium secondary battery having high capacity and good charge-discharge cycle performance is provided. The lithium secondary battery includes a negative electrode (2) containing silicon as a negative electrode active material, a positive electrode (1) containing a positive electrode active material, and a non-aqueous electrolyte. The positive electrode active material is a lithium-transition metal composite oxide including a layered structure represented by the chemical formula LiaNixMnyCozO2, where a, x, y, and z satisfy the expressions: 0≦a≦1.3, x+y+z=1, 0
摘要翻译：提供具有高容量和良好的充放电循环性能的锂二次电池。锂二次电池包括含有硅作为负极活性物质的负极（2），含有正极活性物质的正极（1）和非水电解质。正极活性物质是包含由化学式LiaNixMnyCozO2表示的层状结构的锂 - 过渡金属复合氧化物，其中a，x，y和z满足以下表达式：0＆nlE; a＆nlE; 1.3，x + y + z = 1 ，0

13. 发明申请

US20060204846A1 Lithium secondary battery 审中-公开
标题翻译：锂二次电池
公开(公告)号：US20060204846A1
公开(公告)日：2006-09-14
申请号：US11372219
申请日：2006-03-10
申请人： Takuya Sunagawa , Atsushi Fukui , Taizou Sunano , Hiroshi Minami , Shouichirou Sawa , Maruo Kamino , Toshihiko Saito
发明人： Takuya Sunagawa , Atsushi Fukui , Taizou Sunano , Hiroshi Minami , Shouichirou Sawa , Maruo Kamino , Toshihiko Saito
IPC分类号： H01M4/58 , H01M4/48
CPC分类号： H01M10/052 , H01M2/0257 , H01M2/0275 , H01M4/02 , H01M4/131 , H01M4/134 , H01M4/1395 , H01M4/386 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/58 , H01M10/0567 , H01M10/0587 , H01M2004/021 , Y02T10/7011
摘要： A lithium secondary battery is provided capable of significantly improving charge-discharge cycle performance by preventing gas generation originating from decomposition of the non-aqueous electrolyte while preventing manufacturing cost from increasing. A lithium secondary battery is provided with: a power generating element accommodated in a flexible battery case (6), the power generating element including a negative electrode (2), a positive electrode (1), and a non-aqueous electrolyte. The negative electrode contains negative electrode active material particles composed of silicon and/or a silicon alloy. The positive electrode contains a positive electrode active material composed of a lithium-transition metal composite oxide. The non-aqueous electrolyte contains ions of at least one element selected from the group consisting of Co, Cu, Mg, Mn, Ni, Fe, and Zr.
摘要翻译：提供了一种锂二次电池，其能够通过防止来自非水电解质分解的气体产生而显着提高充放电循环性能，同时防止制造成本增加。锂二次电池设置有容纳在柔性电池壳体（6）中的发电元件，发电元件包括负极（2），正极（1）和非水电解质。负极含有由硅和/或硅合金构成的负极活性物质粒子。正极含有由锂过渡金属复合氧化物构成的正极活性物质。非水电解质含有选自Co，Cu，Mg，Mn，Ni，Fe和Zr中的至少一种元素的离子。

14. 发明授权

US09153841B2 Non-aqueous electrolyte secondary battery, and non-aqueous electrolyte solution for non-aqueous electrolyte secondary battery 有权
标题翻译：非水电解质二次电池，非水电解质二次电池用非水电解液
公开(公告)号：US09153841B2
公开(公告)日：2015-10-06
申请号：US13639396
申请日：2011-04-28
申请人： Hidekazu Yamamoto , Kouhei Tuduki , Taizou Sunano , Maruo Kamino , Youichi Ohashi , Minoru Kotato
发明人： Hidekazu Yamamoto , Kouhei Tuduki , Taizou Sunano , Maruo Kamino , Youichi Ohashi , Minoru Kotato
IPC分类号： H01M6/16 , H01M10/0567 , H01M10/0525 , H01M10/0569 , H01M4/1393 , H01M4/133 , H01M4/1395 , H01M4/134
CPC分类号： H01M10/0567 , H01M4/133 , H01M4/134 , H01M4/1393 , H01M4/1395 , H01M10/0525 , H01M10/0569 , H01M2300/0034 , Y02E60/122
摘要： Provided is a nonaqueous electrolyte secondary battery which, even in the case of using a low-viscosity solvent having a narrow potential window, can increase the electrochemical stability of the nonaqueous electrolyte solution and suppress side reactions of the nonaqueous electrolyte solution during charge and discharge to reduce the degradation of the battery characteristics and has an excellent storage characteristic in high-temperature environments and a nonaqueous electrolyte solution for the nonaqueous electrolyte secondary battery. The nonaqueous electrolyte secondary battery includes: a positive electrode containing a positive-electrode active material; a negative electrode containing a negative-electrode active material; and a nonaqueous electrolyte solution containing a solute dissolved in a nonaqueous solvent, wherein the nonaqueous electrolyte solution further contains benzotrifluoride and a diisocyanate compound and the content of benzotrifluoride is 5% by volume or more in the nonaqueous electrolyte solution except the solute.
摘要翻译：提供一种非水电解质二次电池，即使在使用具有窄势窗的低粘度溶剂的情况下，也能够提高非水电解液的电化学稳定性，抑制非水电解液在充放电期间的副反应降低电池特性的劣化，并且在高温环境中具有优异的储存特性和用于非水电解质二次电池的非水电解质溶液。非水电解质二次电池包括：含有正极活性物质的正极; 含有负极活性物质的负极; 以及含有溶解在非水溶剂中的溶质的非水电解液，其中所述非水电解质溶液还含有苯并三氟化物和二异氰酸酯化合物，并且所述非水电解质溶液中除所述溶质以外，所述三氟甲苯的含量为5体积％以上。

15. 发明授权

US08927158B2 Nonaqueous electrolyte secondary battery and nonaqueous electrolytic solution for nonaqueous electrolyte secondary battery 有权
标题翻译：非水电解质二次电池和非水电解质二次电池用非水电解液
公开(公告)号：US08927158B2
公开(公告)日：2015-01-06
申请号：US13103232
申请日：2011-05-09
申请人： Hidekazu Yamamoto , Kouhei Tuduki , Taizou Sunano , Maruo Kamino , Youichi Ohashi , Minoru Kotato
发明人： Hidekazu Yamamoto , Kouhei Tuduki , Taizou Sunano , Maruo Kamino , Youichi Ohashi , Minoru Kotato
IPC分类号： H01M6/18 , H01M4/134 , H01M10/0567 , H01M10/0568 , H01M10/0569
CPC分类号： H01M4/134 , H01M10/0567 , H01M10/0568 , H01M10/0569 , Y02E60/122
摘要： A nonaqueous electrolyte secondary battery includes a positive electrode having a positive-electrode active material, a negative electrode having a negative-electrode active material, and a nonaqueous electrolytic solution having a nonaqueous solvent dissolving a solute. The negative-electrode active material includes powdered silicon and/or a silicon alloy, the nonaqueous electrolytic solution includes additives composed of at least one fluorinated lithium phosphate selected from the group consisting of lithium monofluorophosphate, lithium difluorophosphate, and lithium trifluorophosphate and a diisocyanate compound, and the nonaqueous solvent includes a chain carbonate compound.
摘要翻译：非水电解质二次电池包括具有正极活性物质的正极，具有负极活性物质的负极和具有溶解溶质的非水溶剂的非水电解液。负极活性物质包括硅粉和/或硅合金，该非水电解液包括由至少一种选自单氟磷酸锂，二氟磷酸锂和三氟磷酸锂的氟化锂磷酸盐和二异氰酸酯化合物组成的添加剂，非水溶剂包括链状碳酸酯化合物。

16. 发明申请

US20110274986A1 NONAQUEOUS ELECTROLYTE SECONDARY BATTERY AND NONAQUEOUS ELECTROLYTIC SOLUTION FOR NONAQUEOUS ELECTROLYTE SECONDARY BATTERY 有权
标题翻译：非电解电解质二次电池非电解二次电池和非电解电解质
公开(公告)号：US20110274986A1
公开(公告)日：2011-11-10
申请号：US13103232
申请日：2011-05-09
申请人： Hidekazu Yamamoto , Kouhei Tuduki , Taizou Sunano , Maruo Kamino , Youichi Ohashi , Minoru Kotato
发明人： Hidekazu Yamamoto , Kouhei Tuduki , Taizou Sunano , Maruo Kamino , Youichi Ohashi , Minoru Kotato
IPC分类号： H01M10/0564
CPC分类号： H01M4/134 , H01M10/0567 , H01M10/0568 , H01M10/0569 , Y02E60/122
摘要： A nonaqueous electrolyte secondary battery includes a positive electrode having a positive-electrode active material, a negative electrode having a negative-electrode active material, and a nonaqueous electrolytic solution having a nonaqueous solvent dissolving a solute. The negative-electrode active material includes powdered silicon and/or a silicon alloy, the nonaqueous electrolytic solution includes additives composed of at least one fluorinated lithium phosphate selected from the group consisting of lithium monofluorophosphate, lithium difluorophosphate, and lithium trifluorophosphate and a diisocyanate compound, and the nonaqueous solvent includes a chain carbonate compound.
摘要翻译：非水电解质二次电池包括具有正极活性物质的正极，具有负极活性物质的负极和具有溶解溶质的非水溶剂的非水电解液。负极活性物质包括硅粉和/或硅合金，该非水电解液包括由至少一种选自单氟磷酸锂，二氟磷酸锂和三氟磷酸锂的氟化锂磷酸盐和二异氰酸酯化合物组成的添加剂，非水溶剂包括链状碳酸酯化合物。

17. 发明申请

US20110217577A1 LITHIUM SECONDARY BATTERY 审中-公开
标题翻译：锂二次电池
公开(公告)号：US20110217577A1
公开(公告)日：2011-09-08
申请号：US13040707
申请日：2011-03-04
申请人： Atsushi Fukui , Taizou Sunano , Maruo Kamino
发明人： Atsushi Fukui , Taizou Sunano , Maruo Kamino
IPC分类号： H01M4/02 , H01M4/38 , H01M2/02
CPC分类号： H01M10/052 , H01M10/0431
摘要： A lithium secondary battery comprises an electrode assembly and a non-aqueous electrolyte. The electrode assembly is made by winding a negative electrode, a positive electrode, and a separator interposed between the negative and positive electrodes. The negative electrode contains a negative electrode active material that is alloyed with lithium. The non-aqueous electrolyte is impregnated in the electrode assembly. At least one of the negative and positive electrodes is divided into a plurality of electrode units which are arranged at spaces for each other along the winding direction.
摘要翻译：锂二次电池包括电极组件和非水电解质。电极组件通过卷绕负极和正极之间的负极和隔膜来制造。负极含有与锂合金化的负极活性物质。非水电解质浸渍在电极组件中。负电极和正极中的至少一个被分成沿着卷绕方向彼此间隔设置的多个电极单元。

18. 发明申请

US20060068290A1 Lithium secondary battery 有权
标题翻译：锂二次电池
公开(公告)号：US20060068290A1
公开(公告)日：2006-03-30
申请号：US11231982
申请日：2005-09-22
申请人： Shouichirou Sawa , Hiroshi Minami , Atsushi Fukui , Taizou Sunano , Takuya Sunagawa , Maruo Kamino , Toshio Yanagida
发明人： Shouichirou Sawa , Hiroshi Minami , Atsushi Fukui , Taizou Sunano , Takuya Sunagawa , Maruo Kamino , Toshio Yanagida
IPC分类号： H01M4/52 , H01M4/50 , H01M4/58
CPC分类号： C01G51/42 , C01G45/1228 , C01G51/50 , C01G53/42 , C01G53/50 , C01P2002/52 , C01P2002/54 , C01P2004/61 , C01P2006/12 , C01P2006/40 , H01M4/0404 , H01M4/386 , H01M4/485 , H01M4/505 , H01M4/525 , H01M10/052 , H01M2004/021
摘要： A lithium secondary battery having high capacity and good charge-discharge cycle performance is provided. The lithium secondary battery includes a negative electrode (2) containing silicon as a negative electrode active material, a positive electrode (1) containing a positive electrode active material, and a non-aqueous electrolyte. The positive electrode active material is a lithium-transition metal composite oxide including a layered structure represented by the chemical formula LiaNixMnyCOzO2, where a, x, y, and z satisfy the expressions: 0≦a≦1.3, x+y+z=1, 0
摘要翻译：提供具有高容量和良好的充放电循环性能的锂二次电池。锂二次电池包括含有硅作为负极活性物质的负极（2），含有正极活性物质的正极（1）和非水电解质。正极活性物质是包含由化学式为Li x Mn x Mn y CO的化学式表示的层状结构的锂 - 过渡金属复合氧化物其中a，x，y和z满足以下表达式：0 <= a <= 1.3，x + y + z = 1,0

19. 发明申请

US20090081556A1 NON-AQUEOUS ELECTROLYTE SECONDARY BATTERY 审中-公开
标题翻译：非水电解质二次电池
公开(公告)号：US20090081556A1
公开(公告)日：2009-03-26
申请号：US12236715
申请日：2008-09-24
申请人： Hidekazu Yamamoto , Taizou Sunano , Maruo Kamino
发明人： Hidekazu Yamamoto , Taizou Sunano , Maruo Kamino
IPC分类号： H01M10/26
CPC分类号： H01M10/0569 , H01M4/38 , H01M4/386 , H01M4/387 , H01M4/405 , H01M6/164 , H01M10/052 , H01M10/0587 , H01M2300/0034 , H01M2300/0037
摘要： A non-aqueous electrolyte secondary battery includes a positive electrode, a negative electrode, a separator interposed between the positive electrode and the negative electrode and a non-aqueous electrolyte. The negative electrode comprises a negative electrode active material to be alloyed with lithium and the non-aqueous electrolyte comprises a non-aqueous solvent containing fluorinated cyclic carbonate and propyl acetate.
摘要翻译：非水电解质二次电池包括正极，负极，介于正极和负极之间的隔膜和非水电解质。负极包括与锂合金化的负极活性物质，非水电解质包含含氟化环状碳酸酯和乙酸丙酯的非水溶剂。

20. 发明授权

US08101295B2 Lithium secondary battery 失效
标题翻译：锂二次电池
公开(公告)号：US08101295B2
公开(公告)日：2012-01-24
申请号：US12056559
申请日：2008-03-27
申请人： Shouichiro Sawa , Taizou Sunano , Maruo Kamino
发明人： Shouichiro Sawa , Taizou Sunano , Maruo Kamino
IPC分类号： H01M6/10 , H01M2/02 , H01M2/18
CPC分类号： H01M10/0587 , H01M4/0404 , H01M4/0435 , H01M4/131 , H01M4/133 , H01M4/1391 , H01M4/1393 , H01M4/622 , H01M4/625 , H01M4/661 , H01M10/0431 , H01M10/052 , H01M10/0525 , Y02T10/7011
摘要： A lithium secondary battery has a wound electrode assembly (5). The wound electrode assembly (5) has a negative electrode (2) having a negative electrode active material layer containing a negative electrode active material capable of alloying with lithium and having a filling density of 2.0 g/cc or less, a positive electrode (1) having a positive electrode active material layer containing a positive electrode active material made of a transition metal composite oxide, a separator (3) disposed between the positive and negative electrodes and having a penetration resistance of 500 g or greater, and a cylindrical hollow space (14) at a winding axis and in the vicinity thereof, wherein the positive electrode (1), the negative electrode (2), and the separator (3) are spirally wound. A columnar center pin (15) having a diameter of from 75% to 95% of the diameter of the hollow space is disposed in the hollow space.
摘要翻译：锂二次电池具有卷绕电极组件（5）。卷绕电极组件（5）具有负极（2），其具有负极活性物质层，负极活性物质层含有与锂合金化的负极活性物质，填充密度为2.0g / cc以下，正极（1 ），其具有含有由过渡金属复合氧化物构成的正极活性物质的正极活性物质层，设置在正极和负极之间并具有500g以上的耐渗透性的隔膜（3）和圆筒状中空空间（14）在卷绕轴及其附近，其中正极（1），负极（2）和隔板（3）螺旋卷绕。具有中空空间直径的75％至95％直径的柱状中心销（15）设置在中空空间中。

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