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1. 发明申请

US20060204846A1 Lithium secondary battery 审中-公开
标题翻译：锂二次电池
公开(公告)号：US20060204846A1
公开(公告)日：2006-09-14
申请号：US11372219
申请日：2006-03-10
申请人： Takuya Sunagawa , Atsushi Fukui , Taizou Sunano , Hiroshi Minami , Shouichirou Sawa , Maruo Kamino , Toshihiko Saito
发明人： Takuya Sunagawa , Atsushi Fukui , Taizou Sunano , Hiroshi Minami , Shouichirou Sawa , Maruo Kamino , Toshihiko Saito
IPC分类号： H01M4/58 , H01M4/48
CPC分类号： H01M10/052 , H01M2/0257 , H01M2/0275 , H01M4/02 , H01M4/131 , H01M4/134 , H01M4/1395 , H01M4/386 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/58 , H01M10/0567 , H01M10/0587 , H01M2004/021 , Y02T10/7011
摘要： A lithium secondary battery is provided capable of significantly improving charge-discharge cycle performance by preventing gas generation originating from decomposition of the non-aqueous electrolyte while preventing manufacturing cost from increasing. A lithium secondary battery is provided with: a power generating element accommodated in a flexible battery case (6), the power generating element including a negative electrode (2), a positive electrode (1), and a non-aqueous electrolyte. The negative electrode contains negative electrode active material particles composed of silicon and/or a silicon alloy. The positive electrode contains a positive electrode active material composed of a lithium-transition metal composite oxide. The non-aqueous electrolyte contains ions of at least one element selected from the group consisting of Co, Cu, Mg, Mn, Ni, Fe, and Zr.
摘要翻译：提供了一种锂二次电池，其能够通过防止来自非水电解质分解的气体产生而显着提高充放电循环性能，同时防止制造成本增加。锂二次电池设置有容纳在柔性电池壳体（6）中的发电元件，发电元件包括负极（2），正极（1）和非水电解质。负极含有由硅和/或硅合金构成的负极活性物质粒子。正极含有由锂过渡金属复合氧化物构成的正极活性物质。非水电解质含有选自Co，Cu，Mg，Mn，Ni，Fe和Zr中的至少一种元素的离子。

2. 发明授权

US07682744B2 Lithium secondary battery 有权
标题翻译：锂二次电池
公开(公告)号：US07682744B2
公开(公告)日：2010-03-23
申请号：US11231982
申请日：2005-09-22
申请人： Shouichirou Sawa , Hiroshi Minami , Atsushi Fukui , Taizou Sunano , Takuya Sunagawa , Maruo Kamino , Toshio Yanagida
发明人： Shouichirou Sawa , Hiroshi Minami , Atsushi Fukui , Taizou Sunano , Takuya Sunagawa , Maruo Kamino , Toshio Yanagida
IPC分类号： H01M4/00 , H01M4/58 , H01M4/50 , H01M6/04
CPC分类号： C01G51/42 , C01G45/1228 , C01G51/50 , C01G53/42 , C01G53/50 , C01P2002/52 , C01P2002/54 , C01P2004/61 , C01P2006/12 , C01P2006/40 , H01M4/0404 , H01M4/386 , H01M4/485 , H01M4/505 , H01M4/525 , H01M10/052 , H01M2004/021
摘要： A lithium secondary battery having high capacity and good charge-discharge cycle performance is provided. The lithium secondary battery includes a negative electrode (2) containing silicon as a negative electrode active material, a positive electrode (1) containing a positive electrode active material, and a non-aqueous electrolyte. The positive electrode active material is a lithium-transition metal composite oxide including a layered structure represented by the chemical formula LiaNixMnyCozO2, where a, x, y, and z satisfy the expressions: 0≦a≦1.3, x+y+z=1, 0
摘要翻译：提供具有高容量和良好的充放电循环性能的锂二次电池。锂二次电池包括含有硅作为负极活性物质的负极（2），含有正极活性物质的正极（1）和非水电解质。正极活性物质是包含由化学式LiaNixMnyCozO2表示的层状结构的锂 - 过渡金属复合氧化物，其中a，x，y和z满足以下表达式：0＆nlE; a＆nlE; 1.3，x + y + z = 1 ，0

3. 发明申请

US20060068290A1 Lithium secondary battery 有权
标题翻译：锂二次电池
公开(公告)号：US20060068290A1
公开(公告)日：2006-03-30
申请号：US11231982
申请日：2005-09-22
申请人： Shouichirou Sawa , Hiroshi Minami , Atsushi Fukui , Taizou Sunano , Takuya Sunagawa , Maruo Kamino , Toshio Yanagida
发明人： Shouichirou Sawa , Hiroshi Minami , Atsushi Fukui , Taizou Sunano , Takuya Sunagawa , Maruo Kamino , Toshio Yanagida
IPC分类号： H01M4/52 , H01M4/50 , H01M4/58
CPC分类号： C01G51/42 , C01G45/1228 , C01G51/50 , C01G53/42 , C01G53/50 , C01P2002/52 , C01P2002/54 , C01P2004/61 , C01P2006/12 , C01P2006/40 , H01M4/0404 , H01M4/386 , H01M4/485 , H01M4/505 , H01M4/525 , H01M10/052 , H01M2004/021
摘要： A lithium secondary battery having high capacity and good charge-discharge cycle performance is provided. The lithium secondary battery includes a negative electrode (2) containing silicon as a negative electrode active material, a positive electrode (1) containing a positive electrode active material, and a non-aqueous electrolyte. The positive electrode active material is a lithium-transition metal composite oxide including a layered structure represented by the chemical formula LiaNixMnyCOzO2, where a, x, y, and z satisfy the expressions: 0≦a≦1.3, x+y+z=1, 0
摘要翻译：提供具有高容量和良好的充放电循环性能的锂二次电池。锂二次电池包括含有硅作为负极活性物质的负极（2），含有正极活性物质的正极（1）和非水电解质。正极活性物质是包含由化学式为Li x Mn x Mn y CO的化学式表示的层状结构的锂 - 过渡金属复合氧化物其中a，x，y和z满足以下表达式：0 <= a <= 1.3，x + y + z = 1,0

4. 发明申请

US20060134517A1 Lithium secondary battery 审中-公开
标题翻译：锂二次电池
公开(公告)号：US20060134517A1
公开(公告)日：2006-06-22
申请号：US11300373
申请日：2005-12-15
申请人： Shouichirou Sawa , Atsushi Fukui , Takuya Sunagawa , Maruo Kamino
发明人： Shouichirou Sawa , Atsushi Fukui , Takuya Sunagawa , Maruo Kamino
IPC分类号： H01M4/58 , H01M4/48 , H01M10/40 , H01M4/62
CPC分类号： H01M4/131 , H01M4/134 , H01M4/1395 , H01M4/364 , H01M4/386 , H01M4/505 , H01M4/525 , H01M10/052 , H01M10/0567 , H01M2004/028
摘要： Charge-discharge cycle performance is improved in a lithium secondary battery utilizing a material containing silicon as a positive electrode active material. A lithium secondary battery includes a negative electrode (2) containing silicon as a negative electrode active material, a positive electrode (1) containing a lithium-transition metal composite oxide, and a non-aqueous electrolyte. Lithium carbonate is added in the positive electrode (1), and carbon dioxide is dissolved in the non-aqueous electrolyte.
摘要翻译：使用含有硅作为正极活性物质的材料的锂二次电池，充放电循环性能提高。锂二次电池包括含有硅作为负极活性物质的负极（2），含有锂 - 过渡金属复合氧化物的正极（1）和非水电解质。在正极（1）中加入碳酸锂，二氧化碳溶解在非水电解液中。

5. 发明授权

US08211569B2 Lithium secondary battery including a negative electrode which is a sintered layer of silicon particles and/or silicon alloy particles and a nonaqueous electrolyte containing carbon dioxide dissolved therein and method for producing same 有权
标题翻译：包括作为硅颗粒和/或硅合金颗粒的烧结层的负极和溶解有二氧化碳的非水电解质的锂二次电池及其制造方法
公开(公告)号：US08211569B2
公开(公告)日：2012-07-03
申请号：US10531047
申请日：2004-06-04
申请人： Shouichirou Sawa , Hiroshi Minami , Mariko Torimae , Atsushi Fukui , Yasuyuki Kusumoto , Katsunobu Sayama , Maruo Kamino
发明人： Shouichirou Sawa , Hiroshi Minami , Mariko Torimae , Atsushi Fukui , Yasuyuki Kusumoto , Katsunobu Sayama , Maruo Kamino
IPC分类号： H01M6/14 , H01M4/134 , H01M4/1395
CPC分类号： H01M10/052 , H01M4/0471 , H01M4/134 , H01M4/386 , H01M4/405 , H01M10/0567 , H01M10/058 , H01M2004/027 , Y10T29/49108
摘要： A rechargeable lithium battery including a negative electrode made by sintering, on a surface of a conductive metal foil as a current collector, a layer of a mixture of active material particles containing silicon and/or a silicon alloy and a binder, a positive electrode and a nonaqueous electrolyte, characterized in that the nonaqueous electrolyte contains carbon dioxide dissolved therein.
摘要翻译：一种可再充电锂电池，包括通过烧结制成的负极，作为集电体的导电金属箔的表面，含有硅和/或硅合金和粘合剂的活性物质颗粒的混合物层，正极和非水电解质，其特征在于，所述非水电解质含有溶解在其中的二氧化碳。

6. 发明申请

US20060003226A1 Lithium secondary battery and method for producing same 有权
标题翻译：锂二次电池及其制造方法
公开(公告)号：US20060003226A1
公开(公告)日：2006-01-05
申请号：US10531047
申请日：2004-06-04
申请人： Shouichirou Sawa , Hiroshi Minami , Mariko Torimae , Atsushi Fukui , Yasuyuki Kusumoto , Katsunobu Sayama , Maruo Kamino
发明人： Shouichirou Sawa , Hiroshi Minami , Mariko Torimae , Atsushi Fukui , Yasuyuki Kusumoto , Katsunobu Sayama , Maruo Kamino
IPC分类号： H01M4/58 , H01M10/40 , H01M4/66
CPC分类号： H01M10/052 , H01M4/0471 , H01M4/134 , H01M4/386 , H01M4/405 , H01M10/0567 , H01M10/058 , H01M2004/027 , Y10T29/49108
摘要： A rechargeable lithium battery including a negative electrode made by sintering, on a surface of a conductive metal foil as a current collector, a layer of a mixture of active material particles containing silicon and/or a silicon alloy and a binder, a positive electrode and a nonaqueous electrolyte, characterized in that the nonaqueous electrolyte contains carbon dioxide dissolved therein.
摘要翻译：一种可再充电锂电池，包括通过烧结制成的负极，作为集电体的导电金属箔的表面，含有硅和/或硅合金和粘合剂的活性物质颗粒的混合物层，正极和非水电解质，其特征在于，所述非水电解质含有溶解在其中的二氧化碳。

7. 发明申请

US20110117431A1 LITHIUM SECONDARY BATTERY AND METHOD OF MANUFACTURING THE SAME 审中-公开
标题翻译：锂二次电池及其制造方法
公开(公告)号：US20110117431A1
公开(公告)日：2011-05-19
申请号：US12868305
申请日：2010-08-25
申请人： Atsushi Fukui , Taizou Sunano , Maruo Kamino
发明人： Atsushi Fukui , Taizou Sunano , Maruo Kamino
IPC分类号： H01M4/62 , H01M10/00
CPC分类号： H01M10/052 , C08G73/10 , C08G73/1085 , H01M4/134 , H01M4/386 , H01M4/525 , H01M4/621 , H01M4/622 , Y02T10/7011 , Y10T29/49115
摘要： A lithium secondary battery including an electrode assembly and a non-aqueous electrolyte impregnated in the electrode assembly, the electrode assembly containing a positive electrode, a negative electrode having a negative electrode current collector and a negative electrode mixture layer formed on the negative electrode current collector, the negative electrode mixture layer containing a binder and negative electrode active material particles, the negative electrode active material particles containing at least one of silicon and a silicon alloy, and a separator interposed between the negative electrode and the positive electrode. The binder contains a polyimide resin having a branch structure formed by imidizing a polyvalent amine having a valency of 3 or more and a tetracarboxylic dianhydride.
摘要翻译：一种锂二次电池，包括电极组件和浸渍在电极组件中的非水电解质，包含正极的电极组件，具有负极集电体的负极和形成在负极集电体上的负极混合层含有粘合剂和负极活性物质粒子的负极混合物层，含有硅和硅合金中的至少一种的负极活性物质粒子以及介于负极和正极之间的隔膜。粘合剂含有通过酰亚胺化三价以上的多价胺和四羧酸二酐形成的分支结构的聚酰亚胺树脂。

8. 发明申请

US20100081063A1 NON-AQUEOUS ELECTROLYTE SECONDARY BATTERY 审中-公开
标题翻译：非水电解质二次电池
公开(公告)号：US20100081063A1
公开(公告)日：2010-04-01
申请号：US12568332
申请日：2009-09-28
申请人： Hidekazu Yamamoto , Atsushi Fukui , Taizou Sunano , Maruo Kamino
发明人： Hidekazu Yamamoto , Atsushi Fukui , Taizou Sunano , Maruo Kamino
IPC分类号： H01M6/16
CPC分类号： H01M10/0568 , H01M4/0435 , H01M4/134 , H01M4/621 , H01M4/70 , H01M10/052 , H01M10/0569
摘要： A non-aqueous electrolyte secondary battery has a positive electrode, a negative electrode, a separator interposed between the positive electrode and the negative electrode, and a non-aqueous electrolyte dissolving a solute in a non-aqueous solvent wherein the negative electrode contains a negative electrode active material containing powdered silicon and/or silicon alloy and a binding agent, and the non-aqueous electrolyte contains a fluorinated cyclic carbonate represented by a general formula (1) below, and wherein when Li storage volume per unit area in the negative electrode during charging is determined as A and the theoretical maximum Li storage volume per unit area in the negative electrode is determined as B, a utilizing rate (%) of negative electrode as expressed by (A/B)×100 is 45% or less.
摘要翻译：非水电解质二次电池具有正极，负极，插入在正极和负极之间的隔膜以及将溶质溶解在非水溶剂中的非水电解质，其中负极含有负极含有硅和/或硅合金粉末和粘合剂的电极活性材料，非水电解质含有下述通式（1）表示的氟化环状碳酸酯，其中当负极中的每单位面积的Li储存容积在充电期间确定为A，将负极中每单位面积的理论最大Li储存容积确定为B，由（A / B）×100表示的负极的利用率（％）为45％以下。

9. 发明申请

US20120082892A1 LITHIUM SECONDARY BATTERY 审中-公开
标题翻译：锂二次电池
公开(公告)号：US20120082892A1
公开(公告)日：2012-04-05
申请号：US13242514
申请日：2011-09-23
申请人： Kei Kobayashi , Atsushi Fukui , Taizou Sunano , Maruo Kamino
发明人： Kei Kobayashi , Atsushi Fukui , Taizou Sunano , Maruo Kamino
IPC分类号： H01M10/052
CPC分类号： H01M4/661 , H01M4/0404 , H01M4/0435 , H01M4/134 , H01M4/1395 , H01M4/662 , H01M4/667 , H01M10/052 , H01M2004/027
摘要： A lithium secondary battery has a positive electrode, a separator, and a negative electrode having a negative electrode current collector and a negative electrode mixture layer formed on a surface of the negative electrode current collector. The negative electrode mixture layer contains a negative electrode active material including a metal element capable of alloying with lithium. The negative electrode current collector includes a substrate made of a Cu—Fe—P alloy foil, and a surface layer provided on both surfaces of the substrate and made of pure copper. The surface layer has a Vickers hardness of 120 and less than that of the substrate. The negative electrode current collector has a proof stress of 308 MPa.
摘要翻译：锂二次电池具有在负极集电体的表面上形成有负极集电体和负极混合层的正极，隔膜和负极。负极合剂层含有负极活性物质，其包含能够与锂合金化的金属元素。负极集电体包括由Cu-Fe-P合金箔制成的基板和设置在基板的两面上并由纯铜制成的表面层。表面层的维氏硬度为120以下，小于基材的维氏硬度。负极集电体的抗张强度为308MPa。

10. 发明申请

US20110151338A1 NON-AQUEOUS ELECTROLYTE SECONDARY BATTERY 有权
标题翻译：非水电解质二次电池
公开(公告)号：US20110151338A1
公开(公告)日：2011-06-23
申请号：US13059770
申请日：2009-08-04
申请人： Hidekazu Yamamoto , Atsushi Fukui , Taizou Sunano , Maruo Kamino
发明人： Hidekazu Yamamoto , Atsushi Fukui , Taizou Sunano , Maruo Kamino
IPC分类号： H01M10/056
CPC分类号： H01M10/052 , H01M4/134 , H01M4/38 , H01M4/386 , H01M4/622 , H01M6/164 , H01M10/0567 , H01M10/0569 , H01M2300/0034 , Y02E60/122
摘要： The present invention is made to improve charge-discharge cycle performances under high temperature environment in a non-aqueous electrolyte secondary battery using a negative electrode containing a negative electrode active material of particulate silicon and/or silicon alloy and a binding agent.A non-aqueous electrolyte secondary battery according to the present invention includes a positive electrode 11, a negative electrode 12, a separator 13, and a non-aqueous electrolyte, wherein the negative electrode includes a negative electrode active material containing particulate silicon and/or silicon alloy and a binding agent, and the non-aqueous electrolyte contains fluorinated cyclic carbonate and a prescribed diisocyanate compound, and when Li storage volume per unit area of the negative electrode of the non-aqueous electrolyte secondary battery under charging condition is determined as A and the theoretical maximum Li storage volume per unit area of the negative electrode is determined as B, a utilizing rate (%) of negative electrode which is expressed by (A/B)×100 is 45% or less.
摘要翻译：本发明的目的在于提高使用含有硅和/或硅合金的负极活性物质的负极和粘合剂的非水电解质二次电池在高温环境下的充放电循环性能。根据本发明的非水电解质二次电池包括正极11，负极12，隔膜13和非水电解质，其中所述负极包括含有颗粒状硅的负极活性物质和/或硅合金和粘合剂，非水电解质含有氟化环状碳酸酯和规定的二异氰酸酯化合物，并且当非水电解质二次电池的负极在充电条件下的每单位面积的Li储存容积确定为A 将负极单位面积的理论最大Li储存容量确定为B，由（A / B）×100表示的负极的利用率（％）为45％以下。

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