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11. 发明授权

US5003015A Process for the polymerization of polar compounds 失效
标题翻译：极性化合物聚合方法
公开(公告)号：US5003015A
公开(公告)日：1991-03-26
申请号：US463711
申请日：1990-01-11
申请人： Gerald Fleischmann , Herbert Eck
发明人： Gerald Fleischmann , Herbert Eck
IPC分类号： C08F4/22 , C08F4/42 , C08F4/72
CPC分类号： C08F4/42
摘要： The invention relates to an improved process for the polymerization of polar compounds which have a C.dbd.C double bond in the .alpha.-position to a carbonyl, nitrile, sulfone, phosphone or nitro group, such as, for example, acrylic acid derivatives, .alpha.-nitroolefins, vinyl sulfone derivatives and vinyl phosphonic acid esters. The quasi-ionic polymerization is initiated by organometallic compounds of silicon, germanium and tin as initiators together with nucleophilic or electrophilic catalysts, and is carried out at temperatures in the range of from -100.degree. C. to +100.degree. C., in which the initiators are selected from silanes, germanes, stannanes, siloxanes, germoxanes or stannoxanes having at least one metal-bonded allyl or propargyl group, which may be substituted by hydrocarbon groups, per metal atom.
摘要翻译：本发明涉及一种改进的在羰基，腈，砜，膦或硝基的α-位上具有C = C双键的极性化合物的聚合方法，例如丙烯酸衍生物，α 乙烯基砜衍生物和乙烯基膦酸酯。准离子聚合由硅，锗和锡的有机金属化合物作为引发剂与亲核或亲电催化剂一起引发，并且在-100℃至+ 100℃的温度下进行，其中引发剂选自具有每个金属原子可被烃基取代的至少一个金属键合的烯丙基或炔丙基的硅烷，锗烷，锡烷，硅氧烷，锗氧烷或锡氧烷。

12. 发明授权

US4948907A Process for preparing low-molecular-weight organo(poly)siloxanes 失效
标题翻译：制备低分子量有机（聚）硅氧烷的方法
公开(公告)号：US4948907A
公开(公告)日：1990-08-14
申请号：US228078
申请日：1988-08-04
申请人： Gerald Fleischmann , Herbert Eck , Petra Wenzeler
发明人： Gerald Fleischmann , Herbert Eck , Petra Wenzeler
IPC分类号： C07F7/18 , C07F7/08
CPC分类号： C07F7/0874
摘要： Linear low-molecular-weight organo(poly)siloxanes which are monofunctional or difunctional and in which, if difunctional, the two functionalities are present in siloxane units which are chemically different from each other are prepared by reacting an octaorganocyclotetrasiloxane with lithium silanolate in a molar ratio of 0.9:1 to 1.1:1 in an electron-donating, aprotic solvent at a temperature below 50.degree. C., in the absence of water, and thereafter reacting the resultant lithium siloxanolate thus obtained with an organohalosilane.
摘要翻译：线性低分子量有机（聚）硅氧烷，其是单官能的或双官能的，并且其中如果是双官能的，则两个官能团存在于硅氧烷单元中，这两个官能团在化学上彼此不同，是通过使八齿组合四环四硅氧烷与硅烷醇锂与摩尔在电子给予的非质子溶剂中，在不存在水的情况下，在低于50℃的温度下，在0.9:1至1.1:1的比例下，使得到的所得锂硅氧烷酯与有机卤代硅烷反应。

13. 发明授权

US4600790A Silicon compounds containing SiC-bonded biuret groups and a method for preparing the same 失效
标题翻译：含有SiC键合的缩二脲基团的硅化合物及其制备方法
公开(公告)号：US4600790A
公开(公告)日：1986-07-15
申请号：US704238
申请日：1985-02-22
申请人： Herbert Eck , Hartmut Menzel , Reinhard Jira , Alfred Prasse
发明人： Herbert Eck , Hartmut Menzel , Reinhard Jira , Alfred Prasse
IPC分类号： C08G18/00 , C07F7/18 , C08G18/77 , C09D7/12 , C09D175/00 , C07F7/08 , C07F7/10
CPC分类号： C09D7/1233 , C07F7/1836 , C08G18/778 , C08K5/5455
摘要： Organosilicon compounds containing SiC-bonded biuret groups are prepared by (I) adding a silane containing 1 or 2 silicon atoms per molecule and an SiC-bonded organic radical having at least one basic ##STR1## group and at least one SiOC-bonded aliphatic radical per molecule to a monoisocyanate or a diisocyanate at a temperature up to 125.degree. C. and (II) maintaining the temperature at 110.degree. C. to 125.degree. C. for at least two minutes. In an alternate procedure the silane and mono- or diisocyanate may be heated to a temperature in the range of from 110.degree. C. up to 200.degree. C. for at least two minutes, after or while adding additional monoisocyanate or diisocyanate.The resultant silicon compounds are used in the preparation of polyurethanes and as additives to lacquers.
摘要翻译：含有SiC键合的缩二脲基团的有机硅化合物通过以下步骤制备：（I）每分子加入含有1或2个硅原子的硅烷和具有至少一个碱性基团的SiC键合的有机基团和至少一个SiOC键合的脂族基团每分子加到单异氰酸酯或二异氰酸酯上，温度高达125℃，和（II）将温度保持在110℃至125℃至少2分钟。在另外的方法中，在添加另外的单异氰酸酯或二异氰酸酯之后，或者加入另外的单异氰酸酯或二异氰酸酯，可将硅烷和单 - 或二异氰酸酯加热至110℃至200℃的温度至少两分钟。所得硅化合物用于制备聚氨酯和作为漆的添加剂。

14. 发明授权

US4532295A Polymerization process for aqueous polymer dispersions of vinyl esters and ethylenic monomers 失效
标题翻译：乙烯基酯和乙烯单体的聚合物水分散体的聚合方法
公开(公告)号：US4532295A
公开(公告)日：1985-07-30
申请号：US625672
申请日：1984-06-28
申请人： Hartmut Brabetz , Herbert Eck , Reinhard Jira , Heinrich Hopf
发明人： Hartmut Brabetz , Herbert Eck , Reinhard Jira , Heinrich Hopf
IPC分类号： C08L31/00 , C08F2/00 , C08F2/16 , C08F2/20 , C08F2/44 , C08F4/34 , C08F4/40 , C08J3/02 , C08L31/04 , C08F210/02 , C04B13/24 , C09J3/14
CPC分类号： C08F2/20 , Y10S526/91 , Y10S526/911 , Y10S526/915
摘要： A process for the preparation of aqueous polymer dispersions comprising polymerizing vinyl esters and up to 50% by weight of the total monomer of compounds with unsaturated ethylenic bonds at a temperature of 10.degree. to 100.degree. C. in the presence of an at least partially water-soluble free-radical initiator and at least one starch member of the group consisting of cyanalkylated starch, hydroxyalkylated starch and carboxyalkylated starch and optionally present conventional adjuvants with the starting mixture containing not more than one-third of the total monomers and the remaining monomers being added by metering during the polymerization, the initiators being at least one member of the group consisting of hydrogen peroxide and organic hydroperoxides in an amount of at least 30 mmol per kg of total monomer mixture and optionally present water-soluble reducing agent and the amount of starch being at least 1% by weight based on the total monomer weight.
摘要翻译：一种制备含水聚合物分散体的方法，包括在至少部分水存在下，在10-100℃温度下使乙烯基酯和至多50重量％的具有不饱和烯键的化合物的总单体聚合可溶的自由基引发剂和由氰烷基化淀粉，羟烷基化淀粉和羧烷基化淀粉组成的组中的至少一种淀粉成分，以及任选存在的起始混合物的起始混合物含有不超过总单体的三分之一，其余单体为在聚合过程中通过计量加入，引发剂为至少一种由过氧化氢和有机氢过氧化物组成的组，其量为至少30mmol / kg总单体混合物和任选存在的水溶性还原剂，淀粉基于单体总重量为至少1重量％。

15. 发明授权

US4337323A Stabilized aqueous dispersions of vinyl chloride polymers 失效
标题翻译：稳定的氯乙烯聚合物水分散体
公开(公告)号：US4337323A
公开(公告)日：1982-06-29
申请号：US204428
申请日：1980-11-06
申请人： Klaus Adler , Klaus Hafener , Herbert Eck
发明人： Klaus Adler , Klaus Hafener , Herbert Eck
IPC分类号： C08L27/00 , C08K3/18 , C08K5/16 , C08K5/17 , C08L1/00 , C08L33/00 , C08L33/02 , C09D127/04 , C09J127/04
CPC分类号： C08K5/175
摘要： Stabilized aqueous dispersions of vinyl chloride polymer having at least 25% by weight of vinyl chloride units in the polymer and having K values of between 20 and 80, having added as a stabilizing agent 0.3-6% by weight of substances selected from the group of compounds according to the general formula ##STR1## wherein n has the meaning of from 0 to 2 or water-soluble salts thereof. The invention also relates to a process of producing the stabilized products by adding the stabilizing agent after polymerization in aqueous dispersion, and to the use of the stabilized dispersions in binders, coating compositions, paints, adhesives, textile auxiliaries and paper-coating compositions.
摘要翻译：在聚合物中具有至少25重量％氯乙烯单元并且K值在20和80之间的氯乙烯聚合物的稳定水分散体，其中加入作为稳定剂的0.3-6重量％的选自以下的物质：根据通式的化合物，其中n具有0至2的含义或其水溶性盐。本发明还涉及通过在水分散体中聚合后添加稳定剂以及在粘合剂，涂料组合物，油漆，粘合剂，纺织助剂和纸涂层组合物中使用稳定的分散体来生产稳定化产物的方法。

16. 发明授权

US06547874B2 Hydrophobicizing agents for hydrophobicizing gypsum-plaster-bound construction materials 失效
公开(公告)号：US06547874B2
公开(公告)日：2003-04-15
申请号：US09769918
申请日：2001-01-25
申请人： Herbert Eck , Klaus Adler
发明人： Herbert Eck , Klaus Adler
IPC分类号： C04B1100
CPC分类号： C04B28/14 , C04B20/1051 , C04B14/062 , C04B20/008 , C04B14/30 , C04B14/04 , C04B24/383 , C04B16/02 , C04B24/42
摘要： The invention relates to a hydrophobicizing agent for gypsum-plaster-bound construction materials comprising a substrate based on pulverulent organic or inorganic solids with a BET surface area >5 g/m2 and comprising one or more organopolysiloxanes having Si-bonded hydrogen (organohydropolysiloxanes) built up from units of the general formula HaSiR1bO(4-a-b)/2, where the radicals R1 are identical or different monovalent hydrocarbon or hydrocarbonoxy radicals having from one to 15 carbon atoms, or are hydroxyl groups, with the proviso that at least one Si-bonded hydrogen atom per molecule is present, and a takes values from 0 to 3, and b takes values from 0 to 3.

17. 发明授权

US06197863B1 Crosslinkable powder composition which is redispersible in water 有权
标题翻译：可再分散于水中的可交联粉末组合物
公开(公告)号：US06197863B1
公开(公告)日：2001-03-06
申请号：US09501723
申请日：2000-02-10
申请人： Herbert Eck , Reiner Figge , Herbert Barthel
发明人： Herbert Eck , Reiner Figge , Herbert Barthel
IPC分类号： C08K318
CPC分类号： E04F13/02 , C04B24/163 , C04B40/0042 , C04B2103/0057 , C04B2111/00482 , C09D201/02 , C04B14/062 , C04B20/008 , C04B20/1051 , C04B24/24 , C04B24/26 , C04B28/02 , C04B20/10 , C04B2103/0053 , C04B2103/0055 , C08L2666/04
摘要： Crosslinkable powder compositions are provided which are redispersible in water and comprise a) from 30 to 95 parts by weight of one or more water-insoluble, film-forming polymers of one or more free-radically polymerizable, ethylenically unsaturated monomers, b) from 5 to 70 parts by weight of one or more water-soluble polymers, where at least one of the polymer components a) and b) comprises one or more comonomer units containing crosslinkable groups, and the parts by weight of a) and b) add up to 100 parts by weight, and c) from 0.5 to 30% by weight, based on the total weight of a) and b), of inorganic or organic solids which are insoluble in water and in organic solvents and have a mean particle size of from 5 nm to 100 &mgr;m, which solids have, chemically bound to their surface, functional groups capable of forming covalent bonds with the crosslinkable groups of the polymers a) and b).
摘要翻译：提供可再分散在水中的可交联粉末组合物，其包含a）30至95重量份的一种或多种一种或多种可自由基聚合的烯属不饱和单体的水不溶性成膜聚合物，b）5至 70重量份的一种或多种水溶性聚合物，其中至少一种聚合物组分a）和b）包含一种或多种含可交联基团的共聚单体单元，并且a）和b）的重量份加到 100重量份，和c）0.5至30重量％，基于a）和b）的总重量，无机或有机固体，其不溶于水和有机溶剂，并且平均粒度为5 nm至100um，其固体与其表面化学结合，能够与聚合物a）和b）的可交联基团形成共价键的官能团。

18. 发明授权

US06191235B1 Process for the preparation of a redispersible dispersion powder composition 失效
标题翻译：制备可再分散粉末组合物的方法
公开(公告)号：US06191235B1
公开(公告)日：2001-02-20
申请号：US08682671
申请日：1996-10-03
申请人： Herbert Eck , Klaus Adler , Heinrich Hopf , Franz Jodlbauer , Dieter Gerhardinger
发明人： Herbert Eck , Klaus Adler , Heinrich Hopf , Franz Jodlbauer , Dieter Gerhardinger
IPC分类号： C08F800
CPC分类号： D06M15/643 , C04B40/0042 , C08J3/12 , C08J3/122 , C08J2359/00 , C08K5/54 , C08K5/5419 , C09D5/024 , D04H1/587 , D04H1/64 , D06M15/227 , D06M15/263 , D06M15/327 , D06M15/333 , D06M15/3568
摘要： The invention concerns a dispersion powder composition which is redispersible in water and is made from water-insoluble organic polymers, the composition being characterized in that it contains 0.1 to 30% by wt., relative to the weight of the organic polymers, of one ormore silicon compounds which are dispersible in water and which have a boiling point at normal pressure of 160° C., selected from the group comprising the silanes, polysilanes, oligosiloxanes, carbosilanes, polycarbosilanes, carbosiloxanes, polycarbosiloxanes and polysilylenedisiloxanes. The invention also concerns methods for manufacturing such compositions and their use.
摘要翻译：本发明涉及一种分散粉末组合物，其可再分散于水中并由水不溶性有机聚合物制成，该组合物的特征在于其相对于有机聚合物的重量为0.1-30重量％可分散在水中并且在常压下为160℃的沸点的硅化合物，选自硅烷，聚硅烷，低聚硅氧烷，碳硅烷，聚碳硅烷，碳硅氧烷，聚硅氧烷和聚硅氧烷二硅氧烷。本发明还涉及制造这种组合物及其用途的方法。

19. 发明授权

US6063865A Crosslinkable powder composition which is redispersible in water 失效
标题翻译：可再分散于水中的可交联粉末组合物
公开(公告)号：US6063865A
公开(公告)日：2000-05-16
申请号：US126675
申请日：1998-07-30
申请人： Peter Ball , Herbert Eck
发明人： Peter Ball , Herbert Eck
IPC分类号： C08L101/12 , C04B40/00 , C08K5/16 , C09D201/00 , C09J201/00 , C08G63/48
CPC分类号： C04B40/0042 , C08K5/16 , C04B2103/0057
摘要： A crosslinkable powder composition is provided which is redispersible in water and comprisesa) from 30 to 95 parts by weight of one or more water-insoluble, film-forming polymers of free-radically polymerizable, ethylenically unsaturated monomers, where from 0.5 to 10% by weight of the monomers, based on the total weight of the polymer a), are ones having one or more substituents selected from the group consisting of aldehyde, keto, epoxide, isocyanate, carboxylic anhydride and aziridine groups,b) from 5 to 70 parts by weight of one or more water-soluble, film-forming polymers, where the parts by weight of a) and b) add up to 100 parts by weight, andc) one or more compounds containing at least two functional groups which are present in salt form and are selected from the group consisting of amines, hydrazides, hydroxylamine esters, aryl- and alkylhydrazines or -hydrazones.
摘要翻译：提供可再分散在水中的可交联的粉末组合物，其包含a）30至95重量份的一种或多种可自由基聚合的烯属不饱和单体的水不溶性成膜聚合物，其中0.5至10重量％基于聚合物a）的总重量，是具有一个或多个选自醛，酮，环氧化物，异氰酸酯，羧酸酐和氮丙啶基团的取代基的单体，b）5至70 重量份的一种或多种水溶性成膜聚合物，其中a）和b）的重量份加到100份重量份，和c）一种或多种含有至少两个官能团的化合物，它们是以盐形式存在，并且选自胺，酰肼，羟胺酯，芳基和烷基肼或腙。

20. 发明授权

US5608011A Crosslinkable polymer powder compositions 失效
标题翻译：可交联聚合物粉末组合物
公开(公告)号：US5608011A
公开(公告)日：1997-03-04
申请号：US526537
申请日：1995-09-11
申请人： Herbert Eck , Peter Ball , Hermann Lutz , Heinrich Hopf
发明人： Herbert Eck , Peter Ball , Hermann Lutz , Heinrich Hopf
IPC分类号： C08J3/20 , C08K5/14 , C08L101/02 , C08C19/20 , C08F8/34 , C08K3/30 , C08K5/41
CPC分类号： C08L101/02 , C08J3/203 , C08K5/14
摘要： The invention relates to water-dispersible or water-soluble polymer powder compositions which can be crosslinked or condensed by acid and comprisesI) one or more pulverulent water-dispersible or water-soluble copolymers which can be crosslinked or condensed by acid,II) one or more pulverulent water-dispersible or water-soluble compounds from the group consisting of alkali metal or ammonium peroxo acid salts, andIII) one or more pulverulent water-dispersible or water-soluble reducing agents.
摘要翻译：本发明涉及可由酸交联或缩合的水分散性或水溶性聚合物粉末组合物，并且包括I）一种或多种可由酸交联或缩合的粉状水分散性或水溶性共聚物，II）一种或更多的粉状水分散性或水溶性化合物，以及III）一种或多种粉状水分散性或水溶性还原剂。

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