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11. 发明授权

US6063888A Liquid curable resin composition 失效
标题翻译：液体固化树脂组合物
公开(公告)号：US6063888A
公开(公告)日：2000-05-16
申请号：US168938
申请日：1998-10-09
申请人： Yoshikazu Yamaguchi , Junji Yoshizawa , Zen Komiya , Takashi Ukachi
发明人： Yoshikazu Yamaguchi , Junji Yoshizawa , Zen Komiya , Takashi Ukachi
IPC分类号： G02B6/44 , C03C25/24 , C08F2/46 , C08F290/00 , C08F299/06 , C08F299/08 , C08G18/28 , C08G18/67 , C08G77/388 , C09D175/14 , C09D175/16 , C09D183/07 , C09D183/10 , G02B1/04 , G03F7/027 , G03F7/038 , G03F7/075 , C08G77/20
CPC分类号： C08G18/672 , C08G18/289 , C08G77/388 , G02B1/048 , Y10T428/2942 , Y10T428/2962 , Y10T428/2991 , Y10T428/2995 , Y10T428/2998
摘要： A liquid radiation curable resin composition comprising a polydimethylsiloxane compound which has (i) at least two urethane bonds in one molecule, (ii) an unreactive organic group at at least one of the ends of the molecule, and (iii) a radical curable ethylenically unsaturated group at the other end of the molecule. The resin composition exhibits superior shelf life in a liquid state and produces cured products having slippery surface. It is suitable as a coating material for optical fibers.
摘要翻译：一种液体辐射固化树脂组合物，其包含聚二甲基硅氧烷化合物，所述聚二甲基硅氧烷化合物在一分子中具有（i）至少两个氨基甲酸酯键，（ii）所述分子的至少一个末端的非反应性有机基团，和（iii）可自由基固化的烯属在分子另一端的不饱和基团。树脂组合物在液态下表现出优异的保存期，并产生具有光滑表面的固化产物。它适用于光纤的涂层材料。

12. 发明授权

US07740944B2 Multilayer coating 有权
标题翻译：多层涂层
公开(公告)号：US07740944B2
公开(公告)日：2010-06-22
申请号：US10469132
申请日：2002-03-01
申请人： Zen Komiya , Masahito Mase , Junji Yoshizawa , Takashi Ukachi
发明人： Zen Komiya , Masahito Mase , Junji Yoshizawa , Takashi Ukachi
IPC分类号： B32B27/40 , C08F2/46
CPC分类号： C03C17/3405 , C03C25/1065 , C03C25/50 , Y10T428/31504 , Y10T428/31554
摘要： The present invention relates to a multilayer coating in which a plurality of photocurable resin cured films are layered on a substrate, wherein at least two adjacent layers comprise the same hindered phenol-type antioxidant.The multilayer coating can be applied onto a substrate, such as glass fibers, vinyl chloride sheets, polycarbonate sheets, glass plates, polyethylene films, wood, acrylic sheets, metal plates, and the like.
摘要翻译：本发明涉及一种多层涂层，其中多个光固化树脂固化膜层叠在基底上，其中至少两个相邻层包含相同的受阻酚型抗氧化剂。可以将多层涂层涂布在基材上，例如玻璃纤维，氯乙烯片，聚碳酸酯片，玻璃板，聚乙烯薄膜，木材，丙烯酸片，金属板等。

13. 发明授权

US07532795B2 Radiation-curable liquid resin composition 失效
标题翻译：可辐射固化液体树脂组合物
公开(公告)号：US07532795B2
公开(公告)日：2009-05-12
申请号：US10568453
申请日：2004-08-20
申请人： Atsuya Takahashi , Takeo Shigemoto , Zen Komiya , Hiroki Ohara
发明人： Atsuya Takahashi , Takeo Shigemoto , Zen Komiya , Hiroki Ohara
IPC分类号： B32B17/02 , G02B6/02 , G02B6/04 , G02B6/036 , G02B6/44 , C08L75/16 , C09D175/16 , C08F290/06 , C08F2/46
CPC分类号： C09D175/16 , C03C25/106 , C08G18/672 , C08G18/8175 , Y10T428/2938 , C08G18/48
摘要： The invention relates to a radiation-curable liquid resin composition comprising: (A) 20-90 wt % of a urethane(meth)acrylate oligomer, and (B) 1-35 wt % of a monomer shown by the following formula (1), wherein R1 represents a hydrogen atom or a methyl group, R2 and R3 individually represent a hydrogen atom or an alkyl group having 1-4 carbon atoms, R4 represents a hydrogen atom or a methyl group, and n represents an integer of 1-6, or a monomer including a hydroxyl group.
摘要翻译：本发明涉及一种可辐射固化液体树脂组合物，其包含：（A）20-90重量％的氨基甲酸酯（甲基）丙烯酸酯低聚物和（B）1-35重量％的由下式（1）表示的单体，其中R1表示氢原子或甲基，R2和R3分别表示氢原子或具有1-4个碳原子的烷基，R4表示氢原子或甲基，n表示1-6的整数，或包含羟基的单体。

14. 发明申请

US20050272829A1 Curable liquid resin composition 审中-公开
标题翻译：可固化液体树脂组合物
公开(公告)号：US20050272829A1
公开(公告)日：2005-12-08
申请号：US10507016
申请日：2003-03-27
申请人： Masanobu Sugimoto , Hideki Sugimoto , Takeo Shigemoto , Zen Komiya , Takashi Ukachi
发明人： Masanobu Sugimoto , Hideki Sugimoto , Takeo Shigemoto , Zen Komiya , Takashi Ukachi
IPC分类号： G02B6/44 , C03C25/10 , C08F283/00 , C08F283/06 , C08F290/06 , C08G18/48 , C08G18/67 , C09D175/16 , C08G2/00
CPC分类号： C09D175/16 , C03C25/1065 , C08F283/006 , C08F283/06 , C08G18/4854 , C08G18/672 , C08G18/48
摘要： This invention relates to a curable liquid resin composition comprising: (a) 5-94 parts by weight of a urethane (meth)acrylate comprising a polyether backbone, at least one urethane group and at least one (meth)acrylate end group (b) 5-94 parts by weight of a polymerizable monomer, and; (c) 0.01-10 parts by weight of a photoinitiator, in 100 parts by weight of the curable liquid resin composition, wherein the cured product of the composition has a glass transition temperature between 30 and 85° C. or less and a stress relaxation time of 30 minutes or less.
摘要翻译：本发明涉及一种可固化液体树脂组合物，其包含：（a）5-94重量份的包含聚醚主链，至少一个氨基甲酸酯基和至少一个（甲基）丙烯酸酯端基（b）的氨基甲酸酯（甲基）丙烯酸酯， 5-94重量份的可聚合单体，和（c）0.01-10重量份的光引发剂，在100重量份的可固化液体树脂组合物中，其中组合物的固化产物的玻璃化转变温度为30-85℃或更低，应力松弛时间30分钟以内。

15. 发明申请

US20050244752A1 Radiation-curable resin composition for adhesives 审中-公开
标题翻译：用于粘合剂的可辐射固化树脂组合物
公开(公告)号：US20050244752A1
公开(公告)日：2005-11-03
申请号：US10508993
申请日：2003-03-23
申请人： Junji Yoshizawa , Atsuya Takahashi , Masahito Mase , Zen Komiya
发明人： Junji Yoshizawa , Atsuya Takahashi , Masahito Mase , Zen Komiya
IPC分类号： C09J4/02 , C08F289/00 , C08F290/06 , C09J4/06 , C09J11/00 , G11B7/24
CPC分类号： C08F290/061 , C08F289/00 , C08F290/06 , C09J4/06
摘要： A radiation-curable resin composition for adhesives comprising (A) a bisphenol-type epoxy (meth)acrylate having a hydroxyl group, (B) a polyfunctional (meth)acrylate having an aliphatic cyclic structure or an aromatic cyclic structure other than the component (A), and (C) a photoinitiator, wherein the content of the component (A) and the content of the component (B) in the composition are respectively 30 wt % or more. The radiation-curable resin composition for adhesives of the present invention exhibits excellent adhesion to silver, silicon compound, and aluminum, superior moisture-heat resistance, and fast curability, especially at the edge of the disk, and therefore is very useful in the manufacture of optical disks in comparison with conventional adhesives.
摘要翻译：一种用于粘合剂的辐射固化树脂组合物，其包含（A）具有羟基的双酚型环氧（甲基）丙烯酸酯，（B）具有脂肪族环状结构的多官能（甲基）丙烯酸酯或除该成分 A）和（C）光引发剂，其中组分（A）的含量和组分（B）中组分的含量分别为30重量％或更多。本发明的粘合剂用辐射固化型树脂组合物对银，硅化合物和铝具有优异的粘合性，优异的耐湿热性和快速固化性，特别是在盘的边缘，因此在制造中非常有用与常规粘合剂相比。

16. 发明申请

US20050228063A1 Radiation curable resin composition 审中-公开
公开(公告)号：US20050228063A1
公开(公告)日：2005-10-13
申请号：US11038572
申请日：2005-01-21
申请人： Zen Komiya , Adrianus Abel , Duurt Alkema , Masahito Mase , Takashi Ukachi
发明人： Zen Komiya , Adrianus Abel , Duurt Alkema , Masahito Mase , Takashi Ukachi
IPC分类号： C03C25/10 , C08F2/46 , C08F2/48 , C08F283/00 , C08F290/06 , C08F290/14 , C08G2/00 , C08G18/28 , C08G18/48 , C08G18/67 , C09D175/16
CPC分类号： C09D175/16 , C03C25/106 , C03C25/1065 , C08F283/006 , C08F290/06 , C08F290/067 , C08F290/14 , C08F290/147 , C08G18/289 , C08G18/4866 , C08G18/672 , Y10T428/19 , Y10T428/2938 , Y10T428/294 , Y10T428/2942 , Y10T428/2956 , Y10T428/31645 , C08G18/48 , C08G18/40
摘要： The present invention provides a curable composition, comprising: a (meth)acrylate urethane compound derived from a polypropylene glycol or a propyleneoxide ethyleneoxide copolymer glycol having a molecular weight between 1,000 and 13,000 and an amount of unsaturation less than 0.01 meq/g. The liquid curable resin composition of the present invention has improved liquid stability and can produce cured products having superior mechanical characteristics by polymerization. The composition further comprises preferably a primary or secondary amine. The liquid curable resin composition can be used as a coating material for optical fibers, adhesives, and the like. The composition is particularly suitable as a coating material for optical fibers for which long-term stability is required.

17. 发明授权

US5913004A Optical glass fiber coating composition 失效
标题翻译：光学玻璃纤维涂料组合物
公开(公告)号：US5913004A
公开(公告)日：1999-06-15
申请号：US840169
申请日：1997-04-14
申请人： Hideaki Takase , Mitsuhito Suwa , Zen Komiya , Takashi Ukachi
发明人： Hideaki Takase , Mitsuhito Suwa , Zen Komiya , Takashi Ukachi
IPC分类号： C03C25/10 , C08F290/06 , C08G18/10 , C08G18/67 , C09D175/16 , G02B6/02 , G02B6/16
CPC分类号： C09D175/16 , C03C25/106 , C08F290/067 , C08G18/10 , C08G18/672
摘要： Provided is an optical glass fiber coating composition which when coated on an optical glass fiber and suitably cured provides a coating having the combination of properties (i) through (iv):(i) a stable tensile modulus that is low at room temperature and over a broad range of temperatures below room temperature,(ii) an adhesion to the optical glass fiber sufficient to prevent structural defects and microbending in the optical glass fiber,(iii) the capability of being removed by stripping from the optical glass fiber substantially no residue left on the optical glass fiber, and(iv) which satisfies each of the following inequalities (I) and (II),X.ltoreq.0.2 kg/mm.sup.2 (I)X/Y.gtoreq.1/10 (II) wherein X is the tensile modulus (kg/mm.sup.2) measured at 23.degree. C. and Y is the tensile modulus (kg/mm.sup.2) measured at -40.degree. C.,This coating composition comprises:(A) a urethane (meth)acrylate formed from,(a) a diol compound containing at least one structure represented by one of the following formulas (1) and (2), ##STR1## (b) a compound containing two isocyanate groups, and (c) a compound containing a (meth)acrylate group and a hydroxy group;(B) a second (meth)acrylate-containing compound of which the homopolymer has a glass transition temperature of at most about 0.degree. C.; and(C) a polymerization initiator.
摘要翻译：提供了一种光学玻璃纤维涂料组合物，其在光学玻璃纤维上涂覆并适当固化时提供了具有性能（i）至（iv）的组合的涂层：（i）在室温和过高时稳定的拉伸模量低于室温的宽范围的温度，（ii）足以防止光学玻璃纤维中的结构缺陷和微弯曲的光学玻璃纤维的粘附，（iii）通过从光学玻璃纤维剥离而基本上没有残留物的去除能力留下在光学玻璃纤维上，和（iv）满足以下不等式（I）和（II）中的每一个，X <= 0.2kg / mm 2（I）X / Y> / = 1/10（II）其中 X为在23℃下测定的拉伸弹性模量（kg / mm2），Y为在-40℃下测定的拉伸弹性模量（kg / mm2）。该涂料组合物包含：（A）形成的氨基甲酸酯（甲基）由（a）含有由下述式（1）表示的至少一种结构的二醇化合物a nd（2），（b）含有2个异氰酸酯基的化合物，（c）含有（甲基）丙烯酸酯基和羟基的化合物; （B）第二（甲基）丙烯酸酯化合物，其均聚物的玻璃化转变温度为至多约0℃; 和（C）聚合引发剂。

18. 发明授权

US5164469A Transparent resin material 失效
标题翻译：透明树脂材料
公开(公告)号：US5164469A
公开(公告)日：1992-11-17
申请号：US648237
申请日：1991-01-31
申请人： Kohei Goto , Zen Komiya , Noboru Yamahara , Akira Iio , Masao Hisatomi , Hiroshi Oka
发明人： Kohei Goto , Zen Komiya , Noboru Yamahara , Akira Iio , Masao Hisatomi , Hiroshi Oka
IPC分类号： C08G61/08 , C08L65/00
CPC分类号： C08L65/00 , C08G61/08
摘要： A transparent resin material consisting of a hydrogenation product of a (co)polymer obtained by subjecting at least one compound represented by general formula (I) or a combination of at least 5% by weight of said compound and 95% by weight or less of other copolymerizable cyclic olefin monomer to metathesis polymerization: ##STR1## wherein A and B are independently hydrogen atoms or C.sub.1-10 hydrocarbon groups; and X and Y are independently hydrogen atoms, C.sub.1-10 hydrocarbon groups, --C(CH.sub.2).sub.n COOR.sup.1 groups or --(CH.sub.2).sub.n OCOR.sup.1 groups [R.sup.1 is a C.sub.1-20 hydrocarbon group and n is 0 or an integer of 1-10] with the proviso that at least one of X and Y is selected from the above --(CH.sub.2).sub.n COOR.sup.1 and --(CH.sub.2).sub.n OCOR.sup.1 groups. Said transparent resin material is moldable and has sufficient optical properties, low hygroscopicity, good heat resistance and excellent adhesion to recording layer.
摘要翻译：将由通式（I）表示的至少一种化合物或至少5重量％的所述化合物的组合和95重量％以下的化合物所得的（共）聚合物的氢化产物组成的透明树脂材料其它可共聚的环烯烃单体进行复分解聚合反应：其中A和B独立地为氢原子或C 1-10烃基; 并且X和Y独立地是氢原子，C 1-10烃基，-C（CH 2）n COOR 1基团或 - （CH 2）nOCOR 1基团[R 1是C 1-20烃基，n是0或1-10的整数] 条件是X和Y中的至少一个选自上述 - （CH 2）n COOR 1和 - （CH 2）nOCOR 1基团。所述透明树脂材料是可模塑的并且具有足够的光学性能，低吸湿性，良好的耐热性和对记录层的优异粘合性。

19. 发明授权

US08367204B2 Liquid curable resin composition and cured products 有权
公开(公告)号：US08367204B2
公开(公告)日：2013-02-05
申请号：US09983216
申请日：2001-10-23
申请人： Hirofumi Uchida , Zen Komiya , Takashi Ukachi
发明人： Hirofumi Uchida , Zen Komiya , Takashi Ukachi
IPC分类号： B32B17/00 , G02B6/00 , C08G18/67
CPC分类号： C09D175/16 , C03C25/106 , C03C25/1065 , C08G18/672 , Y10T428/2933 , Y10T428/2964 , C08G18/48
摘要： A curable resin composition comprising an antioxidant, a UV absorber, and a (meth)acrylate oligomer comprising polyether units. Cured products made from the liquid curable resin composition of the present invention have excellent light stability. The resin composition is suitable as a coating material for optical fibers.

20. 发明授权

US07906566B2 Curable liquid resin composition 有权
标题翻译：可固化液体树脂组合物
公开(公告)号：US07906566B2
公开(公告)日：2011-03-15
申请号：US10571758
申请日：2004-09-17
申请人： Masanobu Sugimoto , Satoshi Kamo , Takeo Shigemoto , Zen Komiya , Paulus Antonius Maria Steeman
发明人： Masanobu Sugimoto , Satoshi Kamo , Takeo Shigemoto , Zen Komiya , Paulus Antonius Maria Steeman
IPC分类号： C09D11/00 , C08G18/00 , B32B15/00 , A01G9/02
CPC分类号： C08G18/672 , C03C25/1061 , C03C25/1065 , C08G18/4854 , C08L75/16 , C09D175/16 , Y10T428/2933 , C08G18/48 , C08L2666/14
摘要： The invention relates to a curable liquid resin composition comprising: (A) a urethane(meth)acrylate having a structure originating from a polyol and a number average molecular weight of 800 g/mol or more, but less than 6,000 g/mol, and (B) a urethane(meth)acrylate having a structure originating from a polyol and a number average molecular weight of 6,000 g/mol or more, but less than 20,000 g/mol, wherein the total amount of the component (A) and component (B) is 20-95 wt % of the curable liquid resin composition and the content of the component (B) is 0.1-30 wt % of the total of the component (A) and component (B).
摘要翻译：本发明涉及一种可固化液体树脂组合物，其包含：（A）具有起始于多元醇的结构和数均分子量为800g / mol以上但小于6,000g / mol的氨基甲酸酯（甲基）丙烯酸酯，以及（B）具有来自多元醇的结构和数均分子量为6000g / mol以上但小于20,000g / mol的氨基甲酸酯（甲基）丙烯酸酯，其中组分（A）和组分（B）为可固化液体树脂组合物的20-95重量％，组分（B）的含量为组分（A）和组分（B）的总量的0.1-30重量％。

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