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1. 发明申请

US20070232713A1 Radiation Curable Liquid Resin Composition for Optical Three-Dimensional Molding and Optical Molded Article Obtained by Photocuring Same 审中-公开
标题翻译：用于光学三维成型的辐射可固化液体树脂组合物和通过光固化获得的光学成型品
公开(公告)号：US20070232713A1
公开(公告)日：2007-10-04
申请号：US11596744
申请日：2005-05-26
申请人： Katsuyuki Takase , Ryouji Tatara , Masanobu Sugimoto , Zen Komiya
发明人： Katsuyuki Takase , Ryouji Tatara , Masanobu Sugimoto , Zen Komiya
IPC分类号： C08G59/18 , B29C67/00 , C08K5/13 , C08K5/524 , C08L63/00
CPC分类号： G03F7/027 , B29C64/00 , G03F7/0037 , G03F7/038
摘要： Provided is a radiation curing liquid resin composition for optical three-dimensional modeling, which has a small step on the side face and excellent surface smoothness, and allows forming a high accuracy optically modeled article, is composed of the components (A) through (F). The content of (A) component in the total quantity of the composition is 0.1 to 10% by mass, and the content of (F) polyether polyol compound is 1 to 35% by mass. (A) A compound having phenolic hydroxyl group and/or phosphite group, (B) A cationic polymerizable compound, (C) A cationic polymerization initiator, (D) A radical polymerizable compound, (E) A radical polymerization initiator, and (F) A polyether polyol compound.
摘要翻译：提供一种用于光学三维建模的辐射固化液体树脂组合物，其在侧面具有小的台阶和优异的表面平滑度，并且允许形成高精度的光学建模的制品由组分（A）至（F ）。组合物中（A）成分的含量为0.1〜10质量％，（F）聚醚多元醇化合物的含量为1〜35质量％。（A）具有酚羟基和/或亚磷酸酯基的化合物，（B）阳离子聚合性化合物，（C）阳离子聚合引发剂，（D）自由基聚合性化合物，（E）自由基聚合引发剂，（F ）聚醚多元醇化合物。

2. 发明申请

US20070203258A1 Curable Liquid Resin Composition 有权
标题翻译：可固化液体树脂组合物
公开(公告)号：US20070203258A1
公开(公告)日：2007-08-30
申请号：US10571758
申请日：2004-09-17
申请人： Masanobu Sugimoto , Satoshi Kamo , Takeo Shigemoto , Zen Komiya , Paulus Steeman
发明人： Masanobu Sugimoto , Satoshi Kamo , Takeo Shigemoto , Zen Komiya , Paulus Steeman
IPC分类号： C09D11/00 , C08G18/00
CPC分类号： C08G18/672 , C03C25/1061 , C03C25/1065 , C08G18/4854 , C08L75/16 , C09D175/16 , Y10T428/2933 , C08G18/48 , C08L2666/14
摘要： The invention relates to a curable liquid resin composition comprising: (A) a urethane(meth)acrylate having a structure originating from a polyol and a number average molecular weight of 800 g/mol or more, but less than 6,000 g/mol, and (B) a urethane(meth)acrylate having a structure originating from a polyol and a number average molecular weight of 6,000 g/mol or more, but less than 20,000 g/mol, wherein the total amount of the component (A) and component (B) is 20-95 wt % of the curable liquid resin composition and the content of the component (B) is 0.1-30 wt % of the total of the component (A) and component (B).
摘要翻译：本发明涉及一种可固化液体树脂组合物，其包含：（A）具有起始于多元醇的结构和数均分子量为800g / mol以上但小于6,000g / mol的氨基甲酸酯（甲基）丙烯酸酯，以及（B）具有来自多元醇的结构和数均分子量为6000g / mol以上但小于20,000g / mol的氨基甲酸酯（甲基）丙烯酸酯，其中组分（A）和组分（B）为可固化液体树脂组合物的20-95重量％，组分（B）的含量为组分（A）和组分（B）的总量的0.1-30重量％。

3. 发明授权

US5053471A Transparent resin material 失效
标题翻译：透明树脂材料
公开(公告)号：US5053471A
公开(公告)日：1991-10-01
申请号：US613939
申请日：1990-11-13
申请人： Kohei Goto , Zen Komiya , Noboru Yamahara , Akira Iio
发明人： Kohei Goto , Zen Komiya , Noboru Yamahara , Akira Iio
IPC分类号： C08G61/08 , C08L65/00
CPC分类号： C08L65/00 , C08G61/08 , G11B7/2538
摘要： A transparent resin material consisting of a (co)polymer obtained by subjecting at least one compound represented by the general formula (I) or a combination of said compound and other copolymerizable monomer to metathesis polymerization, or a hydrogenation product of the (co)polymer: ##STR1## wherein A and B are independently hydrogen atoms or C.sub.1-10 hydrocarbon groups; X and Y are independently hydrogen atoms, C.sub.1-10 hydrocarbon groups, halogen atoms, halogen-substituted C.sub.1-10 hydrocarbon groups, --(CH.sub.2).sub.n COOR.sup.1, --(CH.sub.2).sub.n OCOR.sup.1, --(CH.sub.2).sub.n OR.sup.1, --(CH.sub.2).sub.n CN, --(CH.sub.2).sub.n CONR.sup.2 R.sup.3, --(CH.sub.2).sub.n COOZ, --(CH.sub.2).sub.n OCOZ, --(CH.sub.2).sub.n OZ or --(CH.sub.2).sub.n W [R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently C.sub.1-20 hydrocarbon groups, Z is a halogen-substituted hydrocarbon group, W is SiR.sub.p.sup.5 D.sub.3-p (R.sup.5 is a C.sub.1-10 hydrocarbon group, D is a halogen atom, --OCOR.sup.5 or --OR.sup.5, p is 0 or an integer of 1-3), n is 0 or an integer of 1-10] with the proviso that at least one of X and Y is selected from the above groups other than the hydrogen atom and the hydrocarbon groups, or X and Y may form together ##STR2## and m is 0 or 1. Said transparent resin material is moldable and has sufficient optical properties, low hygroscopicity, good heat resistance and excellent adhesion to recording layer.

4. 发明授权

US08242202B2 Curable liquid resin composition 有权
标题翻译：可固化液体树脂组合物
公开(公告)号：US08242202B2
公开(公告)日：2012-08-14
申请号：US10592490
申请日：2005-03-15
申请人： Hiroshi Yamaguchi , Satoshi Kamo , Takeo Shigemoto , Zen Komiya
发明人： Hiroshi Yamaguchi , Satoshi Kamo , Takeo Shigemoto , Zen Komiya
IPC分类号： C09D11/00 , C08G18/00 , B32B15/00 , C08L75/00 , C08F283/04
CPC分类号： C03C25/106 , C08G18/12 , C08G18/672 , C08G18/8175 , C09D175/16 , Y10T428/2933 , C08G18/48
摘要： The invention relates to a curable liquid resin composition comprising the following components (A), (B), and (C): (A) a urethane (meth)acrylate oligomer, (B) a monomer shown by the following formula (1), CH2═CR1COOR2 (1) wherein R1 represents a hydrogen atom or a methyl group and R2 represents a monovalent organic group, 40 wt % or more of the total amount of the component (B) being a monomer in which the R2 group in the formula (1) is a nonpolar organic group, and the monomer in the component (B) in which the R2 group in the formula (1) is a nonpolar organic group being hereinafter referred to as “nonpolar (meth)acrylate-containing monomer”, and (C) a polymerization initiator.
摘要翻译：本发明涉及一种包含以下组分（A），（B）和（C）的可固化液体树脂组合物：（A）氨基甲酸酯（甲基）丙烯酸酯低聚物，（B）由下式（1），CH2 = CR1COOR2（1）其中R1表示氢原子或甲基，R2表示一价有机基团，作为单体的组分（B）的总量的40重量％以上，其中，式（1）为非极性有机基团，式（1）中的R 2基为非极性有机基团的成分（B）中的单体以下称为“含有非极性（甲基）丙烯酸酯的单体” ，（C）聚合引发剂。

5. 发明申请

US20080254288A1 Curable Liquid Resin Composition 有权
标题翻译：可固化液体树脂组合物
公开(公告)号：US20080254288A1
公开(公告)日：2008-10-16
申请号：US10592490
申请日：2005-03-15
申请人： Hiroshi Yamaguchi , Satoshi Kamo , Takeo Shigemoto , Zen Komiya
发明人： Hiroshi Yamaguchi , Satoshi Kamo , Takeo Shigemoto , Zen Komiya
IPC分类号： B32B27/40 , C08L75/00
CPC分类号： C03C25/106 , C08G18/12 , C08G18/672 , C08G18/8175 , C09D175/16 , Y10T428/2933 , C08G18/48
摘要： The invention relates to a curable liquid resin composition comprising the following components (A), (B), and (C): (A) a urethane (meth)acrylate oligomer, (B) a monomer shown by the following formula (1), CH2═CR1COOR2 (1) wherein R1 represents a hydrogen atom or a methyl group and R2 represents a monovalent organic group, 40 wt % or more of the total amount of the component (B) being a monomer in which the R2 group in the formula (1) is a nonpolar organic group, and the monomer in the component (B) in which the R2 group in the formula (1) is a nonpolar organic group being hereinafter referred to as “nonpolar (meth)acrylate-containing monomer”, and (C) a polymerization initiator.
摘要翻译：本发明涉及一种包含以下组分（A），（B）和（C）的可固化液体树脂组合物：（A）氨基甲酸酯（甲基）丙烯酸酯低聚物，（B）由下式（1），其中R 1表示氢原子或甲基（CH 2）2，其中R 1表示氢原子或甲基 R 2表示一价有机基团，作为单体的成分（B）的总量的40重量％以上，式中R 2〜（1）是非极性有机基团，式（1）中的R 2-2基团为非极性有机基团的成分（B）中的单体以下称为“非极性（（C）聚合引发剂。

6. 发明申请

US20060128856A1 Liquid curable resin composition 审中-公开
标题翻译：液体固化树脂组合物
公开(公告)号：US20060128856A1
公开(公告)日：2006-06-15
申请号：US10529180
申请日：2003-09-29
申请人： Atsuya Takahashi , Junji Yoshizawa , Masakatsu Ukon , Zen Komiya
发明人： Atsuya Takahashi , Junji Yoshizawa , Masakatsu Ukon , Zen Komiya
IPC分类号： C08L93/00
CPC分类号： C09J175/16 , C08F290/067
摘要： Provided is a liquid curing resin composition exhibiting excellent adhesion to PET-PET, MS-PET and the like, having excellent processability, heat resistance and water resistance, and having a high-cure rate. A liquid curing resin composition containing the following components (A) and (B): (A) 30 to 70 wt. % of a urethane (meth)acrylate having a number-average molecular weight of from 10000 to 40000, and (B) 30 to 60 wt. % of an ethylenically unsaturated monomer having a glass transition point, in the form of a homopolymer, of 60° C. or greater.
摘要翻译：本发明提供对PET-PET，MS-PET等具有优异的加工性，耐热性和耐水性优异且固化率高的液体固化性树脂组合物。含有下列组分（A）和（B）的液体固化树脂组合物：（A）30至70重量％％的数均分子量为10000〜40000的氨基甲酸酯（甲基）丙烯酸酯，（B）30〜60重量％％的具有60℃或更高的均聚物形式的具有玻璃化转变点的烯属不饱和单体。

7. 发明申请

US20050282938A1 Curable liquid resin composition 审中-公开
标题翻译：可固化液体树脂组合物
公开(公告)号：US20050282938A1
公开(公告)日：2005-12-22
申请号：US11079480
申请日：2005-03-15
申请人： Hiroshi Yamaguchi , Masanobu Sugimoto , Satoshi Kamo , Zen Komiya
发明人： Hiroshi Yamaguchi , Masanobu Sugimoto , Satoshi Kamo , Zen Komiya
IPC分类号： B05D1/36 , C08F290/06 , C08G18/67 , C09D5/18 , C09D7/12 , C09D155/00 , C09D175/14 , C09D175/16 , G02B6/44
CPC分类号： C09D175/16 , C08G18/672 , G02B6/4402 , G02B6/4436 , G02B6/4438 , C08G18/48
摘要： The invention relates to a curable liquid resin composition which exhibits excellent curability, can be applied at high speed, and produces a cured product having a Young's modulus appropriate for the upjacket layer and excellent coating removal properties of the upjacket layer. The curable liquid resin composition according to the invention comprises: (A) a urethane (meth)acrylate, (B) a reactive diluent, (C) a polymerization initiator, and (D) particles with a number average particle size of 0.1-100 μm.
摘要翻译：本发明涉及一种显示出优异的固化性的可固化液体树脂组合物，可以高速施加，并且可以生产具有适合于鞋面层的杨氏模量和优异的鞋面层的涂层去除性能的固化产物。根据本发明的可固化液体树脂组合物包含：（A）氨基甲酸酯（甲基）丙烯酸酯，（B）反应性稀释剂，（C）聚合引发剂，和（D）数均粒径为0.1-100 妈妈

8. 发明申请

US20050256287A1 Curable liquid resin composition 审中-公开
标题翻译：可固化液体树脂组合物
公开(公告)号：US20050256287A1
公开(公告)日：2005-11-17
申请号：US10504863
申请日：2003-02-17
申请人： Masanobu Sugimoto , Hideki Sugimoto , Zen Komiya , Takashi Ukachi
发明人： Masanobu Sugimoto , Hideki Sugimoto , Zen Komiya , Takashi Ukachi
IPC分类号： G02B6/44 , C03C25/10 , C08F290/06 , C08G18/48 , C08G18/67 , C09D175/16 , C08G18/00
CPC分类号： C09D175/16 , C03C25/106 , C08G18/4808 , C08G18/672 , C08G18/48
摘要： The present invention discusses a curable liquid resin composition comprising a urethane (meth)acrylate obtained by using as polyol components (i) a polyether polyol comprising a structure according to formula (1): —CH2CH(CH3)O—, (ii) a polyether polyol having a cyclic structure and optionally (iii) one or more other polyols. The present invention also discusses a curable liquid resin composition which produces a cured product having high elasticity and high elongation suitable as a secondary material, in particular, as a ribbon matrix material can be provided.
摘要翻译：本发明讨论了包含通过使用多元醇组分（i）包含根据式（1）的结构的聚醚多元醇获得的氨基甲酸酯（甲基）丙烯酸酯的可固化液体树脂组合物：-CH 2 CH 2 CH 3）O-，（ii）具有环状结构的聚醚多元醇和任选地（iii）一种或多种其它多元醇。本发明还讨论了可以提供适合作为二次材料的具有高弹性和高伸长率的固化产物的可固化液体树脂组合物，特别是可以提供带状基质材料。

9. 发明授权

US06319603B1 Liquid curable resin composition 有权
标题翻译：液体固化树脂组合物
公开(公告)号：US06319603B1
公开(公告)日：2001-11-20
申请号：US09260507
申请日：1999-03-02
申请人： Zen Komiya , Yoshikazu Yamaguchi , Tsuyoshi Watanabe , Takashi Ukachi
发明人： Zen Komiya , Yoshikazu Yamaguchi , Tsuyoshi Watanabe , Takashi Ukachi
IPC分类号： G02B604
CPC分类号： G03F7/038 , C03C25/106 , C08F265/06 , C08G59/68 , C08L63/00 , C09D151/003 , G03F7/032 , Y10T428/2938 , C08L2666/04 , C08F222/1006 , C08F2220/1825 , C08F220/14 , C08F220/32
摘要： A liquid curable resin composition comprising (1) a (meth)acrylate polymer having a weight average molecular weight relative to polystyrene standard of at least about 5,000, (2) a ring-opening polymerizable monomer containing at least one epoxy group, and (3) a cationic photopolymerization initiator is disclosed. The composition produces cured products which exhibit superior heat resistance, excellent mechanical strength, and superb adhesive characteristics, and is suitable for use as a photo-curable adhesive, a photo-curable sealing material, a resin for optical three-dimensional molding, and a coating material for optical fibers, and optical fiber ribbon matrix.
摘要翻译：一种液体可固化树脂组合物，其包含（1）相对于聚苯乙烯标准重均分子量为至少约5,000的（甲基）丙烯酸酯聚合物，（2）含有至少一个环氧基的开环聚合单体和（3 ）阳离子光聚合引发剂。该组合物产生显示出优异的耐热性，优异的机械强度和极好的粘合特性的固化产物，并且适合用作光固化性粘合剂，光固化型密封材料，光学三维成型用树脂和光纤涂层材料和光纤带状基体。

10. 发明授权

US06180741B2 Liquid curable resin composition 失效
标题翻译：液体固化树脂组合物
公开(公告)号：US06180741B2
公开(公告)日：2001-01-30
申请号：US09413883
申请日：1999-10-07
申请人： Yoshikazu Yamaguchi , Zen Komiya , Takashi Ukachi
发明人： Yoshikazu Yamaguchi , Zen Komiya , Takashi Ukachi
IPC分类号： C08G77458
CPC分类号： G02B1/046 , C08G18/61 , C08G18/672 , C08L83/08 , C09D4/06 , C08G18/6674 , C08L83/00 , C08F290/148 , C08F290/147
摘要： A liquid curable resin composition exhibiting superior storing stability and suitable for use as a material for optical fiber ribbon matrix, a bundling material, and a material for up-jacketing fibers. The composition contains a first polydimethylsiloxane compound which contains (i) at least two urethane bonds, (ii) an unreactive organic group attached to at least one end of the first polydimethyl-siloxane, and (iii) a (meth)acrylol group attached to at least one end of the first polydimethylsiloxane, and a second polydimethylsiloxane compound which contains (i) at least two urethane bonds and (ii) an unreactive organic group attached to at least one end of the second polydimethylsiloxane, and optionally a third polysiloxane compound which does not contain urethane bonds.
摘要翻译：一种液体固化树脂组合物，其显示出优良的储存稳定性，适合用作光纤带状基体材料，捆扎材料和上覆纤维材料。该组合物包含第一聚二甲基硅氧烷化合物，其包含（i）至少两个氨基甲酸酯键，（ii）连接至第一聚二甲基硅氧烷的至少一个末端的非反应性有机基团，和（iii）（甲基）丙烯酰基第一聚二甲基硅氧烷的至少一个末端和第二聚二甲基硅氧烷化合物，其包含（i）至少两个氨基甲酸酯键和（ii）连接到第二聚二甲基硅氧烷的至少一个末端的非反应性有机基团，以及任选的第三聚硅氧烷化合物，不含氨基甲酸酯键。

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