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    • 11. 发明授权
    • Compositions for souring and softening laundered textile materials, and
stock solutions prepared therefrom
    • 洗涤和软化洗涤纺织材料的组合物,以及由其制备的储备溶液
    • US4426304A
    • 1984-01-17
    • US743970
    • 1976-11-22
    • John D. CikoJohn J. CramerGeoffrey A. Jamieson
    • John D. CikoJohn J. CramerGeoffrey A. Jamieson
    • D06M11/78D06M11/79D06M13/342D06M13/46C11D7/32
    • D06M13/461D06M11/78D06M11/79D06M13/342
    • Liquid and solid compositions are provided for souring and imparting softness to freshly laundered textile materials. When in the form of a stable homogeneous liquid, the composition may contain (a) a quaternized fatty amide, an aqueous emulsion of partially oxidized polyethylene or a fatty amphoteric compound as the softening agent, (b) hydrofluorosilicic acid, ammonium silicofluoride, zinc silicofluoride, ammonium acid fluoride, potassium acid fluoride, or orthophosphoric acid as the souring agent, and (c) water. When in the form of a stable dry solid, the composition may contain (a) a quaternized fatty amide or fatty amphoteric compound as the softening agent, and (b) ammonium silicofluoride, potassium silicofluoride, sodium silicofluoride, zinc silicofluoride, ammonium acid fluoride, sodium acid fluoride or potassium acid fluoride. A method of preparing the liquid composition is provided which insures that it remains stable and homogeneous while awaiting use. Stable homogeneous aqueous stock solutions are also prepared from the liquid or solid compositions of the invention.
    • 提供液体和固体组合物用于酸洗和赋予新鲜洗涤的纺织材料柔软度。 当以稳定均匀液体的形式时,组合物可以含有(a)季铵化脂肪酰胺,部分氧化聚乙烯的水乳液或作为软化剂的脂肪两性化合物,(b)氢氟硅酸,氟硅酸铵,氟化硅硅 ,氟化铵,酸式氟化钾或正磷酸作为酸化剂,和(c)水。 当以稳定的干固体形式时,组合物可以含有(a)季铵化脂肪酰胺或脂肪两性化合物作为软化剂,和(b)氟硅化铵,氟硅化钾,氟硅烷,氟化硅锌,氟化铵, 氟化钠或氟化钾。 提供了制备液体组合物的方法,其确保其在等待使用时保持稳定和均匀。 本发明的液体或固体组合物也制备稳定的均匀含水溶液。
    • 13. 发明授权
    • Liquid laundry detergent comprising a nonionic surfactant and an
alkanolamine
    • 含有非离子表面活性剂和链烷醇胺的液体衣物洗涤剂
    • US4202800A
    • 1980-05-13
    • US812452
    • 1977-07-05
    • John D. CikoRobert A. WardJohn J. Cramer
    • John D. CikoRobert A. WardJohn J. Cramer
    • C11D1/722C11D3/22C11D3/30C11D17/00C11D1/66
    • C11D1/722C11D3/225C11D3/30
    • Excellent liquid laundry-detergent compositions are obtained by combining (1) alkanolamine, (2) nonionic surfactant, (3) sodium carboxymethylcellulose, (4) fabric brightener(s), (5) solvent, and (6) water. The preferred compositions of the invention also usually contain optional ingredients, such as dyes and perfumes. The alkanolamines promote the action of the nonionic surfactants. Moreover, it is desirable to use some triethanolamine for its stabilizing effect. The mixture of alkanolamine and nonionic surfactants is compatible with sodium carboxymethylcellulose, an excellent agent for avoiding redeposition of soil. The compositions according to the invention have good detergent activity when used at temperatures such as 49 to 60 degrees Centigrade. They afford a liquid laundry detergent which is at least as active, pound for pound, as powder laundry detergents now in common use.
    • 通过混合(1)链烷醇胺,(2)非离子表面活性剂,(3)羧甲基纤维素钠,(4)织物增白剂,(5)溶剂和(6)水,得到优良的液体洗衣洗涤剂组合物。 本发明的优选组合物通常还含有任选的成分,例如染料和香料。 链烷醇胺促进非离子表面活性剂的作用。 此外,优选使用一些三乙醇胺作为其稳定效果。 链烷醇胺和非离子表面活性剂的混合物与羧甲基纤维素钠相容,羧甲基纤维素是避免土壤再沉积的优良剂。 当在诸如49至60摄氏度的温度下使用时,根据本发明的组合物具有良好的洗涤剂活性。 它们提供液体洗衣洗涤剂,其至少与现在常用的粉末洗衣洗涤剂一样活跃,磅重。
    • 14. 发明授权
    • Compositions for souring and softening laundered textile materials,
method of preparing the same, and stock solutions prepared therefrom
    • 用于洗涤和洗涤织物的组合物,其制备方法及其制备的储存溶液
    • US4053423A
    • 1977-10-11
    • US545382
    • 1975-01-30
    • John D. CikoJohn J. CramerGeoffrey A. Jamieson
    • John D. CikoJohn J. CramerGeoffrey A. Jamieson
    • C11D3/00D06M11/78D06M11/79D06M13/342D06M13/46D06M13/38
    • D06M11/79C11D3/0015D06M11/78D06M13/342D06M13/461
    • Liquid and solid compositions are provided for souring and imparting softness to freshly laundered textile meterials. When in the form of a stable homogeneous liquid, the composition may contain (a) a quaternized fatty amide, an aqueous emulsion of partially oxidized polyethylene or a fatty amphoteric compound as the siftening agent, (b) hydrofluorosilicic acid, ammonium silicofluoride, zinc silicofluoride, ammonium acid fluoride, potassium acid fluoride, or orthophosphoric acid as the souring agent, and (c) water. When in the form of a stable dry solid, the composition may contain (a) a quaternized fatty amide or fatty amphoteric compound as the softening agent, and (b) ammonium silicofluoride, potassium silicofluoride, sodium silicofluoride, zinc silicofluroide, ammonium acid fluoride, sodium acid fluoride or potassium acid fluoride. A method of preparing the liquid composition is provided which insures that it remains stable and homogeneous while awaiting use. Stable homogeneous aqueous stock solutions are also prepared from the liquid or solid compositions of the invention.
    • 提供液体和固体组合物用于酸洗和赋予新鲜洗涤的纺织材料柔软度。 当以稳定均匀液体的形式时,组合物可以含有(a)季铵化脂肪酰胺,部分氧化聚乙烯的水乳液或作为软化剂的脂肪两性化合物,(b)氢氟硅酸,氟硅酸铵,氟化硅硅 ,氟化铵,酸式氟化钾或正磷酸作为酸化剂,和(c)水。 当以稳定的干固体形式时,该组合物可含有(a)季铵化脂肪酰胺或脂肪两性化合物作为软化剂,和(b)氟化硅铵,氟硅化钾,氟硅烷,氟化硅锌,氟化铵, 氟化钠或氟化钾。 提供了制备液体组合物的方法,其确保其在等待使用时保持稳定和均匀。 本发明的液体或固体组合物也制备稳定的均匀含水溶液。
    • 15. 发明授权
    • Method of imparting nondurable soil release and soil repellency
properties to textile materials
    • 赋予纺织材料无污垢释放和防污性能的方法
    • US4007305A
    • 1977-02-08
    • US535264
    • 1974-12-23
    • Sarwan K. KakarFrank R. KapplerGilbert S. GomesJohn J. Cramer
    • Sarwan K. KakarFrank R. KapplerGilbert S. GomesJohn J. Cramer
    • C11D3/00D06M15/09D06M15/263D06M15/277B05D3/00
    • D06M15/263C11D3/0036D06M15/09D06M15/277Y10T428/2965Y10T428/2969Y10T442/2287
    • Textile materials are treated with an alkaline aqueous medium having a pH value of 7.5-11 and containing 0.25-4% by weight of a dissolved water soluble hydrophilic soil release polymer having carboxylic acid groups and 0.05-1% by weight of a dispersed hydrophobic soil repellent fluorochemical. The soil release polymer and the soil repellent fluorochemical are deposited on the surfaces of the textile fibers and the resulting textile material is dried to impart the desired nondurable soil release and soil repellency properties. The aqueous medium also may contain polyvinylpyrrolidone to further improve the finish. In a preferred variant, the textile material is first contacted with an alkaline aqueous solution of the soil release polymer, and thereafter with an alkaline aqueous medium containing the dispersed soil repellent fluorochemical to reduce the tendency of the deposited soil release polymer to cover the deposited soil repellent fluorochemical molecules. A method of laundering soiled textile material is also provided wherein the washed and rinsed textile material is treated in accordance with the aforementioned method to impart nondurable soil release and soil repellency properties. The treated textile material is provided as a novel product.
    • 纺织材料用pH值为7.5-11的碱性水性介质处理,含有0.25-4重量%的具有羧酸基团的溶解的水溶性亲水污垢释放聚合物和0.05-1重量%的分散的疏水性土壤 驱避氟化物。 将污垢释放聚合物和防污氟化物沉积在纺织纤维的表面上,并将所得的纺织材料干燥以赋予所需的不可剥离的污垢释放和防污性能。 水性介质还可以含有聚乙烯吡咯烷酮以进一步改善涂饰。 在优选的变型中,纺织材料首先与去污聚合物的碱性水溶液接触,然后与含有分散的防污氟化物的碱性水性介质接触,以降低沉积的污垢释放聚合物覆盖沉积的土壤的趋势 排斥性氟化物分子。 还提供了洗涤污染的纺织材料的方法,其中根据上述方法处理洗涤和漂洗的纺织材料以赋予不可持续的污垢释放和防污性能。 经处理的纺织材料作为新产品提供。