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    • 3. 发明授权
    • Agent for textile livening with an antistatic effect and favorable
dermatologic properties
    • 用于纺织品的抗菌剂具有抗静电效果和良好的皮肤病学特性
    • US4326966A
    • 1982-04-27
    • US158692
    • 1980-06-12
    • Jan NovakMiloslav SormKarel UlbertStanislav NespurekDagmar MikulcovaJiri Cmolik
    • Jan NovakMiloslav SormKarel UlbertStanislav NespurekDagmar MikulcovaJiri Cmolik
    • D06M13/368D06M13/38
    • D06M13/368
    • The invention pertains to the textile livening agent with the antistatic effect and favorable dermatologic properties which contains softening, stabilizing, whitening, coloring, scenting and dermatologic components, anionactive, nonionogenic and cationactive tensides and other additives and 2-50 (preferably 4-25) wt. % of 3-(hydroxyalkylamino)-2-hydroxypropyl esters of fatty acids of the general formula RCOOCH.sub.2 CH(OH)CH.sub.2 N(R.sub.1 R.sub.2), where R are the C.sub.16 -C.sub.22 alkyls or alkenyls, R.sub.1 is H, CH.sub.2 CH.sub.2 OH, CH.sub.2 CH.sub.2 CH.sub.2 OH, CH.sub.3 CHCH.sub.2 OH, CH.sub.2 CH(OH)CH.sub.3, CH.sub.3 CH.sub.2 CHCH.sub.2 OH, CH.sub.3 CHCH.sub.2 CH.sub.2 OH, CH.sub.2 CH.sub.2 CH.sub.2 CH.sub.2 OH, or CH.sub.3 CHCH(OH)CH.sub.3, and R.sub.2 is the same substituent as R.sub.1 except for H. The agent serves for the repeated regeneration of antistatic and other properties of fabrics made of synthetic fibers and is applied to washed and rinsed fabrics by a short-termed soaking, moderate squeeze and drying. The surface electric resistivity of the fabrics is effectively reduced even at the low humidity of environment already by a very small amount of the agent. The said agent is not toxic and its effect is not reduced even by certain amounts of anion-active detergents retained by fabric after incomplete rinsing.
    • 本发明涉及具有抗静电效果和有利的皮肤病学特性的纺织活性剂,其含有软化,稳定,增白,着色,香味和皮肤病学成分,阴离子活性,非离子和阳离子表面活性剂和其它添加剂,并且2-50(优选4-25) 重量 %的通式为RCOOCH 2 CH(OH)CH 2 N(R 1 R 2)的脂肪酸的3-(羟基烷基氨基)-2-羟丙基酯,其中R是C16-C22烷基或烯基,R1是H,CH2CH2OH,CH2CH2CH2OH,CH3CHCH2OH,CH2CH (OH)CH 3,CH 3 CH 2 CHCH 2 OH,CH 3 CHCH 2 CH 2 OH,CH 2 CH 2 CH 2 CH 2 OH或CH 3 CHCH(OH)CH 3,并且R 2除了H外,与R 1相同。取代基用于反复再生由合成纤维制成的织物的抗静电和其它性能, 通过短期浸泡,中等挤压和干燥将其施加到洗涤和漂洗的织物上。 即使在环境的低湿度下,织物的表面电阻率也可以通过极少量的试剂有效降低。 所述试剂无毒,即使在不完全冲洗后由织物保留的某些量的阴离子活性洗涤剂也不会降低其效果。
    • 4. 发明授权
    • Aqueous preparations for treating textile substrates comprising
regenerated cellulose
    • 用于处理包含再生纤维素的织物基材的水性制剂
    • US4200564A
    • 1980-04-29
    • US952359
    • 1978-10-18
    • Paul KomminothTibor RobinsonMilica Urosevic
    • Paul KomminothTibor RobinsonMilica Urosevic
    • D06M15/423D06M13/14D06M13/22D06M13/38
    • D06M15/423
    • Disclosed is a treatment process for textile substrates comprising or consisting of regenerated cellulose, which process comprises applying to the substrate an aqueous medium comprising (A) a monomeric, hydrolysis stable, hydrosoluble, resin forming cross linking agent containing at least two N-methylol or N-alkoxymethyl groups, (B) a hydrosoluble, prepolymerized, linear, filler resin forming, cross-linking agent, also containing at least two N-methylol or N-alkoxymethyl groups, (C) a reactive acetal of formula ##STR1## wherein X and Y, independently, are H or CH.sub.2 OH, (D) a first cross-linking catalyst, being an alkaline earth metal salt of a strong acid and (E) a second cross-linking catalyst, being an acidic aluminium salt, subsequently drying the substrate and subjecting same to a temperature at which cross-linking takes place, and an aqueous concentrate for use therein.
    • 公开了一种用于包含再生纤维素或由再生纤维素组成的织物基材的处理方法,该方法包括向基材施加水性介质,该水性介质包含(A)单体,水解稳定的,可水解的树脂形成交联剂,其含有至少两个N-羟甲基或 N-烷氧基甲基,(B)还含有至少两个N-羟甲基或N-烷氧基甲基的水溶性预聚合的线性填料树脂形成交联剂,(C)式(IMA)的反应性缩醛,其中 X和Y独立地是H或CH 2 OH,(D)作为强酸的碱土金属盐的第一交联催化剂和(E)第二交联催化剂,作为酸性铝盐,随后干燥 该基底并经受相当于发生交联的温度,以及其中使用的含水浓缩物。
    • 6. 发明授权
    • Surface modification of polymeric substrates via interaction with azido
formyl or azido sulfonyl compounds
    • 通过与叠氮基甲酰基或叠氮基磺酰基化合物的相互作用来表面改性聚合物底物
    • US4099910A
    • 1978-07-11
    • US820050
    • 1977-07-29
    • John E. Herweh
    • John E. Herweh
    • D06M13/08D06M13/322D06M13/38
    • C07C247/00D06M13/322
    • Azido formyl or azido sulfonyl compounds are provided by compounds of the formula R(CH.sub.2).sub.m X wherein R represents a fluorocarbon or an alkoxy alkyl chain and X represents a sulphonazide or azidoformate group and m is an integer greater than 1. The R group may be C.sub.2 to C.sub.12 linear or branched alkyl, C.sub.2 to C.sub.12 linear or branched alkoxy substituted C.sub.2 to C.sub.12 alkyl, or C.sub.2 to C.sub.12 linear or branched fluoroalkyl. The group (CH.sub.2).sub.m is C.sub.2 to C.sub.10 linear or branched alkylene. These materials upon thermolysis give rise to a reactive intermediate which adds to and protects polymeric substrates such including polyethylene, polypropylene, polystyrene, the natural rubbers, polyamides, polyesters, polybutadienes, polyisoprenes, butadiene-isoprene copolymer, butyl rubber, ethylene-propylene copolymer, ethylene-propylene-dicyclopentadiene terpolymer, and the like, as well as blends thereof.
    • 叠氮基甲酰基或叠氮基磺酰基化合物由式R(CH 2)m X的化合物提供,其中R表示碳氟化合物或烷氧基烷基链,X表示磺酰叠氮基或叠氮基甲酸酯基,m是大于1的整数.R基团可以是 C 2至C 12直链或支链烷基,C 2至C 12直链或支链烷氧基取代的C 2至C 12烷基,或C 2至C 12直链或支链氟烷基。 基团(CH 2)m是C 2至C 10直链或支链亚烷基。 这些材料在热分解时产生反应性中间体,其添加并保护聚合物基质,例如聚乙烯,聚丙烯,聚苯乙烯,天然橡胶,聚酰胺,聚酯,聚丁二烯,聚异戊二烯,丁二烯 - 异戊二烯共聚物,丁基橡胶,乙烯 - 丙烯共聚物, 乙烯 - 丙烯 - 二环戊二烯三元共聚物等,以及它们的共混物。
    • 7. 发明授权
    • Compositions for souring and softening laundered textile materials,
method of preparing the same, and stock solutions prepared therefrom
    • 用于洗涤和洗涤织物的组合物,其制备方法及其制备的储存溶液
    • US4053423A
    • 1977-10-11
    • US545382
    • 1975-01-30
    • John D. CikoJohn J. CramerGeoffrey A. Jamieson
    • John D. CikoJohn J. CramerGeoffrey A. Jamieson
    • C11D3/00D06M11/78D06M11/79D06M13/342D06M13/46D06M13/38
    • D06M11/79C11D3/0015D06M11/78D06M13/342D06M13/461
    • Liquid and solid compositions are provided for souring and imparting softness to freshly laundered textile meterials. When in the form of a stable homogeneous liquid, the composition may contain (a) a quaternized fatty amide, an aqueous emulsion of partially oxidized polyethylene or a fatty amphoteric compound as the siftening agent, (b) hydrofluorosilicic acid, ammonium silicofluoride, zinc silicofluoride, ammonium acid fluoride, potassium acid fluoride, or orthophosphoric acid as the souring agent, and (c) water. When in the form of a stable dry solid, the composition may contain (a) a quaternized fatty amide or fatty amphoteric compound as the softening agent, and (b) ammonium silicofluoride, potassium silicofluoride, sodium silicofluoride, zinc silicofluroide, ammonium acid fluoride, sodium acid fluoride or potassium acid fluoride. A method of preparing the liquid composition is provided which insures that it remains stable and homogeneous while awaiting use. Stable homogeneous aqueous stock solutions are also prepared from the liquid or solid compositions of the invention.
    • 提供液体和固体组合物用于酸洗和赋予新鲜洗涤的纺织材料柔软度。 当以稳定均匀液体的形式时,组合物可以含有(a)季铵化脂肪酰胺,部分氧化聚乙烯的水乳液或作为软化剂的脂肪两性化合物,(b)氢氟硅酸,氟硅酸铵,氟化硅硅 ,氟化铵,酸式氟化钾或正磷酸作为酸化剂,和(c)水。 当以稳定的干固体形式时,该组合物可含有(a)季铵化脂肪酰胺或脂肪两性化合物作为软化剂,和(b)氟化硅铵,氟硅化钾,氟硅烷,氟化硅锌,氟化铵, 氟化钠或氟化钾。 提供了制备液体组合物的方法,其确保其在等待使用时保持稳定和均匀。 本发明的液体或固体组合物也制备稳定的均匀含水溶液。
    • 8. 发明授权
    • Organic antistatic composition
    • 有机抗静电组合物
    • US3898166A
    • 1975-08-05
    • US32414173
    • 1973-01-16
    • GAF CORP
    • COONEY WILLIAM J
    • C09K3/16C08J7/04D06M13/372D06M15/356D06M13/38
    • D06M13/372D06M15/3562
    • An antistatic composition particularly adapted for use on textiles, floor coverings, and related materials, comprising an aqueous liquid fluid medium, having a pH within the range of about 7 to 13 and containing as active ingredient an organic antistatic textile agent and from about 1 to 0.5 parts by weight of a humectant. The humectant may be either a nonionic humectant (such as glycerine) or an ionic humectant (including strong electrolytes such as calcium chloride). When the humectant is nonionic, there must also be present at least 0.01 part by weight of a strong electrolyte, i.e., the salt of a strong base and a strong acid.
    • 一种特别适用于纺织品,地板覆盖物和相关材料的抗静电剂组合物,其包含水性液体介质,其pH值在约7至13范围内,并且作为有效成分含有有机抗静电纺织剂和约1至 0.5重量份的湿润剂。 保湿剂可以是非离子保湿剂(例如甘油)或离子保湿剂(包括强电解质如氯化钙)。 当保湿剂是非离子的时,还必须存在至少0.01重量份的强电解质,即强碱和强酸的盐。
    • 10. 发明授权
    • Detergent-softener compositions containing sulfosuccinates of polyhydroxy tertiary amines
    • 含有多羟基脂肪酸的硫酸酯的洗涤剂组合物
    • US3803036A
    • 1974-04-09
    • US20539671
    • 1971-12-06
    • COLGATE PALMOLIVE CO
    • SUNDBY BWIXON H
    • C07C215/12C07C309/17C11D1/12C11D1/46C11D3/00D06L1/12D06M13/224D06M13/372D06M13/38
    • A61K8/44A61Q5/02C11D1/123C11D1/46C11D3/001Y10S516/04
    • A detergent composition having inherent softening properties consisting essentially of a builder salt and a detergent selected from the group consisting of water-soluble sulfosuccinates of polyhydroxy tertiary amines having the structural formula:

      WHEREIN R1 is a monovalent hydrocarbon radical of 8 to 24, preferably 10 to 20 carbon atoms; R2 is an alkyl or alkylol radical containing 1 to 6 carbon atoms, and R3 is an alkylol radical containing 1 to 6 carbon atoms, and salts thereof. The reaction mixture consists of sulfonated mono-, di-, and/or triesters, depending on the number of reactive hydroxyl groups in the alcoholamine and the amount of dicarboxylic acid utilized. Since the aforedefined sulfonated esters and salts thereof uniquely possess both detergency and softening properties, they may constitute the sole detergent ingredient in the composition, although the presence of other detergents is not precluded.
    • 具有固有软化性质的洗涤剂组合物,其基本上由助洗剂盐和洗涤剂组成,所述助洗剂盐和洗涤剂选自二羧酸的水溶性酯和具有结构式:OHR 2 R 1 CH-CH 2 N-R 3的多羟基叔胺,其中R 1是 8-24个碳原子,优选10-20个碳原子的单价烃基; R2是含有1至6个碳原子的烷基或烷醇基,R3是含有1至6个碳原子的烷醇基,及其盐。 反应混合物由单 - ,二 - 和/或三酯组成,取决于醇胺中反应性羟基的数量和所用二羧酸的量。 由于上述酯和其盐独特地具有洗涤性和软化性,所以它们可以构成组合物中唯一的洗涤剂成分,尽管不排除其它洗涤剂的存在。