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11. 发明授权

US4835314A 2-nitroaniline derivatives 失效
标题翻译： 2-硝基苯胺衍生物
公开(公告)号：US4835314A
公开(公告)日：1989-05-30
申请号：US132789
申请日：1987-12-10
申请人： Eugen Konrad , Thomas Clausen , Hans-Jurgen Braun , Herbert Mager
发明人： Eugen Konrad , Thomas Clausen , Hans-Jurgen Braun , Herbert Mager
IPC分类号： A61K8/00 , A61K8/34 , A61K8/40 , A61K8/41 , A61Q5/06 , A61Q5/10 , C07C211/48 , C07C215/16 , C07C215/48 , C07C215/74 , C09B51/00 , D06P3/08
CPC分类号： A61K8/418 , A61Q5/065
摘要： 2-nitroaniline derivatives of the general formula I: ##STR1## in which R.sup.1 and R.sup.2 represent, independent of one another, hydrogen, an alkyl of 1 to 4 carbon atoms, a monohydroxyalkyl of 2 to 4 carbon atoms or a dihydroxyalkyl of 3 or 4 carbon atoms, provided that R.sup.1 and R.sup.2 do not simultaneously represent alkyl groups of 1 to 4 carbon atoms, and X denotes an alkyl, monohydroxyalkyl, perfluoroalkyl or halogen, for use as an agent in a hair dyeing composition. Also disclosed are new 2-nitroaniline derivatives of the general formula II: ##STR2## in which R.sup.a and R.sup.b denote, independent of one another, ethyl, a monohydroxylalkyl of 2 to 4 carbon atoms or a dihydroxyalkyl of 3 or 4 carbon atoms, when Z is methyl, Cl or Br; or when Z is CH.sub.2 OH or a perfluoroalkyl, R.sup.a denotes hydrogen, a monohydroxyalkyl of 2 to 4 carbon atoms or a dihydroxyalkyl of 3 or 4 carbon atoms, and R.sup.b represents 2-hydroxyethyl or 2,3-dihydroxypropyl.
摘要翻译：通式I的2-硝基苯胺衍生物：其中R 1和R 2彼此独立地表示氢，1至4个碳原子的烷基，2至4个碳原子的单羟基烷基或二羟基烷基 3或4个碳原子，条件是R1和R2不同时代表1至4个碳原子的烷基，X表示烷基，单羟基烷基，全氟烷基或卤素，用作染发组合物中的试剂。还公开了通式II（II）的新的2-硝基苯胺衍生物，其中R a和R b彼此独立地表示乙基，2至4个碳原子的单羟基烷基或3或4个碳的二羟基烷基当Z是甲基时，Cl或Br; 或当Z为CH 2 OH或全氟烷基时，R a表示氢，2至4个碳原子的一羟基烷基或3或4个碳原子的二羟基烷基，R b表示2-羟乙基或2,3-二羟丙基。

12. 发明授权

US4754069A 2-alkyl sulfonyl-1,4-diaminobenzenes, processes for their production and oxidation hair dyeing compositions containing the same 失效
标题翻译： 2-烷基磺酰基-1,4-二氨基苯，其生产和氧化染发组合物的方法
公开(公告)号：US4754069A
公开(公告)日：1988-06-28
申请号：US828351
申请日：1985-12-12
申请人： Hans-Jurgen Braun , Eugen Konrad , Herbert Mager
发明人： Hans-Jurgen Braun , Eugen Konrad , Herbert Mager
IPC分类号： C07C317/18 , A61K8/00 , A61K8/23 , A61K8/33 , A61K8/40 , A61K8/41 , A61K8/46 , A61K8/49 , A61Q5/10 , C07C67/00 , C07C205/11 , C07C205/19 , C07C313/00 , C07C317/04 , C07C317/36 , D06P1/32 , C07C149/42 , A61K7/13
CPC分类号： A61Q5/10 , A61K8/46 , C07C205/11 , C07C205/19 , C07C317/28
摘要： Novel 2-alkyl sulfonyl ethyl-1,4-diaminobenzenes of formula 1 ##STR1## wherein R denotes CH.sub.3 or C.sub.2 H.sub.5 and the salts thereof, a process for making the compositions of formula I as well as compositions for the oxidative dyeing of human hair upon the basis of a developing substance-coupler substance-combination with a content of a composition of formula I as developing substance. The well water soluble developing substances of the formula I result in very natural appearing blond to brown color shades in combination with the coupler substances resorcinol, 4-chororesorcinol,4,6-dichlororesorcinol, 4-hydroxy-1,2-methylenedioxybenzene and 4-amino-1,2-methylenedioxybenzene.
摘要翻译： PCT No.PCT / EP85 / 00222 Sec。 371日期1985年12月12日第 102（e）1985年12月12日日期PCT提交1985年5月13日PCT公布。公开号WO86 / 00303 日期：1986年1月16日。式1的新型2-烷基磺酰基乙基-1,4-二氨基苯其中R表示CH 3或C 2 H 5及其盐，式I化合物的方法作为用于基于显色物质 - 成色剂物质组合的人发氧化染色的组合物，其组合为式I的组成作为显影物质。结构式I的水溶性显影物质与成色剂间苯二酚，4-氯苯酚，4,6-二氯间苯二酚，4-羟基-1,2-亚甲二氧基苯和4- 氨基-1,2-亚甲二氧基苯。

13. 发明授权

US4752467A Hair treatment agent and method for improving the conditon of hair 失效
标题翻译：头发处理剂及改善头发条件的方法
公开(公告)号：US4752467A
公开(公告)日：1988-06-21
申请号：US16988
申请日：1987-02-17
申请人： Eugen Konrad , Herbert Mager , Dietrich Hoch
发明人： Eugen Konrad , Herbert Mager , Dietrich Hoch
IPC分类号： C11D1/90 , A61K8/00 , A61K8/36 , A61K8/362 , A61K8/365 , A61K8/40 , A61K8/44 , A61K31/205 , A61Q5/00 , A61Q5/02 , A61Q5/06 , A61Q5/10 , A61Q5/12 , C11D3/20 , A61K7/075 , A61K7/08
CPC分类号： A61K8/44 , A61K8/362 , A61K8/365 , A61Q5/12
摘要： The subject matter of the invention is an agent and a method for improving the condition of hair on the basis of a combination of 0.1 to 25.0% by weight of trimethyl ammonia acetate betaine of the formula (CH.sub.3).sub.3 N.sup..sym. --CH.sub.2 --COO.sup..crclbar. and 0.1 to 10.0% by weight of at least one aliphatic organic acid as a hair conditioning component. Preferred forms of preparations are a hair conditioning rinse, a hair conditioning emulsion, a hair treatment kit, or a hair strengthener.
摘要翻译：本发明的主题是基于0.1〜25.0重量％的式（CH 3）3 N（+） - CH 2 -COO的三甲基氨基乙酸铵甜菜碱的组合来改善头发状况的试剂和方法（ - ）和0.1〜10.0重量％的作为毛发调理成分的至少一种脂肪族有机酸。优选的制剂形式是头发调理冲洗剂，头发调理乳剂，头发处理试剂盒或毛发加强剂。

14. 发明授权

US4396392A Method for the coloring of hair 失效
标题翻译：毛发着色方法
公开(公告)号：US4396392A
公开(公告)日：1983-08-02
申请号：US127507
申请日：1980-03-05
申请人： Eugen Konrad , Herbert Mager
发明人： Eugen Konrad , Herbert Mager
IPC分类号： A61K8/00 , A61K8/23 , A61K8/33 , A61K8/40 , A61K8/41 , A61K8/46 , A61Q5/10 , A61K7/13
CPC分类号： A61K8/415 , A61Q5/10
摘要： Agents for the oxidative dyeing of hair, containing as coloring component 6-amino-3-methylphenol, also in the form of its salts or phenolates. The coloring component is contained in these agents in a quantity of about 0.01 to 2.0 percent by weight, alone or in a mixture with the customary developing and coupling substances. In the case of a mixture, the 6-amino-3-methylphenol is preferably used at a molar ratio below normal relative to these developing and coupling substances. The oxidative reaction of the 6-amino-3-methylphenol proceeding with an intensive yellow coloring is generally not influenced by the customary developing and coupling substances that may be present.
摘要翻译： PCT No.PCT / EP79 / 00058 Sec。 371日期1980年3月5日 102（e）1980年3月5日PCT PCT。1979年7月25日PCT公布。公开号WO80 / 00303 日期为1980年3月6日。头发的氧化染色剂，其作为着色组分6-氨基-3-甲基苯酚，也以其盐或酚盐的形式。着色组分以单独或与常规显影和偶联物质的混合物的量计含量为约0.01至2.0重量％。在混合物的情况下，相对于这些显影和偶联物质，优选使用6-氨基-3-甲基苯酚的摩尔比低于正常值。进一步强化黄色着色的6-氨基-3-甲基苯酚的氧化反应通常不受常规显影和偶联物质的影响。

15. 发明授权

US4321053A Hair dyeing composition and process 失效
标题翻译：染发组合物及工艺
公开(公告)号：US4321053A
公开(公告)日：1982-03-23
申请号：US115292
申请日：1980-01-25
申请人： Eugen Konrad , Herbert Mager
发明人： Eugen Konrad , Herbert Mager
IPC分类号： A61K20060101 , A61K7/13
CPC分类号： A61Q5/10 , A61K8/347
摘要： A process for preparing a composition, a composition and a process for oxidative dyeing of hair are disclosed. The composition comprises at least one n,5-dihydroxy-1,2,3,4-tetrahydro-naphthalene having the general formula ##STR1## wherein n represents a number from 1,2,3, or 4, and which n,5-dihydroxy-1,2,3,4-tetrahydronaphthalene can be present as such or as a salt of an organic or inorganic base and which n,5-dihydroxy-1,2,3,4-tetrahydro-naphthalene serves as a coupling compound; and at least one developer employed in hair dyeing. Intense and red tinge free blue colorations can be obtained.
摘要翻译：公开了一种用于制备头发氧化染色的组合物，组合物和方法的方法。该组合物包含至少一种具有通式“IMAGE”的n，5-二羟基-1,2,3,4-四氢 - 萘，其中n表示1,2,3或4的数，n，5 - 二羟基-1,2,3,4-四氢萘可以以有机或无机碱的形式存在或作为有机或无机碱的盐存在，并且n，5-二羟基-1,2,3,4-四氢萘用作偶联剂复合; 和至少一名用于染发的开发商。可以获得强烈和红色的无色蓝色。

16. 发明授权

US4134412A Hair setting lotion containing a chitosan derivative 失效
标题翻译：包含壳聚糖衍生物的头发定型乳液
公开(公告)号：US4134412A
公开(公告)日：1979-01-16
申请号：US743290
申请日：1976-11-18
申请人： Paul Gross , Eugen Konrad , Herbert Mager
发明人： Paul Gross , Eugen Konrad , Herbert Mager
IPC分类号： A61K8/00 , A61K8/36 , A61K8/365 , A61K8/73 , A61Q5/06 , A61Q5/10 , A45D7/00 , A61K7/11
CPC分类号： A61Q5/06 , A61K8/736
摘要： Hair setting lotion consisting of an aqueous or aqueous-alcoholic solution of a film-forming resin which contains a water soluble salt of chitosan.
摘要翻译：由含有壳聚糖的水溶性盐的成膜树脂的水溶液或含水醇溶液组成的头发定型乳液。

17. 发明申请

US20070006395A1 Agents containing 4-(2-hydroxyethyl)amino-3-nitro-1-benzotrifluoride for dyeing keratin fibers 审中-公开
标题翻译：含有用于染色角蛋白纤维的4-（2-羟基乙基）氨基-3-硝基-1-苯三氟甲烷的试剂
公开(公告)号：US20070006395A1
公开(公告)日：2007-01-11
申请号：US10545635
申请日：2004-10-19
申请人： Hansruedi Muerner , Herbert Mager
发明人： Hansruedi Muerner , Herbert Mager
IPC分类号： A61K8/00
CPC分类号： A61Q5/10 , A61K8/418
摘要： The composition for coloring keratin fibers contains (a) 4-(2′-hydroxyethyl)amino-3-nitro-1-trifluoromethylbenzene or a salt thereof, (b) one or more developers and (c) one or more couplers. In the method for coloring hair the colorant composition is mixed with an oxidant to form a ready-to-apply colorant and then the ready-to-apply colorant is applied to hair in an amount sufficient for the dyeing of the hair.
摘要翻译：用于着色角蛋白纤维的组合物包含（a）4-（2'-羟乙基）氨基-3-硝基-1-三氟甲基苯或其盐，（b）一种或多种显影剂和（c）一种或多种成色剂。在用于着色毛发的方法中，将着色剂组合物与氧化剂混合以形成即用涂料着色剂，然后将即将施用的着色剂以足以染发头发的量施加到头发上。

18. 发明申请

US20070000072A1 Care hair coloran 审中-公开
标题翻译：护理头发颜色
公开(公告)号：US20070000072A1
公开(公告)日：2007-01-04
申请号：US11357581
申请日：2006-02-17
申请人： Johann Aeby , Herbert Mager , Hans Murner , Magali Bourqui
发明人： Johann Aeby , Herbert Mager , Hans Murner , Magali Bourqui
IPC分类号： A61K8/00
CPC分类号： A61K8/342 , A61K8/06 , A61K8/375 , A61K8/39 , A61Q5/10
摘要： The invention relates to an emulsion-like color carrier mass which comprises (a) water, (b) oxidation color precursors and optionally additionally dyes which attach directly to the hair, (c) at least one nonionic organic thickener with wax-like properties from the group consisting of C12-C24-fatty alcohols and glycerol oleate and mixtures thereof, (d) as nonionic surfactant a mixture of at least one sorbitan fatty acid ester oxyethylated with 4 to 20 mol of ethylene oxide and at least one C12-C24-fatty alcohol oxyethylated with 30 to 70 mol of ethylene oxide, and (e) cosmetically customary cationic resins, and (f) is free from anionic and cationic surfactants.
摘要翻译：本发明涉及一种乳液状着色载体物质，其包含（a）水，（b）氧化颜色前体和任选地附加染料直接附着在毛发上，（c）至少一种具有蜡状特性的非离子有机增稠剂，由C 12 -C 24脂肪醇和甘油油酸酯及其混合物组成的组，（d）作为非离子表面活性剂的至少一种脱水山梨醇脂肪酸酯与4-20摩尔环氧乙烷氧化的脱水山梨醇脂肪酸酯和至少一种C12-C24- 用30-70mol环氧乙烷氧乙基化的脂肪醇，和（e）化妆习惯的阳离子树脂，和（f）不含阴离子和阳离子表面活性剂。

19. 发明授权

US5021066A Oxidative hair dye composition based on a gel vehicle and a process to dye hair 失效
标题翻译：基于凝胶载体的氧化染发剂组合物和染发剂的方法
公开(公告)号：US5021066A
公开(公告)日：1991-06-04
申请号：US449078
申请日：1989-12-08
申请人： Johann Aeby , Herbert Mager , Eugen Konrad
发明人： Johann Aeby , Herbert Mager , Eugen Konrad
IPC分类号： A61K8/00 , A61K8/22 , A61K8/33 , A61K8/34 , A61K8/36 , A61K8/39 , A61K8/40 , A61K8/41 , A61K8/49 , A61Q5/10 , D06P1/32
CPC分类号： A61K8/361 , A61K8/042 , A61K8/342 , A61K8/39 , A61Q5/10
摘要： A composition for the oxidative dyeing of hair based on a gel vehicle and a dye mixture dissolved therein, wherein the gel vehicle containsA) from 12 to 16% by weight of oleic acid,B) from 12 to 30% by weight of nonyl phenol, ethoxylated with from 2 to 6 moles of ethylene oxide, and/or of fatty alcohol, having from 12 to 20 carbon atoms, ethoxylated with from 2 to 6 moles of ethylene oxide,C) from 8 to 14% by weight of fatty alcohol having from 10 to 20 carbon atoms,D) from 4 to 18% by weight of ethanol and/or isopropanol, andE) from 16 to 70% by weight of water.The new composition allows the ammonia it contains to escape more slowly, and it darkens less, when hydrogen peroxide is added, than the known gel hair dye compositions.
摘要翻译：一种用于基于凝胶载体和溶解于其中的染料混合物的毛发的氧化染色的组合物，其中所述凝胶载体含有A）12至16重量％的油酸，B）12至30重量％的壬基苯酚用2至6摩尔环氧乙烷乙氧基化，和/或具有12至20个碳原子的脂肪醇，用2至6摩尔环氧乙烷乙氧基化，C）8至14重量％的脂肪醇具有10至20个碳原子，D）4至18重量％的乙醇和/或异丙醇，和E）16至70重量％的水。新组合物允许其含有的氨更缓慢地逸出，并且当加入过氧化氢时，它比已知的凝胶染发剂组合物变浅。

20. 发明授权

US4755188A Agent and process for the coloring of hair 失效
标题翻译：代理和染发过程
公开(公告)号：US4755188A
公开(公告)日：1988-07-05
申请号：US5256
申请日：1987-01-20
申请人： Eugen Konrad , Hans-Jurgen Braun , Herbert Mager
发明人： Eugen Konrad , Hans-Jurgen Braun , Herbert Mager
IPC分类号： D06P3/08 , A61K8/00 , A61K8/22 , A61K8/23 , A61K8/33 , A61K8/40 , A61K8/41 , A61K8/46 , A61K8/49 , A61Q5/10 , C07C205/19 , A61K7/13
CPC分类号： A61K8/347 , A61Q5/10 , C07C205/19
摘要： A composition and process are disclosed for oxidative coloring of hair on the basis of at least one substituted phenol of the general formula ##STR1## whereby R.sub.1 represents a hydroxy alkyl group with 1 to 4 carbon atoms and R.sub.2 a hydrogen atom or alkyl group with 1 to 4 carbon atoms, or the phenolate thereof, as a coupler substance. The inventive coupler substance, of which 2-hydroxy-methyl-5-methyl-phenol and 3-(.beta.-hydroxy ethyl)-6-methyl-phenol are preferred, should be present in a concentration of about 0.01 to 3.0% by weight, in particular 0.1 to 2.0% by weight. The described coupler substances are active as blue couplers. The obtained color shades are stable, resistant to wear and very well reproducible. They have very favorable characteristics with respect to toxicology and dermatology and do not give the colored hair an unpleasant, penetrating cresolic aroma. The process involves forming an oxidizable developer-coupler combination of a developer substance with the substituted phenol as coupler substance, and an oxidation agent, applying a coloring-effective amount of the combination onto human hair, rinsing the hair after about 10-45 minutes at a temperature between 15.degree. and 50.degree. C., and drying the hair.
摘要翻译：公开了一种组合物和方法，其基于至少一种通式为“IMAGE”的取代苯酚，其中R 1表示具有1至4个碳原子的羟基烷基，R 2表示氢原子或具有1个至4个碳原子，或其酚盐作为成色剂物质。其中优选2-羟基 - 甲基-5-甲基 - 苯酚和3-（β-羟基乙基）-6-甲基 - 苯酚的本发明成色剂物质应以约0.01至3.0重量％的浓度存在，特别是0.1〜2.0重量％。描述的成色剂物质作为蓝色成色剂是有活性的。所获得的色调是稳定的，耐磨损和非常好的重现性。它们在毒理学和皮肤病方面具有非常有利的特性，不会使彩色头发变得不舒服，具有透气性的清香。该方法包括将显影剂物质与取代苯酚作为成色剂物质的可氧化显影剂 - 成色剂组合和氧化剂，将有效量的组合施加到人的头发上，在约10-45分钟后漂洗毛发温度在15°至50°C之间，并干燥头发。

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