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    • 151. 发明授权
    • Ionically and covalently cross-linked polymers and polymer membranes
    • 离子和共价交联的聚合物和聚合物膜
    • US06767585B2
    • 2004-07-27
    • US10275854
    • 2003-05-12
    • Jochen KerresWei ZhangChy-Ming Tang
    • Jochen KerresWei ZhangChy-Ming Tang
    • B05D302
    • C08F8/44
    • The present invention relates to ionically and covalently cross-linked polymers and polymer membranes having recurrent units of the general formula (1), wherein Q is a link, oxygen, sulfur, (2) or (3) and the R radical is a divalent radical of an aromatic or heteroaromatic compound, and which are characterized in that a) R radical comprises at least partially substituents of general formula (4A), (4B), (4C), (4D), (4E), (4F), (4G) and/or (4H), b) R radical comprises at least partially substituents of the general formula (5A) and/or (5B) and/or the R radical is at least partially a group of the general formula (5C) and/or (5D) and c) the R radical comprises at least partially bridges of the general formula (6) linking at least to R radicals together, R1, R2, R3, R4, R5, M, X, Y, Z and m having the herein-mentioned meanings.
    • 本发明涉及具有通式(1)的复发单元的离子交换和共价交联的聚合物和聚合物膜,其中Q是连接,氧,硫,(2)或(3),R基是二价 芳族或杂芳族化合物的基团,其特征在于a)R自由基至少部分包含通式(4A),(4B),(4C),(4D),(4E),(4F), (4G)和/或(4H),b)R自由基至少部分包含通式(5A)和/或(5B)的取代基和/或R基团至少部分为通式(5C )和/或(5D)和c)R基团包含至少部分至少连接至R基团的通式(6)的桥,R 1,R 2,R 3,R 4,R 5,M,X,Y,Z 和m具有这里所述的含义。
    • 156. 发明授权
    • Process for preparing a carrier used in olefin polymerization catalysts
    • 制备用于烯烃聚合催化剂的载体的方法
    • US06417132B1
    • 2002-07-09
    • US09511851
    • 2000-02-23
    • Junfeng RongWei ZhangZhenhua JingXiaoyu Hong
    • Junfeng RongWei ZhangZhenhua JingXiaoyu Hong
    • B01J3100
    • C08F10/00C08F110/02C08F4/6545C08F4/025C08F4/6543C08F2500/12C08F2500/24
    • The present invention relates to a process for preparing a carrier used in olefin polymerization catalysts, comprising suspending anhydrous magnesium chloride in an inert hydrocarbon solvent and then under stirring, activating the magnesium chloride with a C2-C8 alcohol at a temperature of 30° C. to 200° C., with the molar ratio of said alcohol to said magnesium chloride being in the range of 0.05 to 2.5. Moreover, in order to make the resultant catalysts more active, the process according to the present invention can further include a pre-dispersing step conducted prior to the activation step, wherein the dispersing agent is alkoxides of titanium or C3-C8 alcohols and the molar ratio of said dispersing agent to said magnesium chloride is 0.01 to 2.0. The catalyst prepared from the resultant carrier is suitable for polymerizing ethylene or compolymerizing ethylene with alpha-olefin.
    • 本发明涉及一种制备用于烯烃聚合催化剂的载体的方法,包括将无水氯化镁悬浮在惰性烃溶剂中,然后在搅拌下,用C2-C8醇在30℃的温度下活化氯化镁。 至200℃,所述醇与所述氯化镁的摩尔比在0.05至2.5的范围内。 此外,为了使得到的催化剂更具活性,根据本发明的方法还可以包括在活化步骤之前进行的预分散步骤,其中分散剂是钛或C 3 -C 8醇的醇盐, 所述分散剂与所述氯化镁的比例为0.01〜2.0。 由所得载体制备的催化剂适用于聚合乙烯或将α-烯烃与乙烯混合。