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131. 发明授权

US4657988A Repolymerization 失效
标题翻译：再聚合
公开(公告)号：US4657988A
公开(公告)日：1987-04-14
申请号：US834794
申请日：1986-02-28
申请人： Gerald Sugerman , Salvatore J. Monte
发明人： Gerald Sugerman , Salvatore J. Monte
IPC分类号： C08G85/00 , C07F7/00 , C07F9/09 , C08F8/00 , C08F8/42 , C08G18/82 , C08G81/00 , C08K5/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L67/00 , C08L101/00 , C08G63/76
CPC分类号： C07F7/003 , C07F9/09 , C07F9/098 , C08G18/82 , C08G81/00 , C08K5/0091
摘要： Polymeric materials are repolymerized by intensely admixing the polymer with an additive having the formula: ##STR1## wherein M is titanium or zirconium, R, R.sup.1 and R.sup.2 are each a monovalent alkyl, alkenyl, alkynyl, aralkyl, aryl or alkaryl group having up to 20 carbon atoms or a halogen or ether substituted derivative thereof, and, in addition, R.sup.2 may also be an oxy derivative or an ether substituted oxy derivative of said groups; A, B, and C are each a monovalent aroxy, thioaroxy, diester phosphate, diester pyrophosphate, oxyalkylamino, sulfonyl or carboxyl containing up to 30 carbon atoms; and a+b+c=3. The repolymerized polymers have improved physical properties and higher heat distortion temperatures, experience less thermal degradation and show greater solvolysis resistance than the polymers prior to the repolymerization.
摘要翻译：通过将聚合物与具有下式的添加剂强烈混合来聚合高分子材料：其中M是钛或锆，R，R 1和R 2各自是一价烷基，烯基，炔基，芳烷基，芳基或烷芳基，其具有至多 20个碳原子或其卤素或醚取代的衍生物，另外，R 2也可以是所述基团的氧基衍生物或醚取代的氧基衍生物; A，B和C各自是含有至多30个碳原子的单价芳氧基，硫代羟基，二酯磷酸酯，二酯焦磷酸酯，氧烷基氨基，磺酰基或羧基; 和a + b + c = 3。所述重聚聚合物具有改善的物理性能和较高的热变形温度，经历较少的热降解，并且显示比在再聚合之前的聚合物更大的溶剂分解性。

132. 发明授权

US4639366A Polymers containing pendant acid functionalities and labile backbone bonds 失效
公开(公告)号：US4639366A
公开(公告)日：1987-01-27
申请号：US618002
申请日：1984-06-06
申请人： Jorge Heller
发明人： Jorge Heller
IPC分类号： C08G63/06 , A61K9/20 , A61K9/22 , C08G63/00 , C08G65/00 , C08G65/34 , C08G83/00 , C08G85/00 , A61K31/74 , A61K31/765
CPC分类号： A61K9/204 , C08G65/34 , C08G85/00
摘要： The instant invention is directed to a polymer with at least one labile backbone bond per repeat unit and at least one pendant acid functionality per thousand repeat units.The instant invention is also directed to a controlled release device which comprises:(A) a polymer with at least one labile backbone bond per repeat unit and at least one pendant acid functionality per thousand repeat units; and(B) a beneficial substance incorporated within or surrounded by the matrix of said polymer.

133. 发明授权

US4630568A Apparatus for coating substrates by plasma polymerization 失效
标题翻译：用于通过等离子体聚合涂覆基底的装置
公开(公告)号：US4630568A
公开(公告)日：1986-12-23
申请号：US736556
申请日：1985-05-21
申请人： Jorg Kieser
发明人： Jorg Kieser
IPC分类号： C08F2/00 , B01J19/08 , B01J19/12 , B05D7/24 , C08G85/00 , C23C14/22 , C23C16/50 , C23C16/511 , H01J37/32 , C23C16/00
CPC分类号： B05D1/62 , B01J19/126 , C23C16/511 , H01J37/32192 , H01J37/32229 , H01J37/32238 , H01J37/32275 , B01J2219/0894 , H01J2237/3382
摘要： Apparatus for coating substrates by means of a reaction for depositing atoms or molecules which is initiated by a plasma. A reaction chamber (1) is equipped with at least one window (22, 23), penetrable by microwaves, with at least one wave-guide structure (16, 17), arranged outside the chamber (1) and in front of the window (22, 23), and with a distributing means (25) discharging into the chamber.According to the invention and for the purpose of achieving the object of facilitating inspection and repairs, the window (22, 23) penetrable by microwaves, the one or more wave-guide structures (16, 17) and the distributing means (25) are all secured in or on a support frame (10), which can be removed, or swung away, from the reaction chamber (1) as a single unit.
摘要翻译：用于通过用于沉积由等离子体引发的原子或分子的反应来涂覆基底的装置。反应室（1）装备有可被微波穿透的至少一个窗口（22,23），其中至少一个波导结构（16,17）布置在室（1）的外部和窗口的前面（22,23），并且具有排出到所述室中的分配装置（25）。根据本发明，为了实现便于检查和修理的目的，可以由微波穿透的窗口（22,23），一个或多个波导结构（16,17）和分配装置（25）是全部固定在可作为单个单元从反应室（1）移除或摆动的支撑框架（10）中或上。

134. 发明授权

US4623697A Ungelled resins containing hydrolyzable moieties from organosilane compounds 失效
标题翻译：含有有机硅烷化合物的可水解部分的未凝胶化树脂
公开(公告)号：US4623697A
公开(公告)日：1986-11-18
申请号：US728966
申请日：1985-04-30
申请人： Wen-Hsuan Chang , David T. McKeough
发明人： Wen-Hsuan Chang , David T. McKeough
IPC分类号： C08G59/00 , C08F8/42 , C08F16/00 , C08F16/02 , C08F16/06 , C08G59/14 , C08G63/00 , C08G63/91 , C08G65/48 , C08G69/00 , C08G69/48 , C08G77/50 , C08G85/00 , C09D157/06 , C09D183/00 , C09D183/05 , C09D201/02 , C08F8/00
CPC分类号： C09D201/02 , C08G77/50 , C08G85/004 , C09D157/06
摘要： Disclosed is an ungelled resin composition comprising a compound having at least one group containing a silicon atom selected from: ##STR1## wherein Q represents the residue from an organic polyol selected from the group consisting of (1) simple diols, triols and higher hydric alcohols, (2) polyester polyols, (3) polyether polyols, (4) amide-containing polyols, (5) epoxy polyols and (6) polyhydric polyvinyl alcohols, and eachR independently is selected from the group of moieties consisting of hydrogen, and a C.sub.1 -C.sub.10 group joined to Si through an Si-C linkage, andY represents an easily hydrolyzable group.The ungelled resin composition contains an amount of easily hydrolyzable Y moieties directly bonded to silicon atoms such that the ratio of the number of grams of the ungelled resin composition to equivalents of easily hydrolyzable Y moieties in the ungelled resin composition is in a range of from 40 to 667. Preferred resin compositions of the invention can be cured in the presence of atmospheric moisture and a suitable catalyst at a temperature of less than or equal to 121 degrees Celsius within 3 hours.Disclosed is a method for producing the ungelled resin composition.Also disclosed is a nonaqueous composition, particularly a nonaqueous coating composition, containing an ungelled resin composition of the invention. Preferred coating compositions containing an ungelled resin composition of the invention can be cured in the presence of atmospheric moisture and a suitable catalyst at a temperature of less than or equal to 121 degrees C within 3 hours.
摘要翻译：公开了一种无胶凝树脂组合物，其包含具有至少一个含有选自以下的硅原子的基团的化合物：其中Q表示选自（1）简单二醇，三醇和高级醇，（2）聚酯多元醇，（3）聚醚多元醇，（4）含酰胺的多元醇，（5）环氧多元醇和（6）多元聚乙烯醇，并且每个R独立地选自部分由氢组成的C1-C10基团和通过Si-C键与Si连接的C1-C10基团，Y表示易水解基团。未凝胶化树脂组合物含有一定量的直接键合到硅原子上的易水解的Y部分，使得未凝胶化树脂组合物的克数与未凝胶化树脂组合物中容易水解的Y部分的当量之比在40 本发明优选的树脂组合物可在大气湿度和合适的催化剂存在下在3小时内在小于或等于121℃的温度下固化。公开了一种无胶凝树脂组合物的制造方法。还公开了含有本发明的未凝胶化树脂组合物的非水性组合物，特别是非水性涂料组合物。含有本发明的未凝胶化树脂组合物的优选涂料组合物可在大气水分和合适的催化剂存在下在3小时内在小于或等于121℃的温度下固化。

135. 发明授权

US4623676A Protective coating for phototools 失效
公开(公告)号：US4623676A
公开(公告)日：1986-11-18
申请号：US692780
申请日：1985-01-18
申请人： John F. Kistner
发明人： John F. Kistner
IPC分类号： G03F7/027 , C08F2/46 , C08F2/48 , C08F2/50 , C08G59/00 , C08G59/18 , C08G59/20 , C08G59/30 , C08G59/40 , C08G85/00 , G03F1/62 , G03F7/004 , G03F7/028 , G03F7/038 , G03F7/075 , H05K3/06 , G03C1/68 , C08F8/00 , C08F30/08
CPC分类号： G03F1/62
摘要： A radiation-curable composition suitable for use as a protective coating for a photographic element comprises a polymerizable acrylic compound, a polymerizable epoxy-functional silane compound, a free-radical photoinitiator capable of initiating polymerization of said acrylic compound, and 0 to 2 percent of the total composition on a weight basis of a cationic photoinitiator capable of initiating polymerization of said epoxy-functional silane compound, said composition containing epoxy functionality only in a silane compound.

136. 发明授权

US4596644A Method of polymerization 失效
标题翻译：聚合方法
公开(公告)号：US4596644A
公开(公告)日：1986-06-24
申请号：US752287
申请日：1985-07-05
申请人： Christopher P. Banks , Edward Irving
发明人： Christopher P. Banks , Edward Irving
IPC分类号： C08F2/00 , C08F2/58 , C08G8/04 , C08G59/72 , C08G65/26 , C08G75/06 , C08G85/00 , C08L61/00 , C09D5/44 , C25D13/00
CPC分类号： C08G65/2654 , C08G59/72 , C08G75/06 , C08G8/04 , C08L61/00 , C09D5/4476 , Y10T428/31529
摘要： Cationically polymerizable materials, such as epoxide resins, phenoplasts, and aminoplasts, are polymerized by passing an electric current through a composition comprising(A) the cationically polymerizable material, and(B) a boron trifluoride complex,between an anode and a cathode in contact with the composition, whereby polymerized material is deposited on the anode.Typical complexes (B) are those of boron trifluoride with primary, secondary, or tertiary amines or with trialkyl or triaryl phosphines.The method is a particularly suitable means for coating conductive substrates, giving a rapid cure without the need for special formulations to render the polymers electrodepositable.
摘要翻译：通过使电流通过包含（A）阳离子聚合性材料的组合物和（B）三氟化硼配合物，在接触的阳极和阴极之间聚合阳离子可聚合材料，例如环氧树脂，酚醛树脂和氨基塑料。其中聚合材料沉积在阳极上。典型的络合物（B）是三氟化硼与伯，仲或叔胺或三烷基或三芳基膦的络合物。该方法是用于涂覆导电基材的特别合适的方法，可快速固化，而无需特殊配方使聚合物电沉积。

137. 发明授权

US4591487A Method and apparatus for the continuous production of high-molecular polymers 失效
标题翻译：连续生产高分子聚合物的方法和装置
公开(公告)号：US4591487A
公开(公告)日：1986-05-27
申请号：US522047
申请日：1983-08-10
申请人： Rudolf P. Fritsch
发明人： Rudolf P. Fritsch
IPC分类号： C08G85/00 , B01J19/20 , B29B7/48 , B29C47/42 , B29C47/76 , C08F2/00 , C08F2/02 , B01F7/26 , B01J14/00
CPC分类号： B01J19/20 , B29B7/481 , B29C47/42 , B29C47/76 , B29C47/0009
摘要： Apparatus for the continuous production of high molecular polymers in which a plurality of parallel screw shafts coupled together for rotary movement in the same direction within a casing are partially disposed in trough-like recesses in the casing wall and enclose a devolatilization chamber having an opening for connection to a vacuum and forming an extrusion unit with the casing and in which the shafts carry spaced noncircular kneading disks oriented in staggered relationship on the shaft axes with the disks of adjacent shafts meshing to scrape the substance to be treated from each other.
摘要翻译：用于连续生产高分子聚合物的装置，其中多个平行的螺旋轴联接在一起，用于在壳体内沿同一方向旋转运动，部分地设置在壳体壁中的槽状凹槽中，并且包围一个具有开口的开口的脱挥发分室连接到真空并与壳体形成挤出单元，并且其中轴携带间隔非圆形捏合盘，其在轴线上以交错关系定向，相邻轴的盘啮合以将要处理的物质彼此刮擦。

138. 发明授权

US4585693A Polymer-bound ultraviolet stabilizer coating compositions containing cross linkers 失效
标题翻译：含有交联剂的聚合物结合的紫外线稳定剂涂料组合物
公开(公告)号：US4585693A
公开(公告)日：1986-04-29
申请号：US684939
申请日：1984-12-21
申请人： Michael DeBergalis , Robert P. O'Fee
发明人： Michael DeBergalis , Robert P. O'Fee
IPC分类号： C08F8/00 , C08F20/30 , C08G85/00 , C09D7/12 , B32B5/16 , B32B19/00
CPC分类号： C08F20/30 , C08F8/00 , C08G85/00 , C09D7/1241 , C08K5/103 , Y10T428/251 , Y10T428/254 , Y10T428/256 , Y10T428/2804 , Y10T428/31678 , Y10T428/31688 , Y10T428/31699
摘要： Coating compositions containing large amounts of polymer-bound ultraviolet radiation stabilizers and cross linkers give highly ultraviolet absorbent properties.
摘要翻译：含有大量聚合物结合的紫外线辐射稳定剂和交联剂的涂料组合物具有高度的紫外线吸收性能。

139. 发明授权

US4576999A Ultraviolet radiation-curable silicone release compositions with epoxy and/or acrylic functionality 失效
标题翻译：具有环氧树脂和/或丙烯酸官能团的紫外线辐射固化硅酮防粘组合物
公开(公告)号：US4576999A
公开(公告)日：1986-03-18
申请号：US375676
申请日：1982-05-06
申请人： Richard P. Eckberg
发明人： Richard P. Eckberg
IPC分类号： C08F2/00 , C08F2/48 , C08F290/00 , C08F299/00 , C08G59/00 , C08G59/18 , C08G59/20 , C08G59/30 , C08G77/00 , C08G77/06 , C08G77/20 , C08G77/22 , C08G77/38 , C08G77/50 , C08G85/00 , C08K5/00 , C08L83/07 , C09D163/00 , C09D183/06 , C09J163/00 , C08F283/00
CPC分类号： C08K5/0025 , C08G77/38 , C08G77/50 , C09D183/06
摘要： Epoxy- and/or acrylic-functional polysiloxanes are disclosed which, when combined with onium salt photoinitiating catalysts or free-radical photoinitiating catalysts, or both, form ultraviolet radiation-curable release coating compositions which render surfaces non-adherent to other surfaces which would normally adhere thereto. The compositions will cure to such an adhesive state upon brief exposure to ultraviolet radiation. Cure and substrate adhesion may be enhanced by the addition of epoxy monomers where onium salt photocatalysts are included. Preparation of the polymers, coating compositions, catalysts and catalyst blends are also disclosed.
摘要翻译：公开了环氧基和/或丙烯酸官能的聚硅氧烷，其与鎓盐光引发催化剂或自由基光引发催化剂或二者组合时形成紫外线辐射固化的剥离涂料组合物，其使表面不粘附于通常坚持在短时间暴露于紫外线辐射下，组合物将固化至这种粘合剂状态。通过添加含有鎓盐光催化剂的环氧单体，可以提高固化和底物的粘附性。还公开了聚合物，涂料组合物，催化剂和催化剂共混物的制备。

140. 发明授权

US4543376A Heat-curable surface-coating agents, and their use 失效
标题翻译：可热固化的表面涂层剂及其用途
公开(公告)号：US4543376A
公开(公告)日：1985-09-24
申请号：US547092
申请日：1983-10-31
申请人： Eberhard Schupp , Werner Loch , Rolf Osterloh , Klaas Ahlers
发明人： Eberhard Schupp , Werner Loch , Rolf Osterloh , Klaas Ahlers
IPC分类号： C08G59/56 , C08G85/00 , C09D5/44 , C09D5/46 , C09D167/00 , C09D201/00 , C08L63/02
CPC分类号： C09D167/00 , C08G59/56 , C08G85/004 , C09D201/00 , C09D5/4496 , Y10S524/901
摘要： Heat-curable surface-coating agents useful in organically dissolved baking finishes, for powder coating and for cathodic electrocoating contain, as a binder, a mixture of a polyadduct, polycondensate or other polymer which has an average molecular weight M.sub.n of from 500 to 10,000 and, per molecule, on average two or more OH and/or NH groups, and a reaction product of a polyamine which contains on average two or more primary amino groups per molecule and a cyclic carbonic acid ester of the formula (I) ##STR1## where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 each are hydrogen, methyl or ethyl.
摘要翻译：可用于有机溶解烘烤面漆的热固化性表面涂层剂，用于粉末涂料和阴极电泳包含作为粘合剂的多加成物，缩聚物或其它聚合物的混合物，其平均分子量＆lt;上限＆Mn> 500至10,000 每个分子平均有两个或多个OH和/或NH基，每分子含有平均两个或多个伯氨基的多胺和式（I）的环状碳酸酯的反应产物

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