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131. 发明授权

US5693209A Process for metallization of a nonconductor surface 失效
标题翻译：非导体表面的金属化工艺
公开(公告)号：US5693209A
公开(公告)日：1997-12-02
申请号：US518575
申请日：1995-08-23
申请人： Burkhard Bressel , Heinrich Meyer , Walter Meyer , Klaus Gedrat
发明人： Burkhard Bressel , Heinrich Meyer , Walter Meyer , Klaus Gedrat
IPC分类号： C08G61/12 , C25D5/56 , H05K3/18
CPC分类号： H05K3/188 , C08G61/123 , C25D5/56 , H05K2203/0796 , Y10S205/92
摘要： The process for directly metallizing a circuit board having nonconductor surfaces, includes reacting the nonconductor surface with an alkaline permanganate solution to form manganese dioxide chemically adsorbed on the nonconductor surface; forming an aqueous solution of a weak acid and of pyrrole or a pyrrole derivative and soluble oligomers thereof; contacting the aqueous solution containing the pyrrole monomer and its oligomers with the nonconductor surface having the manganese dioxide adsorbed chemically thereon to deposit an adherent, electrically conducting, insoluble polymer product on the nonconductor surface; and directly electrodepositing metal on the nonconductor surface having the insoluble adherent polymer product formed thereon. The oligomers are advantageously formed in aqueous solution containing 0.1 to 200 g/l of the pyrrole monomer at a temperature between room temperature and the freezing point of the solution.
摘要翻译：用于直接金属化具有非导体表面的电路板的方法包括使非导体表面与碱性高锰酸盐溶液反应以形成化学吸附在非导体表面上的二氧化锰; 形成弱酸和吡咯或吡咯衍生物及其可溶性低聚物的水溶液; 使含有吡咯单体及其低聚物的水溶液与其上具有化学吸附的二氧化锰的非导体表面接触，以在非导体表面上沉积粘附的导电不溶性聚合物产物; 并在其上形成有不溶性粘附聚合物产物的非导体表面上直接电沉积金属。低聚物有利地在室温至溶液凝固点之间的温度下形成含有0.1至200g / l吡咯单体的水溶液。

132. 发明授权

US5648453A Electroconductive polymer and process for producing the polymer 失效
标题翻译：导电聚合物和制备聚合物的方法
公开(公告)号：US5648453A
公开(公告)日：1997-07-15
申请号：US476977
申请日：1995-06-07
申请人： Yoshihiro Saida , Yoshiaki Ikenoue , Reiko Ichikawa
发明人： Yoshihiro Saida , Yoshiaki Ikenoue , Reiko Ichikawa
IPC分类号： C08G61/12 , H01B1/12 , C08G75/00 , C08G63/91
CPC分类号： C08G61/123 , H01B1/127
摘要： Electroconductive polymers having a chemical structure represented by, for example, the formula (I) ##STR1## wherein R.sup.1 and R.sup.2 independently represent H, a C.sub.1 to C.sub.20 alkyl or alkoxy group, an amino group, a trihalomethyl group or a phenyl group, X represents S, O, Se, Te or NR.sub.3 R.sub.3 represents H, a C.sub.1 to C.sub.6 alkyl group or an aryl group, M represents a cation such as M.sup.+, an alkali metal ion or a quaternary ammonium ion, and m is 0.2 to 2 and a process for producing the polymer.
摘要翻译：具有由例如H表示的式（I）表示的化学结构的导电聚合物，C1至C20烷基或烷氧基，氨基，三卤代甲基或苯基，X表示S，O，Se，Te 或NR 3 R 3表示H，C 1〜C 6烷基或芳基，M表示阳离子例如M +，碱金属离子或季铵离子，m为0.2〜2，以及该聚合物的制造方法。

133. 发明授权

US5378402A Polymer compositions 失效
标题翻译：聚合物组合物
公开(公告)号：US5378402A
公开(公告)日：1995-01-03
申请号：US516176
申请日：1983-07-21
申请人： Malcolm G. Cross , Robert Lines
发明人： Malcolm G. Cross , Robert Lines
IPC分类号： C08G61/12 , H01B1/12 , H01M4/60 , H01B1/00
CPC分类号： H01M4/60 , C08G61/123 , H01B1/127 , H01B1/128
摘要： Electrically conductive polymers, especially polypyrroles, are formed with a charged polymeric dopant supplying the necessary counter-ions to stabilise the charged conductive form of the conductive polymer. The physical properties of the conductive polymer can thus be usefully modified in ways different from those achieved by non-polymeric dopants or by forming the conductive polymers in pre-existing bodies of non dopant (i.e. uncharged) polymers.
摘要翻译：形成导电聚合物，特别是聚吡咯，带电荷的聚合物掺杂剂提供必要的抗衡离子，以稳定导电聚合物的带电导电形式。因此，导电聚合物的物理性质可以有效地以与非聚合物掺杂物实现的方式不同的方式或通过在非掺杂剂（即不带电荷的）聚合物的预先存在的体内形成导电聚合物而有所改变。

134. 发明授权

US5286413A Mixtures of polar polymers and dedoped conductive polymers, processes for obtaining these mixtures and use of these mixtures to produce electronic, optoelectrical, electrical and electromechanical devices 失效
标题翻译：极性聚合物和脱掺杂导电聚合物的混合物，获得这些混合物的方法和这些混合物的使用以产生电子，光电，电和机电装置
公开(公告)号：US5286413A
公开(公告)日：1994-02-15
申请号：US747374
申请日：1991-08-20
申请人： Etienne Hannecart , Claude Franquinet
发明人： Etienne Hannecart , Claude Franquinet
IPC分类号： C08L101/02 , C08G61/12 , C08J5/18 , C08L27/16 , C08L65/02 , C08L79/00 , C08L81/00 , C08L101/00 , C08L101/12 , H01B1/12 , H01B3/44 , H01B1/00 , H01B1/20
CPC分类号： H01B3/445 , C08G61/123 , C08L27/16 , C08G2261/312 , C08L65/02 , C08L79/00 , C08L81/00
摘要： A polymer mixture, including at least one conductive polymer which has been dedoped to provide at least one dedoped conductive polymer; and at least one polar polymer. The polymer mixture has outstanding dielectric properties so that the polymer mixture is useful for producing electronic, optoelectrical, electrical and electromechanical devices.
摘要翻译：导电聚合物与极性聚合物的混合物，这使得可以获得具有高介电性能的新型产品。

135. 发明授权

US5282955A Electrically conductive polymer composition, method of making same and device incorporating same 失效
标题翻译：导电聚合物组合物，其制备方法和结合相同的装置
公开(公告)号：US5282955A
公开(公告)日：1994-02-01
申请号：US717892
申请日：1991-06-19
申请人： Nicholas Leventis , Young C. Chung
发明人： Nicholas Leventis , Young C. Chung
IPC分类号： G02F1/15 , C08G61/10 , C08G61/12 , C08G73/02 , C09K9/02 , C25D9/02 , G02F1/155 , H01B1/12 , H01M4/60
CPC分类号： H01M4/60 , C08G61/10 , C08G61/123 , C08G73/0266 , G02F1/15 , G02F1/1521 , G02F1/155 , H01B1/127 , H01B1/128 , G02F1/1523 , G02F2001/1517 , G02F2001/1555
摘要： The disclosure relates, inter alia, to a composition and, a method of making the composition. The composition comprises an electrically conductive polymer having a porous structure and a compound formed in situ and coating at least a portion of the surfaces of said polymer. The method of making the composition comprises forming an electrically conductive polymer having a porous structure, contacting the surfaces of the polymer with a solution comprising chemical species capable of being electrochemically formed into a coating material on the surfaces of said structure and electrochemically forming the coating material on the surfaces of the structure.
摘要翻译：本公开尤其涉及组合物和制备该组合物的方法。组合物包含具有多孔结构的导电聚合物和原位形成的化合物，并涂覆所述聚合物的至少一部分表面。制备组合物的方法包括形成具有多孔结构的导电聚合物，使聚合物的表面与包含能够在所述结构的表面上电化学形成涂层材料的化学物质的溶液接触，并电化学地形成涂层材料在结构的表面上。

136. 发明授权

US5254416A Electron conductive high polymer 失效
标题翻译：电子导电高分子
公开(公告)号：US5254416A
公开(公告)日：1993-10-19
申请号：US818287
申请日：1992-01-09
申请人： Tadahiko Kubota
发明人： Tadahiko Kubota
IPC分类号： C08F2/58 , C08F2/00 , C08F34/00 , C08F34/02 , C08F34/04 , C08G61/12 , H01B1/12 , H01M4/60 , H01M10/05 , C08G75/00
CPC分类号： H01M4/60 , C08G61/123
摘要： An electron conductive high polymer is described, having at least a repeating unit represented by following formula (1); ##STR1## wherein X.sub.1 and X.sub.1 ' each represents a divalent linkage group; R.sub.1 and R.sub.1 ' each represents an alkylene group; R.sub.2 represents a cyclic ester derivative group, an acyclic ester derivative group, a cyclic ether derivative group, or a sulfone derivative group; R.sub.3 represents a hydrogen atom, an alkyl group, an aryl group, a cyclic ester derivative group, an acyclic ester derivative group, a cyclic ether derivative group, or a sulfone derivative group; a, b, and c each represents 0 or 1; and Y represents --NR.sub.4 --, --O--, --S--, --Te--, or --Se--wherein R.sub.4 represents a hydrogen atom, an alkyl group, or an aryl group. A positive electrode for battery using the electron conductive high polymer is also described.
摘要翻译：描述了至少具有下式（1）表示的重复单元的电子传导性高分子。（1）其中X1和X1'各自表示二价连接基团; R1和R1'各自表示亚烷基; R2表示环状酯衍生物基团，无环酯衍生物基团，环状醚衍生物基团或砜衍生物基团; R3表示氢原子，烷基，芳基，环状酯衍生物基，无环酯衍生物基，环醚衍生物基或砜衍生物基; a，b和c各自表示0或1; Y表示-NR 4 - ， - O - ， - S - ， - Te-或-Se-，其中R 4表示氢原子，烷基或芳基。还描述了使用电子传导性高分子的电池用正极。

137. 发明授权

US5244562A Use of templated polymers for analyte-activated microelectronic switching devices 失效
标题翻译：使用模板聚合物用于分析物激活的微电子开关器件
公开(公告)号：US5244562A
公开(公告)日：1993-09-14
申请号：US738719
申请日：1991-07-31
申请人： Dale D. Russell
发明人： Dale D. Russell
IPC分类号： A61B5/00 , C08G61/12
CPC分类号： C08G61/123 , A61B5/14532 , G01N2600/00 , Y10S435/817
摘要： Switching devices (10) comprise a micro-electrode (12 or 16a') coated with a templated polymer (14). For example, the template molecule is glucose and the bulk polymer is a thiophene/boronic acid-substituted thiophene copolymer. The switch is activated or inactivated by the concentration of glucose in a solution (38) contacting the coated micro-electrode. Advantageously, the dimensions of the switch may be very small, 10.sup.-6 or less.
摘要翻译：开关装置（10）包括涂覆有模板聚合物（14）的微电极（12或16a'）。例如，模板分子是葡萄糖，本体聚合物是噻吩/硼酸取代的噻吩共聚物。通过与涂覆的微电极接触的溶液（38）中葡萄糖的浓度来激活或灭活开关。有利地，开关的尺寸可以非常小，10-6或更小。

138. 发明授权

US5220048A Substituted benzocyclobutenes, a process for their preparation and their use 失效
标题翻译：取代的苯甲酸酯，其制备方法及其使用
公开(公告)号：US5220048A
公开(公告)日：1993-06-15
申请号：US356826
申请日：1989-05-24
申请人： Marcus Baumann , Walter Fischer , Vratislav Kvita , Carl W. Mayer
发明人： Marcus Baumann , Walter Fischer , Vratislav Kvita , Carl W. Mayer
IPC分类号： B05D1/20 , C07B37/10 , C07C17/00 , C07C17/23 , C07C23/18 , C07C25/22 , C07C41/00 , C07C43/225 , C07C43/29 , C07C63/68 , C07C65/26 , C07C67/00 , C07C69/76 , C07C201/00 , C07C205/11 , C07C205/12 , C07C205/46 , C07C233/65 , C07C235/46 , C07C255/52 , C07C323/09 , C07F7/08 , C08G61/12 , H01B1/12
CPC分类号： B05D1/202 , B82Y30/00 , B82Y40/00 , C07C205/11 , C07C205/46 , C07C25/22 , C07C43/225 , C07C69/76 , C07F7/0818 , C08G61/123 , H01B1/121 , C07C2102/06 , C07C2103/44
摘要： Benzocyclobutene-1,2-dichlorides, -bromides and -iodides which are substituted in the benzene ring are accessible in good yields and short reaction times by reacting substituted 1,2-(dichloromethyl or dibromomethyl)-benzenes with NaI in acetonitrile as the solvent. They can be used together with dienophils, for example 1,4-quinones, in Diels-Alder reactions.
摘要翻译：在苯环中被取代的苯并环丁烯-1,2-二氯化物， - 溴化物和 - 碘化物可通过使取代的1,2-（二氯甲基或二溴甲基） - 苯与NaI在乙腈中作为溶剂而以良好的收率和短的反应时间获得。它们可以与Dien-Alder反应中的双亲体例如1,4-醌配合使用。

139. 发明授权

US5215820A Metal-electroconductive polymer composite fine particles and method for preparing same 失效
标题翻译：金属电极聚合物复合微粒及其制备方法
公开(公告)号：US5215820A
公开(公告)日：1993-06-01
申请号：US799228
申请日：1991-11-27
申请人： Hiroshi Hosokawa , Kensuke Kamada
发明人： Hiroshi Hosokawa , Kensuke Kamada
IPC分类号： C08K3/08 , B22F1/00 , B22F1/02 , B22F9/20 , B22F9/24 , C08G61/12 , C08G69/02 , C08K3/02 , C08K9/04 , C08K9/10 , H01B1/12 , H01B1/22
CPC分类号： C08K9/10 , B22F1/0018 , B22F1/0062 , B22F9/24 , C08G61/123 , C08G69/02 , H01B1/127 , H01B1/22 , Y10T428/256 , Y10T428/2991 , Y10T428/2998
摘要： Metal-electroconductive polymer composite fine particles are here disclosed which comprises metal fine particles and an electroconductive polymer with which the surfaces of the metal fine particles are coated. Since the surfaces of the composite fine particles are coated with the polymer, the composite fine particles are excellent in handling properties and can be uniformly dispersed in an organic material.

140. 发明授权

US5109109A Process for producing aromatic or heterocyclic polymer with metal halides 失效
标题翻译：用金属卤化物生产芳族或杂环聚合物的方法
公开(公告)号：US5109109A
公开(公告)日：1992-04-28
申请号：US625681
申请日：1990-12-12
申请人： Shu Hotta , Mamoru Soga , Nobuo Sonoda
发明人： Shu Hotta , Mamoru Soga , Nobuo Sonoda
IPC分类号： C08G61/10 , C08G61/12
CPC分类号： C08G61/10 , C08G61/123
摘要： A process for producing aromatic polymers which comprise subjecting halogenated aromatic compounds or combinations of aromatic compounds and polyhalogenated aromatic compounds to dehydrohalogenation reaction in the presence of a metal halide for condensation. The halogenated aromatic compounds, aromatic compounds and polyhalogenated aromatic compounds include not only those compounds having benzene nucleus or nuclei, but also compounds of aromatic character such as heterocyclic five-membered compounds. A high degree of polymerization is attained according to the process.
摘要翻译：一种制备芳族聚合物的方法，其包括在卤化金属存在下使卤代芳族化合物或芳族化合物和多卤代芳族化合物的组合脱卤化氢反应进行缩合。卤代芳族化合物，芳族化合物和多卤代芳族化合物不仅包括具有苯核或核的化合物，还包括芳族特性的化合物，例如杂环五元化合物。根据该方法可以获得高度的聚合度。

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