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121. 发明授权

US4344961A Insecticidal benzylfurylmethyl esters of 3-(2,2-dichlorovinyl)-2,2-dimethyl-cyclopropane carboxylic acids 失效
标题翻译： 3-（2,2-二氯乙烯基）-2,2-二甲基 - 环丙烷羧酸的杀虫苄fur甲酯
公开(公告)号：US4344961A
公开(公告)日：1982-08-17
申请号：US232557
申请日：1981-02-09
申请人： Gerd-Ulrich Schwarz , Karl Kiehs , Heinrich Adolphi
发明人： Gerd-Ulrich Schwarz , Karl Kiehs , Heinrich Adolphi
IPC分类号： C07C69/65 , A01N37/10 , A01N43/08 , A01N53/00 , A01N53/04 , A01N53/06 , A01N53/08 , C07C29/40 , C07C41/30 , C07C43/295 , C07C67/00 , C07C69/73 , C07C69/747 , C07C253/00 , C07C255/57 , C07C313/00 , C07C319/20 , C07C323/19 , C07D307/45 , C07D307/58 , C07D307/64
CPC分类号： C07D307/42 , A01N37/10 , A01N43/08 , A01N53/00 , C07C29/40 , C07C41/30
摘要： Novel carboxylic acid esters of the formula ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are identical or different and each is hydrogen, halogen or alkyl or alkenyl of up to 5 carbon atoms,Y is 3-(2,2-dihalogenovinyl)-2,2-dimethyl-cyclopropyl or a radical of the formula ##STR2## where R.sup.4 is unbranched or branched alkyl, alkenyl or alkynyl of up to 4 carbon atoms or is an alicyclic radical of 3 to 7 carbon atoms,R.sup.5 is halogen, alkyl or alkoxy of up to 5 carbon atoms, trihalomethyl, cyano or nitro anda is from 0 to 3 andZ is a radical of the formula ##STR3## where X is oxygen, sulfur or --CH.sub.2 --,R.sup.6, R.sup.7 and R.sup.8 are halogen or alkyl, alkoxy or haloalkyl of up to 5 carbon atoms andb, c and d are from 0 to 3, their preparation and their use in insect and arachnid control.
摘要翻译：新的式（I）的羧酸酯，其中R 1，R 2和R 3相同或不同，各自为氢，卤素或至多5个碳原子的烷基或链烯基，Y为3-（2,2-二卤代乙烯基） - 2,2-二甲基 - 环丙基或下式的基团，其中R 4是至多4个碳原子的直链或支链烷基，烯基或炔基，或者是3至7个碳原子的脂环基，R5是卤素，烷基或至多5个碳原子的烷氧基，三卤代甲基，氰基或硝基，a是0-3，Z是下式的基团其中X是氧，硫或-CH 2 - ，R 6， R7和R8是卤素或至多5个碳原子的烷基，烷氧基或卤代烷基，b，c和d为0-3，它们的制备及其在昆虫和蜘蛛控制中的应用。

122. 发明授权

US4298615A Substituted 2,3-dihydrobenzofurylmethyl esters, their use in pest control, and pest control agents containing these compounds 失效
标题翻译：取代的2,3-二氢苯并呋喃甲基酯，它们在病虫害防治中的用途和含有这些化合物的害虫控制剂
公开(公告)号：US4298615A
公开(公告)日：1981-11-03
申请号：US172526
申请日：1980-07-28
申请人： Gerd-Ulrich Schwarz , Karl Kiehs , Walter Boell , Heinrich Adolphi
发明人： Gerd-Ulrich Schwarz , Karl Kiehs , Walter Boell , Heinrich Adolphi
IPC分类号： A01N43/12 , A01N53/00 , A01N53/04 , A01N57/00 , C07D307/79 , A01N43/08 , C07D307/82
CPC分类号： C07D307/79 , A01N43/12 , A01N53/00
摘要： Substituted 2,3-dihydrobenzofurylmethyl esters of the formula I ##STR1## where R.sup.8 is hydrogen or alkyl of up to 5 carbon atoms, R.sup.9 is alkyl, haloalkenyl or haloalkynyl, each of up to 5 carbon atoms,R.sup.10 is halogen or alkyl of up to 5 carbon atoms,R.sup.11 is halogen or alkyl of up to 5 carbon atoms, A is halogen, alkyl, alkoxy, trihaloalkyl or trihaloalkoxy, each of up to 5 carbon atoms, cyano or nitro,B is alkyl, alkenyl or alkynyl, each of up to 4 carbon atoms, or an alicyclic radical of 3 to 7 carbon atoms and n is from 0 to 3,R.sup.2 is hydrogen, cyano or alkyl, alkenyl or alkynyl, each of up to 5 carbon atoms, andR.sup.3, R.sup.4, R.sup.5, R.sup.6 and R.sup.7 are identical or different and each is hydrogen, halogen or alkyl, alkenyl, alkynyl or alkoxy, each of up to 5 carbon atoms, and R.sup.9 may also be alkenyl of up to 5 carbon atoms if R.sup.2 is cyano or is alkyl, alkenyl or alkynyl, each of up to 5 carbon atoms.The novel compounds are useful in pest control.
摘要翻译：取代的取代的2,3-二氢苯并呋喃基甲基酯其中R8是氢或至多5个碳原子的烷基，R9是烷基，卤代烯基或卤代炔基，各自至多5个碳原子，R10是卤素或至多5个碳原子的烷基，R11为卤素或至多5个碳原子的烷基，A为卤素，烷基，烷氧基，三卤代烷基或三卤代烷氧基，各为至多5个碳原子，氰基或硝基，B为烷基，至多4个碳原子的链烯基或炔基，或3至7个碳原子的脂环族基团，n为0-3，R2为氢，氰基或烷基，烯基或炔基，各自至多5个碳原子，并且R 3，R 4，R 5，R 6和R 7是相同或不同的，各自为氢，卤素或烷基，烯基，炔基或烷氧基，各自至多5个碳原子，并且R 9还可以是至多5个碳原子的链烯基， R2是氰基或烷基，烯基或炔基，各自至多5个碳原子。新型化合物可用于病虫害防治。

123. 发明授权

US4277490A Insecticidal 1-(2-naphthyl)-cyclobutane carboxylate 失效
标题翻译：杀虫剂1-（2-萘基） - 环丁烷羧酸酯
公开(公告)号：US4277490A
公开(公告)日：1981-07-07
申请号：US98715
申请日：1979-11-30
申请人： George Holan , Reimund A. Walser
发明人： George Holan , Reimund A. Walser
IPC分类号： C07C69/753 , A01N37/08 , A01N37/10 , A01N37/34 , A01N37/38 , A01N43/30 , A01N53/00 , A01N53/04 , A01N53/08 , C07C51/00 , C07C61/39 , C07C67/00 , C07C69/74 , C07C69/743 , C07C253/00 , C07C255/38 , C07C255/53 , C07D307/42 , C07D307/45 , C07D307/56 , C07D317/54 , C07C121/75 , C07D305/10
CPC分类号： C07C255/00 , A01N37/10 , A01N37/38 , A01N53/00
摘要： New compounds are described that fall within the general formula I ##STR1## wherein R is hydrogen, or a lower alkyl group, or one of the following groups:(a) 3-phenoxybenzyl(b) 2-benzyl-4-furylmethyl(c) .alpha.-cyano-3-phenoxybenzyl(d) 3,4-methylenedioxybenzyl(e) .alpha.-ethynyl-3-phenoxybenzyl(f) .alpha.-cyano-3-(4-chlorophenoxy)-benzyland A is one of the groups X or Y ##STR2## wherein X.sup.1, X.sup.2, X.sup.3 and X.sup.4 are the same or different groups and each is hydrogen or fluoro, chloro, bromo or methyl group, with the proviso that if X.sup.1 or X.sup.3 is a fluoro group then X.sup.2 or X.sup.4 should not be a bromo group; and wherein Y.sup.1, Y.sup.2, Y.sup.3, Y.sup.4, Y.sup.5 and Y.sup.6 are the same or different groups and each is hydrogen or a fluoro, bromo, chloro or methyl group.Processes of making the compounds are described. The compounds in which R.sup.3 is one of groups (a) to (f) are insecticides and insecticidal methods and compositions containing them are described.
摘要翻译：描述了新的化合物，其归属于其中R是氢或低级烷基的通式I（IMA）中，或下列基团之一：（a）3-苯氧基苄基（b）2-苄基-4-呋喃基甲基（c ）（d）（e）α-乙炔基-3-苯氧基苄基（f）α-氰基-3-（4-氯苯氧基） - 苄基的（甲基）亚甲二氧基苄基，（A）是X 或其中X 1，X 2，X 3和X 4为相同或不同的基团，并且各自为氢或氟，氯，溴或甲基，条件是如果X 1或X 3为氟基，则X 2或X 4应为不是溴族; 并且其中Y 1，Y 2，Y 3，Y 4，Y 5和Y 6相同或不同，各自为氢或氟，溴，氯或甲基。描述了制备化合物的方法。其中R3是基团（a）至（f）之一的化合物是杀虫剂和杀虫剂方法以及含有它们的组合物。

124. 发明授权

US4271180A Synergistic mixture of three pyrethroid series insecticidal compounds 失效
标题翻译：三种拟除虫菊酯系列杀虫化合物的协同混合物
公开(公告)号：US4271180A
公开(公告)日：1981-06-02
申请号：US58159
申请日：1979-07-17
申请人： Takashi Yamaguchi , Goro Shinjo , Yoshitoshi Okuno
发明人： Takashi Yamaguchi , Goro Shinjo , Yoshitoshi Okuno
IPC分类号： A01N53/00 , A01N53/02 , A01N53/04 , A01N53/08 , A01N43/36 , A01N37/00 , A01N37/08 , A01N43/08
CPC分类号： A01N53/00
摘要： An insecticidal composition containing an inert carrier and as active ingredients an insecticidally effective amount of a mixture comprising 2-allyl-3-methylcyclopento-2-ene-1-one-4-yl 2',2',3',3'-tetramethylcyclopropanecarboxylate or 2-propargyl-3-methylcyclopento-2-ene-1-one-4-yl 2',2',3',3'-tetramethylcyclopropanecarboxylate, and 3-phenoxybenzyl chrysanthemate, 5-benzyl-3-furylmethyl chrysanthemate or 3-phenoxybenzyl 2',2'-dimethyl-3'-(2",2"-dichlorovinyl)cyclopropane-1'-carboxylate, and N-(3,4,5,6-tetrahydrophthalimido)methyl chrysanthemate, which has synergistic lethal and knock-down effect on harmful insanitary insects as well as a synergistic flushing-out effect on cockroaches particularly as oil sprays, emulsifiable concentrates and aerosols.
摘要翻译：一种含有惰性载体和活性成分的杀虫组合物，其杀虫有效量的混合物包含2-烯丙基-3-甲基环戊-2-烯-1-酮-4-基2'，2'，3'，3'- 四甲基环丙烷羧酸酯或2-炔丙基-3-甲基环戊-2-烯-1-酮-4-基2'，2'，3'，3'-四甲基环丙烷羧酸酯和3-苯氧基苄基菊酸酯，5-苄基-3-呋喃基甲基菊酸酯或 3' - （2“，2” - 二氯乙烯基）环丙烷-1'-羧酸酯和N-（3,4,5,6-四氢邻苯二甲酰亚氨基）甲基菊酸酯的3-苯氧基苄基，对有害的无害昆虫具有协同的致命和击倒作用，以及对蟑螂的协同冲洗效果，特别是作为喷雾剂，可乳化浓缩物和气溶胶。

125. 发明授权

US4235927A Insecticidal benzylfurylmethyl perhaloalkylvinylcyclopropanecarboxylates 失效
标题翻译：杀虫杀螨甲基全卤代烷基乙烯基环丙烷羧酸酯
公开(公告)号：US4235927A
公开(公告)日：1980-11-25
申请号：US55212
申请日：1979-07-06
申请人： John F. Engel
发明人： John F. Engel
IPC分类号： A01N37/10 , A01N53/00 , A01N53/04 , C07C17/26 , C07C29/52 , C07C35/32 , C07C57/38 , C07C61/40 , C07F9/54 , A01N9/28 , C07D307/54
CPC分类号： C07F9/5442 , A01N37/10 , A01N53/00 , C07C17/2635 , C07C29/52 , C07C35/32 , C07C57/38 , C07C61/40
摘要： Perhaloalkylvinylcyclopropanecarboxylates having the general formula ##STR1## are disclosed wherein one of Y and Z is a perhaloalkyl group and the other is hydrogen, halogen, or lower alkyl. Compounds in which R is hydroxy, halogen or lower alkoxy are intermediates for preparation of insecticidal esters in which R is an optionally substituted benzylfurylmethoxy group. The insecticidal efficacy and preparation of the compounds and intermediates therefor are described and exemplified.
摘要翻译：公开了具有通式“IMAGE”I的全卤代烷基乙烯基环丙烷羧酸酯，其中Y和Z之一是全卤代烷基，另一个是氢，卤素或低级烷基。其中R是羟基，卤素或低级烷氧基的化合物是制备杀虫剂的中间体，其中R是任选取代的苄基甲氧基。化合物及其中间体的杀虫功效及其制备方法进行了说明和实例。

126. 发明授权

US4220655A Pesticidal 5-oxo-2,5 dihydropyrrole 失效
标题翻译：杀虫剂5-氧代-2,5-二氢吡咯
公开(公告)号：US4220655A
公开(公告)日：1980-09-02
申请号：US962843
申请日：1978-11-20
申请人： Beat Bohner , Marcus Baumann
发明人： Beat Bohner , Marcus Baumann
IPC分类号： C07D207/26 , A01N43/36 , A01N43/40 , A01N43/54 , A01N43/60 , A01N43/74 , A01N43/82 , A01N43/836 , A01N47/06 , A01N47/18 , A01N47/22 , A01N53/00 , A01N53/04 , A61K31/402 , C07D207/38 , C07D207/44 , C07D207/448 , C07D401/04 , C07D417/04 , A01N9/22 , C07D207/24
CPC分类号： C07D207/448 , A01N43/36 , A01N43/40 , A01N43/54 , A01N43/60 , A01N43/74 , A01N43/82 , A01N47/06 , A01N47/18 , A01N47/22 , A01N53/00 , C07D207/38
摘要： The present invention relates to novel 3,4-dimethyl-2-hydroxy-5-oxo-2,5-dihydropyrrole compounds substituted on the nitrogen atom, to processes for producing them, to their use in agriculture for combating animal and plant pests and also for regulating plant growth, and to compositions containing these novel pyrrole compounds.The novel 3,4-dimethyl-2-hydroxy-5-oxo-2,5-dihydropyrrole compounds substituted on the nitrogen atom correspond to the formula ##STR1## wherein A represents the hydroxyl group, a halogen atom or an O-acyl radical, andR represents an aryl radical, an aralkyl radical, or an heteroaromatic radical which has 5-6 ring members and which is bound by way of a carbon atom.
摘要翻译：本发明涉及在氮原子上取代的新型3,4-二甲基-2-羟基-5-氧代-2,5-二氢吡咯化合物，其制备方法，用于农业用于对抗动植物害虫和也用于调节植物生长，以及含有这些新颖的吡咯化合物的组合物。在氮原子上取代的新型3,4-二甲基-2-羟基-5-氧代-2,5-二氢吡咯化合物对应于下式：其中A表示羟基，卤素原子或O-酰基，R表示芳基，芳烷基或具有5-6个环成员且通过碳原子结合的杂芳族基团。

127. 发明授权

US4176189A Insecticidal and acaricidal hydantoin N-methylol esters 失效
标题翻译：杀虫剂和杀螨剂乙内酰脲N-羟甲基酯
公开(公告)号：US4176189A
公开(公告)日：1979-11-27
申请号：US909107
申请日：1978-05-24
申请人： Nobushige Itaya , Masachika Hirano
发明人： Nobushige Itaya , Masachika Hirano
IPC分类号： A01N43/50 , A01N53/00 , A01N53/04 , A01N53/10 , C07D233/72 , A61K31/415 , C07D405/12
CPC分类号： C07D233/72 , A01N43/50 , A01N53/00
摘要： Hydantoin N-methylol esters of the formula, ##STR1## wherein one of X and Y is a carbonyl group and the other is a methylene, ethylidene or propylidene group, R.sub.1 is a lower alkyl, lower alkenyl or lower alkynyl having up to 3 carbon atoms, R.sub.2 is a group represented by the formula, ##STR2## in which R.sub.3 is a hydrogen atom or a methyl group; when R.sub.3 is a hydrogen atom, R.sub.4 is a methoxyiminomethyl or 2,2-disubstituted vinyl group in which the substituents can be selected from the group consisting of methyl, vinyl, fluorine, chlorine and bromine, or both of the substituents may form tetramethylene chain; when R.sub.3 is a methyl group, R.sub.4 is a methyl group; R.sub.5 is a methyl, methoxy, fluorine, chlorine, bromine or 3,4-methylenedioxy group; and n is 1 or 2, a process for producing the same, insecticides and acaricides containing the same as an active ingredient, and novel intermediate compounds.
摘要翻译：乙酰头孢菌素N-羟甲基酯，其中X和Y中的一个是羰基，另一个是亚甲基，亚乙基或亚丙基，R 1是具有至多3个碳的低级烷基，低级链烯基或低级炔基原子，R 2是由下式表示的基团，其中R 3是氢原子或甲基; 当R3为氢原子时，R4为甲氧基亚氨基甲基或2,2-二取代的乙烯基，其中取代基可以选自甲基，乙烯基，氟，氯和溴，或两者均可形成四亚甲基链 ; 当R 3为甲基时，R 4为甲基; R5是甲基，甲氧基，氟，氯，溴或3,4-亚甲二氧基; n为1或2，其制造方法为含有与活性成分相同的杀虫剂和杀螨剂，以及新型中间体化合物。

128. 发明授权

US4163787A Substituted pyridine methyl esters of cyclopropane carboxylic acids and their use as insecticides 失效
标题翻译：环丙烷羧酸的取代吡啶甲酯及其作为杀虫剂的用途
公开(公告)号：US4163787A
公开(公告)日：1979-08-07
申请号：US859908
申请日：1977-12-12
申请人： Sudarshan K. Malhotra , Michael J. Ricks
发明人： Sudarshan K. Malhotra , Michael J. Ricks
IPC分类号： A01N53/00 , A01N53/04 , C07D213/64 , C07D213/647 , C07D213/70 , C07D405/12 , A61K31/44
CPC分类号： C07D213/647 , A01N53/00 , C07D213/70
摘要： Substituted pyridine methyl esters of cyclopropane carboxylic acids and the geometric and optical isomers thereof are prepared which correspond to the formula: ##STR1## wherein X independently represents alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, alkylthio of 1 to 4 carbon atoms, alkylsulfonyl of 1 to 4 carbon atoms, trifluoromethyl, 3,4-methylenedioxy, chloro, fluoro or bromo; n represents an integer of 0 to 2; Y represents oxygen or sulfur; R represents hydrogen, cyano or ethynyl and Z represents chloro, fluoro or bromo. These compounds have been found to exhibit a high degree of insecticidal activity and compositions containing said compounds are so employed.
摘要翻译：制备环丙烷羧酸的取代吡啶甲酯及其几何和旋光异构体，其对应于下式：其中X独立地表示1至4个碳原子的烷基，1至4个碳原子的烷氧基， 1至4个碳原子的烷硫基，1至4个碳原子的烷基磺酰基，三氟甲基，3,4-亚甲二氧基，氯，氟或溴; n表示0〜2的整数， Y表示氧或硫; R代表氢，氰基或乙炔基，Z代表氯，氟或溴。已经发现这些化合物具有高度的杀虫活性，因此使用含有所述化合物的组合物。

129. 发明授权

US4100298A Dispirocyclopropane carboxylate pesticides 失效
公开(公告)号：US4100298A
公开(公告)日：1978-07-11
申请号：US771236
申请日：1977-02-23
申请人： Royston H. Davis , Robert J. G. Searle
发明人： Royston H. Davis , Robert J. G. Searle
IPC分类号： C07C69/753 , A01N53/04 , A01N53/06 , A01N53/08 , A01N53/10 , C07C61/13 , C07C67/00 , C07C253/00 , C07C255/38 , C07D209/48 , C07D209/49 , C07D307/45 , A01N9/24 , A01N9/20 , C07C121/66
CPC分类号： C07D209/49 , C07C61/13 , C07D307/42
摘要： Certain dispirocyclopropane carboxylates are useful as pesticides.

130. 发明授权

US4100297A Novel anti-acarid methods 失效
标题翻译：新型抗螨方法
公开(公告)号：US4100297A
公开(公告)日：1978-07-11
申请号：US770303
申请日：1977-02-22
申请人： Jean Andre Grandadam , Simone Heurtaux
发明人： Jean Andre Grandadam , Simone Heurtaux
IPC分类号： A01N53/02 , A01N53/04 , A01N53/08 , A23K1/16 , A61K31/215 , A61K31/275 , A61K31/34 , A61K31/341 , A61K31/36 , A61K31/40 , A61K31/403 , A61K31/4035 , A61P33/00 , C07C69/747 , C07D209/49 , C07D307/45
CPC分类号： A61K31/36 , A23K20/105 , A23K20/111 , A23K20/121 , A23K20/132 , A61K31/215 , A61K31/275 , A61K31/34 , A61K31/40
摘要： Novel antiacaridal composition comprising an effective amount of at least one compound selected from the group consisting of cis and trans, racemic and optically active isomers of a compound of the formula ##STR1## wherein R.sub.1 is selected from the group consisting of hydrogen, halogen and alkyl of 1 to 8 carbon atoms, R.sub.2 is selected from the group consisting of hydrogen, halogen, alkyl of 1 to 8 carbon atoms and alkoxy carbonyl of 2 to 8 carbon atoms and R.sub.1 and R.sub.2 taken together with the carbon atom to which they are attached form a cycloalkyl of 3 to 6 carbon atoms and R is selected from the group consisting of ##STR2## and a pharmaceutical carrier and to a method of combatting acarids in warm-blooded animals.
摘要翻译：包含有效量的至少一种选自下式的化合物的顺式和反式，外消旋和旋光异构体的化合物的新型抗龋齿组合物，其中R 1选自氢，卤素和 1至8个碳原子的烷基，R 2选自氢，卤素，1至8个碳原子的烷基和2至8个碳原子的烷氧基羰基，R 1和R 2与它们所在的碳原子一起连接形成3至6个碳原子的环烷基，R选自由下列组成的组：药物载体和方法在温血动物中殴打螨虫。

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