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111. 发明授权

US5763353A Hydrogenation catalyst precursor, hydrogenation catalyst and production process for alcohols 失效
标题翻译：氢化催化剂前体，氢化催化剂和醇的生产方法
公开(公告)号：US5763353A
公开(公告)日：1998-06-09
申请号：US789540
申请日：1997-01-27
申请人： Yasuo Kadono , Yasuyuki Hattori , Masamitsu Horio , Fumihiko Nakamura
发明人： Yasuo Kadono , Yasuyuki Hattori , Masamitsu Horio , Fumihiko Nakamura
IPC分类号： B01J23/00 , B01J23/745 , B01J23/80 , C07C29/149 , B01J23/72
CPC分类号： B01J23/005 , B01J23/745 , B01J23/80 , C07C29/149
摘要： The present invention provides a hydrogenation catalyst precursor which does not bring about a problem of environmental pollution involved in copper-chromium catalysts and has a high activity, a high durability and a high selectivity as compared with those of conventional copper-iron-aluminum catalysts, a hydrogenation catalyst obtained by reducing the same, and a production process for alcohols using the above hydrogenation catalyst. The hydrogenation catalyst precursor described above comprises copper, iron and aluminum and containing as a principal component a compound oxide of copper, iron and aluminum in which an atomic ratio Cu:Fe:Al is 1:(0.02 to 0.4):(1.0 to 4.0) and which has a copper-aluminum spinel structure.
摘要翻译：本发明提供一种不与铜铬催化剂相关的环境污染问题的氢化催化剂前体，与常规铜 - 铁 - 铝催化剂相比具有高活性，高耐久性和高选择性，通过还原得到的氢化催化剂和使用上述氢化催化剂的醇的制备方法。上述氢化催化剂前体包括铜，铁和铝，并以铜，铁和铝的复合氧化物为主要成分，其中原子比Cu：Fe：Al为1：（0.02〜0.4）：1.0〜4.0 ），其具有铜 - 铝尖晶石结构。

112. 发明授权

US5728896A Process for the preparation of hydroxymethyl-cyclopropane 失效
标题翻译：制备羟甲基环丙烷的方法
公开(公告)号：US5728896A
公开(公告)日：1998-03-17
申请号：US601931
申请日：1996-02-15
申请人： Lutz Frohn , Reinhard Langer , Gerhard Darsow , Eberhard Zirngiebl , Jorg-Dietrich Jentsch , Bernd Pennemann , Christoph Tiburtius
发明人： Lutz Frohn , Reinhard Langer , Gerhard Darsow , Eberhard Zirngiebl , Jorg-Dietrich Jentsch , Bernd Pennemann , Christoph Tiburtius
IPC分类号： B01J23/06 , C07B61/00 , C07C27/02 , C07C29/149 , C07C31/133 , C07C29/136
CPC分类号： C07C29/149 , B01J23/06 , C07C2101/02
摘要： Hydroxymethyl-cyclopropane (cyclopropyl-methanol) can be obtained in a manner which is both economical and environment-friendly by catalytic hydrogenation of cyclopropanecarboxylic acid alkyl esters under increased pressure at elevated temperature if a chromium-free zinc oxide catalyst is employed as the catalyst.
摘要翻译：如果使用无铬氧化锌催化剂作为催化剂，可以通过环烷基羧酸烷基酯在升高的压力下在升高的温度下的催化氢化，以经济和环境友好的方式获得羟甲基 - 环丙烷（环丙基甲醇）。

113. 发明授权

US5689003A Ruthenium hydrogenation catalysts 失效
标题翻译：钌氢化催化剂
公开(公告)号：US5689003A
公开(公告)日：1997-11-18
申请号：US646594
申请日：1996-05-08
申请人： Richard Paul Beatty , Rocco Angelo Paciello
发明人： Richard Paul Beatty , Rocco Angelo Paciello
IPC分类号： C07D307/33 , B01J31/22 , B01J31/24 , C07B61/00 , C07C29/09 , C07C29/149 , C07C31/20 , C07C209/36 , C07C209/46 , C07C209/48 , C07C211/27 , C07C211/46 , C07C249/02 , C07C253/30 , C07F15/00 , C07C209/32
CPC分类号： B01J31/2404 , B01J31/2295 , C07C209/36 , C07C209/48 , C07C249/02 , C07C253/30 , C07C29/149 , C07F15/0046 , C07F15/0053 , B01J2231/641 , B01J2231/643 , B01J2531/821 , B01J2531/96
摘要： The invention relates to a novel ruthenium complex having the formula Ru(.eta..sup.3 --C.sub.6 H.sub.8 --PCy.sub.2)(PCy.sub.3)Cl, wherein Cy is cyclohexyl; its use in the preparation of RuHCl(H.sub.2)(PCy.sub.3).sub.2 and RuH.sub.2 (H.sub.2).sub.2 (PCy.sub.3).sub.2 ; and the use of the complexes as catalysts in hydrogenation, imination and reductive hydrolysis processes.
摘要翻译：本发明涉及具有式Ru（eta 3-C6H8-PCy2）（PCy3）Cl的新型钌络合物，其中Cy是环己基; 其用于制备RuHCl（H2）（PCy3）2和RuH2（H2）2（PCy3）2; 以及在氢化，仿制和还原水解过程中使用络合物作为催化剂。

114. 发明授权

US5658843A Method for preparing copper-containing hydrogenation reaction catalyst and method for producing alcohol 失效
标题翻译：制备含铜加氢反应催化剂的方法及其制备方法
公开(公告)号：US5658843A
公开(公告)日：1997-08-19
申请号：US448580
申请日：1995-06-06
申请人： Kiyoshi Tsukada , Yasuyuki Hattori , Taku Mimura , Osamu Tabata , Futoshi Nishigaki
发明人： Kiyoshi Tsukada , Yasuyuki Hattori , Taku Mimura , Osamu Tabata , Futoshi Nishigaki
IPC分类号： B01J23/72 , B01J23/60 , B01J23/70 , B01J23/745 , B01J23/80 , B01J23/86 , B01J37/00 , B01J37/16 , B01J37/18 , C07B61/00 , C07C29/149 , C07C31/125
CPC分类号： B01J37/18 , B01J23/60 , B01J23/72 , B01J23/80 , B01J23/868 , B01J37/16 , C07C29/149 , B01J23/745 , B01J37/0009
摘要： A method for preparing a copper-containing hydrogenation reaction catalyst includes the step of reducing a formed precursor of a copper-containing hydrogenation reaction catalyst with hydrogen gas or a mixture of hydrogen and inert gas by liquid phase reduction in a stream of a solvent. The reductive activation is carried out by the two steps of performing the first stage of liquid phase reduction by which the catalyst precursor is activated in the temperature range of from 20.degree. to 140.degree. C. so that at least 10% by weight of the copper oxide contained in the catalyst precursor can be reduced by the time when the temperature passes 140.degree. C., and then performing the second stage of liquid phase reduction by which the catalyst precursor is further activated in the temperature range of from 140.degree. to 250.degree. C. The catalyst thus obtained has markedly improved catalytic activity and selectivity. An alcohol of high quality can be obtained at a high productivity using the catalyst in a fixed bed continuous reaction system.
摘要翻译： PCT No.PCT / JP94 / 00077 Sec。 371日期：1995年6月6日 102（e）日期1995年6月6日PCT 1994年1月20日PCT PCT。公开号WO95 / 19844 日期：1995年7月27日制备含铜氢化反应催化剂的方法包括以下步骤：用氢气或氢气和惰性气体的混合物在流中通过液相还原将还原形成的含铜氢化反应催化剂的前体的溶剂。还原活化通过进行第二阶段的液相还原的两个步骤进行，催化剂前体在20℃至140℃的温度范围内被活化，因此至少10重量％的铜包含在催化剂前体中的氧化物可以在温度达到140℃时降低，然后进行第二阶段的液相还原，催化剂前体在140°至250°的温度范围内进一步活化因此得到的催化剂显着地改善了催化活性和选择性。使用固定床连续反应体系中的催化剂可以以高生产率获得高质量的醇。

115. 发明授权

US5599986A Process for the preparation of alkali metal salts of diformylamide 失效
标题翻译：二酰胺的碱金属盐的制备方法
公开(公告)号：US5599986A
公开(公告)日：1997-02-04
申请号：US513501
申请日：1995-08-31
申请人： Jonathan C. Evans , Christian T. Goralski , Cynthia L. Rand , Paul C. Vosejpka
发明人： Jonathan C. Evans , Christian T. Goralski , Cynthia L. Rand , Paul C. Vosejpka
IPC分类号： A61K31/135 , A61P43/00 , C07C20060101 , C07C17/16 , C07C25/24 , C07C29/147 , C07C29/149 , C07C33/48 , C07C69/65 , C07C209/62 , C07C211/29 , C07C231/08 , C07C231/24 , C07C233/13 , C07C233/90 , C07C233/00
CPC分类号： C07C17/16 , C07C211/29 , C07C233/13 , C07C25/24 , C07C29/147 , C07C33/483 , C07C69/65
摘要： The present invention relates to a novel process for preparing alkali metal salts of diformylamide and a novel crystalline form of sodium diformylamide.
摘要翻译：本发明涉及一种制备二酰胺的碱金属盐的新方法和二甲酰胺钠的新结晶形式。

116. 发明授权

US5414159A Process 失效
标题翻译：处理
公开(公告)号：US5414159A
公开(公告)日：1995-05-09
申请号：US174320
申请日：1993-12-30
申请人： Paul Appleton , Michael A. Wood
发明人： Paul Appleton , Michael A. Wood
IPC分类号： B01J23/889 , C07B61/00 , C07C27/02 , C07C29/149 , C07C31/27 , C07C35/14 , C07C29/136 , C07C31/20
CPC分类号： C07C35/14 , C07C29/149 , C07C2101/14
摘要： A process is described for the production of cyclohexanedimethanol by hydrogenation of a dialkyl cyclohexanedicarboxylate which comprises the steps of:(a) providing a hydrogenation zone containing a charge of a granular reduced manganese promoted copper catalyst;(b) forming a vaporous feed stream of a hydrogenatable material comprising a dialkyl cyclohexanedicarboxylate and from about 0.1 wt % up to about 15 wt % of an acidic material at a feed temperature which is in the range of from about 150.degree. C. to about 350.degree. C. and which is above the dew point of the feed stream and at a feed pressure which is in the range of from about 150 psia (about 10.34 bar) up to about 2000 psia (about 137.90 bar), said vaporous mixture having a known hydrogen-containing gas:dialkyl cyclohexanedicarboxylate ratio;(c) supplying the vaporous feed stream to the hydrogenation zone;(d) maintaining hydrogenation conditions in the hydrogenation zone which are effective to maintain the reaction mixture in contact with the catalyst above its dew point;(e) passing the vaporous feed stream through the hydrogenation zone: and(f) recovering from the hydrogenation zone a product stream comprising cyclohexanedimethanol.
摘要翻译：描述了通过氢化环己烷二羧酸二烷基酯制备环己烷二甲醇的方法，该方法包括以下步骤：（a）提供含有粒状还原锰促进铜催化剂装料的氢化区; （b）在约150℃至约20℃的进料温度下，形成包含环己烷二羧酸二烷基酯和约0.1重量％至约15重量％酸性物质的可氢化材料的气态进料流 350℃，高于进料流的露点，进料压力在约150psia（约10.34巴）至约2000psia（约137.90巴）的范围内，所述蒸气混合物具有已知的含氢气体：环己烷二羧酸二烷基酯比例; （c）将蒸气进料流供应到氢化区; （d）保持加氢区中的氢化条件，其有效地使反应混合物与催化剂接触高于其露点; （e）使气态进料流通过氢化区;和（f）从氢化区回收包含环己烷二甲醇的产物流。

117. 发明授权

US5399792A Process for the production of unsaturated fatty alcohols 失效
标题翻译：生产不饱和脂肪醇的方法
公开(公告)号：US5399792A
公开(公告)日：1995-03-21
申请号：US204251
申请日：1994-05-06
申请人： Guenther Demmering
发明人： Guenther Demmering
IPC分类号： C07C29/149 , C07C31/20 , C07C33/02 , C07C33/025
CPC分类号： C07C29/149
摘要： Unsaturated fatty alcohols with 6 to 22 C atoms can be produced by directly hydrating deacidified and/or non-deacidified glyceride oils containing monounsaturated and/or polyunsaturated, straight chain and/or branched-chain fatty acids having 6 to 22 C atoms in the fatty acid residue, by applying a 30 to 100-fold excess of hydrogen in a pressure range from 50 to 300 bars, at temperatures from 200.degree. to 400.degree. C., to zinc-chrome-catalysts of the spinel type, while largely preserving the olefinic double bonds and with formation of propane and 1,2-propylene glycol.
摘要翻译： PCT No.PCT / EP92 / 01985。 371日期：1994年5月6日 102（e）日期1994年5月6日PCT提交1992年8月28日PCT公布。公开号WO93 / 05003 具有6至22个碳原子的不饱和脂肪醇可以通过直接水合含有单不饱和和/或多不饱和的直链和/或支链脂肪酸的脱酸和/或非脱酸甘油酯油，其具有6 至22 C原子，通过在50至300巴的压力范围内，在200-400℃的温度下，将30至100倍过量的氢施加至铬 - 铬催化剂尖晶石型，同时在很大程度上保持烯属双键并形成丙烷和1,2-丙二醇。

118. 发明授权

US5395987A Preparation of cyclohexanedimethanol with a particular ratio 失效
标题翻译：以特定比例制备环己烷二甲醇
公开(公告)号：US5395987A
公开(公告)日：1995-03-07
申请号：US175502
申请日：1993-12-30
申请人： Colin Rathmell , Richard C. Spratt , Michael W. M. Tuck
发明人： Colin Rathmell , Richard C. Spratt , Michael W. M. Tuck
IPC分类号： B01J23/889 , C07B61/00 , C07C27/02 , C07C29/149 , C07C31/27 , C07C31/13 , C07C27/04
CPC分类号： C07C31/276 , C07C29/149 , C07C2101/14
摘要： A continuous process is described for the production of 1,4-cyclohexanedimethanol (CHDM) having a desired or predetermined trans-:cis- isomer ratio by catalytic hydrogenation of a dialkyl 1,4-cyclohexanedicarboxylate in the presence of an ester hydrogenation catalyst. The process is capable of being operated for an extended period of time during which the hydrogenation catalyst declines in catalytic activity and comprises feeding a vaporous mixture of the dialkyl 1,4-cyclohexanedicarboxylate and hydrogen to a hydrogenation zone containing the hydrogenation catalyst and recovering CHDM product. The degree of conversion of the dialkyl 1,4-cyclohexanedicarboxylate at a particular combination of temperature and pressure is related to the trans-:cis- isomer ratio of the CHDM product and may be varied by adjusting at least one feed condition selected from (i) the dialkyl 1,4-cyclohexanedicarboxylate feed rate and (ii) the hydrogen-containing gas:dialkyl 1,4-cyclohexanedicarboxylate molar ratio. As catalyst activity declines during operation of the process over an extended period of time at a particular combination of temperature and pressure, the degree of conversion of the dialkyl 1,4-cyclohexanedicarboxylate and/or the trans-:cis- isomer ratio of the CHDM product may be maintained at a constant value by adjusting at least one of the feed conditions referred to above. The determination of the Actual Activity and Reference Activity of the catalyst and the Actual and Effective Residence Times are included in the hydrogenation process.
摘要翻译：描述了在酯加氢催化剂存在下通过催化氢化1,4-环己烷二羧酸二烷基酯生产具有所需或预定的反式 - 顺式 - 异构体比例的1,4-环己烷二甲醇（CHDM）的连续方法。该方法能够长时间运行，在此期间氢化催化剂催化活性下降，并且包括将1,4-环己烷二羧酸二烷基酯和氢气的蒸气混合物进料到含氢化催化剂的氢化区和回收CHDM产物。在特定的温度和压力组合下，1,4-环己烷二羧酸二烷基酯的转化度与CHDM产物的反式 - 顺式 - 异构体比例有关，并且可以通过调节至少一种进料条件来改变，所述进料条件选自（i ）1,4-环己烷二羧酸二烷基酯进料速率和（ii）含氢气体：1,4-环己烷二羧酸二烷基酯摩尔比。随着催化剂活性在特定的温度和压力组合下长时间运行过程中催化剂活性下降，1,4-环己烷二羧酸二烷基酯的转化率和/或CHDM的反式 - 顺式异构体比例可以通过调节至少一种上述进料条件将产物保持在恒定值。催化剂的实际活性和参考活性的确定以及实际和有效的停留时间包括在加氢过程中。

119. 发明授权

US5395986A Process for the production of cyclohexanedimethanol 失效
标题翻译：环己烷二甲醇生产方法
公开(公告)号：US5395986A
公开(公告)日：1995-03-07
申请号：US174314
申请日：1993-12-30
申请人： John Scarlett , Michael A. Wood
发明人： John Scarlett , Michael A. Wood
IPC分类号： B01J23/42 , B01J23/44 , B01J23/60 , B01J23/72 , B01J23/86 , B01J23/889 , C07B53/00 , C07B61/00 , C07C29/149 , C07C31/27
CPC分类号： C07C29/149 , C07C31/276 , C07C2101/14
摘要： A process is described for the production of cyclohexanedimethanol having a trans-:cis-isomer ratio greater than about 1:1 by hydrogenation of a dialkyl (e.g. dimethyl) cyclohexanedicarboxylate having a trans-:cis-isomer ratio less than about 1:1 which comprises:(a) providing a hydrogenation zone containing a charge of a granular heterogeneous ester hydrogenation catalyst;(b) supplying to the hydrogenation zone a vaporous feed stream containing hydrogen and a hydrogenarable material comprising a dialkyl cyclohexanedicarboxylate at an inlet temperature which is above its dew point of the mixture;(c) maintaining the hydrogenation zone under temperature and pressure conditions which are conducive to effecting hydrogenation of esters;(d) passing the vaporous feed stream through the hydrogenation zone; and(e) recovering from the hydrogenation zone a product stream containing cyclohexanedimethanol having a trans-:cis-isomer ratio greater than 1:1.In this process it is preferred to use dimethyl 1,4-cyclohexanedicarboxylate to produce 1,4-cyclohexanedimethanol.
摘要翻译：描述了通过氢化具有反式 - 顺式异构体比例小于约1:1的二烷基（例如二甲基）环己烷二羧酸酯制备具有大于约1:1的反式 - 顺式 - 异构体比例的环己烷二甲醇的方法，其中包括：（a）提供含有粒状非均相酯加氢催化剂装料的氢化区; （b）在高于其混合物露点的入口温度下向氢化区供应含有氢的气态进料流和包含环己烷二羧酸二烷基酯的可氢化材料; （c）在有利于酯化氢化的温度和压力条件下保持氢化区; （d）使蒸汽进料流通过氢化区; 和（e）从氢化区回收含有反式 - 顺式异构体比大于1:1的环己烷二甲醇的产物流。在该方法中，优选使用1,4-环己烷二羧酸二甲酯来制备1,4-环己烷二甲醇。

120. 发明授权

US5391771A Hydrogenation of citric acid 失效
标题翻译：柠檬酸氢化
公开(公告)号：US5391771A
公开(公告)日：1995-02-21
申请号：US130003
申请日：1993-09-30
申请人： Hans-Juergen Weyer , Rolf Fischer , Christoph Sigwart
发明人： Hans-Juergen Weyer , Rolf Fischer , Christoph Sigwart
IPC分类号： C07C29/149 , C07C31/22 , C07C51/377 , C07C55/22 , C07C67/327 , C07D307/06 , C07D307/12 , C07D307/16 , C07D307/68 , C07D309/06 , C07D315/00 , C07D305/12 , C07C27/00 , C07C51/36
CPC分类号： C07D315/00 , C07C29/149 , C07C31/22 , C07C51/377 , C07C67/327 , C07D307/06 , C07D307/12 , C07D307/16 , C07D309/06
摘要： A process for the preparation of propane-1,2,3-tricarboxylic acid, tetrahydrofurfurylacetic acid and the C.sub.1 - to C.sub.20 -alkyl or C.sub.7 - to C.sub.12 -aralkyl esters thereof, propane-1,2,3-trimethanol, 3-methyltetrahydrofuran, 3-(2'-hydroxyethyl)tetrahydrofuran, 4-hydroxymethyltetrahydropyran, 2-methyl-.gamma.-butyrolactone and/or 3-methyl-.gamma.-butyrolactone, comprises reacting citric acid or the C.sub.1 - to C.sub.20 -alkyl or C.sub.7 - to C.sub.12 -aralkyl esters thereof on hydrogenation catalysts in non-aqueous solvents at from 50.degree. to 400.degree. C. and at from 1 to 400 bar.
摘要翻译：丙烷-1,2,3-三羧酸，四氢糠基乙酸及其C 1 -C 20烷基或C 7〜C 12 - 芳烷基酯的制备方法，丙烷-1,2,3-三甲醇，3-甲基四氢呋喃，3-（2'-羟乙基）四氢呋喃，4-羟甲基四氢吡喃，2-甲基-γ-丁内酯和/或3-甲基-γ-丁内酯，包括使柠檬酸或C 1 -C 20烷基或C 7至C 12 - 烷基酯在氢化催化剂的溶剂中，在50至400℃和1至400巴之间。

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