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101. 发明授权

US5294732A Polysubstituted fullerenes and their preparation 失效
标题翻译：多取代富勒烯及其制备方法
公开(公告)号：US5294732A
公开(公告)日：1994-03-15
申请号：US996207
申请日：1992-12-23
申请人： Long Y. Chiang , Ravindra B. Upasanti , John W. Swirczewski
发明人： Long Y. Chiang , Ravindra B. Upasanti , John W. Swirczewski
IPC分类号： C08L101/00 , C01B31/02 , C07B41/02 , C07B41/12 , C07B43/00 , C07C35/44 , C07C37/60 , C07C39/17 , C07C63/70 , C07C205/41 , C07C215/44 , C07C219/24 , C07C233/06 , C07C233/14 , C07C233/21 , C07C233/23 , C08G63/16 , C07C39/23 , C07C235/40
CPC分类号： B82Y30/00 , B82Y40/00 , C01B31/0206 , C01B31/0213 , C07C201/10 , C07C201/12 , C07C205/41 , C07C209/68 , C07C213/02 , C07C213/08 , C07C231/06 , C07C231/12 , C07C37/70 , C07C51/27 , C07C51/285 , C07C63/70 , C08G63/16 , C07C2103/97 , C07C2104/00 , Y10S977/734 , Y10S977/738 , Y10S977/753 , Y10S977/842 , Y10S977/848
摘要： The present invention is directed to polysubstituted fullerene moieties having a plurality of substituents thereon wherein the substituents are selected from the group consisting of hydroxy in combination with hydroxy, amino, oxide, nitro, organocarboxy, amide and mixtures thereof.
摘要翻译：本发明涉及其上具有多个取代基的多取代富勒烯部分，其中取代基选自羟基与羟基，氨基，氧化物，硝基，有机羧基，酰胺及其混合物组合。

102. 发明授权

US5183939A Process for the racemization of optically active 1-aryl-alkylamines 失效
标题翻译：光活性1-芳基 - 氨基甲酸酯的制备方法
公开(公告)号：US5183939A
公开(公告)日：1993-02-02
申请号：US796109
申请日：1991-11-21
申请人： Johannes R. Jansen , Martin Littmann
发明人： Johannes R. Jansen , Martin Littmann
IPC分类号： C07B55/00 , C07C209/66 , C07C209/68 , C07C209/82 , C07C209/88 , C07C211/27 , C07C211/29 , C07C211/30 , C07C217/58
CPC分类号： C07C209/68 , C07B2200/07
摘要： A new process for the racemization of optically active 1-aryl-alkylamines of the formula (I) ##STR1## in which Ar represents optionally substituted aryl andR represents alkyl,which is characterized in that compounds of the formula (I) which largely have the R- or S-configuration at the carbon atom marked by * are reacted with metal alkoxides in dimethyl sulphoxide, optionally in the presence of appropriate alcohols, at temperatures between 0.degree. C. and 200.degree. C.
摘要翻译：用于使式（I）的光学活性1-芳基 - 烷基胺外消旋化的新方法其中Ar表示任选取代的芳基，R表示烷基，其特征在于式（I）化合物在0℃和200℃之间的温度下，在由*标记的碳原子上大部分具有R-或S-构型的金属醇盐在二甲基亚砜中任选地在适当的醇存在下与二甲基亚砜反应。

103. 发明授权

US5103059A Process for alkylation of aromatic diamines 失效
标题翻译：芳族氨基酸的处理方法
公开(公告)号：US5103059A
公开(公告)日：1992-04-07
申请号：US601516
申请日：1990-10-23
申请人： Kryn G. Ihrman , Olan W. Mitchell , R. Woodrow Wilson, Jr.
发明人： Kryn G. Ihrman , Olan W. Mitchell , R. Woodrow Wilson, Jr.
IPC分类号： B01J31/14 , C07B61/00 , C07C209/68 , C07C211/50
CPC分类号： C07C209/68 , B01J31/143 , B01J2231/4205
摘要： Production of alkyl substituted aromatic diamines by reacting triethylaluminum with an aromatic diamine and a chloride ion source in the presence of an olefin is disclosed. The alkyl substituted aromatic diamines are useful as chain extenders in polyurethane processes.

104. 发明授权

US5082970A Process for recycling amine isomer 失效
标题翻译：回收胺异构体的方法
公开(公告)号：US5082970A
公开(公告)日：1992-01-21
申请号：US665506
申请日：1991-03-06
申请人： Tamim F. Braish
发明人： Tamim F. Braish
IPC分类号： C07B61/00 , C07C209/00 , C07C209/68 , C07C211/38 , C07C211/42
CPC分类号： C07C209/68 , C07C211/38 , C07C2102/10 , Y02P20/582
摘要： A novel process for converting trans-isomeric N-methyl-4-(3,4-dichlorophenyl)-1,2,3,4-tetrahydro-1-naphthaleneamine to cis-isomeric N-methyl-4-(3,4-dichlorophenyl)-1,2,3,4-tetrahydro-1-naphthaleneamine is disclosed. The process involves contacting trans-isomeric N-methyl-4-(3,4-dichlorophenyl)-1,2,3,4-tetrahydro-1-naphthaleneamine, or a mixture of same with up to about an equal part by weight of the corresponding cis-isomer, with a basic equilibration agent like potassium tert.-butoxide in a reaction-inert polar organic solvent to ultimately afford a cis/trans-mixture wherein the amount of cis-amine present in said mixture achieves a constant value of about 2:1 on a weight-by-weight basis. The aforesaid resultant mixture is useful as an intermediate product that ultimately leads to pure cis-(1S) (4S)-N-methyl-4-(3,4-dichlorophenyl)-1,2,3,4-tetrahydro-1-naphthaleneamine (sertraline), which is a known antidepressant agent.
摘要翻译：将反式异构体N-甲基-4-（3,4-二氯苯基）-1,2,3,4-四氢-1-萘胺转化成顺式异构体N-甲基-4-（3,4-二氯苯基）二氯苯基）-1,2,3,4-四氢-1-萘胺。该方法包括将反式异构体N-甲基-4-（3,4-二氯苯基）-1,2,3,4-四氢-1-萘胺或其混合物与至多约等于重量份的相应的顺式异构体与碱性平衡剂如叔丁醇钾在反应惰性极性有机溶剂中反应，最终得到顺式/反式混合物，其中所述混合物中存在的顺式胺的量达到恒定值约2:1，以重量计。上述所得混合物可用作最终导致纯的顺式 - （1S）（4S）-N-甲基-4-（3,4-二氯苯基）-1,2,3,4-四氢-1- 萘胺（舍曲林）是已知的抗抑郁药。

105. 发明授权

US4978789A Process for production of alkenyl substituted aromatic compound 失效
标题翻译：烯基取代芳族化合物的制备方法
公开(公告)号：US4978789A
公开(公告)日：1990-12-18
申请号：US376929
申请日：1989-07-10
申请人： Katsuo Taniguchi , Shigeki Fujikawa , Yoshito Kurano
发明人： Katsuo Taniguchi , Shigeki Fujikawa , Yoshito Kurano
IPC分类号： C07C37/00 , C07C209/68
CPC分类号： B01J23/862 , B01J23/825 , B01J23/835 , B01J23/8472 , B01J37/031 , C07C209/68 , C07C37/001 , B01J2523/00
摘要： A process for producing an alkenyl substituted aromatic compound having the general formula (I): ##STR1## wherein Ar represents an aromatic ring, R.sup.1 represents an alkenyl group having 2 to 8 carbon atoms, p is 1, 2, or 3 provided that R.sup.1 may be the same or different when p is 2 or 3, R.sup.2 represents an alkyl group having 1 to 8 carbon atoms, q is 0, 1, or 2 provided that R.sup.2 may be the same or different when q is 2, X represents --OH or --NR.sup.3 R.sup.4 wherein R.sup.3 and R.sup.4 independently represent hydrogen or an alkyl group having 1 to 2 carbon atoms, n is 1 or 2, provided that the sum of p and q is 1, 2, or 3 comprising the step of catalytically dehydrogenating an alkyl substituted aromatic compound having the general formula (III): ##STR2## wherein R.sup.5 represents an alkyl group having 2 to 8 carbon atoms and Ar, R.sup.2, X, p, q, and n are the same as defined above, n is 1 or 2, provided that R.sup.5 may be the same or different when p is 2 or 3 in the presence of a catalyst comprising (a) at least one iron oxide as a main component and (b) at least one oxide of metals belonging to the group III, IV or V of the periodic table of atoms.This catalyst can produce an alkenyl substituted aromatic compound having a hydroxyl or amino group in the aromatic ring thereof from the dehydrogenation of the corresponding alkyl substituted aromatic compound at a high yield and high selectivity and has a prolonged catalyst life.
摘要翻译：一种制备具有通式（I）的烯基取代的芳族化合物的方法：其中Ar表示芳族环，R 1表示具有2至8个碳原子的链烯基，p是1,2或3 条件是当p为2或3时，R 1可以相同或不同，R 2表示具有1至8个碳原子的烷基，q为0,1或2，条件是当q为2时，R 2可以相同或不同， X表示-OH或-NR 3 R 4，其中R 3和R 4独立地表示氢或具有1至2个碳原子的烷基，n为1或2，条件是p和q之和为1,2或3，包括步骤催化脱氢具有通式（III）的烷基取代的芳族化合物：其中R 5表示具有2至8个碳原子的烷基，Ar，R 2，X，p，q和n与 n为1或2，条件是当催化剂存在时p为2或3时，R 5可以相同或不同，所述催化剂包含（a）至少一种i 氧化物作为主要成分，和（b）属于元素周期表第III，IV或V族的金属的至少一种氧化物。该催化剂可以以高产率和高选择性从相应的烷基取代的芳族化合物的脱氢产生其芳环中具有羟基或氨基的烯基取代的芳族化合物，并具有延长的催化剂寿命。

106. 发明授权

US4973754A Preparation of bis(p-aminocumyl)benzenes 失效
标题翻译：双（对氨基辛基）苯的制备
公开(公告)号：US4973754A
公开(公告)日：1990-11-27
申请号：US352233
申请日：1989-05-15
申请人： Simon M. Li
发明人： Simon M. Li
IPC分类号： C07C209/68
CPC分类号： C07C209/68
摘要： Bis(p-aminocumyl)benzenes are prepared by treating diisopropylbenzene derivatives with a primary or secondary aniline in the presence of a catalytic amount of an acidic perfluorinated polymer.
摘要翻译：通过在催化量的酸性全氟化聚合物的存在下用伯或仲苯胺处理二异丙基苯衍生物来制备双（对氨基己基）苯。

107. 发明授权

US4824601A Liquid antioxidant produced by alkylating diphenylamine with a molar excess of diisobutylene 失效
标题翻译：通过用二异丁腈摩尔过量的二苯胺烷基化生成的液体抗氧化剂
公开(公告)号：US4824601A
公开(公告)日：1989-04-25
申请号：US144596
申请日：1988-01-11
申请人： Janet Franklin
发明人： Janet Franklin
IPC分类号： C07C209/68 , C08K5/17 , C08K5/18 , C08L7/00 , C09K15/18 , C10M133/12 , C10M133/14 , C10M159/12 , C10N30/10
CPC分类号： C09K15/18 , C07C209/68 , C10M133/12 , C10M2215/064
摘要： Process is described for the production of a liquid antioxidant composition by reaction of diphenylamine with diisobutylene comprising reacting diphenylamine with diisobutylene in a molar ratio of from 1:1.1 to 1:2.5 and in the presence of an acid activated earth catalyst, while ensuring that the concentration of diisobutylene remains substantially constant throughout the reaction period at a reaction temperature of at least 160.degree. C., the reaction being effected for such a period that the content of 4,4'-dioctyldiphenylamine in the reaction mass, excluding catalyst, is below 25% by weight; and removing catalyst and unreacted diisobutylene; the product of this process; and the use of this product as a stabilizer for organic material against oxidative degradation.
摘要翻译：描述了通过二苯胺与二异丁烯的反应生产液体抗氧化剂组合物的方法，包括使二苯胺与摩尔比为1:1.1比1:2.5的二异丁烯和酸活化的土催化剂的存在下反应，同时确保在整个反应期间，二异丁烯的浓度在至少160℃的反应温度下保持基本上恒定，反应进行到反应物料中不含催化剂的4,4'-二辛基二苯胺的含量低于 25％（重量）; 除去催化剂和未反应的二异丁烯; 这个过程的产物; 以及使用该产品作为有机材料的抗氧化降解的稳定剂。

108. 发明授权

US4804784A Process for preparing methyl- and ethyl-substituted primary anilines 失效
标题翻译：制备甲基和乙基取代的主要苯胺的方法
公开(公告)号：US4804784A
公开(公告)日：1989-02-14
申请号：US782573
申请日：1985-10-01
申请人： Frank J. Weigert
发明人： Frank J. Weigert
IPC分类号： C07C209/68 , F02B1/04 , C07C85/24
CPC分类号： C07C209/68 , F02B1/04
摘要： A process is disclosed for the preparation of methyl- and ethyl-substituted anilines by contacting anilines of specified formula at about 250.degree.-525.degree. C. and about 10 kPa-10 MPa of pressure in the of presence of a nonbasic metal oxide catalyst which when it is a zeolite has pore dimensions of at least about 0.52 nm and has cages with dimensions greater than about 0.75 nm.
摘要翻译：公开了一种制备甲基和乙基取代的苯胺的方法，该方法是在非碱性金属氧化物催化剂存在下，通过在约250-55℃和约10kPa-10MPa的压力下接触特定式的苯胺，当沸石具有至少约0.52nm的孔尺寸并且具有大于约0.75nm的尺寸的笼。

109. 发明授权

US4721810A Catalytic alkylation of aromatic amines with ethers 失效
标题翻译：芳香胺与醚的催化烷基化
公开(公告)号：US4721810A
公开(公告)日：1988-01-26
申请号：US618005
申请日：1984-06-06
申请人： Duane C. Hargis
发明人： Duane C. Hargis
IPC分类号： C07D295/02 , B01J21/06 , B01J23/00 , C07B61/00 , C07C67/00 , C07C209/00 , C07C209/16 , C07C209/18 , C07C209/68 , C07C211/50 , C07C231/00 , C07C231/08 , C07C233/06 , C07D207/06 , C07D207/08 , C07D207/26 , C07D207/267 , C07D207/32 , C07D207/323 , C07D233/32 , C07D295/08 , C07C89/02 , C07C85/24
CPC分类号： C07D207/08 , C07C209/68 , C07D207/06 , C07D207/267 , C07D207/323 , C07D233/32
摘要： Aromatic amines are alkylated by reaction with an acyclic ether or an unstrained cyclic ether in the presence of a B-subgroup metal oxide alkylation catalyst, preferably a Group IV-B metal oxide with or without a minor proportion of a Group VI-B or Group VIII metal oxide, so that alkylation of the aromatic amine occurs. Under most reaction conditions ether alkylating agents such as diethyl ether not consumed in the alkylation reaction pass through the reaction zone undecomposed and thus can be readily recovered for recycle or other use.
摘要翻译：在B族亚烷基金属氧化物烷基化催化剂，优选具有或不具有少量VI-B或组的少量IV-B族金属氧化物的存在下，通过与无环醚或未应变环状醚的反应将芳族胺烷基化 VIII金属氧化物，从而发生芳族胺的烷基化。在大多数反应条件下，在烷基化反应中未消耗的醚烷基化剂如二乙醚未分解通过反应区，因此可以容易地回收再循环或其它用途。

110. 发明授权

US4705895A 5,5'-diamino or 5,5'-diacetamido-2,2'-bis(diphenylphosphino)-1,1'-binaphthyls 失效
标题翻译： 5,5'-二氨基或5,5'-二乙酰氨基-2,2'-双（二苯基膦基）-1,1'-联萘
公开(公告)号：US4705895A
公开(公告)日：1987-11-10
申请号：US937805
申请日：1986-11-21
申请人： Tamon Okano , Hidenori Kumobayashi , Susumu Akutagawa , Jitsuo Kiji , Hisatoshi Konishi , Keiichi Fukuyama , Yasunobu Shimano
发明人： Tamon Okano , Hidenori Kumobayashi , Susumu Akutagawa , Jitsuo Kiji , Hisatoshi Konishi , Keiichi Fukuyama , Yasunobu Shimano
IPC分类号： B01J31/00 , B01J31/24 , C07B61/00 , C07C209/68 , C07F9/50 , C07F15/00
CPC分类号： C07F9/5027 , C07C209/68 , C07F15/0073
摘要： A phosphine compound represented by formula: ##STR1## wherein R represents a hydrogen atom or an acetyl group; and Ph represents a phenyl group. The phosphine compound is capable of forming a complex with a metallic element, e.g., rhodium, ruthenium, palladium, etc., which exhibits high performances as a catalyst for asymmetric syntheses.
摘要翻译：由式表示的膦化合物：其中R表示氢原子或乙酰基; Ph表示苯基。膦化合物能够与作为不对称合成催化剂显示高性能的金属元素例如铑，钌，钯等形成络合物。

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