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    • 101. 发明授权
    • Method for enhancing lithographic imaging of isolated and semi-isolated features
    • 用于增强隔离和半隔离特征的光刻成像的方法
    • US08546069B2
    • 2013-10-01
    • US12354247
    • 2009-01-15
    • Wu-Song HuangGregory R. McIntyre
    • Wu-Song HuangGregory R. McIntyre
    • G03F7/40
    • G03F7/2022G03F7/095G03F7/26
    • The present invention relates to photolithography methods for enhancing lithographic imaging of isolated and semi-isolated features. A first layer of a first photoresist is formed over a substrate. A second layer of a second photoresist is formed over the first layer. The second photoresist includes a polymer containing an absorbing moiety. The second layer is exposed through a first patterned mask and developed to form a first relief image. The first relief image and the first layer are exposed through a second patterned mask. One of the first and the second patterned masks includes a dense pattern, while the other includes an isolated or a semi-isolated pattern. The first relief image and base soluble regions of the first layer are removed to form a second relief image with an isolated or a semi-isolated pattern. The second layer can also be bleachable upon exposure and bake in the present invention.
    • 本发明涉及用于增强孤立和半隔离特征的光刻成像的光刻方法。 在衬底上形成第一光致抗蚀剂的第一层。 在第一层上形成第二光致抗蚀剂层。 第二光致抗蚀剂包括含有吸收部分的聚合物。 第二层通过第一图案化掩模曝光并显影以形成第一浮雕图像。 第一浮雕图像和第一层通过第二图案掩模曝光。 第一和第二图案化掩模中的一个包括密集图案,而另一个包括隔离或半隔离图案。 去除第一层的第一浮雕图像和底部可溶区域以形成具有隔离或半隔离图案的第二浮雕图像。 第二层也可以在本发明中曝光和烘烤时可漂白。
    • 106. 发明授权
    • Low refractive index polymers as underlayers for silicon-containing photoresists
    • 低折射率聚合物作为含硅光致抗蚀剂的底层
    • US07439302B2
    • 2008-10-21
    • US11195566
    • 2005-08-02
    • Wu-Song HuangSean D. BurnsMahmoud Khojasteh
    • Wu-Song HuangSean D. BurnsMahmoud Khojasteh
    • G03F7/11C08F8/14C08F8/32
    • G03F7/091G03F7/094Y10S438/952
    • A new underlayer composition that exhibits high etch resistance and improved optical properties is disclosed. The underlayer composition comprises a vinyl or acrylate polymer, such as a methacrylate polymer, the polymer comprising at least one substituted or unsubstituted naphthalene or naphthol moiety, including mixtures thereof. Examples of the polymer of this invention include: where each R1 is independently selected from an organic moiety or a halogen; each A is independently a single bond or an organic moiety; R2 is hydrogen or a methyl group; and each X, Y and Z is an integer of 0 to 7, and Y+Z is 7 or less. The organic moiety mentioned above may be a substituted or unsubstituted hydrocarbon selected from the group consisting of a linear or branched alkyl, halogenated linear or branched alkyl, aryl, halogenated aryl, cyclic alkyl, and halogenated cyclic alkyl, and any combination thereof. The compositions are suitable for use as a planarizing underlayer in a multilayer lithographic process, including a trilayer lithographic process.
    • 公开了具有高耐蚀刻性和改善的光学性能的新型底层组合物。 底层组合物包含乙烯基或丙烯酸酯聚合物,例如甲基丙烯酸酯聚合物,该聚合物包含至少一个取代或未取代的萘或萘酚部分,包括其混合物。 本发明的聚合物的实例包括:其中每个R 1独立地选自有机部分或卤素; 每个A独立地是单键或有机部分; R 2是氢或甲基; X,Y,Z为0〜7的整数,Y + Z为7以下。 上述有机部分可以是选自直链或支链烷基,卤代直链或支链烷基,芳基,卤代芳基,环状烷基和卤代环状烷基的取代或未取代的烃及其任何组合。 该组合物适合用作多层光刻工艺中的平坦化底层,包括三层光刻工艺。
    • 109. 发明申请
    • ADVANCED CHEMICALLY AMPLIFIED RESIST FOR SUB 30NM DENSE FEATURE RESOLUTION
    • 先进的化学放大电阻,用于30NM密度特征分辨率
    • US20070248908A1
    • 2007-10-25
    • US11380098
    • 2006-04-25
    • Wu-Song HuangDavid MedeirosGregory Wallraff
    • Wu-Song HuangDavid MedeirosGregory Wallraff
    • G03C1/00
    • G03F7/0392G03F7/38
    • The present invention discloses a chemically amplified (CA) resist composition for printing features having a dimension of about 30 nm or less and a method of forming a material structure having a pattern containing features having a dimension of about 30 nm or less by using the inventive CA resist. The CA resist composition comprises (a) about 1 to about 50 weight % of a copolymer, (b) about 0.02 to about 25 weight % of a photoacid generator, (c) about 47 to about 99 weight % of a solvent, and (d) about 0.004 to about 25 weight % of a base additive. The copolymer comprises at least one hydrophilic monomer unit containing one or more polar functional groups and at least one hydrophobic monomer unit containing one or more aromatic groups. Some, but not all, of the one or more polar functional groups in the copolymer are protected with acid labile moieties having a low activation energy.
    • 本发明公开了一种用于印刷尺寸为约30nm或更小的特征的化学放大(CA)抗蚀剂组合物,以及通过使用本发明形成具有尺寸为约30nm或更小的特征的图案的材料结构的方法 CA抗拒。 CA抗蚀剂组合物包含(a)约1至约50重量%的共聚物,(b)约0.02至约25重量%的光酸产生剂,(c)约47至约99重量%的溶剂和( d)约0.004至约25重量%的基础添加剂。 共聚物包含至少一个含有一个或多个极性官能团的亲水性单体单元和至少一个含有一个或多个芳族基团的疏水性单体单元。 共聚物中一个或多个极性官能团的一些但不是全部由具有低活化能的酸不稳定部分保护。