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    • 104. 发明授权
    • Color photographs and method for preparation of the same
    • 彩色照片及其制备方法
    • US5194348A
    • 1993-03-16
    • US462930
    • 1990-01-12
    • Masakazu MorigakiNobuo SetoOsamu TakahashiHideaki Naruse
    • Masakazu MorigakiNobuo SetoOsamu TakahashiHideaki Naruse
    • G03C7/392
    • G03C7/39296G03C7/39208G03C7/39236G03C7/3924G03C7/39248G03C7/39252G03C7/39256G03C7/39268G03C7/39272
    • Disclosed in a color photograph containing a storability-improving compound capable of forming a chemical bond with an aromatic amine series color developing agent that remains in a photographic material after having been processed for color development to give a chemically inactive and substantially colorless compound in at least one photographic layer on a support. Also disclosed is a method for preparation of color photographs wherein a photographic material containing a silver halide emulsion layer and a color image-forming coupler capable of forming a dye by an oxidation-coupling reaction with an aromatic amine series color developing agent, as coated on a support, is imagewise exposed to light and then subjected to photographic processing, comprising carrying out the photographic processing in the presence of the afore described storability-improving compound. By the use of the storability-improving compound, the color images formed on the color photographs do not fade when stored for long periods of time.
    • 公开在含有能够与芳族胺系彩色显影剂形成化学键的储存性提高化合物的彩色照片中,所述芳香族胺系彩色显影剂在经过显色处理后保留在照相材料中,以至少至少产生化学惰性和基本上无色的化合物 支持上的一个照相层。 还公开了一种制备彩色照片的方法,其中含有卤化银乳剂层的照相材料和能够通过与芳族胺系彩色显影剂的氧化偶合反应形成染料的彩色成像剂,涂覆在 支撑体,成像曝光,然后进行照相处理,包括在上述保存性改善化合物的存在下进行照相处理。 通过使用保存性提高化合物,在长时间存储时,彩色照片上形成的彩色图像不会褪色。
    • 106. 发明授权
    • Thermal transfer dye donating material
    • 热转印染料
    • US5128312A
    • 1992-07-07
    • US730749
    • 1991-07-16
    • Mitsugu TanakaMasakazu MorigakiSeiiti Kubodera
    • Mitsugu TanakaMasakazu MorigakiSeiiti Kubodera
    • B41M5/385B41M5/26B41M5/388B41M5/39C09B53/00C09B53/02
    • B41M5/39C09B53/02Y10S428/913Y10S428/914Y10T428/265Y10T428/273Y10T428/277
    • Disclosed is a thermal transfer dye donating material, which has, on a support, a dye donating layer containing a dye of a general formula (I): ##STR1## wherein R.sub.1 represents a hydrogen atom or an alkyl group; R.sub.2 to R.sub.8 each represent a hydrogen atom, an alkyl group, an alkoxy group, a halogen atom, an acylamino group, an alkoxycarbonyl group, a cyano group, an alkoxycarbonylamino group, an aminocarbonylamino group, a sulfonylamino group, a carbamoyl group, a sulfamoyl group or an acyl group; A represents ##STR2## wherein R.sub.9 and R.sub.10, which may be the same or different, each represents a hydrogen atom, an alkyl group or an aryl group; X represents a nitrogen atom or ##STR3## R.sub.11 representing a hydrogen atom, an alkyl group or an aryl group; Y represents a non-metallic atomic group necessary for forming a 5-membered to 7-membered ring; and R.sub.3 and R.sub.4 may optionally be bonded to each other to form a ring; and R.sub.6 and R.sub.9, and/or R.sub.9 and R.sub.10, and/or R.sub.7 and R.sub.10 may optionally be bonded to each other to form a ring. The transferred image from the material has an excellent light-fastness.
    • 公开了一种热转移染料供体材料,其在载体上具有含有通式(I)的染料的染料供体层:其中R 1表示氢原子或烷基; R2至R8各自表示氢原子,烷基,烷氧基,卤素原子,酰氨基,烷氧基羰基,氰基,烷氧基羰基氨基,氨基羰基氨基,磺酰基氨基,氨基甲酰基, 氨磺酰基或酰基; A表示,其中R 9和R 10可以相同或不同,各自表示氢原子,烷基或芳基; X表示表示氢原子,烷基或芳基的氮原子或R 11表示的化合物。 Y表示形成5元至7元环所必需的非金属原子团; 并且R 3和R 4可以任选地彼此键合形成环; 和R 6和R 9,和/或R 9和R 10,和/或R 7和R 10可任选地彼此键合形成环。 从材料转印的图像具有优异的耐光性。
    • 108. 发明授权
    • Silver halide color photographic material containing 5-pyrazolone
magenta coupler and amine-type stain preventing agent
    • 含有5-吡唑啉酮品红成色剂和胺型防污剂的卤化银彩色照相材料
    • US5096805A
    • 1992-03-17
    • US683503
    • 1991-04-05
    • Kozo AokiMasakazu Morigaki
    • Kozo AokiMasakazu Morigaki
    • G03C7/26G03C7/30G03C7/305G03C7/32G03C7/384G03C7/392
    • G03C7/30529G03C7/3012G03C7/3225
    • A silver halide color photographic material containing at least one silver halide emulsion and at least one kind of 5-pyrazolone couplers having the releasable group shown by following formula (I) at the coupling position and at least one kind of the compounds shown by following formula (II): ##STR1## wherein L.sub.1 and L.sub.2 each represents a methylene group or an ethylene group; l and m each represents 0 or 1; R.sub.1 represents a hydrogen atom, an alkyl group, an aryl group, or a heterocyclic group; R.sub.2 represents a group bonded to A by a carbon atom, an oxygen atom, a nitrogen atom or a sulfur atom; A represents a carbon atom or a sulfur atom; n represents 1 when A is a carbon atom, or 1 or 2 when A is a sulfur atom; B represents a carbon atom, an oxygen atom, a nitrogen atom, or a sulfur atom; and X represents an atomic group necessary for forming a ring; said R.sub.1 and R.sub.2 may combine with each other to form a ring; and when B is a carbon atom or a nitrogen atom, said B and R.sub.2 may combine with each other to form a ring; ##STR2## wherein R.sub.21 represents a hydrogen atom, a hydroxy group, or a substituted or unsubstituted alkyl, alkenyl, alkoxy, acyl, aryloxy, heterocyclic oxy or acyloxy group and R.sub.22 and R.sub.23 each represents a substituted or unsubstituted alkyl, alkenyl or heterocyclic group; said R.sub.21, R.sub.22 and R.sub.23 may form together a nitrogen-containing monocyclic or polycyclic heterocyclic ring and the sum of the carbon atom numbers of R.sub.21, R.sub.22, and R.sub.23 is at least 10.
    • 含有至少一种卤化银乳剂和至少一种在偶合位置具有下式(I)所示的可释放基团的5-吡唑啉酮成色剂的卤化银彩色照相材料和至少一种下式所示的化合物 (II):其中L 1和L 2各自表示亚甲基或亚乙基; l和m各自表示0或1; R1表示氢原子,烷基,芳基或杂环基; R2表示通过碳原子,氧原子,氮原子或硫原子与A键合的基团; A表示碳原子或硫原子; 当A为碳原子时,n表示1,A为硫原子时为1或2。 B表示碳原子,氧原子,氮原子或硫原子; X表示形成环所需的原子团; 所述R1和R2可以相互结合形成环; 当B为碳原子或氮原子时,所述B和R2可以相互结合形成环; (II)其中R21表示氢原子,羟基或取代或未取代的烷基,烯基,烷氧基,酰基,芳氧基,杂环氧基或酰氧基,R22和R23各自表示取代或未取代的烷基,烯基 或杂环基; 所述R 21,R 22和R 23可以一起形成含氮单环或多环杂环,R 21,R 22和R 23的碳原子数之和至少为10。
    • 110. 发明授权
    • Silver halide color photographic materials
    • 卤化银彩色照相材料
    • US5041365A
    • 1991-08-20
    • US555676
    • 1990-07-19
    • Osamu TakahashiHideaki NaruseMasakazu MorigakiNobutaka OhkiNobuo Furutachi
    • Osamu TakahashiHideaki NaruseMasakazu MorigakiNobutaka OhkiNobuo Furutachi
    • G03C7/26G03C7/38G03C7/392
    • G03C7/3805G03C7/39252
    • The present invention provides silver halide color photographic materials having a layer which contains at least one magenta color image-forming oleophilic coupler of the following formulae (I) and/or (II) and at least one of the following formula (III): ##STR1## in which Ar represents a phenyl group which is substituted by at least one substituent selected from the group consisting of a halogen atom, an alkyl group, an alkoxy group, an alkoxycarbonyl group and a cyano group; Y represents an acylamino group or an anilino group; and Z.sub.1 represents a group capable of being removed by coupling, ##STR2## in which X represents a hydrogen atom or a substituent; Z.sub.2 represents a hydrogen atom or a group capable of being removed by coupling;W represents a hydrogen atom, an acyl group or an aliphatic or aromatic sulfonyl group;Za and Zb each represent a methine group, a substituted methine group or --N.dbd.; andX, Z.sub.2 or the substituted methine of Za or Zb may form a dimer or higher polymer, ##STR3## in which A represents an alkyl group, an aryl group, a heterocyclic group, an acyl group, an alkoxy group, an aryloxy group, a heterocyclic oxy group, an alkylthio group, an arylthio group or an amino group, which may be substituted or unsubstituted; R.sub.1 and R.sub.2 each independently represents a hydrogen atom or a substituted or unsubstituted alkyl group; R.sub.3a and R.sub.3b each represents a hydrogen atom, an alkyl group, an aryl group, an alkoxy group, an aryloxy group, an alkylthio group or an arylthio group; R.sub.4 represents an alkyl group, an aryl group or a heterocyclic group; and D represents an oxygen atom or a sulfur atom.The use of the combination of the magenta couplers(s) of the formulae (I) and/or (II) and the stain-inhibitory additive(s) of the formula (III) provides photographic light-sensitive materials that are almost free from stains when such materials are preserved for a long period of time after having been exposed, developed and then photographically processed.