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91. 发明授权

US06960549B2 Catalyst modifiers and their use in the polymerization of olefin(s) 失效
标题翻译：催化剂改性剂及其在烯烃聚合中的应用
公开(公告)号：US06960549B2
公开(公告)日：2005-11-01
申请号：US09932520
申请日：2001-08-17
申请人： Timothy T. Wenzel , Dick A. Nagaki , Simon Mawson , David James Schreck , Thomas H. Peterson
发明人： Timothy T. Wenzel , Dick A. Nagaki , Simon Mawson , David James Schreck , Thomas H. Peterson
IPC分类号： C08F2/40 , C08F4/659 , C08F4/6592 , C08F110/02 , B01J31/00 , B01J37/00 , C08F4/02 , C08F4/60
CPC分类号： C08F110/02 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F2/40
摘要： The present invention relates to the use of at least one acid and at least one base and/or at least one reductant and at least one oxidant that when used with a polymerization catalyst in a polymerization process results in the controllable generation of a catalyst inhibitor that renders the polymerization catalyst substantially or completely inactive.
摘要翻译：本发明涉及使用至少一种酸和至少一种碱和/或至少一种还原剂和至少一种氧化剂，当在聚合方法中与聚合催化剂一起使用时，可以产生可控制的催化剂抑制剂，使聚合催化剂基本上或完全无活性。

92. 发明授权

US06936226B2 Catalyst delivery method, a catalyst feeder and their use in a polymerization process 失效
标题翻译：催化剂输送方法，催化剂进料器及其在聚合过程中的应用
公开(公告)号：US06936226B2
公开(公告)日：2005-08-30
申请号：US09808576
申请日：2001-03-14
申请人： Agapios K. Agapiou , Kathryn A. Russell
发明人： Agapios K. Agapiou , Kathryn A. Russell
IPC分类号： B01J8/00 , B01J8/24 , B01J19/26 , C08F2/00 , C08F2/34 , C08F2/40 , C08F4/60 , C08F4/607 , C08F4/6192 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F210/16 , B01F15/00
CPC分类号： C08F10/00 , B01J8/0005 , B01J8/003 , B01J8/004 , B01J8/24 , B01J19/26 , B01J2208/00 , B01J2219/00162 , B01J2219/00164 , B01J2219/00186 , C08F4/65912 , C08F4/65922 , C08F210/16 , Y10S526/901 , C08F4/61916 , C08F2/005 , C08F2/34 , C08F210/14 , C08F2500/12 , C08F2500/18
摘要： The present invention relates to an improved catalyst delivery method for introducing a supported bulky ligand metallocene-type catalyst system to a reactor for polymerizing one or more olefin(s). In particular, the invention provides for a method of introducing a supported metallocene-type catalyst system into a polymerization reactor by and in the presence of a carrier solution of an antistatic agent and a liquid diluent. Also, the invention is directed toward a catalyst feeder for use in a polymerization process.
摘要翻译：本发明涉及用于将负载的大体积配体金属茂型催化剂体系引入到用于聚合一种或多种烯烃的反应器中的改进的催化剂递送方法。特别地，本发明提供了一种通过在抗静电剂和液体稀释剂的载体溶液存在下将载体茂金属型催化剂体系引入聚合反应器的方法。此外，本发明涉及用于聚合方法的催化剂进料器。

93. 发明授权

US06844400B2 Apparatus for preparing polyolefin products and methodology for using the same 有权
公开(公告)号：US06844400B2
公开(公告)日：2005-01-18
申请号：US10758168
申请日：2004-01-15
申请人： C. Edward Baxter, Jr. , Daniel Herndon , James G. Wakeland , Russel E. Reid, Sr. , Gilbert Valdez
发明人： C. Edward Baxter, Jr. , Daniel Herndon , James G. Wakeland , Russel E. Reid, Sr. , Gilbert Valdez
IPC分类号： B01J8/00 , B01J8/20 , B01J19/24 , C08F2/00 , C08F2/40 , C08F6/02 , C08F10/00
CPC分类号： B01J19/2425 , B01J8/007 , B01J8/20 , B01J19/2405 , B01J19/2465 , B01J2208/00212 , B01J2208/00283 , B01J2219/00006 , B01J2219/00038 , B01J2219/00085 , B01J2219/0011 , B01J2219/00272 , C08F6/02 , C08F10/00 , C08L23/00
摘要： Apparatus for olefin polymerization includes a plurality of shell and tube olefin polymerization reactors, each of which has an olefin polymerization reaction mixture inlet connection and a crude polyolefin product outlet connection. Each reactor is equipped with a recirculation system including a pump arranged to circulate a reaction mixture through the tube side of the reactor independently of the introduction of olefin polymerization reaction mixture into the reactor. The apparatus also includes an inlet reaction mixture distribution manifold and an outlet polymerization reaction mixture collection manifold interconnecting the reactors for operation in parallel. The apparatus also includes catalyst composition and catalyst modifier inlets for each reactor arranged such that a catalyst modifier to may be introduced into each reactor at a rate which is independent of the introduction of catalyst composition. The apparatus further incorporates a crude polyolefin product catalyst removal and wash system including a plurality of settler vessels, associated piping and an inlet for a catalyst killing agent. This crude polyolefin product catalyst removal and wash system operates to receive crude polyolefin product from the crude polyolefin product outlet and remove residual catalyst therefrom.

94. 发明授权

US06127495A Preparation of polymers of C.sub.2 -C.sub.12 -alkenes with the addition of a reaction retarder 失效
标题翻译：通过加入反应缓凝剂制备C2-C12-烯烃的聚合物
公开(公告)号：US06127495A
公开(公告)日：2000-10-03
申请号：US866386
申请日：1997-05-30
申请人： Joachim Rosch , Wolfgang Bidell , Franz Langhauser
发明人： Joachim Rosch , Wolfgang Bidell , Franz Langhauser
IPC分类号： C08F2/38 , C08F2/40 , C08F4/619 , C08F4/6192 , C08F4/625 , C08F4/64 , C08F4/6592 , C08F10/00 , C08F110/02 , C08F110/06
CPC分类号： C08F10/00 , C08F110/02 , C08F110/06 , C08F4/61912 , C08F4/61916 , C08F4/61925 , Y02P20/584 , Y10S526/904
摘要： Polymers of C.sub.2 -C.sub.12 -alkenes are prepared at from -50 to 300.degree. C. and from 0.5 to 3000 bar in the presence of a catalyst system by a process in which a compound of the general formula I ##STR1## where M.sup.1 is boron, aluminum, gallium, indium or thallium andR.sup.1 and R.sup.2 are each hydrogen, C.sub.1 -C.sub.10 -alkyl, C.sub.6 -C.sub.15 -aryl, alkylaryl or arylalkyl each having 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical, or 5- to 7-membered cycloalkyl which in turn may carry C.sub.1 -C.sub.10 -alkyl as a substituent, or R.sup.1 and R.sup.2 together form a cyclic group, is added of 4 to 15 carbon atoms.
摘要翻译：在催化剂体系的存在下，在-50至300℃和0.5至3000巴下制备C2-C12-烯烃的聚合物，其中通式Ⅰ的化合物，其中M1是硼，铝，镓，铟或铊，R 1和R 2分别为烷基中具有1至10个碳原子且在芳基中具有6至20个碳原子的每个氢，C 1 -C 10 - 烷基，C 6 -C 15 - 芳基，烷基芳基或芳基烷基，或 5-7元环烷基又可以携带C1-C10-烷基作为取代基，或者R1和R2一起形成环状基团，其中含有4-15个碳原子。

95. 发明授权

US5929179A Method for preventing fouling in polymerization reactors 失效
标题翻译：防止聚合反应器结垢的方法
公开(公告)号：US5929179A
公开(公告)日：1999-07-27
申请号：US860947
申请日：1997-09-03
申请人： Guy Strobbe , Paul Allemeersch , Edwin Vanheer
发明人： Guy Strobbe , Paul Allemeersch , Edwin Vanheer
IPC分类号： B01J19/24 , C08F2/00 , C08F2/40 , C08F10/00 , C08F110/02 , C08F210/16
CPC分类号： C08F210/16 , B01J19/2435 , C08F110/02
摘要： The invention relates to a method for preventing fouling in polymerization reactors, in particular in loop reactors, in which alpha-olefins are polymerized or copolymerized in particle form in the presence of catalysts. A mixture of alpha-olefin-acrylonitrile copolymers and polymeric polyamines is added into a reactor in order to prevent the fouling of the reactor.
摘要翻译： PCT No.PCT / FI95 / 00696 Sec。 371日期：1997年9月3日 102（e）1997年9月3日PCT PCT 1997年6月21日PCT公布。 WO96 / 19503 PCT出版物日期1996年6月27日本发明涉及在聚合反应器，特别是环管反应器中防止结垢的方法，其中α-烯烃在催化剂存在下以颗粒形式聚合或共聚。将α-烯烃 - 丙烯腈共聚物和聚合多胺的混合物加入到反应器中以防止反应器的结垢。

96. 发明授权

US5914418A Polymerization inhibitor for acrylic-functional silanes 失效
标题翻译：丙烯酸官能硅烷聚合抑制剂
公开(公告)号：US5914418A
公开(公告)日：1999-06-22
申请号：US839587
申请日：1997-04-15
申请人： Ryuzo Mikami , Tadashi Okawa
发明人： Ryuzo Mikami , Tadashi Okawa
IPC分类号： C07B63/04 , C07C43/164 , C07C215/66 , C07C381/12 , C07C391/00 , C07F7/08 , C07F7/12 , C07F7/14 , C07F7/18 , C07F9/54 , C08F2/38 , C08F2/40 , C09K15/20 , C09K15/32
CPC分类号： C07F9/5456 , C07F7/0879 , C07F7/12 , C07F7/14 , C07F7/1876
摘要： A method for inhibiting polymerization of acrylic-functional silanes comprising forming a mixture comprising an acrylic-functional silane and a polymerization inhibitor described by formula ##STR1## where n is 0 or 1; M is an atom selected from a group consisting of N, P, As, Sb, O, S, Se, Sn, and I; R is an independently selected monovalent hydrocarbon group or hydrogen atom; m is 1, 2, or 3; and X is a conjugate base of an organic acid or inorganic acid.
摘要翻译：一种抑制丙烯酸官能硅烷聚合的方法，包括形成含有丙烯酸官能的硅烷和阻聚剂的混合物，其中n为0或1; M是选自N，P，As，Sb，O，S，Se，Sn和I的原子; R是独立选择的一价烃基或氢原子; m为1,2或3; X是有机酸或无机酸的共轭碱。

97. 发明授权

US5914379A Compression of ethylenically unsaturated monomers 有权
公开(公告)号：US5914379A
公开(公告)日：1999-06-22
申请号：US174247
申请日：1998-10-16
申请人： Heinz Friedrich Sutoris , Alexander Aumuller , Andreas Koch , Andreas Deckers , Eckard Schauss , Roger Klimesch , Arend Jouke Kingma , Wilhelm Weber
发明人： Heinz Friedrich Sutoris , Alexander Aumuller , Andreas Koch , Andreas Deckers , Eckard Schauss , Roger Klimesch , Arend Jouke Kingma , Wilhelm Weber
IPC分类号： C08F2/34 , C07B63/04 , C07C7/20 , C07C11/04 , C08F2/38 , C08F2/40 , C08F10/00 , C08F210/02 , C08F10/02
CPC分类号： C08F10/00 , C07B63/04 , C07C11/04 , C07C7/20 , C08F2/40 , C08F210/02
摘要： A process for compressing ethylenically unsaturated monomers at a pressure of 200-5000 bar in the absence of a polymerization initiator comprises carrying out compression in the presence of a sterically hindered amine derivative.

98. 发明授权

US5886764A Polyester resin-based high index ophthalmic lenses having improved optical uniformity and/or tintability 失效
标题翻译：具有改善的光学均匀性和/或着色性的聚酯树脂基高折射率眼科镜片
公开(公告)号：US5886764A
公开(公告)日：1999-03-23
申请号：US874189
申请日：1997-06-13
申请人： Thomas J. Engardio , Philip D. Dalsin , Dae Ki Kang , Jean S. Lee
发明人： Thomas J. Engardio , Philip D. Dalsin , Dae Ki Kang , Jean S. Lee
IPC分类号： G02C7/02 , C08F2/40 , C08F283/01 , C08F299/04 , C08K5/00 , C08K5/01 , C08K5/1515 , C08K5/38 , G02B1/04
CPC分类号： G02B1/041 , C08F283/01 , C08K5/0008
摘要： Unsaturated polyester resin-based compositions that are modified for unexpected improvement in uniform, low optical distortion and/or improved tint speed by the addition of one or more additives selected from an allylic ester and/or an acrylic monomer, together with an exotherm depressant, making the modified polyester resin-based composition commercially viable for casting ophthalmic lenses. The additive(s) and exotherm depressant are useful to modify the polyester for sufficient enhancement of optical distortion and/or tint speed such that any unsaturated polyester resin, capable of producing a clear, low color casting, will be improved sufficiently to provide a composition having the required properties for an ophthalmic lens.
摘要翻译：通过添加选自烯丙基酯和/或丙烯酸类单体的一种或多种添加剂与放热抑制剂一起而改进的均匀，低光学变形和/或改进色调速度的不饱和聚酯树脂基组合物，使得改性聚酯树脂基组合物在商业上可用于铸造眼镜片。添加剂和放热抑制剂可用于改性聚酯以充分增强光学变形和/或着色速度，使得能够产生透明的低色铸件的任何不饱和聚酯树脂将被充分改善以提供组合物具有所需的眼科镜片性能。

99. 发明授权

US5728872A Stabilized acrylic acid compositions 失效
标题翻译：稳定的丙烯酸组合物
公开(公告)号：US5728872A
公开(公告)日：1998-03-17
申请号：US266330
申请日：1994-06-27
申请人： Lutz Riemenschneider
发明人： Lutz Riemenschneider
IPC分类号： C08F2/40 , C07C51/50 , C07C57/075 , C08F2/38 , C08F20/00 , C08F20/06 , C07C57/02
CPC分类号： C07C51/50
摘要： A stabilized acrylic acid composition is provided in which the polymerization of the acrylic acid is inhibited during the distillation process for purifying or separating the acrylic acid as well as during transport and storage. The compositions of the present invention comprise three components: (A) acrylic acid, (B) a stable nitroxyl radical, e.g., the nitroxyl radical 4-hydroxy-2,2,6,6-tetramethyl-1-piperidinyloxy (CAS registry number 2226-96-2) (HTEMPO), and (C) a dihetero-substituted benzene compound having at least one transferable hydrogen, e.g., a quinone derivative such as the mono-methyl-ether of hydroquinone (MEHQ). During the distillation process, transport and storage, components (B) and (C) are present in a polymerization-inhibiting amount. During the distillation process, oxygen (D) is preferably added with components (B) and (C).
摘要翻译：提供了一种稳定的丙烯酸组合物，其中丙烯酸的聚合在蒸馏过程中被抑制以净化或分离丙烯酸，以及在运输和储存期间。本发明的组合物包含三种组分：（A）丙烯酸，（B）稳定的硝酰基，例如硝酰基4-羟基-2,2,6,6-四甲基-1-哌啶基氧基（CAS登记号 2226-96-2）（HTEMPO）和（C）具有至少一个可转移氢的二杂异取代的苯化合物，例如醌衍生物，例如氢醌的单甲基醚（MEHQ）。在蒸馏过程中，运输和储存，组分（B）和（C）以聚合抑制量存在。在蒸馏过程中，氧（D）优选加入成分（B）和（C）。

100. 发明授权

US5548042A Process for the production of polypropylene 失效
标题翻译：聚丙烯生产工艺
公开(公告)号：US5548042A
公开(公告)日：1996-08-20
申请号：US293473
申请日：1994-08-19
申请人： Mark G. Goode
发明人： Mark G. Goode
IPC分类号： C08F2/00 , C08F2/34 , C08F2/40 , C08F4/60 , C08F4/658 , C08F10/00 , C08F10/06 , C08F110/06 , C08F210/16
CPC分类号： C08F10/06 , C08F110/06 , C08F210/16 , C08F2410/05 , Y10S526/901
摘要： A process comprising contacting propylene in two reaction zones connected in series, under gas phase polymerization conditions, with a transition metal catalyst system comprising(a) introducing the catalyst into the first reaction zone;(b) partially deactivating the catalyst and simultaneously increasing the monomer level to achieve a desired resin productivity in the first zone; and(c) transferring resin together with catalyst from the first zone to the second zone having purged the deactivator or added activator in sufficient amount to achieve a desired resin productivity in the second zone.
摘要翻译：一种方法，其包括在气相聚合条件下，串联连接的两个反应区中的丙烯与过渡金属催化剂体系接触，所述过渡金属催化剂体系包含（a）将催化剂引入第一反应区; （b）部分地使催化剂失活并同时增加单体水平以在第一区域中实现期望的树脂生产率; 和（c）将树脂与催化剂一起从第一区转移到第二区，该区具有足够量的去活化剂或加入的活化剂，以在第二区中达到所需的树脂生产率。

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