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91. 发明授权

US4852989A Bleaching compounds and compositions comprising fatty peroxyacids salts thereof and precursors therefor having amide moieties in the fatty chain 失效
标题翻译：包含其脂肪过氧酸盐及其前体的漂白化合物和组合物在脂肪链中具有酰胺部分
公开(公告)号：US4852989A
公开(公告)日：1989-08-01
申请号：US47804
申请日：1987-05-08
申请人： Michael E. Burns , Frederick E. Hardy
发明人： Michael E. Burns , Frederick E. Hardy
IPC分类号： C07C409/40 , C11D3/39
CPC分类号： C07C409/40 , C11D3/3945
摘要： This invention relates to bleaching compounds and compositions that provide effective and efficient surface bleaching of textiles over a wide range of bleach solution temperatures. The bleaching compounds of the invention yield a peroxyacid with a polar amide link in the hydrophobic chain when used in the bleaching compositions. In a preferred embodiment, the bleaching compositions of the invention are also detergent compositions.

92. 发明授权

US4558147A Ultraviolet radiation-curable silicone release compositions 失效
标题翻译：紫外线辐射固化硅氧烷防粘组合物
公开(公告)号：US4558147A
公开(公告)日：1985-12-10
申请号：US527299
申请日：1983-08-26
申请人： Richard P. Eckberg , Richard A. Striker , Frank J. Modic
发明人： Richard P. Eckberg , Richard A. Striker , Frank J. Modic
IPC分类号： C08F299/08 , C07C409/38 , C07C409/40 , C08F290/00 , C08G77/00 , C08G77/20 , C08G77/22 , C08G77/28 , C08G77/38 , C08G77/392 , C08K5/14 , C08L83/00 , C08L83/04 , C08L83/07 , C08L83/08 , C09D183/04 , C09D183/07 , C09D183/08 , C09J7/02 , C07F7/08
CPC分类号： C08G77/392 , C09D183/08
摘要： Novel UV-curable silicone release coating compositions and photocatalysts therefor are provided which include mercaptoalkoxyalkyl-functional polysiloxanes and vinyl-functional photoreactive terpolymers, both of which are especially compatable with certain perbenzoate ester photocatalysts. The addition of certain polyaromatic photosensitizers to enhance cure is also disclosed.
摘要翻译：提供了新的可UV固化的有机硅剥离涂料组合物及其光催化剂，其包括巯基烷氧基烷基官能的聚硅氧烷和乙烯基官能的光反应性三元共聚物，它们都与某些过苯甲酸酯酯光催化剂特别相容。还公开了加入某些多芳族光敏剂以增强固化。

93. 发明授权

US4522991A Method for polymerizing ethylenically unsaturated monomer with novel organic percarbonates 失效
标题翻译：用新型有机过碳酸酯聚合烯属不饱和单体的方法
公开(公告)号：US4522991A
公开(公告)日：1985-06-11
申请号：US642304
申请日：1984-08-20
申请人： Robert H. Tang
发明人： Robert H. Tang
IPC分类号： C07C409/40 , C08F2/08 , C08F14/06 , C08F214/06 , C08F299/04 , C08F4/32
CPC分类号： C07C255/00 , C08F299/0457
摘要： Organic peroxydicarbonates represented by the following graphic formula are described. ##STR1## In the formula, R and R' are each selected from an alkyl group containing from 1 to 4 carbon atoms, a cycloalkyl group of from 5 to 7 carbon atoms, a C.sub.1 -C.sub.4 alkyl substituted cycloalkyl group, or participate in a cycloalkyl group having from 5 to 7 carbon atoms, provided that when one of R and R' is cycloalkyl, the other is alkyl. The peroxydicarbonates are useful as initiators for the polymerization or copolymerization of ethylenically unsaturated monomers or the cross-linking of unsaturated polyester resins. The organic peroxydicarbonates can be used in combination with commercially available peroxydicarbonates, particularly those having a shorter half-life.
摘要翻译：描述由以下图形公式表示的有机过氧化二碳酸酯。在该式中，R和R'各自选自含有1至4个碳原子的烷基，5至7个碳原子的环烷基，C 1 -C 4烷基取代的环烷基，或者参与具有5至7个碳原子的环烷基，条件是当R和R'中的一个是环烷基时，另一个是烷基。过氧二碳酸酯可用作烯属不饱和单体的聚合或共聚的引发剂或不饱和聚酯树脂的交联。有机过氧碳酸氢盐可以与市售的过氧化二碳酸酯组合使用，特别是半衰期较短的那些。

94. 发明授权

US4201875A Catalyst and process for producing hydroperoxides 失效
标题翻译：催化剂和生产氢过氧化物的方法
公开(公告)号：US4201875A
公开(公告)日：1980-05-06
申请号：US930077
申请日：1978-08-01
申请人： Yulin Wu , Marvin M. Johnson , Gerhard P. Nowack
发明人： Yulin Wu , Marvin M. Johnson , Gerhard P. Nowack
IPC分类号： B01J23/50 , C07C409/04 , C07C409/08 , C07C409/10 , C07C409/14 , C07C409/40 , C07C179/02
CPC分类号： C07C409/40 , B01J23/50 , C07C407/00 , C07C409/04 , C07C409/08 , C07C409/14 , C07C2101/08 , C07C2101/14 , C07C2101/18 , C07C2101/20
摘要： Organic hydroperoxides are prepared by reacting an organic compound with oxygen in the presence of a novel catalyst comprising metallic silver supported upon an inorganic support selected from the oxides and carbonates of metals of Groups IIa, IIb, IIIb, and IVb.
摘要翻译：有机氢过氧化物是通过有机化合物与氧反应制备的，该催化剂包含负载在选自IIa，Ⅱb，Ⅲb和Ⅳb族金属的氧化物和碳酸酯的无机载体上的金属银的新型催化剂。

95. 发明授权

US4129586A Peroxide free radical initiators containing ultraviolet light stabilizing groups 失效
标题翻译：含有紫外光稳定基团的过氧化物自由基引发剂
公开(公告)号：US4129586A
公开(公告)日：1978-12-12
申请号：US803493
申请日：1977-06-06
申请人： Chester S. Sheppard , Ronald E. MacLeay
发明人： Chester S. Sheppard , Ronald E. MacLeay
IPC分类号： C07C409/16 , C07C409/34 , C07C409/38 , C07C409/40 , C07C409/42 , C07C409/44 , C08F4/32 , C08K5/14 , C08K5/23 , C07C179/06 , C07C179/10 , C07C179/18
CPC分类号： C08K5/14 , C07C409/16 , C07C409/34 , C07C409/38 , C07C409/40 , C08F4/32 , C08K5/23
摘要： Compounds which contain azo or peroxide linkages as well as the radical of an ultraviolet light stabilizing group are described. These compounds function as polymerization initiators which cause an ultraviolet light stabilization group to be chemically bound to the polymer.
摘要翻译：描述了含有偶氮或过氧化物键的化合物以及紫外光稳定基团的基团。这些化合物起着聚合引发剂的作用，其使紫外光稳定基团与聚合物化学键合。

96. 发明授权

US4104311A Organometallic complexes as oxidation catalysts 失效
标题翻译：有机金属配合物作为氧化催化剂
公开(公告)号：US4104311A
公开(公告)日：1978-08-01
申请号：US525548
申请日：1974-11-20
申请人： Howard P. Angstadt
发明人： Howard P. Angstadt
IPC分类号： C07C29/50 , C07C45/36 , C07C45/53 , C07C409/04 , C07C409/08 , C07C409/10 , C07C409/14 , C07C409/40 , C07C179/04
CPC分类号： C07C409/14 , C07C29/50 , C07C407/00 , C07C409/04 , C07C409/08 , C07C409/10 , C07C45/36 , C07C45/53 , C07C2101/10 , C07C2101/14 , C07C2101/16 , C07C2102/28
摘要： Organometallic complexes formed between trialkylphosphates and transition metal salts, including rare earth metals, have been found to be effective catalysts for the oxidation of olefins and secondary and tertiary alkylaromatics to form valuable oxidation products, particularly hydroperoxides, or their decomposition products.
摘要翻译：已经发现，在三烷基磷酸盐和过渡金属盐（包括稀土金属）之间形成的有机金属络合物是用于烯烃和仲和叔烷基芳族化合物氧化以形成有价值的氧化产物，特别是氢过氧化物或其分解产物的有效催化剂。

97. 发明授权

US4042773A Peroxide free radical initiators containing ultraviolet light stabilizing groups 失效
标题翻译：含有紫外光稳定基团的过氧化物自由基引发剂
公开(公告)号：US4042773A
公开(公告)日：1977-08-16
申请号：US680546
申请日：1976-04-27
申请人： Chester S. Sheppard , Ronald E. MacLeay
发明人： Chester S. Sheppard , Ronald E. MacLeay
IPC分类号： C07C409/16 , C07C409/22 , C07C409/40 , C07F5/04 , C07F9/09 , C08F2/00 , C08F2/48 , C08F4/34 , C08F4/36 , C08F12/08
CPC分类号： C07F5/04 , C07F9/095 , C08F4/34
摘要： Compounds which contain azo or peroxide linkages as well as the radical of an ultraviolet light stabilizing group are described. These compounds function as polymerization initiators which cause an ultraviolet light stabilization group to be chemically bound to the polymer.
摘要翻译：描述了含有偶氮或过氧化物键的化合物以及紫外光稳定基团的基团。这些化合物起着聚合引发剂的作用，其使紫外光稳定基团与聚合物化学键合。

98. 发明授权

US4001207A Tertiary-aliphatic amidazo compounds 失效
标题翻译：季戊四酰胺化合物
公开(公告)号：US4001207A
公开(公告)日：1977-01-04
申请号：US148885
申请日：1971-06-01
申请人： Ronald Edward MacLeay , Chester Stephen Sheppard
发明人： Ronald Edward MacLeay , Chester Stephen Sheppard
IPC分类号： C07C245/04 , C07C255/65 , C07C261/02 , C07C281/20 , C07C331/12 , C07C409/40 , C07D251/54 , C07D251/66 , C07D271/10 , C07D271/113 , C08F4/04 , C08F283/01 , C08F299/04 , C08J9/10 , C09B43/00 , C07C107/02 , C07C109/06
CPC分类号： C09B43/00 , C07D251/66 , C08F283/01 , C08F4/04
摘要： Amidazo compounds, (R").sub.3 C--N=N--C(=O)--N(R.sub.3)(R.sub.4), where (R").sub.3 C-- is t-alkyl or t-aralkyl, such as t-butylazoformamide, which are useful as polyester resin curing agents and the like.

99. 发明授权

US3956269A Azo free radical initiators containing ultraviolet light stabilizing groups 失效
标题翻译：含有紫外光稳定基团的偶氮自由基引发剂
公开(公告)号：US3956269A
公开(公告)日：1976-05-11
申请号：US435623
申请日：1974-01-22
申请人： Chester S. Sheppard , Ronald E. MacLeay
发明人： Chester S. Sheppard , Ronald E. MacLeay
IPC分类号： C07C409/34 , C07C409/38 , C07C409/40 , C07C409/44 , C08F4/04 , C08F4/32 , C08F283/01 , C07C107/02
CPC分类号： C08F4/32 , C07C407/00 , C07C409/34 , C07C409/38 , C07C409/40 , C07C409/44 , C08F283/01 , C08F4/04
摘要： Compounds which contain azo linkages as well as the radical of an ultraviolet light stabilizing group are described. These compounds function as polymerization initiators which cause an ultraviolet light stabilization group to be chemically bound to the polymer.
摘要翻译：描述了含有偶氮键的化合物以及紫外光稳定基团的基团。这些化合物起着聚合引发剂的作用，其使紫外光稳定基团与聚合物化学键合。

100. 发明授权

US3917744A Tertiary-aliphatic {60 -(peracyl)azo compounds as initiators for the polymerization of unsaturated polyesters and vinyl monomers 失效
标题翻译：叔碳酸酯（60-（全酰基））偶氮化合物作为不饱和聚酯和乙烯基单体聚合的引发剂
公开(公告)号：US3917744A
公开(公告)日：1975-11-04
申请号：US45063974
申请日：1974-03-13
申请人： PENNWALT CORP
发明人： MACLEAY RONALD EDWARD , SHEPPARD CHESTER STEPHEN
IPC分类号： C07C409/40 , C07C409/42 , C08F4/04 , C08F283/01 , C08F299/04 , C08L67/06 , C07C107/02
CPC分类号： C08F299/0457 , C08F4/04 , C08F283/01 , C08F4/00
摘要： D R A W I N G
New tertiary-aliphatic alpha-(peracyl)azo compounds represented by the formula

PROCESSES FOR PREPARING I where R is
and n is 1 or

and n is 2 by reacting a t-aliphatic Alpha -chloroazo compound

with peracids or their salts selected from

with the corresponding acylating agent; and the use of these compounds as polymerization initiators for vinyl monomers and as curing agents for resins. For example, 2-t-butylazo-2(acetylperoxy)-4-methylpentane is prepared by reacting the sodium salt of 2-t-butylazo-2-hydroperoxy-4-methylpentane with acetyl chloride; and the product used to polymerize vinyl chloride at 30*C. and to cure unsaturated polyester-styrene resins at room temperature.

processes for preparing compounds I by reacting t-aliphatic azo compounds of the formula
摘要翻译：由式R1 |（R“）3C-N = N-C-OO ---- R（I）表示的新的叔脂族α-（全酰基）偶氮化合物; | R2n通过使叔脂族α-氯偶氮化合物R1 |（R“）3C-N = NC反应制备I的制备方法，其中R为O，PARALLEL-CR 3，n为1或O为ORA，PARALLEL PARALLEL-CR6C-，n为2 -Cl（II）| R2与过酸或其盐选自O平行R 3 -COOM（III）和OO平行平行MOOCR6COOM（IV）; 通过使式R1 |（R“）3C-N = N-C-OOM（V）| R 2的叔脂族偶氮化合物与相应的酰化剂反应来制备化合物I的方法; 以及这些化合物作为乙烯基单体的聚合引发剂和作为树脂固化剂的用途。例如，2-叔丁基偶氮-2-（乙酰基过氧基）-4-甲基戊烷是通过使2-叔丁基偶氮-2-氢过氧基-4-甲基戊烷的钠盐与乙酰氯反应制备的; 和用于在30℃下聚合氯乙烯并在室温下固化不饱和聚酯 - 苯乙烯树脂的产品。

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