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    • 4. 发明授权
    • Method of electrochemically producing epoxides
    • 电化学生产环氧化物的方法
    • US5980724A
    • 1999-11-09
    • US112657
    • 1998-07-09
    • David G. RobertsPeter C. FollerRobert H. TangYingchao Zhang
    • David G. RobertsPeter C. FollerRobert H. TangYingchao Zhang
    • C25B3/04C25B3/00C25B7/00
    • C25B3/04
    • Described is a method of electrochemically converting .alpha.-halohydrins, e.g., 1-chloro-2-hydroxypropane and 1,3-dichloro-2-hydroxypropane, to epoxides, e.g., propylene oxide and epichlorohydrin. An electrolytic cell is provided having (1) a catholyte compartment containing a cathode assembly comprising a cathode and a bipolar ion exchange membrane, (2) an anode compartment containing an anode assembly comprising either (a) a hydrogen consuming gas diffusion anode and a current collecting electrode or (b) a hydrogen consuming gas diffusion anode which is fixedly held between a hydraulic barrier and a current collecting electrode, and (3) at least one pair of intermediate compartments separating the catholyte and anode compartments and separated from each other by an anion exchange membrane. The following are introduced into the cell: a first aqueous conductive electrolyte solution into the catholyte compartment; hydrogen gas into the anode compartment; an aqueous solution of .alpha.-halohydrin into the first compartment of the pair of intermediate compartments; and a second aqueous conductive electrolyte solution into the second compartment of the pair of intermediate compartments. Direct current is passed through the electrolytic cell, and an aqueous solution comprising epoxide is removed from the first compartment.
    • 描述了将α-卤代醇如1-氯-2-羟基丙烷和1,3-二氯-2-羟基丙烷电化学转化为环氧化物,例如环氧丙烷和表氯醇的方法。 提供一种电解池,其具有(1)阴极电解液室,其包含阴极组件,阴极组件包括阴极和双极离子交换膜,(2)阳极室,其包含阳极组件,阳极组件包括(a)消耗氢的气体扩散阳极和电流 收集电极或(b)固定保持在液压屏障和集电电极之间的消耗氢的气体扩散阳极,以及(3)至少一对隔离阴极电解液室和阳极室的中间隔室, 阴离子交换膜。 将以下物质引入电池中:将第一水性导电电解质溶液引入到阴极电解液室中; 氢气进入阳极室; 将α-卤代醇的水溶液注入到该对中间隔室的第一隔室中; 以及第二水性导电电解质溶液进入所述一对中间隔室中的第二隔室。 直流电流通过电解槽,从第一隔室除去包含环氧化物的水溶液。
    • 5. 发明授权
    • Method of converting amine hydrohalide into free amine
    • 将胺氢卤化物转化为游离胺的方法
    • US5904829A
    • 1999-05-18
    • US914601
    • 1997-08-18
    • Peter C. FollerDavid G. RobertsRobert H. Tang
    • Peter C. FollerDavid G. RobertsRobert H. Tang
    • B01D61/44C07C209/68C25B3/00C25B1/00C25B7/00C25B9/00
    • B01D61/445C07C209/68C25B3/00
    • Describes a method of electreochemically converting amine hydrohalide, e.g., amine hydrochloride, into free amine, e.g., free ethyleneamine. An electrolytic cell is provided having (1) a catholyte compartment containing a cathode assembly comprising a cathode and a bipolar ion exchange membrane, (2) an anode compartment containing an anode assembly comprising either (a) a hydrogen consuming gas diffusion anode and a current collecting electrode or (b) a hydrogen consuming gas diffusion anode which is fixedly held between a hydraulic barrier and a current collecting electrode, and (3) at least one pair of intermediate compartments separating the catholyte and anode compartments and separated from each other by an anion exchange membrane. The following are introduced into the cell: a first aqueous conductive electrolyte solution into the catholyte compartment; hydrogen gas into the anode compartment; an aqueous solution of amine hydrohalide into the first compartment of the pair of intermediate compartments; and a second aqueous conductive electrolyte solution into the second compartment of the pair of intermediate compartments. Direct current is passed through the electrolytic cell, and an aqueous solution comprising free amine is removed from the first compartment.
    • 描述了将胺氢卤化物(例如胺盐酸盐)电化学转化成游离胺,例如游离亚乙基胺的方法。 提供一种电解池,其具有(1)阴极电解液室,其包含阴极组件,阴极组件包括阴极和双极离子交换膜,(2)阳极室,其包含阳极组件,阳极组件包括(a)消耗氢的气体扩散阳极和电流 收集电极或(b)固定保持在液压屏障和集电电极之间的消耗氢的气体扩散阳极,以及(3)至少一对隔离阴极电解液室和阳极室的中间隔室, 阴离子交换膜。 将以下物质引入电池中:将第一水性导电电解质溶液引入到阴极电解液室中; 氢气进入阳极室; 胺氢卤酸盐的水溶液进入该对中间隔室的第一隔室; 以及第二水性导电电解质溶液进入所述一对中间隔室中的第二隔室。 直流电流通过电解槽,从第一隔室除去包含游离胺的水溶液。
    • 9. 发明授权
    • Method for polymerizing bis(allyl carbonate) resin
    • 聚合双(烯丙基碳酸酯)树脂的方法
    • US4613656A
    • 1986-09-23
    • US674115
    • 1984-11-23
    • Robert H. Tang
    • Robert H. Tang
    • C08F18/24C08F110/00
    • C08F18/24
    • Fully cured, intact, solid castings of bis(allyl carbonate) resin, e.g., diethylene glycol bis(allyl carbonate), are prepared by polymerizing the resin with between about 0.75 and about 1.50 parts, per hundred parts of resin, of a monoperoxycarbonate, e.g., tertiarybutylperoxy isopropyl carbonate. An adhesion reducing amount, e.g., between about 25 and about 75 parts, per million parts of resin, of a mold release agent is incorporated into the liquid resin monomer to avoid cracking of the casting. Use of a mold release agent is not required when the resin is prepolymerized to about 15-50 percent allylic utilization.
    • 通过将树脂与每100份树脂的单过氧碳酸酯的约0.75至约1.50份聚合制备双(烯丙基碳酸酯)树脂的完全固化,完整的固体铸件,例如二甘醇双(碳酸烯丙酯) 例如叔丁基过氧化异丙基碳酸酯。 将每百万份树脂的脱模剂的粘合降低量例如约25至约75份加入到液态树脂单体中以避免铸件破裂。 当树脂预聚合至约15-50%的烯丙基利用时,不需要使用脱模剂。