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91. 发明申请

US20170113991A1 PROCESS FOR PRODUCING HYDROQUINONE AND DERIVATES 有权
公开(公告)号：US20170113991A1
公开(公告)日：2017-04-27
申请号：US14922358
申请日：2015-10-26
申请人： Chang Chun Plastics Co. Ltd.
发明人： Chien Fu Huang , Yi Hung Chou
IPC分类号： C07C46/06 , C07C37/60 , C07C45/28
CPC分类号： C07C46/06 , C07C37/07 , C07C37/60 , C07C45/28 , C07C46/04 , Y02P20/584 , C07C50/04 , C07C39/04 , C07C50/02 , C07C50/24 , C07C39/08 , C07C39/245
摘要： The present disclosure relates to an improved, environmentally friendly, process for producing compounds such as hydroquinone (benzene-1,4-diol) and its derivatives. The process can be carried out at ambient temperature and pressure using a recyclable copper catalyst and recyclable intermediate materials. The process generally entails reacting an aromatic compound such as benzene with hydrogen peroxide in the present of a pure elemental copper catalyst or a copper (I) salt catalyst to form oxidation product such as benzoquinone, and reducing the compound to hydroquinone or a hydroquinone derivative.

92. 发明申请

US20160176795A1 PROCESS FOR PRODUCING AROMATIC DIHYDROXY COMPOUND 有权
标题翻译：生产芳族二羟基化合物的方法
公开(公告)号：US20160176795A1
公开(公告)日：2016-06-23
申请号：US14764344
申请日：2014-09-11
申请人： MITSUI CHEMICALS, INC.
发明人： Yuya GOTO , Takashi NABETA
IPC分类号： C07C37/60
CPC分类号： C07C37/60 , B01J29/89 , Y02P20/52 , C07C39/08
摘要： [Problem] To provide a process for producing an aromatic dihydroxy compound, in which a hydroquinone compound is highly selectively produced while suppressing formation of by-products derived from a solvent and maintaining a high yield based on hydrogen peroxide when a phenol compound is allowed to react with hydrogen peroxide. [Solution]A process for producing an aromatic dihydroxy compound, including allowing a phenol compound to react with hydrogen peroxide in the presence of a titanosilicate, a C4-C5 alcohol containing a tertiary or quaternary carbon, and water and/or methanol, the amount of the water and/or methanol being 5 to 90 mass % based on the total mass of the reaction liquid.
摘要翻译：本发明提供一种芳香族二羟基化合物的制造方法，其中氢醌化合物被高选择性地制备，同时抑制来自溶剂的副产物的形成，并且当使苯酚化合物被允许时，保持基于过氧化氢的高收率与过氧化氢反应。 [方案]一种芳族二羟基化合物的制备方法，其包括使苯酚化合物在钛硅酸盐，含有叔或季碳的C 4 -C 5醇和水和/或甲醇的存在下与过氧化氢反应，所述量的水和/或甲醇为5〜90质量％，基于反应液的总质量。

93. 发明申请

US20160039676A1 Fullerene Derivatives and Their Applications in Organic Photovoltaics 有权
标题翻译：富勒烯衍生物及其在有机光伏中的应用
公开(公告)号：US20160039676A1
公开(公告)日：2016-02-11
申请号：US14799568
申请日：2015-07-14
申请人： Nano and Advanced Materials Institute Limited
发明人： Wing Leung WONG , Lai To LEUNG , Liang ZHANG , Chi Mei CHOW , Haojun ZHU , Lai Fan LAI , Kwok Keung Paul HO
IPC分类号： C01B31/02 , C07F7/18 , C07F7/08 , H01L51/00 , C07D207/323 , C07D209/18 , C07C67/04 , C07C37/60 , H01L51/42 , C07D295/033
CPC分类号： C01B31/0213 , C01B32/152 , C07C2/86 , C07C29/48 , C07C67/05 , C07C2604/00 , C07D207/323 , C07D209/18 , C07D295/033 , C07F7/081 , C07F7/1804 , H01L51/0047 , H01L51/0094 , H01L51/42 , C07C13/62 , C07C69/76 , C07C35/44
摘要： The present invention relates to new fullerene derivatives of formulae 1a-d, 2 and 3: method of synthesizing said derivatives, and applications thereof in organic photovoltaics, e.g., organic solar cells. In particular, the fullerene derivatives of the present invention are soluble in non-halogenated solvents such that an environmental-friendly and low-cost fabrication method for industrialization of solar cell based on the new fullerene derivatives is provided. An ink formulation for forming a thin film on a substrate of organic photovoltaics comprising at least one of the fullerene derivatives of the present invention is also provided. Greater than 3% power conversion efficiency of the organic solar cells (area=0.16 cm2) formed based on the fullerene derivatives of the present invention with less pollution and lower cost in fabrication can be achieved in the present invention.
摘要翻译：本发明涉及式1a-d，2和3的新型富勒烯衍生物：合成所述衍生物的方法及其在有机太阳能电池例如有机太阳能电池中的应用。特别地，本发明的富勒烯衍生物可溶于非卤化溶剂，从而提供了基于新的富勒烯衍生物的太阳能电池工业化的环保且低成本的制造方法。还提供了一种用于在包含至少一种本发明的富勒烯衍生物的有机光伏基板上形成薄膜的油墨配方。在本发明中可以实现基于本发明的富勒烯衍生物形成的具有较少污染和较低制造成本的有机太阳能电池（面积= 0.16cm 2）的3％以上的功率转换效率。

94. 发明申请

US20140073818A1 Method for hydroxylating phenols and phenol ethers 有权
标题翻译：苯酚和苯酚醚的羟基化方法
公开(公告)号：US20140073818A1
公开(公告)日：2014-03-13
申请号：US14118082
申请日：2012-05-15
申请人： Laurent Garel , Stephanie Normand , Pascal Pitiot , Jean-Christophe Bigouraux
发明人： Laurent Garel , Stephanie Normand , Pascal Pitiot , Jean-Christophe Bigouraux
IPC分类号： C07C41/26 , C07C37/60
CPC分类号： C07C41/26 , C07C37/60 , Y02P20/582 , C07C39/08
摘要： A method for hydroxylating phenols and phenol ethers using hydrogen peroxide and specifically, a method for hydroxylating phenol using hydrogen peroxide. The method for hydroxylating a phenolic substrate selected from a phenol or a phenol ether by reacting such phenolic substrate with hydrogen peroxide in the presence of an acid catalyst comprises the following steps, implemented consecutively or simultaneously: a first step consisting of mixing a phenolic substrate with a hydrogen peroxide solution under conditions in which the temperature is sufficient for the initial phenolic substrate to remain liquid and for minimizing the conversion rate of the hydrogen peroxide; a second step consisting of carrying out the phenolic substrate hydroxylation reaction under adiabatic conditions, the acid catalyst being added at the mixing stage and/or at the beginning of the hydroxylation reaction; and a third step, if necessary, consisting of recovering the hydroxylated product.
摘要翻译：使用过氧化氢使酚和酚醚羟基化的方法，具体地说，使用过氧化氢使苯酚羟基化的方法。在酸催化剂存在下使这种酚类底物与过氧化氢反应，通过使酚类底物与过氧化氢反应来羟基化选自酚或酚醚的方法包括以下步骤：连续或同时实施：第一步，将酚类底物与过氧化氢溶液，其中温度足以使初始酚类底物保持液体并使过氧化氢的转化率最小化; 第二步是在绝热条件下进行酚类底物羟基化反应，在混合阶段和/或在羟化反应开始时加入酸催化剂; 如果需要，第三步是回收羟基化产物。

95. 发明申请

US20110178342A1 PROCESS FOR PRODUCING CUMENE 有权
标题翻译：生产过程的方法
公开(公告)号：US20110178342A1
公开(公告)日：2011-07-21
申请号：US13119781
申请日：2009-09-23
申请人： Shyh-Yuan Henry Hwang , Dana E. Johnson , Joseph C. Peters , Chung-Ming Chi , Kevin J. Fallon , Francis A. Demers
发明人： Shyh-Yuan Henry Hwang , Dana E. Johnson , Joseph C. Peters , Chung-Ming Chi , Kevin J. Fallon , Francis A. Demers
IPC分类号： C07C37/60 , C07C2/64
CPC分类号： C07C2/864 , C07C29/145 , C07C37/08 , C07C2529/70 , Y02P20/52 , C07C15/085 , C07C31/10 , C07C39/04
摘要： A process is described for producing cumene comprising contacting a feed stream comprising benzene and a further feed stream comprising isopropanol or a mixture of isopropanol and propylene in the presence of an alkylation catalyst comprising at least a molecular sieve of the MCM-22 family in an alkylation zone under alkylation conditions of at least partial liquid phase and with a water concentration in the liquid phase of at least 50 ppm to react at least part of said isopropanol and benzene to produce an effluent stream containing cumene.
摘要翻译：描述了一种用于生产异丙基苯的方法，包括在包含至少分子筛MCM-22族的烷基化催化剂的烷基化催化剂存在下，使包含苯的进料流和包含异丙醇或异丙醇和丙烯的混合物的另外的进料流接触，在至少部分液相的烷基化条件下，在液相中的水浓度为至少50ppm以使至少部分所述异丙醇和苯反应以产生含有枯烯的流出物流。

96. 发明授权

US06936740B1 Dense phase oxidation of benzene 失效
标题翻译：苯的强相氧化
公开(公告)号：US06936740B1
公开(公告)日：2005-08-30
申请号：US10921686
申请日：2004-08-19
申请人： Robert N. Cochran , Jay F. Miller , Eric John Beckman , Sarah Emma Jones
发明人： Robert N. Cochran , Jay F. Miller , Eric John Beckman , Sarah Emma Jones
IPC分类号： C07C37/58 , C07C37/60 , C07C39/04
CPC分类号： C07C37/58 , C07C37/60 , C07C39/04
摘要： Phenol is formed by reaction of oxidant and benzene over a solid catalyst such as Pd on TS-1, the reaction being carried out in carbon dioxide solvent at conditions effective to provide a dense phase reaction mixture.
摘要翻译：苯酚通过氧化剂和苯在固体催化剂如Pd在TS-1上的反应形成，反应在有效提供致密相反应混合物的条件下在二氧化碳溶剂中进行。

97. 发明授权

US6080895A Process of producing catechol derivatives 失效
标题翻译：生产邻苯二酚衍生物的方法
公开(公告)号：US6080895A
公开(公告)日：2000-06-27
申请号：US91525
申请日：1998-06-19
申请人： Yoshiro Furukawa , Keishi Takenaka
发明人： Yoshiro Furukawa , Keishi Takenaka
IPC分类号： C07C41/26 , C07C45/55 , C07C45/68 , C07C45/71 , C07C37/60
CPC分类号： C07C45/71 , C07C41/26 , C07C45/55 , C07C45/68 , Y02P20/55
摘要： An improved process for producing a catechol derivative (1) useful as a intermediate of pharmaceuticals and agricultural chemicals, being shown by the following reaction scheme. The process is characterized in that formulation in the first step is carried out in the two stages, that is, the reaction is carried out in the presence of a tin catalyst at 60-85.degree. C. to a conversion of 30 to 80% and then is completed at 95-105.degree. C. to produce a salicylaldehyde derivative (3) in a high yield and a high selectivity. Thereby, the objective catechol derivative (1) can be obtained in a high yield and with a high purity. ##STR1## In the above formula, R is alkyl, cycloalkyl, aralkyl, alkoxy, halogen atom, allyl, or aryl, and R.sup.1 is a hydroxy protective group.
摘要翻译： PCT No.PCT / JP96 / 03650。 371日期：1998年6月19日 102（e）1998年6月19日PCT PCT 1996年12月13日PCT公布。出版物WO97 / 22574 日期：1997年6月26日通过以下反应方案示出了用作药物和农药中间体的儿茶酚衍生物（1）的改进方法。该方法的特征在于第一步中的配方在两个阶段进行，即反应在锡催化剂存在下在60-85℃下进行，转化率为30-80％，然后在95-105℃下完成，以高产率和高选择性生产水杨醛衍生物（3）。由此，能够以高收率和高纯度获得目标儿茶酚衍生物（1）。在上式中，R是烷基，环烷基，芳烷基，烷氧基，卤素原子，烯丙基或芳基，R 1是羟基保护基。

98. 发明授权

US5965476A Silica/zeolite composite materials in spherical form and process for their preparation 失效
标题翻译：二氧化硅/沸石复合材料球形及其制备方法
公开(公告)号：US5965476A
公开(公告)日：1999-10-12
申请号：US801593
申请日：1997-02-14
申请人： Luigi Balducci , Raffaele Ungarelli , Cristina Tonini
发明人： Luigi Balducci , Raffaele Ungarelli , Cristina Tonini
IPC分类号： B01J29/04 , B01J29/06 , B01J29/70 , B01J29/80 , B01J29/89 , C01B37/00 , C01B39/02 , C07C37/60 , B01J32/00
CPC分类号： C07C37/60 , B01J29/80 , B01J29/89 , B01J29/7007 , Y02P20/52
摘要： The present invention relates to silica/zeolite composite materials in spherical form and the process for their preparation which occurs by the dispersion of submicronic particles of titanium silicalite, beta zeolite, or mixtures of beta zeolite with titanium silicalite, in a silica sol synthesized by acid hydrolysis of silicon alkoxides; the hybrid sol thus obtained, subjected to emulsification and gelation techniques in organic mediums, produces these materials in a spherical form with an average diameter of between 20 and 150 .mu.m and containing up to 70% by weight of titanium silicalite, beta zeolite or mixtures of titanium silicalite/beta zeolite.The materials of the invention, having a high mechanical resistance and characterized by a surface area of between 300 and 800 m.sup.2 /g, are applied as catalysts; in particular, those consisting of titanium silicalite or mixtures of titanium silicalite/beta zeolite are advantageously used in oxidation reactions of organic compounds with hydrogen peroxide.
摘要翻译：本发明涉及球形二氧化硅/沸石复合材料及其制备方法，其通过在硅酸钠溶液中分解而制得的二氧化硅/沸石复合材料，其通过将钛硅沸石，β沸石的亚微米级颗粒或β-沸石与钛硅沸石的混合物分散在由硅酸硅烷醇盐的水解; 由此获得的在有机介质中进行乳化和凝胶化技术的混合溶胶将这些材料制成球形，平均直径为20至150μm，并含有至多70重量％的钛硅沸石，β沸石或混合物的钛硅质岩/β沸石。本发明的具有高机械性能并且表征面积在300-800m2 / g之间的材料被用作催化剂; 特别是由钛硅沸石或钛硅沸石/β沸石的混合物组成的有机化合物与过氧化氢的氧化反应有利地使用。

99. 发明授权

US5912391A Method for hydroxylating aromatic compounds 失效
标题翻译：羟基化芳香族化合物的方法
公开(公告)号：US5912391A
公开(公告)日：1999-06-15
申请号：US971777
申请日：1997-11-17
申请人： Terence Michael Barnhart , Annah Waswa Hughes
发明人： Terence Michael Barnhart , Annah Waswa Hughes
IPC分类号： B01J31/22 , C07B61/00 , C07C37/58 , C07C39/04 , C07C39/07 , C07C37/60
CPC分类号： C07C37/58 , Y02P20/52 , Y02P20/584
摘要： Aromatic compounds such as benzene, toluene and xylene are hydroxylated by reaction with oxygen and hydroquinone or a substituted hydroquinone in the presence of a vanadium compound, typically a pentavalent vanadium oxy chelate with picolinic acid or a substituted picolinic acid. The vanadium compound may be produced in situ by reaction of the chelating agent with a tetravalent or pentavalent precursor vanadium compound.
摘要翻译：芳族化合物如苯，甲苯和二甲苯通过与钒和氢醌或取代的氢醌在钒化合物（通常为五价钒氧基螯合物）与吡啶甲酸或取代的吡啶甲酸的存在下反应而羟基化。钒化合物可以通过螯合剂与四价或五价前体钒化合物的反应原位产生。

100. 发明授权

US5756861A Method for production for phenol and its derivatives 失效
标题翻译：苯酚及其衍生物的生产方法
公开(公告)号：US5756861A
公开(公告)日：1998-05-26
申请号：US727398
申请日：1997-01-07
申请人： Gennady Ivanovich Panov , Alexandr Sergeevich Kharitonov , Galina Antolievan Sheveleva
发明人： Gennady Ivanovich Panov , Alexandr Sergeevich Kharitonov , Galina Antolievan Sheveleva
IPC分类号： B01J29/46 , B01J29/10 , C07B61/00 , C07C37/60 , C07C39/04 , C07C39/08 , C07C37/00
CPC分类号： C07C37/60 , Y02P20/52
摘要： A method for partial oxidation of aromatic compounds such as benzene, phenol, chlorobenzene, fluorobenzene, toluene, ethylbenzene and the like, with a molar deficiency of nitrous oxide over a catalyst such as a ZSM-5 or ZSM-11 zeolite. The method is advantageous for producing phenol from benzene at high production rates, high nitrous oxide conversion and high selectivity toward the production of phenol.
摘要翻译： PCT No.PCT / RU95 / 00066 Sec。 371日期1997年1月7日 102（e）日期1997年1月7日PCT提交1995年4月12日PCT公布。 WO95 / 27691 PCT出版物日期：1995年10月19日一种芳族化合物如苯，苯酚，氯苯，氟苯，甲苯，乙苯等的部分氧化的方法，在ZSM-5或ZSM-11等催化剂上具有一氧化二氮摩尔不足沸石。该方法有利于以高生产率，高一氧化二氮转化率和苯酚生产的高选择性从苯生产苯酚。

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