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91. 发明授权

US08697916B2 Process for the preparation of Cu—Cr oxides for selective oxidation reactions 有权
标题翻译：制备用于选择性氧化反应的Cu-Cr氧化物的方法
公开(公告)号：US08697916B2
公开(公告)日：2014-04-15
申请号：US13623618
申请日：2012-09-20
申请人： Council of Scientific & Industrial Research
发明人： Rajaram Bal , Bipul Sarkar , Shubhra Acharyya Shankha , Shilpi Ghosh , Chandrashekar Pendem , Kumar Jagdish
IPC分类号： C07C45/36 , C07C37/06 , B01J23/00
CPC分类号： B01J23/868 , B01J35/002 , B01J37/0018 , B01J37/036 , B01J37/10 , B01J37/16 , C07B33/00 , C07C29/48 , C07C45/28 , C07C49/78 , C07C47/54
摘要： The present invention provides a process for the preparation of Cu—Cr oxides by hydrothermal synthesis method using hydrazine as a reducing agent and cetyltrimethylammonium bromide as a surfactant and these oxides are very active for selective oxidation of benzene, toluene and ethylbenzene to produce phenol, benzaldehyde and acetophenone, respectively.
摘要翻译：本发明提供了通过使用肼作为还原剂和十六烷基三甲基溴化铵作为表面活性剂的水热合成方法制备Cu-Cr氧化物的方法，并且这些氧化物对苯，甲苯和乙苯的选择性氧化非常有活性，以产生苯酚，苯甲醛和苯乙酮。

92. 发明授权

US08669385B2 Oxidative cleavage of unsaturated carboxylic acids 有权
标题翻译：不饱和羧酸的氧化裂解
公开(公告)号：US08669385B2
公开(公告)日：2014-03-11
申请号：US13501666
申请日：2010-10-12
申请人： Richard G. Blair
发明人： Richard G. Blair
IPC分类号： C07C51/16
CPC分类号： C07C51/373 , B01J8/10 , B01J8/16 , B01J2219/182 , B01J2219/1946 , C07C45/36 , C07C47/02 , C07C47/54 , C07C47/21 , C07C59/74 , C07C59/147 , C07C59/153
摘要： Provided are processes for the oxidative cleavage of a double bond in an unsaturated carboxylic acid. The process includes contacting the unsaturated carboxylic acid with a mild oxidizing agent and agitating the unsaturated carboxylic acid and the mild oxidizing agent for a time sufficient to cleave a double bond of the unsaturated carboxylic acid and produce a product comprising an aldehyde. The process is typically carried out in a mill, such as a ball, hammer, attrition, or jet mill.
摘要翻译：提供了在不饱和羧酸中双键氧化裂解的方法。该方法包括使不饱和羧酸与温和的氧化剂接触，并搅拌不饱和羧酸和温和的氧化剂一段足以裂解不饱和羧酸的双键并产生包含醛的产物的时间。该方法通常在诸如球，锤，磨耗或喷射磨的研磨机中进行。

93. 发明申请

US20130085305A1 PROCESS FOR THE PREPARATION OF CU-CR OXIDES FOR SELECTIVE OXIDATION REACTIONS 有权
标题翻译：用于选择性氧化反应的CU-CR氧化物的制备方法
公开(公告)号：US20130085305A1
公开(公告)日：2013-04-04
申请号：US13623618
申请日：2012-09-20
申请人： Council of Scientific & Industrial Research
发明人： Rajaram Bal , Bipul Sarkar , Shubhra Acharyya Shankha , Shilpi Ghosh , Chandrashekar Pendem , Kumar Jagdish
IPC分类号： B01J23/86 , C07C45/28 , C07B33/00 , C07C29/48
CPC分类号： B01J23/868 , B01J35/002 , B01J37/0018 , B01J37/036 , B01J37/10 , B01J37/16 , C07B33/00 , C07C29/48 , C07C45/28 , C07C49/78 , C07C47/54
摘要： The present invention provides a process for the preparation of Cu—Cr oxides by hydrothermal synthesis method using hydrazine as a reducing agent and cetyltrimethylammonium bromide as a surfactant and these oxides are very active for selective oxidation of benzene, toluene and ethylbenzene to produce phenol, benzaldehyde and acetophenone, respectively.
摘要翻译：本发明提供了通过使用肼作为还原剂和十六烷基三甲基溴化铵作为表面活性剂的水热合成方法制备Cu-Cr氧化物的方法，并且这些氧化物对苯，甲苯和乙苯的选择性氧化非常有活性，以产生苯酚，苯甲醛和苯乙酮。

94. 发明申请

US20120264956A1 OXIDATIVE CLEAVAGE OF UNSATURATED CARBOXYLIC ACIDS 有权
标题翻译：不饱和羧酸的氧化清除
公开(公告)号：US20120264956A1
公开(公告)日：2012-10-18
申请号：US13501666
申请日：2010-10-12
申请人： Richard G. Blair
发明人： Richard G. Blair
IPC分类号： C07C51/373 , C07C59/74 , C07C59/147
CPC分类号： C07C51/373 , B01J8/10 , B01J8/16 , B01J2219/182 , B01J2219/1946 , C07C45/36 , C07C47/02 , C07C47/54 , C07C47/21 , C07C59/74 , C07C59/147 , C07C59/153
摘要： Provided are processes for the oxidative cleavage of a double bond in an unsaturated carboxylic acid. The process includes contacting the unsaturated carboxylic acid with a mild oxidizing agent and agitating the unsaturated carboxylic acid and the mild oxidizing agent for a time sufficient to cleave a double bond of the unsaturated carboxylic acid and produce a product comprising an aldehyde. The process is typically carried out in a mill, such as a ball, hammer, attrition, or jet mill.
摘要翻译：提供了在不饱和羧酸中双键氧化裂解的方法。该方法包括使不饱和羧酸与温和的氧化剂接触，并搅拌不饱和羧酸和温和的氧化剂一段足以裂解不饱和羧酸的双键并产生包含醛的产物的时间。该方法通常在诸如球，锤，磨耗或喷射磨的研磨机中进行。

95. 发明授权

US07718827B2 Process for the ruthenium-catalysed oxidation of alcohols by means of hypochlorite 有权
标题翻译：通过次氯酸盐钌催化氧化醇的方法
公开(公告)号：US07718827B2
公开(公告)日：2010-05-18
申请号：US11476528
申请日：2006-06-28
申请人： Wolfgang Mägerlein , Angela Köckritz , Andrea Dittmar , Michael Sebek
发明人： Wolfgang Mägerlein , Angela Köckritz , Andrea Dittmar , Michael Sebek
IPC分类号： C07C45/38
CPC分类号： C07C269/06 , B01J21/063 , B01J21/066 , B01J23/462 , B01J23/6562 , B01J23/8906 , B01J23/8913 , B01J23/8926 , B01J35/0013 , B01J35/006 , B01J35/1014 , B01J37/0238 , B01J37/349 , C07B41/06 , C07C45/30 , C07C201/12 , C07C47/54 , C07C47/55 , C07C47/542 , C07C47/575 , C07C271/18 , C07C205/44
摘要： The present invention relates to a process for preparing aldehydes or ketones using an alkali metal hypochlorite or an alkaline earth metal hypochlorite in the presence of a ruthenium catalysts.
摘要翻译：本发明涉及在钌催化剂存在下使用碱金属次氯酸盐或碱土金属次氯酸盐制备醛或酮的方法。

96. 发明申请

US20100010269A1 APPARATUS AND PROCESS FOR USE IN THREE-PHASE CATALYTIC REACTIONS 审中-公开
标题翻译：在三相催化反应中使用的装置和方法
公开(公告)号：US20100010269A1
公开(公告)日：2010-01-14
申请号：US12444239
申请日：2007-10-05
申请人： Stanislaw Tadeusz Kolaczkowski
发明人： Stanislaw Tadeusz Kolaczkowski
IPC分类号： C07C45/29 , B01J8/04
CPC分类号： B01J19/285 , B01J8/0453 , B01J8/0496 , B01J10/007 , B01J19/249 , C07C45/38 , C07C47/54
摘要： A reactor for carrying out a heterogeneously catalyzed reaction includes at least first and second reaction zones that are arranged in series and that each include catalytic material, heat transfer zones that are located between said serially arranged reaction zones, and a pulse-generating device, which is arranged to deliver pulses to liquid in the reactor. The reactor allows three-phase reactions to be carried out efficiently and can reduce the impact of deposited reaction by-products on reaction efficiency.
摘要翻译：用于进行非均相催化反应的反应器包括至少串联排列的第一反应区和第二反应区，每个包括催化材料，位于所述连续排列的反应区之间的传热区和脉冲发生装置，其中布置成将脉冲输送到反应器中的液体。反应器可以有效地进行三相反应，并可以减少沉积的反应副产物对反应效率的影响。

97. 发明授权

US07608248B2 Stable isotope-labeled aromatic amino acids, method for incorporating the same in target protein and method for NMR-structural analysis of proteins 有权
标题翻译：稳定同位素标记的芳香族氨基酸，将其与靶蛋白结合的方法和蛋白质的NMR结构分析方法
公开(公告)号：US07608248B2
公开(公告)日：2009-10-27
申请号：US11414756
申请日：2006-04-28
申请人： Masatsune Kainosho , Tsutomu Terauchi
发明人： Masatsune Kainosho , Tsutomu Terauchi
IPC分类号： A61B5/055 , C12P13/04 , C12P9/00 , C07K1/00
CPC分类号： C07C47/575 , C07B2200/05 , C07C47/54 , C07C229/08 , C07C229/36 , C07D209/20 , C07D233/64 , C07K1/00 , C12P21/02 , G01N24/08 , G01R33/465
摘要： The present invention herein provides, for instance, a stable isotope-labeled phenylalanine wherein a carbon atom of the phenyl group linked to an amino acid residue is 13C, 2 to 4 carbon atoms of the remaining 5 carbon atoms constituting the phenyl group are 12C atoms to which deuterium atoms are bonded, and the remaining carbon atoms are 13C atoms to which hydrogen atoms are linked, and a stable isotope-labeled tyrosine wherein a carbon atom of the phenyl group linked to an amino acid residue is 13C, the carbon atom bonded to the hydroxyl group (OH group) of the phenyl group is 12C or 13C, 2 to 4 carbon atoms of the remaining 4 carbon atoms constituting the phenyl group are 12C atoms to which deuterium atoms are bonded, and the remaining carbon atoms are 13C atoms to which hydrogen atoms are linked. The stable isotope-labeled amino acid permits the elimination of such a conventional problem concerning the complexity of the NMR signals ascribed to aromatic rings, the complexity being a principal cause of making the NMR analysis difficult, encountered when using the conventional uniformly labeled amino acid residue. Moreover, the isotope-labeled amino acid likewise permits the substantial improvement of the sensitivity thereof to the NMR spectroscopic analysis.
摘要翻译：本发明提供例如稳定同位素标记的苯丙氨酸，其中与氨基酸残基连接的苯基的碳原子为13 C，构成苯基的剩余5个碳原子的2至4个碳原子为12 C原子氘原子键合在其上，剩余的碳原子是与氢原子连接的13 C原子，和与氨基酸残基连接的苯基的碳原子为13 C的稳定的同位素标记的酪氨酸，碳原子键合苯基的羟基（OH基）为12℃或13℃，构成苯基的剩余4个碳原子的2〜4个碳原子为氘原子键合的12 C原子，剩余碳原子为13 C原子氢原子连接在其上。稳定的同位素标记的氨基酸允许消除关于归因于芳环的NMR信号的复杂性的常规问题，当使用常规的均匀标记的氨基酸残基时，复杂性是使NMR分析困难的主要原因。此外，同位素标记的氨基酸同样允许其对NMR光谱分析的敏感性的显着提高。

98. 发明授权

US07411099B2 Process for the liquid phase oxidation of toluene to benzaldehyde 有权
标题翻译：将甲苯液相氧化成苯甲醛的方法
公开(公告)号：US07411099B2
公开(公告)日：2008-08-12
申请号：US11533549
申请日：2006-09-20
申请人： Raghunath Vitthal Chaudhari , Kalpendra Baburao Rajurkar , Sunil Sopana Tonde , Vilas Hari Rane
发明人： Raghunath Vitthal Chaudhari , Kalpendra Baburao Rajurkar , Sunil Sopana Tonde , Vilas Hari Rane
IPC分类号： C07C45/36
CPC分类号： C07C45/36 , C07C47/54
摘要： The present invention provides a liquid phase oxidation of toluene by using catalyst containing manganese (Manganese II acetate) in presence of Lewis acid (Stannous (II) chloride) and a bromide promoter (NaBr), at a temperature of 120° C. and at a pressure of air in the range of 70-400 psig, in presence of carboxylic acid (acetic acid), as a solvent, to obtain high selectivity to benzaldehyde (76%). High activity was obtained with minimum byproducts such as benzoic acid, benzyl alcohol and benzyl acetate.
摘要翻译：本发明通过在路易斯酸（氯化亚锡（II））和溴化促进剂（NaBr）的存在下，在120℃的温度和在120℃的温度下，使用含有锰（锰II）的催化剂提供甲苯的液相氧化在羧酸（乙酸）存在下，作为溶剂，在70-400psig范围内的空气压力，以获得对苯甲醛（76％）的高选择性。用最小的副产物如苯甲酸，苄醇和乙酸苄酯得到高活性。

99. 发明授权

US07288649B2 Catalyst comprising cyclic acylurea compound and process for producing organic compounds using the catalyst 有权
标题翻译：包含环状酰基脲化合物的催化剂和使用该催化剂生产有机化合物的方法
公开(公告)号：US07288649B2
公开(公告)日：2007-10-30
申请号：US11233017
申请日：2005-09-23
申请人： Yasutaka Ishii , Naruhisa Hirai
发明人： Yasutaka Ishii , Naruhisa Hirai
IPC分类号： C07D251/00
CPC分类号： B01J31/0249 , B01J31/26 , B01J2231/323 , B01J2231/42 , C07C29/50 , C07C45/36 , C07C49/453 , C07C49/675 , C07C51/265 , C07C51/313 , C07C67/29 , C07C201/08 , C07C201/12 , C07C253/30 , C07C2601/14 , C07C2603/74 , C07D251/34 , Y02P20/55 , C07C47/55 , C07C47/54 , C07C47/542 , C07C63/06 , C07C63/26 , C07C63/313 , C07C55/14 , C07C255/57 , C07C69/157 , C07C205/05 , C07C205/44 , C07C205/57 , C07C35/37
摘要： A catalyst of the invention includes a cyclic acylurea compound having a cyclic acylurea skeleton represented by following Formula (I): wherein R is a hydrogen atom or a hydroxyl-protecting group; n is 1 or 2; G is a carbon atom or a nitrogen atom, where two Gs are the same or different when n is 2. The catalyst may include the cyclic acylurea compound and a metallic compound in combination. In the presence of the catalyst, (A) a compound capable of forming a radical is allowed to react with (B) a radical scavenging compound and thereby yields an addition or substitution reaction product of the compound (A) and the compound (B) or a derivative thereof. This catalyst can produce an organic compound with a high selectivity in a high yield as a result of, for example, an addition or substitution reaction under mild conditions.
摘要翻译：本发明的催化剂包括具有由下式（I）表示的环状酰基脲骨架的环状酰基脲化合物：其中R是氢原子或羟基保护基团; n为1或2; G是碳原子或氮原子，当n为2时，两个G相同或不同。催化剂可以包括环状酰基脲化合物和金属化合物。在催化剂存在下，使（A）能够形成自由基的化合物与（B）自由基清除化合物反应，从而得到化合物（A）和化合物（B）的加成或取代反应产物，或其衍生物。作为例如在温和条件下的添加或取代反应的结果，该催化剂可以以高产率生产高选择性的有机化合物。

100. 发明申请

US20070212267A1 Method and apparatus for performing micro-scale chemical reactions 审中-公开
标题翻译：用于进行微量化学反应的方法和装置
公开(公告)号：US20070212267A1
公开(公告)日：2007-09-13
申请号：US11711831
申请日：2007-02-28
申请人： Michael Organ , Eamon Comer
发明人： Michael Organ , Eamon Comer
IPC分类号： B01J19/00
CPC分类号： B01J19/0046 , B01J19/0093 , B01J19/126 , B01J23/44 , B01J31/0237 , B01J31/0239 , B01J31/04 , B01J31/2239 , B01J31/2265 , B01J31/2404 , B01J37/0215 , B01J37/031 , B01J2219/00286 , B01J2219/00333 , B01J2219/00344 , B01J2219/00367 , B01J2219/00369 , B01J2219/00389 , B01J2219/00418 , B01J2219/00423 , B01J2219/00585 , B01J2219/0059 , B01J2219/00599 , B01J2219/0072 , B01J2219/00747 , B01J2219/00788 , B01J2219/00822 , B01J2219/00824 , B01J2219/00831 , B01J2219/00835 , B01J2219/0086 , B01J2219/00862 , B01J2219/00873 , B01J2219/00891 , B01J2219/00941 , B01J2219/1227 , B01J2231/4211 , B01J2231/4261 , B01J2231/543 , B01J2531/821 , B01J2531/824 , B01J2531/96 , C07C1/321 , C07C41/30 , C07C45/65 , C07C45/68 , C07C51/353 , C07C67/343 , C07C201/12 , C07C209/02 , C07C213/08 , C07C253/30 , H05B6/806 , C07C15/14 , C07C47/54 , C07C49/794 , C07C49/86 , C07C47/546 , C07C47/575 , C07C63/04 , C07C69/618 , C07C69/65 , C07C69/734 , C07C211/52 , C07C217/58 , C07C217/60 , C07C255/34 , C07C205/06 , C07C205/56 , C07C43/215 , C07C43/23 , C07C43/205
摘要： A reactor apparatus includes at least one reaction capillary having a lumen for receiving a reactant to undergo a reaction, and a magnetron for irradiating reactant contained in at least a portion of the capillary with microwaves. A method of micro-reacting a reactant includes providing a capillary, and irradiating the reactant in the capillary with microwaves to facilitate a chemical reaction in the capillary by which the reactant is converted into a desired product.
摘要翻译：反应器装置包括具有用于接收反应物进行反应的内腔的至少一个反应毛细管，以及用于用包含在毛细管的至少一部分中的反应物照射微波的磁控管。使反应物微反应的方法包括提供毛细管，并用微波照射毛细管中的反应物以促进毛细管中的化学反应，通过该化学反应将反应物转化成所需产物。

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